Long-term oxidization and phase transition of InN nanotextures
© Sarantopoulou et al; licensee Springer. 2011
Received: 7 October 2010
Accepted: 16 May 2011
Published: 16 May 2011
The long-term (6 months) oxidization of hcp-InN (wurtzite, InN-w) nanostructures (crystalline/amorphous) synthesized on Si  substrates is analyzed. The densely packed layers of InN-w nanostructures (5-40 nm) are shown to be oxidized by atmospheric oxygen via the formation of an intermediate amorphous In-O x -N y (indium oxynitride) phase to a final bi-phase hcp-InN/bcc-In2O3 nanotexture. High-resolution transmission electron microscopy, energy-dispersive X-ray spectroscopy, electron energy loss spectroscopy and selected area electron diffraction are used to identify amorphous In-O x -N y oxynitride phase. When the oxidized area exceeds the critical size of 5 nm, the amorphous In-O x -N y phase eventually undergoes phase transition via a slow chemical reaction of atomic oxygen with the indium atoms, forming a single bcc In2O3 phase.
Recent investigations reveal that oxygen contamination plays the most prominent, though not the only role for optimum semiconducting and optical properties of InN films [1–3]. Oxidization is a constraint of using InN in a variety of applications, such as solar cells, charge memories, and light emitting diodes, despite its excellent semiconducting properties. Furthermore, the long-term functionality of InN films is directly related to the growing methodologies because the oxidization rate depends on the morphology and the quality of the InN surfaces . However, reactive sputtering of InN films in oxygen indicated no evidence of direct formation of In2O3. It was suggested therefore that oxygen accelerates the formation of an intermediate amorphous indium oxynitride phase inside the InN matrix, which eventually oxidizes InN completely to form In2O3. This argument was further supported by the fact that immediate oxidization of InN films was observed at temperatures higher than 600 K but not at room temperature .
The oxidization process of InN films in air at room temperatures was investigated previously using X-ray diffraction, X-ray photoelectron spectroscopy , and high-resolution transmission electron microscopy (HRTEM) [8, 9].
However, few data are currently available in the literature for the long-term oxidization (aging) process of InN films at ambient conditions . Recent investigations of long-term oxidization of hcp-InN lattices grown on GaN/sapphire substrates indicate a phase transformation of hcp-InN to an alloy phase of fcc-InN (InN-zb) and fcc-In2O3, (InN-zb/In2O3), after exposing the films for 36 months at ambient conditions . The above studies suggested the formation of an intermediate amorphous In-O x -N y phase, but a direct observation of this phase has not been reported yet in the literature, nor the phase transformation process was analyzed in relation to the dimensions of the nanodomains.
Among the various growth techniques of nitride films, pulsed laser deposition (PLD) has been employed to grow high-quality nitride films, with the advantage of eliminating either the need for substrate's nitridation or for the formation of an intermediate amorphous buffer layer. This approach was feasible because PLD was carried out in a less-reactive atmosphere in comparison to different methodologies . PLD with a KrF laser, both in vacuum and in nitrogen, was used for depositing InN film on a sapphire substrate . Furthermore, the InN crystalline quality and the electron mobility of InN films grown on c-plane sapphire substrates in nitrogen at 248 nm were highly correlated with the substrate's surface nitridation [13, 14].
Growing the nitride films by PLD at 157 nm (molecular fluorine laser) is advantageous because it ionizes the target material and the ambient gases, such as nitrogen, with only one or two photons. Owing to the high energy per photon at 157 nm (7.9 eV), relatively lower laser energy and flux are required to ablate the target in comparison with longer laser wavelengths [15–17]. The nitride molecular structures are therefore formed at lower plasma temperature, either in the substrate or in the plume. Molecular species with small dissociation energy such as the InN molecules are efficiently formed at cooler laser plasma. Good quality bi-phase nitride nanospheroid and crystal structures grown by PLD at 157 nm were demonstrated recently [18, 19].
