Nanofluids for heat transfer: an engineering approach
 Elena V Timofeeva^{1}Email author,
 Wenhua Yu^{1},
 David M France^{2},
 Dileep Singh^{3} and
 Jules L Routbort^{1}
DOI: 10.1186/1556276X6182
© Timofeeva et al; licensee Springer. 2011
Received: 4 November 2010
Accepted: 28 February 2011
Published: 28 February 2011
Abstract
An overview of systematic studies that address the complexity of nanofluid systems and advance the understanding of nanoscale contributions to viscosity, thermal conductivity, and cooling efficiency of nanofluids is presented. A nanoparticle suspension is considered as a threephase system including the solid phase (nanoparticles), the liquid phase (fluid media), and the interfacial phase, which contributes significantly to the system properties because of its extremely high surfacetovolume ratio in nanofluids. The systems engineering approach was applied to nanofluid design resulting in a detailed assessment of various parameters in the multivariable nanofluid systems. The relative importance of nanofluid parameters for heat transfer evaluated in this article allows engineering nanofluids with desired set of properties.
Introduction
Suspensions of solid submicron and nanometersized particles in various fluids (also called nanofluids) have been considered for applications as advanced heat transfer fluids for almost two decades. However, due to the wide variety and the complexity of the nanofluid systems, no agreement has been achieved on the magnitude of potential benefits of using nanofluids for heat transfer applications. Large volume of studies devoted to characterization of individual thermophysical properties of nanofluids, such as thermal conductivity, viscosity, and agglomeration of nanoparticles, has been summarized in a number of review articles [1–9].
Evaluation of cooling efficiency, i.e., ability to remove heat from the heat source, includes assessing flow regimedependent contributions from thermal conductivity, viscosity, specific heat, and density of the fluid and also depends on the applied flow regime. The studies devoted to evaluation of the heat transfer performance of nanofluids are scarce and inconclusive compared to the studies on the thermophysical properties of various nanofluids indicating a significant gap between fundamental research and practical applications of nanofluids for thermal management.
In this article we present a summary of systematic experimental studies of both thermophysical properties and heat transfer in nanofluids. We believe that the underestimated complexity and the controversy of nanofluid systems is related to the solid/liquid boundary layers between nanoparticles and the liquid, which at significant surface area of nanoparticles contribute to the fluid properties, resulting in threephase systems. The approach to nanofluids as threephase systems (instead of traditional consideration of nanofluids as twophase systems of solid and liquid) allows for deeper understanding of correlations between the engineering parameters, nanofluid properties, and cooling performance. The factors contributing to the fluid cooling efficiency are discussed first, followed by a review of nanofluid engineering parameters and a brief analysis of their contributions to basic thermophysical properties. Finally, a systems engineering approach is used to describe how various nanofluid parameters contribute to the cooling performance. The latter also offers insights into the principles of the efficient nanofluid design.
Cooling efficiency of nanofluids
The initial promise of nanofluids as advanced heat transfer fluids was based on the increased thermal conductivity of nanoparticle suspensions. Low thermal conductivity of conventional fluids improves when the solid particles are added. However, the magnitudes of the effects reported in the literature are scattered from few percent (as predicted by effective medium theory (EMT) [10–12]) to hundred percents per volume concentration of nanoparticles (i.e., abnormal enhancements [4, 13, 14]). Theoretical works exploring the mechanisms that could be responsible for abnormally enhanced thermal conductivities are widely presented in the literature [2, 15].
where φ is the particle volume concentration, μ is the dynamic viscosity of the nanofluid (eff) and the base fluid (0), and C_{ μ }and C_{ k }are viscosity and thermal conductivity enhancement coefficients, determined from experimental viscosity and thermal conductivity ratios. However, it is not very practical when efficiencies of two fluids are compared in the same system geometry (i.e., tube diameter).
