Open Access

Photochemically reduced polyoxometalate assisted generation of silver and gold nanoparticles in composite films: a single step route

  • Sangaraju Shanmugam1,
  • Balasubramanian Viswanathan1Email author and
  • Thirukkallam K Varadarajan1
Nanoscale Research Letters20072:175

DOI: 10.1007/s11671-007-9050-z

Received: 6 January 2007

Accepted: 15 February 2007

Published: 13 March 2007


A simple method to embed noble metal (Ag, Au) nanoparticles in organic–inorganic nanocomposite films by single step method is described. This is accomplished by the assistance of Keggin ions present in the composite film. The photochemically reduced composite film has served both as a reducing agent and host for the metal nanoparticles in a single process. The embedded metal nanoparticles in composites film have been characterized by UV–Visible, TEM, EDAX, XPS techniques. Particles of less than 20 nm were readily embedded using the described approach, and monodisperse nanoparticles were obtained under optimized conditions. The fluorescence experiments showed that embedded Ag and Au nanoparticles are responsible for fluorescence emissions. The described method is facile and simple, and provides a simple potential route to fabricate self-standing noble metal embedded composite films.


Polyoxometalates Organic–inorganic nanocomposite Silver Gold Fluorescence


Authors’ Affiliations

Department of Chemistry, Indian Institute of Technology Madras


  1. S. Foster, M. Antonietii, Adv. Mater. 10, 195 (1998); R.P. Andres, J.C. Bielefeld, J.I. Henderson, D.B. Janes, V.R. Kolagunta, C.P. Kubiak, W.J. Mahoney, R.G. Osifchinm, Science 273, 1690 (1996); A.P. Alivasators, Science 271, 933 (1996)Google Scholar
  2. H. Hirai, H. Wakabayashi, M. Komiyama, Chem. Lett. 1047, 1983 (1983); K. Ghosh, S.N. Maiti, J. Appl. Polym. Sci. 60, 323 (1996)Google Scholar
  3. Thomas JM: Pure Appl. Chem. 1988, 60: 1517. View ArticleGoogle Scholar
  4. Perenboom JAAJ, Wyder P, Meier P: Phys. Rep. 1981, 78: 173. COI number [1:CAS:528:DyaL38XmtFaktA%3D%3D] 10.1016/0370-1573(81)90194-0View ArticleGoogle Scholar
  5. Klabunde KJ: Nanoscale Materials in Chemistry. Wiley Interscience, New York; 2001.View ArticleGoogle Scholar
  6. T.S. Ahmadi, Z.L. Wang, T.C. Green, A. Henglein, M.A. El-Sayed, Science 272, 1924 (1996); P.Y. Silvert, R.H. Urbina, N. Duvauchelle, V. Vijayakrishnan, K.T. Elhsissen, J. Mater. Chem. 6, 573 (1996)Google Scholar
  7. P.V. Kamat, J. Phys. Chem. B 106, 7729 (2002); Y. Zhou, C.Y. Wang, Y.R. Zhu, Z.Y. Chen, Chem .Mater. 11, 2310 (1999)Google Scholar
  8. Tu WX, Lin HF: Chem. Mater.. 2000, 12: 564. COI number [1:CAS:528:DC%2BD3cXjsVOi] 10.1021/cm990637lView ArticleGoogle Scholar
