Study of the oxygen vacancy influence on magnetic properties of Fe- and Co-doped SnO2 diluted alloys
© Borges et al.; licensee Springer. 2012
Received: 9 July 2012
Accepted: 15 September 2012
Published: 28 September 2012
Transition-metal (TM)-doped diluted magnetic oxides (DMOs) have attracted attention from both experimental and theoretical points of view due to their potential use in spintronics towards new nanostructured devices and new technologies. In the present work, we study the magnetic properties of Sn0.96TM0.04O2 and Sn0.96TM0.04O1.98(VO)0.02, where TM = Fe and Co, focusing in particular in the role played by the presence of O vacancies nearby the TM. The calculated total energy as a function of the total magnetic moment per cell shows a magnetic metastability, corresponding to a ground state, respectively, with 2 and 1 μB/cell, for Fe and Co. Two metastable states, with 0 and 4 μB/cell were found for Fe, and a single value, 3 μB/cell, for Co. The spin-crossover energies (ES) were calculated. The values are ES0/2 = 107 meV and ES4/2 = 25 meV for Fe. For Co, ES3/1 = 36 meV. By creating O vacancies close to the TM site, we show that the metastablity and ES change. For iron, a new state appears, and the state with zero magnetic moment disappears. The ground state is 4 μB/cell instead of 2 μB/cell, and the energy ES2/4 is 30 meV. For cobalt, the ground state is then found with 3 μB/cell and the metastable state with 1 μB/cell. The spin-crossover energy ES1/3 is 21 meV. Our results suggest that these materials may be used in devices for spintronic applications that require different magnetization states.
KeywordsTin dioxide Diluted magnetic semiconductors Magnetic properties ab initio calculations Electronic structure
Nowadays, dilute magnetic oxides (DMOs) are potential candidates for both spintronic devices and nanodevices applications. Although the existence of room temperature ferromagnetism (FM) in transition metal (TM)-doped SnO2 has been reported, the origin of the FM is still controversial. There are indications that the FM comes from different sources, metallic clusters, secondary phases, or is due to a free carrier-mediated mechanism in the bulk. The presence of oxygen vacancies is systematically related to the observed ferromagnetic state. These systems are good candidates to obtain materials with a half-metallic behavior, with 100% spin-polarized carriers at the Fermi level.
Tin dioxide (SnO2) doped with transition metals (TMs) have been extensively investigated recently due to the resulting important magnetic properties[1–6]. The ferromagnetic behavior has been observed at room temperature in Cr-, Mn-, Fe- and Co-doped SnO2 DMO systems[7–12], indicating the potential of such systems for spintronic applications. It has also been observed that the presence of oxygen vacancies appears to be required for producing FM in DMOs, such as, e.g., in Co-doped ZnO, in Co-doped TiO2[14, 15], in Fe- and Co-doping in In2O3[16, 17], and in Fe-, Co-, and Cr- doped SnO2[7, 18, 19]. A theoretical model proposed by Coey et al. to interpret the FM in these semiconducting oxides requires the existence of oxygen vacancies in close proximity to TM sites in order to maintain the charge neutrality. For Cr-doped SnO2 nanoparticles, the obtained FM behavior is limited by a maximum doping concentration xL which has a strong relation with structural changes revealed from X-ray diffraction measurements. The presence of oxygen vacancies in these Sn1 − xTM x O2 samples, in which the TM concentrations x varies from 0% to 10%, has been detected by electron paramagnetic resonance experiments. Many efforts have been made in attempt to characterize and understand the mechanisms involved in the ferromagnetic behavior observed in such systems.
In this work, we study the oxygen vacancy influence on magnetic properties of the Fe- and Co-doped SnO2 diluted alloys. First, the systems Sn1 − xMT x O2, for x = 0.04, were studied through ab initio electronic structure calculations performed within the spin density functional theory. The concentration of x = 0.04 corresponds to a typical experimental value. Second, an oxygen vacancy nearest neighbor to the TM atom in the alloys was introduced. Sn1 − xTM x O2 − y(VO) y systems, with x = 0.04 and y = 0.02, and its consequences for the magnetic behavior of these systems were considered. Finally, an investigation about the magnetic metastability was done, and the spin-crossover phenomenon was studied. A metamagnetic state is the key underlying conceptual mechanism for storage, memory, and display device and nanodevice applications, and this work shows that DMO materials based on Fe- and Co-doped SnO2 taking into account the oxygen vacancy influence could be engineered to display different stable magnetized states.