Introduction of nanoparticles to the fluid affects all of thermophysical properties and should be accounted for in the nanofluid evaluations [18, 19]. Density and specific heat are proportional to the volume ratio of solid and liquid in the system, generally with density increasing and specific heat decreasing with addition of nanoparticles to the fluid. According to Equation (3) the increase in density, specific heat, and thermal conductivity of nanofluids favors the heat transfer coefficient; however, the welldescribed increase in the viscosity of nanoparticle suspensions is not beneficial for heat transfer. The velocity term in Equation (3) also represents the pumping power penalties resulting from the increased viscosity of nanofluids [16, 20].
Thus, the challenge in the development of nanofluids for heat transfer applications is in understanding of how micro and macroscale interactions between the particles and the fluid affect the properties of the fluid. This requires a complex approach that accounts for changes in all important thermophysical properties caused by introduction of nanomaterials to the fluid. It is obvious that the properties of suspensions depend on many system variables (i.e., engineering parameters) such as the nanoparticle material, concentration, size, and shape, the properties of the base fluid, and the presence of additives, surfactants, electrolyte strength, and pH. Below we discuss how each of the above parameters affects individual nanofluids properties.
Nanofluid engineering parameters
Nanoparticles
Great varieties of nanoparticles are commercially available and can be used for preparation of nanofluids. Nanoparticle material, concentration, size, and shape all contribute to the nanofluid properties.
As it was mentioned previously the materials with the higher thermal conductivity, specific heat, and density are beneficial for heat transfer.
The size of nanoparticles defines the surfacetovolume ratio and for the same volume concentrations suspension of smaller particles will have a higher area of the solid/liquid interface. Therefore, the contribution of interfacial effects will be stronger in such a suspension [23, 24]. Interactions between the nanoparticles and the fluid are manifested through the interfacial thermal resistance, also known as Kapitza resistance (R_{ k }), which rises because interfaces act as an obstacle to heat flow and diminish the overall thermal conductivity of the system [25]. The values of Kapitza resistance are constant for the particular solid/liquid interface defined by the strength of solidliquid interaction and can be correlated to the wetting properties of the interface [25]. When the interactions between the nanoparticle surfaces and the fluid are weak (nonwetting case) the rates of energy transfer are small resulting in relatively large values of R_{ k }. The overall contribution of the solid/liquid interface to the macroscopic thermal conductivity of nanofluids is negative and was found proportional to the total area of the interface, increasing with decreasing particle sizes [24, 26].
The size of nanoparticles also affects the viscosity of nanofluids. In general, the viscosity increases as the volume concentration of particles increases. Studies of suspensions with the same volume concentration and material of nanoparticles but different sizes [26, 27] showed that the viscosity of suspension increases as the particle size decreases. This behavior is related to formation of structured layers of the fluid along the nanoparticle interfaces that move with the particles in the flow [28]. The thicknesses of those fluid layers depend on the strength of particlefluid interactions while the volume of immobilized fluid increases in proportion to the total area of the solid/liquid interface. The "effective volume concentration" (immobile fluid and nanoparticles) is higher in suspensions of smaller nanoparticles resulting in higher viscosity. Therefore, contributions of interfacial effects, negligible at micron particle sizes, become very important for nanoparticle suspensions. To achieve benefit for heat transfer, the suspensions of larger nanoparticles with the higher thermal conductivity and lower viscosity should be used.
where g is the gravitational acceleration. As one can see from Equation (8), the stability of a suspension (defined by lower settling rates) improves if: (a) the density of the solid material (ρ_{p}) is close to that of the fluid (ρ_{0}), (b) the viscosity of the suspension (μ) is high, and (c) the particle radius (r) is small.
Effects of the nanoparticles shapes on the thermal conductivity and viscosity of aluminaEG/H_{2}O suspensions [24] are also strongly related to the total area of the solid/liquid interface. In nanofluids with nonspherical particles the thermal conductivity enhancements predicted by the HamiltonCrosser equation [11] (randomly arranged elongated particles provide higher thermal conductivities than spheres, EMT [29]) are diminished by the negative contribution of the interfacial thermal resistance as the sphericity of nanoparticles decreases [24]. Elongated particles and agglomerates also result in higher viscosity at the same volume concentration as spheres due to structural limitation of rotational and transitional Brownian motion. Therefore, it can be concluded that spherical particles or low aspect ratio spheroids are more practical for achieving lower viscosities in nanofluidsthe property that is highly desirable for minimizing the pumping power penalties in cooling system applications.
