Nanoscale Visualization of Elastic Inhomogeneities at TiN Coatings Using Ultrasonic Force Microscopy
© to the authors 2009
Received: 26 May 2009
Accepted: 18 August 2009
Published: 16 September 2009
Ultrasonic force microscopy has been applied to the characterization of titanium nitride coatings deposited by physical vapor deposition dc magnetron sputtering on stainless steel substrates. The titanium nitride layers exhibit a rich variety of elastic contrast in the ultrasonic force microscopy images. Nanoscale inhomogeneities in stiffness on the titanium nitride films have been attributed to softer substoichiometric titanium nitride species and/or trapped subsurface gas. The results show that increasing the sputtering power at the Ti cathode increases the elastic homogeneity of the titanium nitride layers on the nanometer scale. Ultrasonic force microscopy elastic mapping on titanium nitride layers demonstrates the capability of the technique to provide information of high value for the engineering of improved coatings.
KeywordsPVD nanostructured coatings TiN Ultrasonic force microscopy Scanning probe microscopy Nanomechanics
The technological relevance of titanium nitride (TiN) deposited by Physical vapor deposition (PVD) is reflected in its wide range of applications, from hard protective coatings in cutting tool industry to biomaterial in implantable devices [1, 2]. In such applications, phenomena such as cracking, wear and corrosion, among others, depend essentially on surface and subsurface features, e.g., microstructure, stress distribution, elastic discontinuities, defects and chemical composition [3–8].
Scanning acoustic microscopy (SAM) constitutes an outstanding tool to observe subsurface features such as elastic discontinuities in thin film materials. When an acoustic microscope is operated in imaging mode (qualitative mode), the image contrast provides a clear distinction of elastic gradients in the surface structure; nevertheless, the resolution is limited to the microscopic level at most [9–12].
Recently, a new family of scanning probe microscopy (SPM) techniques based on the use of atomic force microscopy (AFM) with ultrasound excitation has been proposed [13, 14]. It has been demonstrated that these procedures provide a valuable means for the characterization of dynamic elastic, viscoelastic and adhesive material properties, and permit to obtain subsurface information. Among them, the technique of ultrasonic force microscopy (UFM) [15–18] relies in the so-called “mechanical-diode” effect, in which a cantilever tip is in contact with the sample surface, and normal ultrasonic vibration is excited at the tip-sample contact. If the excitation frequency is high enough, or is not coincident with a high-order cantilever contact resonance, the cantilever will not be able to linearly follow the surface vibration due to its inertia. Nevertheless, if the ultrasonic excitation amplitude is sufficiently high that the tip-sample distance is modulated within the nonlinear tip-sample force interaction regime, the cantilever experiences a static force during the time that the ultrasonic excitation is acting. This force is called “the ultrasonic force”, and it can be understood as the net force that acts upon the cantilever during a complete ultrasonic cycle, due to the nonlinearity of the tip-sample interaction force. The cantilever behaves then as a mechanical diode, and it deflects when the tip-sample contact vibrates at ultrasonic frequencies of sufficiently high amplitude. The magnitude of the ultrasonic force, or of the ultrasonic-force-induced additional cantilever deflection (UFM signal), is dependent on the details of the tip-sample interaction force, and hence on material properties such as elasticity and adhesion. In this way, surface and/or subsurface nanoscale elastic discontinuities and stress fields can be easily detected with UFM.
Earlier reports have presented a continuum mechanic description of the tip-sample interaction of the UFM response using the Johnson–Kendall–Roberts (JKR) model, demonstrating that with this technique it is -in principle- possible to measure absolute stiffness values of nanoscale contacts, and effectively differentiate materials with distinct elastic constants [17, 19]. Also, methods to obtain information about the work of adhesion and the adhesion hysteresis at the tip-sample contact using UFM have been proposed [20, 21]. UFM has been successfully applied to the study of nanometer-sized Ge islands epitaxially grown on a Si (100) substrate . Nanoscale mapping of these islands revealed variations in the UFM contrast, which were attributed to local variations in elasticity. More recently, Cuberes et al.  applied UFM to investigate the elastic nanostructure of individual Sb particles. In that study, the UFM images also revealed variations in the particle stiffness, attributed to locally strained regions within the Sb nanoparticles.