The calculations were based on the spin density functional theory. We employed the projector augmented wave method implemented in the Vienna ab-initio simulation package (VASP-PAW)[22, 23]. The exchange-correlation potential used was the generalized gradient approximation in the Perdew, Burke, and Ernzerhof approach. The method has been previously used to study the structural and electronic properties of bulk rutile SnO2. The valence electronic distributions for the PAWs representing the atoms were Sn 4d105s25p2, Fe 3d74s1, Co 3d74s2, and O 2s22p6. The onsite correction Hubbard U for Co- and Fe d orbitals was not considered. Previous calculations for Cr doping SnO2 taking into account a U correction show no major changes in our conclusions. Scalar relativistic effects were taken into account. To describe the alloys, we used a 72-atom supercell (24 Sn and 48 O atoms) and a 4 × 4 × 4 mesh of Monkhorst-Pack k-points for integration in the Brillouin zone. All the calculations were done with a 490-eV energy cutoff in the plane-wave expansions, and the systems were fully relaxed until the residual forces on the ions were less than 10 meV/Å.
Results and discussion
We studied the systems Sn0.96TM0.04O2 and the Sn0.96TM0.04O1.98(VO)0.02 (with TM = Fe and Co) with the oxygen vacancy as the TM nearest neighbor. In both cases, a single tin atom was substituted with a TM atom in the 72-atom supercell, simulating the x = 0.04 impurity and y = 0.02 oxygen vacancy concentrations. For all cases, the total energy was calculated for several magnetic moment values.
It was recently shown by us that when a Sn atom is replaced by a chromium atom in SnO2, a high-spin (HS) ground state with a magnetic moment m = 2 μB/cell and a low-spin state (LS) with a magnetic moment m = 0 μB/cell are obtained. For this case, a spin crossover becomes possible with an energy barrier of 114 meV calculated for the transition from m = 0 to 2 μB/cell. When an oxygen vacancy (out of the six first neighbors of Cr) is considered, the behavior of the total energy versus the magnetic moment per cell showed the appearance of a second HS configuration, with magnetic moment m = 4 μB/cell and an energy barrier of 32 meV relative to the 2 μB/cell state. The ground state, however, remains as the 2 μB/cell magnetic moment HS state. The energy barrier for the m = 0 to 2 μB/cell transition was reduced to 27 meV. Comparing this value with the one for this barrier in the DMO without the vacancy (114 meV), a drastic transition for the DMO without the vacancy of 114 meV, a drastic reduction by about 75% is observed.
A better understanding of the behavior for the magnetic moment can be obtained if we analyze the oxidation states of the TM and of the neighbor atoms around it. For the Sn0.96Fe0.04O2 alloy, the Fe4+ (3d4) impurity replacing Sn4+ allows the magnetic states m = 0, 2, and 4 μB/cell. In this case, the neighborhood does not contribute to the magnetization of the system. When an oxygen vacancy is taken into account, the impurity state changes from Fe4+ to Fe3+ (3d5) and to Fe2+ (3d6), and the neighboring atoms contribute to the magnetic moment. For m = 2 μB/cell, the oxidation state is Fe3+ where four spin-up and one spin-down electrons from Fe plus one spin-down electron arising from the neighboring atoms allow for the metastable state (with m = 2 μB/cell). For the m = 4 and 6 μB/cell, the oxidation state is Fe2+ where five spin-up and one spin-down electrons from Fe originate the state m = 4 μB/cell, while five spin-up and one spin-down electrons from Fe plus two spin-up electrons arising from the neighboring atoms allow the metastable state with m = 6 μB/cell. These findings are in agreement with the experimental data[27–30].