Base fluid
The influence of base fluids on the thermophysical properties of suspensions is not very well studied and understood. However, there are few publications indicating some general trends of the base fluid effects.
Suspensions of the same Al_{2}O_{3} nanoparticles in water, ethylene glycol (EG), glycerol, and pump oil showed increase in relative thermal conductivity (k_{eff}/k_{0}) with decrease in thermal conductivity of the base fluid [23, 30]. On the other hand, the alteration of the base fluid viscosity [31] (from 4.2 to 5500 cP, by mixing two with approximately the same thermal conductivity) resulted in decrease in the thermal conductivity of the Fe_{2}O_{3} suspension as the viscosity of the base fluid increased. Comparative studies of SiC suspensions in water and 50/50 ethylene glycol/water mixture with controlled particle sizes, concentration, and pH showed that relative change in thermal conductivity due to the introduction of nanoparticles is ~5% higher in EG/H_{2}O than in H_{2}O [27]. This effect cannot be explained simply by the lower thermal conductivity of the EG/H_{2}O base fluid since the difference in enhancement values expected from EMT is less than 0.1% [15]. Therefore, the "base fluid effect" observed in different nanofluid systems is most likely related to the lower value of the interfacial thermal resistance (better wettability) in the EG/H_{2}O than in the H_{2}Obased nanofluids.
Relative viscosity decreases with the increase of the average particle size in both EG/H_{2}O than in H_{2}Obased suspensions. However, at the same volume concentration of nanoparticles relative viscosity increase is smaller in the EG/H_{2}O than in H_{2}Obased nanofluids, especially in suspensions of smaller nanoparticles [27]. According to the classic EinsteinBachelor equation for hard noninteracting spheres [32], the percentage viscosity increase should be independent of the viscosity of the base fluid and only proportional to the particle volume concentration. Therefore, the experimentally observed change in viscosity increase in base fluids can be related to the difference in structure and thickness of immobilized fluid layers around the nanoparticles, affecting the effective volume concentration and ultimately the viscosity of the suspensions [24, 26, 27].
Since both high thermal conductivity and low viscosity increases in nanofluids are important for heat transfer performance, the nanofluids prepared from more viscous base fluids will have greater potential for practical applications.
Viscosity increase in nanofluids was shown to depend not only on the type of the base fluid, but also on the pH value (in protonic fluids) that establishes zeta potential (charge at the particle's slipping plane). Particles of the same charge repel each other minimizing the particleparticle interactions that strongly affect viscosity [24, 26, 33]. It was demonstrated that the viscosity of the aluminabased nanofluids can be decreased by 31% by only adjusting the pH of the suspension without affecting the thermal conductivity [24]. Nanoparticles in suspensions can be welldispersed (particles move independently) or agglomerated (ensembles of particles move together). Depending on the particle concentration and the magnitude of particleparticle interactions that are affected by pH, surfactant additives and particle size and shape, a dispersion/agglomeration equilibrium establishes in nanoparticle suspension. Extended agglomerates can provide increased thermal conductivity as described in the literature [34, 35], but agglomeration and clustering of nanoparticles result in undesirable viscosity increase and/or settling of suspensions.
Introduction of other additives (salts and surfactants) may also affect the zeta potential at the particle surfaces. Nonionic surfactants provide steric insulation of nanoparticles preventing Van der Waals interactions, while ionic surfactants may serve as both electrostatic and steric stabilization. The thermal conductivity of surfactants is significantly lower than water and ethylene glycol. Therefore, addition of such additives, while improving viscosity, typically reduces the thermal conductivity of suspension.
