Carbonaceous materials have recently received attention in electronic applications and measurement systems. In this work, we demonstrate the electrical behavior of carbon films fabricated by methane arc discharge decomposition technique. The current-voltage (I-V) characteristics of carbon films are investigated in the presence and absence of gas. The experiment reveals that the current passing through the carbon films increases when the concentration of CO2 gas is increased from 200 to 800 ppm. This phenomenon which is a result of conductance changes can be employed in sensing applications such as gas sensors.
Continuous emission of carbon dioxide (CO2) and other greenhouse gases by industrial activities has been increased recently and has led to global warming. This calls for the need to develop low-cost, sensitive, resettable sensors that can be used to monitor the CO2 concentration in industrial exhaust gases [1–3].
Over the past few years, graphene and carbon nanotubes have become the center of attention in the sensor manufacturing technology [4–8]. Furthermore, their unique electrical properties such as tunable conductance and high charge mobility make them ideal for application as sensing medium in nanotechnology [9, 10]. In this paper, we have designed and developed a method for the fabrication of a carbon film material implementing high-voltage AC arc discharge [11–14]. In the proposed system, pure methane in atmospheric pressure is passed over the electrodes inside a Pyrex glass tube chamber where the carbon film fabrication process takes place [15–17]. Once the arc ignites between the graphite electrodes, the methane gas starts to decompose to its constituent species. At the end of this process, a fine soot of carbonaceous material remains between the two electrodes. The material produced this way is then checked through high-resolution optical microscopy as well as scan electron microscopy (SEM) to observe the material physical and structural characteristics. Once the carbon films are grown, the measurement process is carried out.
Arc discharge decomposition
Generally, when a voltage is applied to two electrodes, an electrical potential is created which tends to move electrons from the positive pole to the negative. This is what causes an electric flow of electrons or electric current through a wire or resistance. When there are no conductive wires and/or resistors connecting the two electrodes, i.e., there is either an insulating barrier or simply the ambient air between them, no flow of electrons occurs under normal circumstances for low voltages. In case of high-voltage arc discharge, when the voltage is increased, the methane between the electrodes is ionized. In this situation, the non-conductive medium breaks down and becomes conductive, allowing for the charge carriers to travel through it. This phenomenon occurs very fast and is usually accompanied by sparks and light emissions. As a matter of fact, the electrons inside the gap are accelerated with the applied voltage and cause electron impact ionization. When methane is present in the gap between the electrodes, it will be defragmented into carbon and hydrocarbon species. This electric arc discharge under flowing methane is then used in the experiment for carbon decomposition.
In Figure 1, the complete experimental setup for carbon film fabrication has been demonstrated.
To start the decomposition process, an insulated reactor chamber was designed and fabricated employing a Pyrex glass tube which was enclosed with two Teflon flanges at two ends to prevent gas leakage. A PCB board on which the electrodes were mounted in specific fixed distances was put in this chamber; the distance between them is 1,531 μm. One end of the Pyrex tube reactor was attached to a gas flow controller (PC-controlled, model Sierra Co. CA, USA) and the gas cylinder, while the other end was connected to a gas bubbler tube so as to absorb the pollutant gases from the reactor outlet released after the decomposition process. Different values of pure methane gas (200 to 800 ppm) were passed through the chamber using a gas flow meter. A pressure regulator was implemented to make sure the gas flow had the atmospheric pressure. Single-phase AC electrical power was fed to a high-voltage power supply with built-in amplifier to control and manipulate the operating voltage. This voltage was then increased to kilovolt scale using a step-up neon transformer. The neon transformer was used at normal operating frequency (50 Hz) to produce high voltage. This high voltage was applied to the two electrodes to start the methane decomposition process. To monitor the applied high voltage, a high-voltage probe Tektronix (20 kV DC/40 kV AC, US Patent 015-049, ×1:1,000; Beaverton, OR, USA) was coupled to a four-channel oscilloscope (LeCroy, Chestnut Ridge, NY, USA; WJ354A WaveJet 354A, 500 MHz, 4 CHs, 500 kp/Ch, 1 GS/s) to record the signal measurements. Details of the operating parameters of the arc discharge methane decomposition process are provided in Table 1.
Operating parameters of carbon strands
At room environment
1 to 26 kV
200 to 800 ppm
Pure methane (99.99%)
Diagnostics of the carbon film
Once the arc discharge is initiated, methane decomposition starts causing the resultant carbon atoms to deposit and stack up between the two electrodes creating a conductive bridge. The growth time was measured to be 11.6 s at the voltage of 16.4 kV. The carbon film fabricated in this process is inspected using high-resolution optical microscopy, as shown in Figure 2. There are three configurations for installing the electrodes on the PCB board, namely, plane to plane (PTP), tip to plane (TTP), and tip to tip (TTT); however, in this study, we have only investigated the TTT structure.