In this article, the long-term oxidization of InN from the atmospheric oxygen at the nanoscale level and the correlation between the oxidization rate and the size of the InN nanostructures are analyzed. InN-w nanocrystals (5-40 nm) surrounded by amorphous nanodomains are grown on Si  substrates from an indium target by 157 nm PLD in nitrogen. HRTEM, energy-dispersive X-ray spectroscopy (EDXS), electron energy loss spectroscopy (EELS), and selected area electron diffraction (SAED) analysis are employed to analyze the oxidization process.
This article is organized as follows: In "Experimental procedure" section, the experimental conditions and the analytic methodologies are presented. The morphology of the InN nanostructures is presented in sections "Morphology of InN films" and "High resolution images of InN nanostructures." The structure and the morphology of long-term-oxidized InN nanostructures are given in section "Structure and morphology of long-term-oxidized InN nanostructures" while in section "Amorphous In-O x -N y and In2O3 nanostructures," the relations among the amorphous In-O x -N y , the crystalline InN, and In2O3 phases are discussed and analyzed.
The ablative targets are of high-purity (99.999%) indium foils (Good-Fellow) of 1.0-mm thickness. These are mounted inside the chamber on a motorized x-y-z stage, allowing alignment with the beam by external control. The target is oriented normal to the axis of the incident beam.
Films are deposited on Si  substrates at the relatively low laser energy of 20 mJ at 15-Hz repetition rate. The pulse duration is 15 ns at full width at half maximum. The laser beam is focused on the target along the laser beam direction with a CaF2 lens of 5-cm focal length to a 200-μm spot. The intensity of the focused beam on the target is approximately 6 TW. The Si  substrate is placed approximately 3-5 mm away from the target and perpendicular to the optical axis of the laser beam (Figure 1). Before deposition, the vacuum chamber was evacuated down to 10-4 Pa under heating to remove contaminants on the chamber's inner surfaces. The film is deposited at 105 Pa in nitrogen gas at ambient temperature. Research grade N2 (99.999%) is flooded into the chamber before irradiation. The CaF2 lens is protected from the ablative products by a 1-mm-thin CaF2 window that needs to be replaced after 10 h. The laser beam is focused along the Z-direction with micro resolution. The growth rate of the film is 170 nm/h. By changing the laser energy, the background gas pressure, the target-substrate distance and the repetition rate of the laser, films of different morphologies are grown [24, 25].
Scanning electron microscopy (SEM, Jeol 840A), EDXS and atomic force microscopy (AFM, Quesant Nomad) are employed to evaluate the morphology and roughness of the films. The structure of the film is studied using a Jeol 2010 FEG scanning transmission electron microscope and a Jeol 2100 transmission electron microscope (TEM) operating at 200 kV, with EELS compositional analysis capabilities.
Small fragments of InN films are transferred to a lacey-carbon-coated Ni grid and examined in the microscope. HRTEM and SAED have been employed to examine the nanostructure and crystalline quality of the InN films. HRTEM measurements are carried out to study the lattice image structural relationship between the hexagonal InN and cubic In2O3 nanostructures.
Results and discussion
Morphology of InN films
The InN structure was first identified by EDXS, (Figure 2c), recorded 2 days after the growth of film. The spectrum indicates the presence of either the amorphous or crystalline InN . Oxygen was non-detectable, confirming the low oxidization rate at 2 days after the growth of film.
The growth of InN crystals by 157-nm PLD sidesteps some constraints imposed by the low reactivity of nitrogen. The InN crystalline phase is formed either through the ionic interaction of the molecular species on the target, or in the plume near the target's surface. Indeed, two 157-nm photons are required to ionize the N2 molecule from its ground electronic state. This condition is satisfied directly on the target because of the high-intensity-focused laser beam.