  9. Mizukoshi Y, Oshima R, Maeda Y, Nagata Y: Langmuir. 1999, 15: 2733. COI number [1:CAS:528:DyaK1MXhvVeisbg%3D] 10.1021/la9812121View ArticleGoogle Scholar
  10. Henglein A, Giersig M: J. Phys. Chem. B. 1999, 103: 9533. COI number [1:CAS:528:DyaK1MXmsVKntr4%3D] 10.1021/jp9925334View ArticleGoogle Scholar
  11. Stellacci F, Bauer CA, Meyer-Friedrichen T, Wenseleers W, Alain V, Kuebler SM, Pond SJ, Zhang Y, Marder SR, Perry JW: Adv. Mater. 2002, 14: 194. COI number [1:CAS:528:DC%2BD38Xht1Ojurw%3D] 10.1002/1521-4095(20020205)14:3<194::AID-ADMA194>3.0.CO;2-WView ArticleGoogle Scholar
  12. Smith GB, Deller CA, Swift PD, Gentle A, Garrett PD, Fisher WK, Smith GB, Deller CA, Swift PD, Gentle A, Garrett PD, Fisher WK: J. Nanopart. Res. 2002, 4: 157. COI number [1:CAS:528:DC%2BD38XmvVOrtb0%3D] 10.1023/A:1020186701109View ArticleGoogle Scholar
  13. Park I-W, Yoon M, Kim YM, Kim Y, Yoon H, Song HJ, Volkov V, Avilov A, Park YJ: Solid State Commun. 2003, 126: 385. COI number [1:CAS:528:DC%2BD3sXivVOgtbk%3D] 10.1016/S0038-1098(03)00189-3View ArticleGoogle Scholar
  14. F.P. Zamborini, M.C. Leopold, J.F. Hicks, P.J. Kulesza, M.A. Malik, R.W. Murray, J. Am. Chem. Soc. 124, 8958 (2002); E.C. Walter, K. Ng, M.P. Zach, R.M. Penner, F. Favier, Microelectron. Eng. 61–62, 555 (2002)Google Scholar
  15. Rudoy VM, Ershov BG, Sukhov NL, Dement’eva OV, Zaitseva AV, Seliverstov AF, Kartseva ME, Ogarev VA: Colloid J. 2002, 64: 755. COI number [1:CAS:528:DC%2BD38XptlOjsL8%3D] 10.1023/A:1021510508346View ArticleGoogle Scholar
  16. C. Aymonier, U. Schlotterbeck, L. Antonietti, P. Zacharias, R. Thomann, J.C. Tiller, S. Mecking, Chem. Commun. 3018 (2002); S. Shanmugam, B. Viswanathan, T.K. Varadarajan, Mater. Chem. Phys. 95, 51 (2006)Google Scholar
  17. V.M. Rudoay, B.G. Ershov, N.L. Sukhov, O.V. Dement’eva, A.V. Zaitseva, A.F. Seliverstov, M.E. Kartseva, V.A. Ogarev, Colloid J. 64, 755 (2002)Google Scholar
  18. Y. Zhang, F. Chen, J. Zhuang, Y. Tang, D. Wang, Y. Wang, A. Dong, N. Ren, N. Chem. Commun. 2814 (2002); Y. Zhou, H. Itoh, T. Uemura, K. Naka, Y. Chujo, Chem. Commun. 613 (2001); S.K. Mandal, R.K. Roy, A.K. Pal, J. Phys. D: Appl. Phys. 36, 261 (2003); L. Yang, G.H. Li, J.G. Zhang, L.D. Zhang, Y.L. Liu, Q.M. Wang, Appl. Phys. Lett. 78, 102 (2001); Y. Dirix, C. Bastiaansen, W. Caseri, P. Smith, J. Mater. Sci. 34, 3859 (1999); L. Yang, G.H. Li, L.D. Zhang, Appl. Phys. Lett. 76, 1537 (2000); G. Mitrikas, C.C. Trapalis, G. Kordas, J. Chem. Phys. 111, 8098 (1999); T. He, A. Kunitake, O. Nakao, Chem. Mater.15, 4401 (2003)Google Scholar
  19. Pope MT: Heteropoly and Isopoly Oxometalates. Springer, Berlin; 1983.View ArticleGoogle Scholar
  20. Pope MT, Muller A: Angew. Chem. 1991, 30: 34. 10.1002/anie.199100341View ArticleGoogle Scholar