In this article, the results of an UFM investigation consisting in nanoscale elastic mapping are presented, along with X-ray Diffraction (XRD) and scanning electron microscopy (SEM) analysis of magnetron sputtered TiN films produced by varying the sputtering power applied to the Ti cathode. The aim of this investigation is to test the potential of UFM for nanoscale mapping of hard coatings and assess the elastic quality and possible origin of the UFM response (elastic discontinuities) in the TiN films.
Preparation of TiN Coatings
TiN coatings were prepared by dc magnetron sputtering onto polished AISI 304 stainless steel (SS) discs in a vacuum chamber at room temperature using a water-cooled Ti target. SS-AISI-304 is commonly used in chemical, marine, food processing and hospital surgical equipments, etc. due to its good chemical and mechanical properties, and it is expected that good-quality deposited PVD-TiN coatings will further improve its surface properties. Depositions were carried out varying the power at the cathodeW S = 100, 150 and 200 W in a N2and Ar atmosphere with a N2:Ar ratio of 50% and a total pressure of 1.3 Pa with grounded substrates during 60 min, for all experiments. The discharge was started using a pure Ar atmosphere yielding a titanium layer of about 500 nm. After that, the N2:Ar ratio was fixed, and the TiN layer was deposited without interruption.
Characterization of TiN Coatings
being A the ultrasonic excitation amplitude, ω the ultrasonic frequency, T ult the ultrasonic time period, h eq corresponds to the quasi-static equilibrium position reached by the tip in the presence of ultrasonic vibration. F ult is responsible of the ultrasonic deflection (or UFM response) of the cantilever. In the presence of ultrasound, due to the nonlinearity of the tip-sample force, the tip moves from an initial position h o to a quasistatic equilibrium position (UFM deflection) h eq, which is larger the higher the ultrasonic excitation amplitude, as can be seen in Fig. 1b. Quantitative analysis of the UFM data requires an accurate calibration of the system and in most cases a better understanding of the dynamic tip-sample interactions .
Our AFM–UFM set-up (Fig. 1a) allows us to simultaneously record the AFM image in contact mode (topography) and the UFM image (elastic mapping) of a same TiN area. UFM imaging was stable in all the analyzed samples, and the recorded images showed no sign of deterioration in time. From the topographic images recorded in AFM contact mode, it is possible to determine the root-mean-square (RMS) roughness at each of the sample surfaces. The sample surface structure was also investigated by SEM, and the coating thicknesses were obtained from SEM cross sectional views. The grain size was measured both with AFM and SEM, obtaining consistent results.
Results and Discussion
Influence of sputtering powerW Son texture coefficientT C, film thickness, grain size and surface root-mean-square (RMS) roughness of TiN thin films
Film thickness (μm)
Grain size (nm)
RMS-AFM roughness (nm)
1.7 ± 0.11
225 ± 39
25.2 ± 1.2
2.1 ± 0.13
297 ± 57
33.1 ± 1.1
2.9 ± 0.09
203 ± 74
23.5 ± 1.7
In order to estimate the degree of preferred orientation in our coatings, the texture coefficient T C has been evaluated. T C is defined as T C (200) = I 200/(I 111 + I 200) and T C (111) = I 111/(I 111 + I 200) , where I is the integrated intensity for the hkl planes. The outcomes are shown in Table 1. The (200) plane, with T C (200) ≈ 0.8 is the preferred orientation for all the sputtering power W S values studied here. These results demonstrate that a power increase at the cathode has only a subtle influence on the change of preferred orientation in the coatings. The surface energy of TiN is the lowest for the (001) orientation (81 meV Å−2 for TiN (001) and 85 and 346 meV Å−2 for the N and Ti-terminated TiN(111) surfaces ), which means that a (001) growth texture should develop in the first growth stages. Changes in texture upon the growth of thicker TiN films (>1µm thickness) have been observed in other studies and have been related to strain energy minimization, with lower-strained grains growing at the expense of those more highly strained [30, 31]. Pelleg et al.  and Oh and Je  have argued that since the biaxial elastic modulus along the (111) direction (E 111 = 418 GPa) is lower than along the (002), (E 002 = 556) the texture should change from (001) to (111) as the film thickness increases, in order to minimize the strain energy term. Nevertheless, in our case, even with film thicknesses >1 μm, the (002) orientation is the one preferred (see Table 1). Numerous reports in the literature underline the importance of kinetic issues in the development of a specific texture in TiN coatings [25, 27, 34–36]. In this respect, aspects such as anisotropy in adatom mobility and surface diffusion can play a decisive role. The composition of the gas mixture strongly influences the eventual crystallographic texture adopted by the TiN films. In our current study, with a used composition of N2:Ar ratio of 50%, an effective dissociation of N2 is expected. In these conditions, a continuous source of atomic N is available near the surface. Chemisorption N atoms will alter the diffusion of Ti, enhance the TiN surface nucleation rate and lower the chemical potential of the (100) surface, leading to a preferential growth of the  grains. Such atomistic processes have been previously proposed by Gall et al.  and Mahieu et al.  to explain the growth of  TiN grains.
