Vibration-assisted upconversion of molecular luminescence induced by scanning tunneling microscopy
© Miwa et al.; licensee Springer. 2013
Received: 17 December 2012
Accepted: 20 March 2013
Published: 1 May 2013
We investigate the effects of coupling between a molecular exciton, which consists of an electron and a hole in a molecule, and a surface plasmon (exciton-plasmon coupling) on the electron transitions of the molecule using nonequilibrium Green’s function method. Due to the exciton-plasmon coupling, excitation channels of the molecule arise in the energy range lower than the electronic excitation energy of the molecule. It is found that the electron transitions via these excitation channels give rise to the molecular luminescence and the vibrational excitations at the bias voltage lower than the electronic excitation energy of the molecule. Our results also indicate that the vibrational excitations assist the emission of photons, whose energy exceeds the product of the elementary charge and the bias voltage, (upconverted luminescence).
KeywordsUpconversion Molecular luminescence Scanning tunneling microscope Surface plasmon Molecular vibration Exciton-plasmon coupling Nonequilibrium Green’s function method
Light emission from molecules on metal substrates induced by tunneling current of a scanning tunneling microscope (STM) has attracted much attention owing to its fascinating new physics and its wide applicability in molecular nano-electronics and nano-optics [1–6]. Since surface plasmons localized near the tip-substrate gap region generate an intense electromagnetic field, effects of the interaction between the intense electromagnetic field and the transition moments of the molecular excitations and de-excitations are expected to occur [7–11]. Therefore, in STM-induced light emission (STM-LE) from the molecule on the metal substrate, the interplay between the excitation/de-excitation processes of the molecule and the surface plasmons plays an important role. To understand this from a microscopic point of view, there is a need to investigate the dynamics of the molecule and the surface plasmons within the framework of quantum many-body theory. We have recently investigated the effects of coupling between a molecular exciton, which consists of an electron and a hole in the molecule, and the surface plasmon (exciton-plasmon coupling) on the luminescence properties of the molecule and the surface plasmons with the aid of the nonequilibrium Green’s function method . Our results have shown that the luminescence spectral profiles of the molecule and the surface plasmons can be strongly influenced by the interplay between their dynamics resulting from the exciton-plasmon coupling.
where and c m (m = e, g) are creation and annihilation operators for an electron with energy ϵ m in state |m〉. Operators b† and b are boson creation and annihilation operators for a molecular vibrational mode with energy ; a† and a are for a surface plasmon mode with energy , and and b β are for a phonon mode in the thermal phonon bath, with Q b = b + b† and . The energy parameters M, V, and U β correspond to the coupling between electronic and vibrational degrees of freedom on the molecule (electron-vibration coupling), the exciton-plasmon coupling, and the coupling between the molecular vibrational mode and a phonon mode in the thermal phonon bath.
where X = exp[-λ(b† - b)], and .
where 〈⋯ 〉 H and denote statistical average in representations by system evolution for H and , respectively. τ is the Keldysh contour time variable, and T C is the time ordering along the Keldysh contour.
where L r and L< are the retarded and lesser projection of L.
The parameters are given so that they correspond to the experiment on the STM-LE from TPP molecules on the gold surface : , , and . The statistical average is taken for temperature T = 80 K . The square of λ is reported to be 0.61 on the basis of first-principles calculations . The parameter U β is given so that the molecular vibrational lifetime due to the coupling to the thermal phonon bath is 13 ps . A Markovian decay is assumed for the surface plasmon so that the plasmon lifetime for V=0 eV becomes 4.7 fs [13, 18]. The coefficient Tpl is set in the range of 10-4 to 10-2, where the tunneling current is I t = 200 pA, and an excitation probability of the surface plasmons per electron tunneling event is considered to be in the range of 10-2 to 1.
Results and discussion
The dependence of luminescence spectra on Tpl and is also shown in Figure 2. The luminescence intensity increases as Tpl increases. The luminescence intensity in the energy range lower than e Vbias is proportional to Tpl, and the intensity of the upconverted luminescence is proportional to the square of Tpl. As the energy of the surface plasmon mode is shifted to the low-energy side, the luminescence intensity increases. This increase is attributed to the fact that since the energy of the surface plasmon mode is lower than e Vbias, the electron transitions in the molecule in the energy range lower than e Vbias are enhanced by the surface plasmons.
The exciton-plasmon coupling has a strong influence on the luminescence property of the molecule. The excitation channels of the molecule arise even in the energy range lower than the HOMO-LUMO gap energy . It is found that the electron transitions of the molecule via these excitation channels give rise to the molecular luminescence and the vibrational excitations at the bias voltage . Our results also indicate that the vibrational excitations assist the occurrence of the upconverted luminescence.
Highest occupied molecular orbital-lowest unoccupied molecular orbital
Scanning tunneling microscope
Scanning tunneling microscope-induced light emission.
This work is supported in part by MEXT (Ministry of Education, Culture, Sports, Science and Technology) through the G-COE (Special Coordination Funds for the Global Center of Excellence) program ‘Atomically Controlled Fabrication Technology’, Grant-in-Aid for Scientific Research on Innovative Areas Program (2203-22104008), and Scientific Research (c) Program (22510107). It was also supported in part by JST (Japan Science and Technology Agency) through the ALCA (Advanced Low Carbon Technology Research and Development) Program ‘Development of Novel Metal-Air Secondary Battery Based on Fast Oxide Ion Conductor Nano Thickness Film’ and the Strategic Japanese-Croatian Cooperative Program on Materials Science ‘Theoretical modeling and simulations of the structural, electronic and dynamical properties of surfaces and nanostructures in materials science research’. Some of the calculations presented here were performed in the ISSP (Institute of Solid State Physics) Super Computer Center, University of Tokyo. The authors gratefully acknowledge useful discussions with Professor Wilson Agerico Diño and Professor Hiroshi Nakanishi of Osaka University.
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