Facile synthesis of monodisperse ZnS capped CdS nanocrystals exhibiting efficient blue emission

  • Myriam Protière1 and

    Affiliated with

    • Peter Reiss2Email author

      Affiliated with

      Nanoscale Research Letters20061:62

      DOI: 10.1007/s11671-006-9001-0

      Published: 25 July 2006

      Abstract

      A new method for the capping of colloidal CdS nanocrystals with ZnS shells is presented. A combination of the monomolecular precursor zinc ethylxanthate (Zn(ex)2) and zinc stearate was used to replace hazardous organometallic reagents usually applied in this procedure, i.e. bis(trimethylsilyl) sulfide and diethylzinc. Its simple preparation, air-stability and low decomposition temperature of 150 °C make Zn(ex)2a very suitable source for the ZnS shell growth. With this precursor, highly luminescent CdS/ZnS core/shell nanocrystals (Q.Y. 35–45%), exhibiting narrow emission linewidths of 15–18 nm (FWHM) in the blue spectral region, can reproducibly be obtained.

      Keywords

      Semiconductor nanocrystals CdS ZnS Fluorescence Blue emission

      [115]

      Authors’ Affiliations

      (1)
      CEA Grenoble, DRT/LITEN/DTNM/L2T
      (2)
      CEA Grenoble, DSM/DRFMC/SPrAM (UMR 5819 CEA-CNRS-Université Joseph Fourier 1)/LEMOH

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      © to the authors 2006