The absence of reflections of ε-Ti2N or any known titanium oxide in the XRD patterns demonstrates that if present those phases are in quantities below the detection sensitivity of our technique. According to the Ti–N phase diagram, ε-Ti2N forms at temperatures below 1050 °C in the range of 3 at. % N to 41 at. % N [37, 38]. Nevertheless, sputtering is a nonequilibrium process. The nonappearance of the ε-Ti2N phase in our TiN films may be due to the quite low ratio T s/T m ≈ 0.03 (substrate temperature T s ≈ 100 °C; melting temperature T m ≈ 2949 °C). This assumption is supported by the experiments described by Kiran et al. . In , TiN x layers with 0.4 < x ≤ 0.5 were deposited at T s ≈ 80 °C with RF magnetron sputtering. XRD results only showed a pure TiN phase in the diffraction pattern. After annealing the samples at 500 °C, the ε-Ti2N clearly appeared in the diffraction patterns. In that case, annealing was required (and sufficient) to form the ε-Ti2N phase, stable at 500 °C in the mentioned nitrogen concentration range.
TiN Surface Structure
Nanoscale Elastic Mapping
The softer TiN regions in the Fig. 4b, d are attributed to the presence of substoichiometric impurities. Sputtered coatings often show compositional fluctuations due to variations in molecular impingement rates. Changes in the Ti:N ratio may lead to the formation of substoichiometric TiN upon the substrate surface [3, 42]. Recently, Kiran et al.  identified the presence of TiN x in TiN films using optical and electrical methods. Nevertheless, the presence of substoichiometric impurities is not apparent in the XRD patterns in Fig. 2a. In case TiN x is present, the appearance of TiN x -related XRD peaks would be expected, since the TiN x species preserve the δ-NaCl structure over a wide range of composition, 0.42 ≥ x ≥ 1.2 . Still, it is possible that the sensitivity XRD is insufficient to disclose small traces of TiN substoichiometric species located at or near the very surface of TiN films. On the other hand, it is well known that the chemical composition of sputtered TiN strongly influences the measured values of the Young Modulus E. Variations in E ranging from ≈175 GPa in substoichiometric TiN0.45 to 590 GPa in stoichiometric TiN  are reported in the literature. The increment in E with the N content can be explained as due to the increased strain in the Ti lattice when N incorporates . Substoichiometric TiN is typically highly defective, building regions with intercolumnar porosity and low mass density [42, 45, 46], that can act as weak points of lower strength . Such regions are indeed expected to appear softer in the UFM contrast. Microdroplets such as those observed in Fig. 4a incorporate in the solid state from the target during deposition of the TiN film. Carvalho et al.  has suggested that they consist of softer α-Ti phase and a rim of a TiN layer formed by diffusion of N into the α-Ti. A nonhomogenous diffusion of reactive species over and around α-Ti microdroplets may generate substoichiometric TiN, explaining the variety in UFM contrast in Fig. 4b, d.