Likewise, for the Sn0.96Co0.04O2 dilute magnetic alloy, the Co4+ (3d5) and Co3+ (3d6) impurity replacing Sn4+ give rise to the magnetic states m = 1 and 3 μB/cell, respectively. For m = 1 μB/cell, three spin-up and two spin-down electrons from cobalt and for m = 3 μB/cell four spin-up and two spin-down electrons from cobalt plus one spin-up electron arising from the neighboring atoms allow this metastable state. The states Co3+ (3d6) and Co2+ (3d7) are possible when an oxygen vacancy is taken into account for m = 1 and 3 μB/cell, respectively. For m = 1 μB/cell, four spin-up and two spin-down electrons plus one spin-down electron from neighboring atoms are involved. For m = 3 μB/cell, five spin-up and two spin-down electrons from cobalt give rise to this metastable state. Experimental studies have confirmed the incorporation of Co2+ cations into the rutile SnO2 lattice.
The influence of the oxygen vacancy in the magnetic and electronic properties of iron and cobalt as impurities in a DMO configuration in rutile SnO2 was studied using first principle calculations performed within the spin-density functional theory. A magnetic metastability was observed for both impurity cases. Energy barriers were obtained for the spin crossover between the m = 0 and 2 μB/cell and between the m = 2 and 4 μB/cell states in Sn0.96Fe0.04O2. For Sn0.96Co0.04O2, the observed magnetic metastability and energy barrier were obtained for the spin crossover between the m = 3 and 1 μB/cell states.
When an oxygen vacancy is considered as one of the six first neighbors to the Fe and Co impurities in these alloys (Sn0.96Fe0.04O1.98(VO)0.02 and Sn0.96Co0.04O1.98(VO)0.02), a considerable modification is observed in the magnetic metastability behavior, with new allowed states appearing for iron. For the cobalt impurity, the presence of an oxygen vacancy promoted a ground state exchange between the magnetic state 1 and 3 μB/cell. This behavior is attributed to the relative contributions of the intra-atomic exchange interaction effects and the inter-atomic electron motion effects due to the crystalline field, which are responsible for the relaxations around the TM impurities. Finally, to manipulate the electron spin opens new possibilities to engineering new spintronic devices, and TM-doped DMOs are potential candidates to represent a new kind of material, which display magnetic metastability, SCO phenomena, and a half-metallic behavior.
PDB is an assistant professor at the Universidade Federal de Viçosa. LMRS is a senior lecturer and research professor at Texas State University-San Marcos. HWLA is an associate professor at Universidade Federal de São João del Rei. EFS is an associate professor at Universidade Federal de Pernambuco. LVCA is an associate professor at Universidade de São Paulo.
The authors thank the support received from the Brazilian research financial agencies CNPq (grant nos. 564.739/2010-3/NanoSemiCon, 302.550/2011-9/PQ, 470.998/2010-5/Univ, 472.312/2009-0/PQ, 303578/2007-6/PQ, and 577.219/2008-1/JP), CAPES, FACEPE (grant no. 0553 to 1.05/10/APQ), FAPEMIG, and FAPESP. LS also acknowledge the partial support from the Materials Science, Engineering and Commercialization Program of Texas State University.
- Mathew X, Enriquez JP, Mejía-Garcia C, Contreras-Puente G, Cortes-Jacome MA, Toledo Antonio JA, Hays J, Punnoose A: Structural modifications of SnO2 due to the incorporation of Fe into the lattice. J Appl Phys 2006, 100: 073907–1-073907–7.
- Kimura H, Fukumura T, Kawasaki M, Inaba K, Hasegawa T, Koinuma H: Rutile-type oxide-diluted magnetic semiconductor: Mn-doped SnO2. Appl Phys Lett 2002, 80: 94–96. 10.1063/1.1430856View Article
- Wang W, Wang Z, Hong Y, Tang J, Yu M: Structure and magnetic properties of Cr/Fe-doped SnO2 thin films. J Appl Phys 2006, 99: 08M115–1-08M115–3.