Irregular-shaped grains observed previously [7, 29], were associated with nucleated InN hexagonal crystal islands (grown along the Z-direction) that eventually were enlarged laterally along the InN plane. Moreover, in previous studies, it was confirmed that the surface morphology of InN samples was influenced by the lattice mismatch (InN: hexagonal, a = 0.354 nm, c = 0.570 nm. Si: diamond cubic a = 0.543 nm), between the samples and the Si (111) substrate leading to the growth of three-dimensional islands with size and density depending on the substrate temperature .
The lattice mismatch is the source of shear stresses at the interface that tailors the morphology of the film , e.g., dendrite structure in our case. The InN crystal has a lattice mismatch with most of monocrystalline substrates, and therefore different morphologies are expected to grow on different substrates .
High-resolution images of InN nanostructures
The long-term phase transformation from the hcp-InN phase to the metastable fcc-InN structure reported previously  is undetectable because of the growth of the film on a different substrate where the lattice mismatch provided the required strain for phase transformation.
Structure and morphology of long-term-oxidized InN nanostructures
Three different methods are used for specifying the stoichiometric composition of the crystal nanodomains: EDXS, EELS, and SAED because results among these three methods may vary. This inconsistency is not only due to the presence of stray X-ray radiation at EDXS, especially at rough films with broad size distribution of nanodomains but also due to the difference between the cross sections of the electron and the X-ray beams (5 and 450 nm, respectively).
This point is further strengthened by previous investigations on the size of monocrystals. It was found that they exhibit a sharp Gaussian distribution at the nanoscale (approx. 10 nm) . It is unlikely therefore that long 3D crystal structures are grown either in the plume, or directly on the Si substrate with PLD. The relatively small size of the crystal nanostructures is credited to the short range of ionic forces that are responsible for the short spatial correlation between the atoms of the crystal structure. Three different nanostructured groups with average size of 5 (A), 25 (B), and 40 nm (C) are identified, Figure 6a, b, although larger crystal domains are grown through the aggregation of small nanocrystal domains (<5 nm). Furthermore, crystal structures with their Laue levels slightly rotated with respect to each other (Figure 6b, D) should correspond to a superposition of uncorrelated crystal nanostructures  (separated by a relatively large distance in comparison to the correlation length). The HRTEM images indicate the superposition of crystal areas of different contrast and with parallel Laue levels, indicated within the periphery of the circles C1 and C2 (Figure 5) and within the areas E and F (Figure 6a). Furthermore, various amorphous nanodomains are formed, such as the ones within the periphery of the triangle and the circle B (Figure 5), and the areas within the periphery of the circles E and F (Figure 6a).
The nanoclusters tend to nucleate primarily on the substrate, but the size distribution of nanodomains is an indication that crystallization in the plume is possible too.
The average experimental concentrations of nitrogen and oxygen are affected negligibly as observed from the X-ray absorbance, and the molar ratio of InN/In2O3 is estimated as 0.3/0.7. Indeed, owing to the MIV and MV absorption edges of In, the mass absorption coefficients (MACs) for OKα and NKα are 1.9 × 104 and 3.7 × 103 cm2/g, respectively. In addition, owing to the K absorption edge of nitrogen, the MACs of OKα and NKα lines in nitrogen are 1.7 × 104 and 1.5 × 103 cm2/g, respectively. The calculated attenuation of OKα line in a 10-nm-thick crystal (0.5InN/0.5In2O3) is approx. 10%, and the attenuation of the NKα line is approx. 2%.
The SAED images were obtained with fast Fourier transmission (FFT) on HRTEM images. This technique eliminates part of the information from the initial image, while preserving the periodical information, such as the lattice plane fringes. In the experimental SAED pattern, six clear rings made of discrete spots can be fitted (Figure 9).