Figure 5a corresponds to an AFM topographic image recorded next to the softer grain in Fig. 4d, with higher resolution. Figure 5b (D-AFM) is the derivative of the image in Fig. 5a, plotted to provide a better appreciation of edges or slopes variations in the topography. Figure 5c shows the UFM image simultaneously recorded with Fig. 5a. The white “halo” around the grains in Fig. 5c originates from an increase in the tip-sample contact area between the edges of the grains [22, 23], and it allows us to estimate an upper limit of the UFM resolution of ≈5 nm with the used tip. From Fig. 5b, it can be distinguished that some grains show grooves (some marked by the circles) that appear as stiffer stripes in the UFM image (Fig. 5c). Stiffness in these sites may be a result of surface tensions generated by grain coarsening during grain growth and film thickening. During coarsening, shrinkage and elimination of small grains result in an increase in the average size of the remaining grains, and as a result, the total surface area increases and the grain boundary regions decrease [27, 47]. Grain boundary collapse may give rise to the formation of grooves such as those apparent in Fig. 5a, c. From Fig. 5c, it is also noticeable that on the grains type i in Fig. 4d, the brighter contrast is due to the presence of stiffer stripes. These cannot be related to any topographic feature in Fig. 5a, b and probably originate from subsurface defects. Stiffness in these grains may be associated to the trapped impurities at the subsurface region such as oxygen and/or argon atoms might explain the differences in stiffness in these grains. Results in the literature demonstrate that such impurities may indeed be present [8, 26, 44], and they are expected to induce local lattice strain, hinder the dislocation movement, and thus enhance the local stiffness and strength.
As mentioned earlier, the increase inW Sfrom 100 to 200 W increases the total energy and Ti fluxes supplied to the growing film. Hence, the formation of substoichiometric and defective regions is expected to decrease, since the availability of the species and their mobility increases. As a result, the surface coverage will be more effective.
In this work, UFM has been applied to nanoscale elastic mapping of PVD-TiN coatings with a lateral resolution of ≈5 nm.
The UFM image contrast lateral reveals nanoscale inhomogeneities in stiffness on the TiN films prepared with different sputtering power. Those have been explained as due to the presence of softer substoichiometric TiN and/or trapped subsurface gas within the films.
According to XRD analysis, the TiN coatings preferentially grow in the (200) orientation, even though some TiN grains exhibit a (111) orientation. The presence of substoichiometric TiN phases or titanium oxides is not evident from the XRD data. When increasing the sputtering power, the TiN coatings become thicker, denser, flatter, and—according to the UFM study—more elastically homogenous. These characteristics have been attributed to a higher availability and enhanced surface/bulk diffusivity of Ti and N species.
The UFM data provide evidence of surface tensions related to grain boundaries collapse and subsequent formation of grooves generated because of grain coarsening during grain growth and film thickening.
In service operation of engineering elements coated with PVD-TiN films, the presence of impurities and structural defects that give rise to elastic discontinuities leads to detriment of the mechanical properties and of the protection against corrosion. Nanoscale elastic mapping of nanostructured hard coatings can be used for indentifying weak structural regions, and constitutes a novel tool of high value for the improvement of quality and design of thin films.
Funding from the National Science and Technology Council of Mexico (CONACYT) and the Junta de Castilla-La Mancha (JCCM) in Spain, under grant 004Eo.38467U and project PCI-08-0092 respectively, are gratefully acknowledged. J. A. H thanks the National Science and Technology Council of Mexico, CONACYT for financial support for a three-month stay in the Laboratory of Nanotechnology in Almadén, Spain.