  21. Sadakane M, Steckhan E: Chem. Rev. 1998, 98 : 219. COI number [1:CAS:528:DyaK1cXotVSgsQ%3D%3D] 10.1021/cr960403aView ArticleGoogle Scholar
  22. Troupis A, Hiskia A, Papaconstantinou E: Angew. Chem. Int. Ed. 2002, 41: 1911. COI number [1:CAS:528:DC%2BD38XkslWmtbY%3D] 10.1002/1521-3773(20020603)41:11<1911::AID-ANIE1911>3.0.CO;2-0View ArticleGoogle Scholar
  23. Mandal S, Selvakannan PR, Pasricha R, Sastry M: J. Am. Chem. Soc. 2003, 125: 8440. COI number [1:CAS:528:DC%2BD3sXkslensL0%3D] 10.1021/ja034972tView ArticleGoogle Scholar
  24. Shanmugam S, Viswanathan B, Varadarajan TK: J. Mol. Catal. A. 2005, 241: 52. COI number [1:CAS:528:DC%2BD2MXhtVymtrbJ] 10.1016/j.molcata.2005.06.063View ArticleGoogle Scholar
  25. Vagara MG, Papaconstantinou E, Pope MT: Inorg. Chem. 1970, 9: 662. 10.1021/ic50085a045View ArticleGoogle Scholar
  26. Shanmugam S, Viswanathan B, Varadarajan TK: J. Member. Sci. 2006, 275: 105. COI number [1:CAS:528:DC%2BD28Xitlaqsrw%3D] 10.1016/j.memsci.2005.09.009View ArticleGoogle Scholar
  27. Dirix Y, Bastiaansen C, Caseri W, Smith P: Adv. Mater. 1999, 11: 223. COI number [1:CAS:528:DyaK1MXhvFKqtb4%3D] 10.1002/(SICI)1521-4095(199903)11:3<223::AID-ADMA223>3.0.CO;2-JView ArticleGoogle Scholar
  28. Hussian I, Brust M, Papworth AJ, Cooper AI: Langmuir. 2003, 19: 4831. 10.1021/la020710dView ArticleGoogle Scholar
  29. Kreibig U, Vollmer M: Optical Properties of Metal Clusters. Springer, Berlin; 1995.View ArticleGoogle Scholar
  30. Shin HS, Choi HC, Jung Y, Kim SB, Song HJ, Shin HJ: Chem. Phys. Lett. 2004, 383: 418. COI number [1:CAS:528:DC%2BD3sXpvF2gtLw%3D] 10.1016/j.cplett.2003.11.054View ArticleGoogle Scholar
  31. Wertheim, GK, Dicenzo, SB 1986D.N.E. Buchanan, Phys. Rev. B5384G.K. Wertheim, S.B. Dicenzo, S.E. Youngquist, Phys. Rev. Lett. 51, 2310 (1983)Google Scholar
  32. Henglein A, Linnert T, Mulvaney P: Ber.der Bunsen-Gesellschaft. 1990, 94: 1449. View ArticleGoogle Scholar
  33. Zheng J, Dickson RM: J. Am. Chem. Soc. 2002, 124: 13982. COI number [1:CAS:528:DC%2BD38XotlCqu7c%3D] 10.1021/ja028282lView ArticleGoogle Scholar
  34. Gao J, Fu J, Lin C, Lin J, Han Y, Yu X, Pan C: Langmuir. 2004, 20: 9775. COI number [1:CAS:528:DC%2BD2cXnvFGns78%3D] 10.1021/la049197pView ArticleGoogle Scholar
  35. Geddes CD, Parfenov A, Gryczynski I, Lakowicz JR: Chem. Phys. Lett. 2003, 380: 269. COI number [1:CAS:528:DC%2BD3sXotVygurc%3D] 10.1016/j.cplett.2003.07.029View ArticleGoogle Scholar
  36. Arnold GW, Borders JA: J. Appl. Phys. 1977, 48: 1488. COI number [1:CAS:528:DyaE2sXhvFyjtb0%3D] 10.1063/1.323867View ArticleGoogle Scholar
  37. Lee L, Wang JX, Adzic RR, Robinsion IK, Gewirth AA: J. Am. Chem. Soc. 2001, 123: 8838. COI number [1:CAS:528:DC%2BD3MXlslyksbk%3D] 10.1021/ja0161352View ArticleGoogle Scholar


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