Effect of the carbon nanotube surface characteristics on the conductivity and dielectric constant of carbon nanotube/poly(vinylidene fluoride) composites
© Carabineiro et al; licensee Springer. 2011
Received: 27 October 2010
Accepted: 7 April 2011
Published: 7 April 2011
Commercial multi-walled carbon nanotubes (CNT) were functionalized by oxidation with HNO3, to introduce oxygen-containing surface groups, and by thermal treatments at different temperatures for their selective removal. The obtained samples were characterized by adsorption of N2 at -196°C, temperature-programmed desorption and determination of pH at the point of zero charge. CNT/poly(vinylidene fluoride) composites were prepared using the above CNT samples, with different filler fractions up to 1 wt%. It was found that oxidation reduced composite conductivity for a given concentration, shifted the percolation threshold to higher concentrations, and had no significant effect in the dielectric response.
Carbon nanotubes (CNTs) have attracted particular interest because of their remarkable mechanical and electrical properties . The combination of these properties with very low densities suggests that CNTs are ideal candidates for high-performance polymer composites . In order to increase the application range of polymers, highly conductive nanoscale fillers can be incorporated into the polymeric matrix. As CNTs present high electrical conductivity (103-104 S/cm), they have been widely used . Therefore, CNT/polymer composites are expected to have several important applications, namely, in the field of sensors and actuators . However, in order to properly tailor the composite material properties for specific applications, the relevant conduction mechanisms must be better understood.
The experimental percolation thresholds for CNT composites results in a wide range of values for the same type of CNT/polymer composites , being a deviation from the bounds predicted by the excluded volume theory and a dispersion for the values of the critical exponent (t) [6, 7]. It was demonstrated that the conductivity of CNT/polymer composites can be described by a single junction expression  and that the electrical properties also strongly depend on the characteristics of the polymer matrix . This article explores the effects of nanotubes surface modifications in the electrical response of the composites.
Preparation and characterization of the modified CNT samples
Commercial multi-walled CNTs (Nanocyl - 3100) have been used as received (sample CNTs). Further details on this material can be found elsewhere . CNTs sample was functionalized by oxidation under reflux with HNO3 (7 M) for 3 h at 130°C, followed by washing with distilled water until neutral pH, and drying overnight at 120°C (sample CNTox was obtained). The CNTox material was heat treated under inert atmosphere (N2) at 400°C for 1 h (sample CNTox400) and at 900°C for 1 h (sample CNTox900), to selectively remove surface groups. The obtained samples were characterized by adsorption of N2 at -196°C, temperature-programmed desorption (TPD) and determination of pH at the point of zero charge (pHPZC) from acid-base titration according to the method of the literature . The total amounts of CO and CO2 evolved from the samples were obtained by integration of the TPD spectra.
Polymer films with thicknesses between 40 and 50 μm were produced by mixing different amounts of CNT (from 0.1 to 1.0%) with N, N-dimethylformamide (DMF, Merck 99.5%) and PVDF (Solef 1010, supplied by Solvay Inc., molecular weight = 352 × 103 g/mol) according to the procedure described previously . Solvent evaporation, and consequent crystallization, was performed inside an oven at controlled temperature. The samples were crystallized for 60 min at 120°C to ensure the evaporation of all DMF solvents. After the crystallization process, the samples were heated until 230°C and maintained at that temperature for 15 min to melt and erase all polymer memory. This procedure produced α-PVDF crystalline phase samples .
Topography of the samples and CNT distribution was performed by scanning electron microscopy (SEM, FEI - NOVA NanoSEM 200). The dielectric response of the nanocomposites was evaluated by dielectric measurements with a Quadtech 1920. Circular gold electrodes of 5-mm diameter were evaporated by sputtering onto both sides of each sample. The complex permittivity was obtained by measuring the capacity and tan δ in the frequency range of 100 Hz to 100 kHz at room temperature. The volume resistivity of the samples was obtained by measuring the characteristic I-V curves at room temperature using a Keithley 6487 picoammeter/Voltage source.
Results and discussion
Characterization of CNT samples
BET surface areas obtained by adsorption of N2 at -196°C and amounts of CO2 and CO obtained by integration of areas under TPD spectra
BET surface area (m2/g)
All the samples release higher amounts of CO than CO2 groups (Table 1). The CNTox sample has the highest amount of surface oxygen. This sample also presents the lowest ratio CO/CO2 and the lowest value of pHPZC, indicating that this is the most acidic sample. CNTox900 presents the highest CO/CO2 ratio, suggesting the less-acidic characteristics, which matches well with the pHPZC results (Table 1). The acidic character of the samples decreases by increasing the thermal treatment temperature, since the acidic groups are removed at lower temperatures than neutral and basic groups, as seen in previous studies [10, 13, 14].
The CNT samples have N2 adsorption isotherms of type II (not shown), as expected for non-porous materials . The surface areas of the samples, calculated by the BET method (SBET), are included in Table 1. It can be observed that the oxidation treatments lead to an increase of the specific surface area. This occurs because the process opens the endcaps of CNTs and creates sidewall openings . The specific surface areas of the samples slightly increase as the thermal treatment temperature increases, since carboxylic acids and other groups, introduced during oxidation, are removed.
Composites processing and characterization
Dielectric measurements show that the incorporation of the CNT in the PVDF matrix but leads to a gradual increase of the dielectric constant (ε') as the amount of the filler is increased (Figure 4b). The increase of the ε' is larger for the pristine CNT. A maximum for the 0.5% pristine CNT sample with ε' 22 at a frequency of 10 kHz at room temperature was found, whereas for the functionalized nanocomposites the value is 16. The frequency behavior of the dielectric permittivity is similar to the one obtained for the pure polymer, except for an increase of the low frequency dielectric constant and dielectric loss (not shown) with increasing CNT loading due to interfacial polarization effects (Figure 4b). No noticeable differences have been observed for the different oxidation treatments in terms of the dielectric response. In a previous study , it was demonstrated that an increase in the dielectric constant is related with the formation of a capacitor network.
The effect of surface modifications of multi-walled CNTs on the electrical response of CNT/PVDF nanocomposites has been investigated. The main effect of oxidation is a reduction of the composite conductivity for a given concentration and a shift of the percolation threshold to higher concentrations. On the other hand, no significant differences have been observed between the nanocomposites prepared with the different functionalized CNTs. The reduction of the electrical surface conductivity of the CNT due to the oxidation process, together with an increase of the surface area and defect formation, is at the origin of the observed effects.
scanning electron microscopy.
The authors thank the Fundação para a Ciência e a Tecnologia (FCT), Portugal, for financial support through the projects PTDC/CTM/69316/2006 and NANO/NMed-SD/0156/2007), and CIENCIA 2007 program for SAC. V.S. and J.N.P. also thank FCT for the SFRH/BPD/63148/2009 and SFRH/BD/66930/2009 grants.
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