- Steyer PH, Mege A, Pech D, Mendibide C, Fontaine J, Pierson J-F, Esnouf C, Goudeau P: Surf. Coat. Technol.. 2008, 202: 2268. COI number [1:CAS:528:DC%2BD1cXit1SqsL8%3D] COI number [1:CAS:528:DC%2BD1cXit1SqsL8%3D] 10.1016/j.surfcoat.2007.08.073View Article
- V. Karagkiozaki, S. Logothetidis, N. Kalfagiannis, S. Lousinian, G. Giannoglou, Nanomedicine. doi:10.1016/j.nano.2008.07.005(2008)
- Kiran MSRN, Krishna MG, Padmanabhan KA: Appl. Surf. Sci. 2008, 255: 1934. COI number [1:CAS:528:DC%2BD1cXhsVChs7nM]; Bibcode number [2008ApSS..255.1934K] COI number [1:CAS:528:DC%2BD1cXhsVChs7nM]; Bibcode number [2008ApSS..255.1934K] 10.1016/j.apsusc.2008.06.122View Article
- Krella A, Czyzniewski A: Wear. 2008, 265: 963. COI number [1:CAS:528:DC%2BD1cXmvFOmtr0%3D] COI number [1:CAS:528:DC%2BD1cXmvFOmtr0%3D] 10.1016/j.wear.2008.02.004View Article
- Hidalgo JA, Montero-Ocampo C: ECS Transactions. 2007,6(13):35. COI number [1:CAS:528:DC%2BD1cXit1Oitrc%3D] COI number [1:CAS:528:DC%2BD1cXit1Oitrc%3D] 10.1149/1.2811694View Article
- Perry AJ, Sue JA, Martin PJ: Surf. Coat. Technol.. 1996, 81: 17. COI number [1:CAS:528:DyaK28XjsV2gs7s%3D] COI number [1:CAS:528:DyaK28XjsV2gs7s%3D] 10.1016/0257-8972(95)02531-6View Article
- Perry AJ: J. Vac. Sci. Technol. A. 1990,8(3):1351. COI number [1:CAS:528:DyaK3cXltVKltr4%3D]; Bibcode number [1990JVST....8.1351P] COI number [1:CAS:528:DyaK3cXltVKltr4%3D]; Bibcode number [1990JVST....8.1351P] 10.1116/1.576881View Article
- Benbelghit A, Boutassouna D, Helifa B, Lefkaier IK: NDT & E International. 2006, 39: 76. COI number [1:CAS:528:DC%2BD2MXhtVKqtbjF] COI number [1:CAS:528:DC%2BD2MXhtVKqtbjF] 10.1016/j.ndteint.2005.06.004View Article
- Robert L, Brunet N, Flaherty T, Randles T, Matthaei-Schulz E, Vetters H, Rats D, von Stebut J: Surf. Coat. Technol.. 1999, 116: 119–327. 10.1016/S0257-8972(99)00316-3
- Kim JO, Achenbach JD, Mirkarimi PB, Shinn M, Barnett SA: J. Appl. Phys.. 1992, 72: 1805. COI number [1:CAS:528:DyaK38Xmt1ensLg%3D]; Bibcode number [1992JAP....72.1805K] COI number [1:CAS:528:DyaK38Xmt1ensLg%3D]; Bibcode number [1992JAP....72.1805K] 10.1063/1.351651View Article
- Cuberes MT: Friction and ultrasonics. In Fundamentals of Friction and Wear on the Nanometer Scale. Edited by: Gnecco E, Meyer E. Springer, Berlin; 2007.
- Cuberes MT: Mechanical-diode mode Ultrasonic Friction Force Microscopies. In Applied Scanning Probe Methods XI. Edited by: Bhushan B, Fuchs H. Springer, Berlin Heidelberg; 2009.