The experimental SAED patterns are compared to the simulated patterns of the intensity distribution of the diffracted beam (yellow inlets, Figure 9) for three different phases (a, bcc-In2O3; b, hcp-InN; and c, bcc-In). The experimental SAED patterns are usually slightly distorted because of non-optimized alignment of the microscope and the nonlinearity of the CCD camera.
First, the d spacing values are calculated for cubic bcc In2O3 nanostructures. The poor matching of peak positions between the calculated and the experimental profiles of Figure 9a (bcc-In2O3) indicates that additional crystalline phases besides bcc-In2O3 and hcp-InN are present, forming an alloy texture of hcp-InN/bcc-In2O3, and that a certain amount of oxygen is present in the form of amorphous In2O3 or In-O x -N y non-detectable with SAED. This result is in agreement with the direct identification of the amorphous phase from the HRTEM images (Figure 6E).
The same procedure is applied for pure hexagonal hcp-InN and tetragonal indium. In all the cases, the agreement with the experimental SAED patterns is lacking.
The sum of simulated patterns for 50% hcp-InN and 50% bcc-In2O3 is in agreement with the experimental ones, indicating the coexistence of cubic bcc-In2O3 and hexagonal hcp-InN phases in the films (Figure 9d).
Amorphous In-O x -N y and In2O3nanostructures
It is generally accepted that InN is transformed first to the amorphous In-O x -N y /In2O3 phase and then subsequently to the crystalline In2O3 phase either by aging or annealing. It has been reported that after the initial growth of InN and subsequent formation of oxynitride, a mixed crystalline phase of In2O3 and InN crystals was grown after a short annealing time (10 min) at 550°C . The cubic In2O3 phase was formed layer-by-layer, after subsequent oxidization of the hexagonal InN layers .
Substitution of nitrogen by oxygen is possible in principle, since both atoms have similar atomic radii . At room temperature and up to 800 K, the heat of formation of crystalline In2O3 (221 kcal/mol) is higher than the heat of formation of crystalline InN (34 kcal/mol) , and therefore, even in the presence of oxygen, InN is preferably formed.
In the present study, InN is growing in pure nitrogen, and thus, the formation of In2O3 during the ablative phase is negligible. Furthermore, the oxidization of the post-ablated pure indium nanodomains from the atmospheric oxygen or the direct transformation of the crystal phase of InN to In2O3 are improbable to occur because oxidization via those pathways is energetically unfavorable. Following the film's exposure to atmospheric oxygen, the oxidization of InN is taking place slowly. The initially physisorbed oxygen eventually becomes chemisorbed inside the InN lattice. Therefore, the oxidization of the InN crystal should take place through the formation of an intermediate amorphous phase.
The single crystal layers are clearly identified, and the inset of FFT of real images and the experimental results indicate that the crystal In2O3, InN, and the amorphous In-O x -N y oxynitride phases coexist in the form of neighboring distinct nanodomains after the long-term exposure of InN to atmospheric conditions (Figure 6a, F).
InN-w crystal nanostructures are grown by PLD at 157 nm from an indium target in nitrogen without post-growth annealing or target heating. After exposing the films to oxygen at ambient conditions for 6 months, HRTEM imaging, EDXS, EELS, and SAED analyses reveal that long-term oxidization is taking place slowly through the formation of an intermediate amorphous In-O x -N y oxynitride phase, directly identified by HRTEM. The atmospheric oxygen, diffused inside the InN grid, oxidizes the film slowly. This process consists of two stages: first, the intermediate amorphous phase is formed and, when it exceeds the critical size of 5 nm, the In2O3 crystalline phase is formed via phase transition. Finally, oxidization at a larger scale occurs from the agglomeration of the small-sized-oxidized crystal nanodomains.
atomic force microscopy
energy-dispersive X-ray spectroscopy
electron energy loss spectroscopy
fast Fourier transmission
high-resolution transmission electron microscopy
mass absorption coefficients
pulsed laser deposition
selected area electron diffraction
scanning electron microscopy
transmission electron microscope.
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