It should be mentioned here that all thermophysical properties have some temperature dependence. The thermal conductivity of fluids may increase or decrease with the temperature; however, it was shown that relative enhancement in the thermal conductivity due to addition of nanoparticles remains constant [29, 36]. The viscosity of most fluids strongly depends on the temperature, typically decreasing with increasing temperature. It was noted in a couple of nanofluid systems that the relative increase in viscosity is reduced as temperature rises [26, 27]. The fact of constant thermal conductivity increase and viscosity decrease with temperature makes nanofluids technology very promising for hightemperature application. The density and specific heat of nanofluids change insignificantly within the practical range of current cooling applications. Stability of nanofluids could be improved with temperature increase due to increase in kinetic energy of particles, but heating also may affect the suspension stability provided by electrostatic or/and steric methods. Further studies are needed in this area.
Systems engineering approach to nanofluids
Systems engineering is an interdisciplinary field widely used for designing and managing complex engineering project, where the properties of a system as a whole may greatly differ from the sum of the parts' properties [37]. The decision matrix approach used in this study is a semiquantitative technique for ranking multidimensional nanofluid engineering options [38]. It also offers an alternative way to look at the inner workings of a nanofluid system and allows for design choices addressing the heat transfer demands of a given industrial application.
Systems engineering approach to nanofluid design.
ENGINEERING PARAMETERS  Nanoparticle material  Nanoparticle concentration  Nanoparticle shape  Nanoparticle size  Base fluid  Zeta potential/fluid pH  Kapitza resistance  Additives  Temperature  

NANOFLUID PROPERTIES  
Stability  ⇑  ▲  ▲  ▲  ■↓  ○  ■  x  ■  ? 
Density  ⇑  ■  ■↑  x  x  ■  x  x  x  x 
Specific Heat  ⇑  ■  ■↓  x  x  ■  x  x  x  ▲ 
Thermal Conductivity  ⇑  ○  ■↑  ○  ■↑  ▲  ○  ■↓  ▲  ○ 
Viscosity  ⇓  ▲  ■↓  ■  ■↓  ■↑  ■  x  ○  ■ 
Heat Transfer Coefficient  ⇑  ■  ■↑*  ■  ■↑  ■  ■  ■↓  ○  ■ 
Pumping Power Penalty  ⇓  x  ■  ■  ■↑  ■  ■  x  ○  ■ 
Relative Importance  4.0  6.25  3.75  5.0  5.25  4.0  2.0  2.75  3.75 
Applications of the decision matrix (Table 1) are not limited to the design of new nanofluids; it also can be used as guidance for improving the performance of existing nanoparticle suspensions. While the particle material, size, shape, concentration, and the base fluid parameters are fixed in a given nanofluid, the cooling performance still can be improved by remaining adjustable nanofluid parameters in order of their relative importance, i.e., by adjusting the zeta potential and/or by increasing the test/operation temperatures in the above case. Further studies are needed to define the weighted importance and sensitivity of each nanofluid property contributing to the heat transfer.
Summary
The article first identifies the thermophysical properties of nanofluids that are important for heat transfer using the fluid dynamicsbased cooling efficiency criteria for singlephase fluids. Then the nanofluid engineering parameters are reviewed in regards to their influence on the thermophysical properties of nanoparticle suspensions. The individual nanofluid parameterproperty correlations are summarized and analyzed using the system engineering approach, which allows identifying the most influential nanofluid parameters. The relative importance of engineering parameters resulted from such analysis suggests the potential nanofluid design options. Importantly, the criteria are not weighted to allow a quick selection process. The nanoparticle concentration, base fluid, and particle size appear to be the most influential parameters for improving the heat transfer efficiency of nanofluid.
Abbreviations
 EG:

ethylene glycol
 EMT:

effective medium theory.
Declarations
Acknowledgements
This study is funded by the DOE Industrial Technology Program #M68008852. Argonne National Laboratory is a US Department of Energy Office of Science Laboratory under contract number DEAC0206CH11357 by UChicago Argonne, LLC.
Authors’ Affiliations
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