- Kolosov O, Yamanaka K: Jpn. J. Appl. Phys.. 1993, 32: L1095. COI number [1:CAS:528:DyaK3sXmsFOjt7Y%3D]; Bibcode number [1993JaJAP..32L1095K] COI number [1:CAS:528:DyaK3sXmsFOjt7Y%3D]; Bibcode number [1993JaJAP..32L1095K] 10.1143/JJAP.32.L1095View Article
- Yamanaka K, Ogiso H, Kolosov O: Jpn. J. Appl. Phys.. 1994, 33: 3197. Bibcode number [1994JaJAP..33.3197Y] Bibcode number [1994JaJAP..33.3197Y] 10.1143/JJAP.33.3197View Article
- Dinelli F, Biswas SK, Briggs GAD, Kolosov OV: Phys. Rev. B. 2000, 61: 13995. COI number [1:CAS:528:DC%2BD3cXjs1SmurY%3D]; Bibcode number [2000PhRvB..6113995D] COI number [1:CAS:528:DC%2BD3cXjs1SmurY%3D]; Bibcode number [2000PhRvB..6113995D] 10.1103/PhysRevB.61.13995View Article
- Cuberes MT, Briggs GAD, Kolosov O: Nanotechnology. 2001, 12: 53. COI number [1:CAS:528:DC%2BD3MXjt1Srsr8%3D]; Bibcode number [2001Nanot..12...53C] COI number [1:CAS:528:DC%2BD3MXjt1Srsr8%3D]; Bibcode number [2001Nanot..12...53C] 10.1088/0957-4484/12/1/310View Article
- Muthuswami L, Geer RE: Appl. Phys. Lett.. 2004, 84: 5082. COI number [1:CAS:528:DC%2BD2cXltVegsbY%3D]; Bibcode number [2004ApPhL..84.5082M] COI number [1:CAS:528:DC%2BD2cXltVegsbY%3D]; Bibcode number [2004ApPhL..84.5082M] 10.1063/1.1756673View Article
- Inagaki K, Matsuda O, Wright OB: Appl. Phys. Lett.. 2002, 80: 2386. COI number [1:CAS:528:DC%2BD38XisVersL4%3D]; Bibcode number [2002ApPhL..80.2386I] COI number [1:CAS:528:DC%2BD38XisVersL4%3D]; Bibcode number [2002ApPhL..80.2386I] 10.1063/1.1463212View Article
- Szoszkiewicz R, Kulik AJ, Gremaud G: J. Chem. Phys.. 2005, 122: 134706. COI number [1:STN:280:DC%2BD2M3hsVWmtA%3D%3D]; Bibcode number [2005JChPh.122m4706S] COI number [1:STN:280:DC%2BD2M3hsVWmtA%3D%3D]; Bibcode number [2005JChPh.122m4706S] 10.1063/1.1869412View Article
- Kolosov OV, Castell MR, Marsh CD, Andrew G, Briggs D, Kamins TI, Stanley-Williams R: Phys. Rev. Lett.. 1998, 81: 1046. COI number [1:CAS:528:DyaK1cXkvFShtL8%3D]; Bibcode number [1998PhRvL..81.1046K] COI number [1:CAS:528:DyaK1cXkvFShtL8%3D]; Bibcode number [1998PhRvL..81.1046K] 10.1103/PhysRevLett.81.1046View Article
- Cuberes MT, Stegemann B, Kaiser B, Rademann K: Ultramicroscopy. 2007, 107: 1053. COI number [1:CAS:528:DC%2BD2sXot1Oqtr8%3D] COI number [1:CAS:528:DC%2BD2sXot1Oqtr8%3D] 10.1016/j.ultramic.2007.05.001View Article
- J.J. Martı´nez, M.T. Cuberes, in Energy dissipation in the mechanical-diode jump of a nanoscale contact, in Nanoscale, ed. by Y. Ando, R. Bennewitz, R.W. Carpick, W.G. Sawyer (Mater. Res. Soc. Symp. Proc. Volume 1085E, Warrendale, PA, 2008)View Article
- Patsalas P, Gravalidis C, Logothetidis S: J. Appl. Phys.. 2004, 11: 6234. Bibcode number [2004JAP....96.6234P] Bibcode number [2004JAP....96.6234P] 10.1063/1.1811389View Article