- Ogale SB, Choudhary RJ, Buban JP, Lofland SE, Shinde SR, Kale SN, Kulkarni VN, Higgins J, Lanci C, Simpson JR, Browning ND, Das Sarma S, Drew HD, Greene RL, Venkatesan T: High temperature ferromagnetism with a giant magnetic moment in transparent Co-doped SnO2-δ. Phys Rev Lett 2003, 91: 077205–1-077205–1.View Article
- Torres CER, Errico L, Golmar F, Navarro AMM, Cabrera AF, Duhalde S, Sánchez FH, Weissmann M: The role of the dopant in the magnetism of Fe-doped SnO2 films. J Magn Magn Mater 2007, 316: e219-e222. 10.1016/j.jmmm.2007.02.094View Article
- Batzill M, Burst JM, Diebold U: Pure and cobalt-doped SnO2(101) films grown by molecular beam epitaxy on Al2O3. Thin Solid Films 2005, 484: 132–139. 10.1016/j.tsf.2005.02.016View Article
- Van Komen C, Thurber A, Reddy KM, Hays J, Punnoose A: Structure–magnetic property relationship in transition metal (M = V, Cr, Mn, Fe, Co, Ni) doped SnO2 nanoparticles. J Appl Phys 2008, 103: 07D141–1-07D141–3.View Article
- Hong NH, Sakai J, Prellier W, Hassini A: Transparent Cr-doped SnO2 thin films: ferromagnetism beyond room temperature with a giant magnetic moment. J Phys Condens Matter 2005, 17: 1697. 10.1088/0953-8984/17/10/023View Article
- Fitzgerald CB, Venkatesan M, Dorneles LS, Gunning R, Stamenov P, Coey JMD, Stampe PA, Kennedy RJ, Moreira EC, Sias US: Magnetism in dilute magnetic oxide thin films based on SnO2. Phys Rev B 2006, 74: 115307–1-115307–10.View Article
- Chen W, Li J: Magnetic and electronic structure properties of Co-doped SnO2 nanoparticles synthesized by the sol–gel-hydrothermal technique. J Appl Phys 2011, 109: 083930–1-083930–4.
- Sharma A, Varshney M, Kumar S, Verma KD, Kumar R: Magnetic properties of Fe and Ni doped SnO2 nanoparticles. Nanomater Nanotechnol 2011, 1: 29–33.
- Sharma A, Singh AP, Thakur P, Brookes NB, Kumar S, Lee CG, Choudhary RJ, Verma KD, Kumar R: Structural, electronic, and magnetic properties of Co doped SnO2 nanoparticles. J Appl Phys 2010, 107: 093918. 10.1063/1.3415541View Article
- Singhal RK, Samariyba A, Xing YT, Kumar S, Dolia SN, Deshpande UP, Shripathi T, Saitovitch EB: Electronic and magnetic properties of Co-doped ZnO diluted magnetic semiconductor. J Alloys and Compounds 2010, 496: 324–330. 10.1016/j.jallcom.2010.02.005View Article
- Singhal RK, Samariya A, Kumar S, Xing YT, Jain DC, Deshpande UP, Shripathi T, Saitovitch E, Chen CT: On the longevity of H-mediated ferromagnetism in Co doped TiO2: a study of electronic and magnetic interplay. Solid State Commun 2010, 150: 1154–1157. 10.1016/j.ssc.2010.03.018View Article
- Singhal RK, Samariya A, Kumar S, Xing YT, Jain DC, Dolia SN, Deshpande UP, Shripathi T, Saitovitch EB: Study of defect-induced ferromagnetism in hydrogenated anatase TiO2:Co. J Appl Phys 2010, 107: 113916. 10.1063/1.3431396View Article
- Samariya A, Singhal SK, Kumar S, Xing YT, Sharma SC, Kumari P, Jain DC, Dolia SN, Deshpande UP, Shripathi T, Saitovitch E: Effect of hydrogenation vs. re-heating on intrinsic magnetization of Co doped In2O3. Appl Surf Sci 2010, 257: 585–590. 10.1016/j.apsusc.2010.07.037View Article
- Singhal RK, Samariya A, Kumar S, Sharma SC, Xing YT, Deshpande UP, Shripathi T, Saitovitch E: A close correlation between induced ferromagnetism and oxygen deficiency in Fe doped In2O3. Appl Surf Sci 2010, 257: 1053–1057. 10.1016/j.apsusc.2010.07.106View Article