- Carvalho NJM, Zoestbergen E, Kooi BJ, Th J, De Hosson M: Thin Solid Films. 2003, 429: 179. COI number [1:CAS:528:DC%2BD3sXjtFWlurk%3D]; Bibcode number [2003TSF...429..179C] COI number [1:CAS:528:DC%2BD3sXjtFWlurk%3D]; Bibcode number [2003TSF...429..179C] 10.1016/S0040-6090(03)00067-1View Article
- Abadias G: Surf. Coat. Technol.. 2008, 202: 2223. COI number [1:CAS:528:DC%2BD1cXit1Sqs7o%3D] COI number [1:CAS:528:DC%2BD1cXit1Sqs7o%3D] 10.1016/j.surfcoat.2007.08.029View Article
- Tung H-M, Huang J-H, Tsai D-G, Ai C-F, Yu G-P: Mat. Sci. Eng. A. 2009, 500: 104. 10.1016/j.msea.2008.09.006View Article
- Gall D, Kodambaka S, Wall MA, Petrov I, Greene JE: J. Appl. Phys.. 2003, 93: 9086. COI number [1:CAS:528:DC%2BD3sXktValt7k%3D]; Bibcode number [2003JAP....93.9086G] COI number [1:CAS:528:DC%2BD3sXktValt7k%3D]; Bibcode number [2003JAP....93.9086G] 10.1063/1.1567797View Article
- Zhao JP, Wang X, Chen ZY, Yang SQ, Shi TS, Liu XH: J. Phys. D Appl. Phys.. 1997, 30: 5. COI number [1:CAS:528:DyaK2sXkvFGluw%3D%3D]; Bibcode number [1997JPhD...30....5Z] COI number [1:CAS:528:DyaK2sXkvFGluw%3D%3D]; Bibcode number [1997JPhD...30....5Z] 10.1088/0022-3727/30/1/002View Article
- Lim SHN, McCulloch DG, Bilek MMM, McKenzie DR: J. Appl. Phys.. 2003, 93: 4283. COI number [1:CAS:528:DC%2BD3sXitlenuro%3D]; Bibcode number [2003JAP....93.4283L] COI number [1:CAS:528:DC%2BD3sXitlenuro%3D]; Bibcode number [2003JAP....93.4283L] 10.1063/1.1558995View Article
- Pelleg J, Zevin LZ, Lungo S, Croitoru N: Thin Solid Films. 1991, 197: 117. COI number [1:CAS:528:DyaK3MXisFOhsr8%3D]; Bibcode number [1991TSF...197..117P] COI number [1:CAS:528:DyaK3MXisFOhsr8%3D]; Bibcode number [1991TSF...197..117P] 10.1016/0040-6090(91)90225-MView Article
- Oh UC, Je JH: J. Appl. Phys.. 1993, 74: 1692. COI number [1:CAS:528:DyaK3sXmtlyhtr8%3D]; Bibcode number [1993JAP....74.1692O] COI number [1:CAS:528:DyaK3sXmtlyhtr8%3D]; Bibcode number [1993JAP....74.1692O] 10.1063/1.355297View Article
- Banerjee R, Chandra R, Ayyub P: Thin Solid Films. 2002, 405: 64. COI number [1:CAS:528:DC%2BD38Xhs1Omsbk%3D]; Bibcode number [2002TSF...405...64B] COI number [1:CAS:528:DC%2BD38Xhs1Omsbk%3D]; Bibcode number [2002TSF...405...64B] 10.1016/S0040-6090(01)01705-9View Article
- Li TQ, Noda S, Tsuji Y, Ohsawa T, Komiyama H: J. Vac. Sci. Technol. A. 2002, 20: 583. COI number [1:CAS:528:DC%2BD38XjsFKmu78%3D]; Bibcode number [2002JVST...20..583L] COI number [1:CAS:528:DC%2BD38XjsFKmu78%3D]; Bibcode number [2002JVST...20..583L] 10.1116/1.1458944View Article
- Mahieu S, Ghekiere P, De Winter G, Heirwegh S, Depla D, De Gryse R, Lebedev OI, Van Tendeloo G: J. Cryst. Growth. 2005, 279: 100. COI number [1:CAS:528:DC%2BD2MXjvVOms7k%3D]; Bibcode number [2005JCrGr.279..100M] COI number [1:CAS:528:DC%2BD2MXjvVOms7k%3D]; Bibcode number [2005JCrGr.279..100M] 10.1016/j.jcrysgro.2005.02.014View Article