- Hays J, Punnoose A, Baldner R, Engelhard MH, Peloquin J, Reddy KM: Relationship between the structural and magnetic properties of Co-doped SnO2 nanoparticles. Phys Rev B 2005, 72: 075203–1-075203–7.View Article
- Misra SK, Andronenko SI, Rao S, Bhat SV, Van Komen C, Punnoose A: Cr3+ electron paramagnetic resonance study of Sn1−xCrxO2 (0.00 ≤ x ≤ 0.10). J Appl Phys 2009, 105: 07C514–1-07C514–3.View Article
- Coey JMD, Venkatesan M, Fitzgerald CB: Donor impurity band exchange in dilute ferromagnetic oxides. Nat Mater 2005, 4: 173–179. 10.1038/nmat1310View Article
- Cui XY, Delley B, Freeman AJ, Stampfl C: Magnetic metastability in tetrahedrally bonded magnetic III-nitride semiconductors. Phys Rev Lett 2006, 97: 016402–1-016402–4.View Article
- Kresse G, Furthmuller J: Efficiency of ab-initio total energy calculations for metals and semiconductors using a plane-wave basis set. Comput Mater Sci 1996, 6: 15. 10.1016/0927-0256(96)00008-0View Article
- Kresse G, Furthmuller J: Efficient iterative schemes for ab initio total-energy calculations using a plane-wave basis set. Phys Rev B 1996, 54: 11169. 10.1103/PhysRevB.54.11169View Article
- Perdew JP, Burke K, Ernzerhof M: Generalized gradient approximation made simple. Phys Rev Lett 1996, 77: 3865. 10.1103/PhysRevLett.77.3865View Article
- Borges PD, Scolfaro LMR, Leite Alves HW, da Silva EF Jr: DFT study of the electronic, vibrational, and optical properties of SnO2. Theor Chem Acc 2010, 126: 39–44. 10.1007/s00214-009-0672-3View Article
- Borges PD, Scolfaro LMR, Leite Alves HW, da Silva EF Jr, Assali LVC: Magnetic and electronic properties of Sn1–xCrxO2 diluted alloys. Mater Sci Eng B 2011, 176: 1378–1381. 10.1016/j.mseb.2011.01.017View Article
- Fitzgerald CB, Venkatesan M, Douvalis AP, Huber S, Coey JMD, Bakas T: SnO2 doped with Mn, Fe or Co: room temperature dilute magnetic semiconductors. J Appl Phys 2004, 95: 7390–7392. 10.1063/1.1676026View Article
- Sánchez LC, Calle AM, Arboleda JD, Osorio J, Nomura K, Barrero CA: Fe-doped SnO2 obtained by mechanical alloying. Microelectronics J 2008, 39: 1320. 10.1016/j.mejo.2008.01.026View Article
- Xue-Yun Z, Shi-Hui G, Xiu-Feng H, Ya-Lu Z, Yu-Hua X, Zhen-Chao W, Li Z, Ming-Jie L: Role of defects in magnetic properties of Fe-doped SnO2 films fabricated by the sol–gel method. Chin Phys B 2009, 18: 4025–4029. 10.1088/1674-1056/18/9/068View Article
- Beltran JJ, Sánchez LC, Osorio J, Tirado L, Baggio-Saitovitch EM, Barrero CA: Crystallographic and magnetic properties of Fe-doped SnO2 nanopowders obtained by a sol–gel method. J Mater Sci 2010, 45: 5002–5011. 10.1007/s10853-010-4454-zView Article
- Liu XF, Sun Y, Yu RH: Role of oxygen vacancies in tuning magnetic properties of Co-doped SnO2 insulating films. J Appl Phys 2007, 101: 123907–1-123907–6.
- Moruzzi VL: Singular volume dependence of transition-metal magnetism. Phys Rev Lett 1986, 57: 2211–2214. 10.1103/PhysRevLett.57.2211View Article
This article is published under license to BioMed Central Ltd. This is an Open Access article distributed under the terms of the Creative Commons Attribution License (http://creativecommons.org/licenses/by/2.0), which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.