- de Souza GB, Foerster CE, da Silva SLR, Serbena FC, Lepienski CM, dos Santos CA: Surf. Coat. Technol.. 2005, 191: 76. 10.1016/j.surfcoat.2004.08.207View Article
- Elstner F, Ehrlich A, Giegengack H, Kupfer H, Richter F: J. Vac. Sci. Technol. A. 1994,12(2):476. COI number [1:CAS:528:DyaK2cXisFOku7g%3D]; Bibcode number [1994JVST...12..476E] COI number [1:CAS:528:DyaK2cXisFOku7g%3D]; Bibcode number [1994JVST...12..476E] 10.1116/1.579155View Article
- Petrov I, Barna PB, Hultman L, Greene JE: J. Vac. Sci. Technol. A. 2003,21(5):S117. COI number [1:CAS:528:DC%2BD3sXntV2itro%3D]; Bibcode number [2003JVST...21S.117P] COI number [1:CAS:528:DC%2BD3sXntV2itro%3D]; Bibcode number [2003JVST...21S.117P] 10.1116/1.1601610View Article
- Subramanian B, Ashok K, Jayachandran M: Appl. Surf. Sci.. 2008, 255: 2133. COI number [1:CAS:528:DC%2BD1cXhsVChsL7O]; Bibcode number [2008ApSS..255.2133S] COI number [1:CAS:528:DC%2BD1cXhsVChsL7O]; Bibcode number [2008ApSS..255.2133S] 10.1016/j.apsusc.2008.07.083View Article
- Ekpe SD, Dew SK: J. Vac. Sci. Technol. A. 2003, 21: 476. COI number [1:CAS:528:DC%2BD3sXhs1enu70%3D]; Bibcode number [2003JVST...21..476E] COI number [1:CAS:528:DC%2BD3sXhs1enu70%3D]; Bibcode number [2003JVST...21..476E] 10.1116/1.1554971View Article
- Mader W, Fischmeister HF, Bergmann E: Thin Solid Films. 1989, 182: 141. COI number [1:CAS:528:DyaK3cXit1Wns7g%3D]; Bibcode number [1989TSF...182..141M] COI number [1:CAS:528:DyaK3cXit1Wns7g%3D]; Bibcode number [1989TSF...182..141M] 10.1016/0040-6090(89)90251-4View Article
- Guemmaz M, Mosser A, Ahuja R, Parlebas JC: Int. J. Inor. Mat.. 2001, 3: 1319. COI number [1:CAS:528:DC%2BD38XjtVGrug%3D%3D] COI number [1:CAS:528:DC%2BD38XjtVGrug%3D%3D] 10.1016/S1466-6049(01)00151-9View Article
- Vaz F, Ferreira J, Ribeiro E, Rebouta L, Lanceros-Méndez S, Mendes JA, Alves E, Goudeau Ph, Rivière JP, Ribeiro F, Moutinho I, Pischow K, de Rijk J: Surf. Coat. Technol.. 2005, 191: 317. COI number [1:CAS:528:DC%2BD2cXhtVKqtbvF] COI number [1:CAS:528:DC%2BD2cXhtVKqtbvF] 10.1016/j.surfcoat.2004.01.033View Article
- Logothetidis S, Meletis EI, Stergioudis G, Adjaottor AA: Thin Solid Films. 1999, 338: 304. COI number [1:CAS:528:DyaK1MXhtFKgu7Y%3D]; Bibcode number [1999TSF...338..304L] COI number [1:CAS:528:DyaK1MXhtFKgu7Y%3D]; Bibcode number [1999TSF...338..304L] 10.1016/S0040-6090(98)00975-4View Article
- Richter F, Kupfer H, Giegengack H, Shaarschmidt G, Elstner F, Hecht G: Surf. Coat. Technol.. 1992, 54: 338.View Article
- Sundgren J-E: Thin Solid Films. 1985, 128: 21. COI number [1:CAS:528:DyaL2MXlvF2rtb0%3D]; Bibcode number [1985TSF...128...21S] COI number [1:CAS:528:DyaL2MXlvF2rtb0%3D]; Bibcode number [1985TSF...128...21S] 10.1016/0040-6090(85)90333-5View Article