Inspection by scan electron microscopy
A scanning electron microscope (SEM) scans the samples with a focused beam of electrons. As the electrons collide with the atoms in the sample, they produce various signals which can be detected and measured . These signals provide information about the surface topography and composition of the sample. Microphotographic images from SEM have been provided in Figure 3a,b,c,d.
Among all types of carbon allotropes, only graphene, graphite, and CNTs show electrical conductivity. On the other hand, the carbon films also show conducting behavior. This implies that the grown carbonaceous materials belong to one of the above types of graphitized carbon. With reference to similar images from carbon materials published in the literature [19–21], it can be observed by comparison that the scanned material is composed of carbon.
Results of optical emission spectroscopy
The optical emission during arc discharge decomposition was captured in the wavelengths ranging from 385 to 750 nm through a spectrophotometer (StellarNet, Tampa, FL, USA), and the data of the recorded spectra was sketched using MATLAB software. Three evolved peaks of methane species were prominent which belong to CH, C2, and Hα as shown in Figures 4 and 5. As illustrated in Figure 4, the spectrum consists of the evolved phase of ionized species of methane which indicates peaks of CH at 397 and 431 nm, swan band C2 appearing at 516.75, and hydrogen Hα appearing at 657.33 nm. These species represent the phenomenon of methane cracking under high-voltage arc discharge conditions as described in recent studies . As soon as the gas breakdown occurs, plasma species will react with each other through ionization and recombination, and the gas enters another phase as shown in Figure 5 which is similar to black body curve. This phenomenon reflects the burning effect of carbon species during carbon deposition on sensor template. It was observed that the carbon agglomeration occurs at high temperatures which helps in the deposition of carbon between the electrodes on the PCB-designed sensor templates .
The results of the evolved species in the second phase are different from initial ionization process of pure methane regarding the evolved species. In the second phase, the high peak belongs to C2 radical which also indicates that the concentration of C2 is much higher in the methane plasma than the other evolved species. The second spectrum also indicates the pyrolysis process of gaseous hydrocarbons that causes carbon deposition between electrodes. The evolved species consist of swan band C2 which appears at 516.75 nm and C2 at 590 nm, while the two peaks corresponding to hydrogen Hα and CH are absent.
The appearances of the peaks in the spectra of both phases of pure methane are listed in Table 2.
Species of pure methane evolved during decomposition process
Excitation energy (eV)
Evolved in first phase
Evolved in second phase
Measurements of electrical characteristics
Once the carbon film was produced, a series of low DC voltage measurements were conducted on them in order to reveal their actual current-voltage characteristics. To do this, a DC power supply was employed to apply low voltage to the two electrodes and the carbon film in between. Figure 6 provides a schematic of the electrical circuit implemented in the measurements. The voltage was increased from 0 to 5 V, and the corresponding currents passing through the circuit were recorded using a micro-Ampermeter.
Results and discussion
After growing the carbon film, both sides of the chamber must be opened to release the methane gas inside it. After about 20 min, when there is almost no gas present in the chamber, we start to apply the DC voltage and measure the resulting I-V characteristics. The measurements were repeated in the presence of gas with concentrations of 200, 400, and 800 ppm. The current-voltage readings are provided in Figure 7a,b,c,d,e.
In the presence of gas, higher values of current were read which proves the higher conductivity when the carbon films are subjected to gas. Also, as the concentration of gas was increased from 200 to 800 ppm, the current passing through the channel increased further. This phenomenon can be explained by the fact that gas molecules are adsorbed on the carbon film surface and will increase channel conductivity.
In the next step of the study, in order to provide a platform for analytical investigations, MATLAB software was used to fit a curve of exponential form to the corresponding set of experimental data with maximum accuracy (regressions very close to 1). The resulting formula is in the form of Equation 1.
Constants a, b, c, and d in Equation 1 and the corresponding regression values as well as R2, SSE, and RMSE errors are provided in Table 3.
Values for parameters a, b, c, and d and the corresponding regressions
F(x) = aexp(bx) + cexp(dx)
7.859e + 5
−7.859e + 5
2.999e + 6
−2.999 + 6
A set of experiments were carried out to fabricate carbon films using high-voltage arc discharge methane decomposition method. High-resolution optical microscopy as well as OES and SEM imaging techniques were implemented to verify the fact that the substances obtained are carbonaceous materials. The carbon films were then used as the channel in an electrical circuit to measure their current-voltage characteristics. Among all types of carbon allotropes, only graphene, graphite, and CNTs show electrical conductivity. On the other hand, the carbon films also show conducting behavior. This implies that the grown carbon films belong to one of the above types of graphitized carbon. It was observed that higher currents pass through the channel when it is exposed to higher concentrations of gas. A mathematical model was obtained for the experimental results using MATLAB curve fitting tool. With the aid of this mathematical representation, it will be possible to characterize and predict the electrical behavior of the carbon films. This will provide a reliable mathematical model which can be used in gas sensing applications to minimize the need for conducting experimental studies.
The authors would like to thank Ministry of Education (MOE), Malaysia (grant Vot. No. 4 F382) and the Universiti Teknologi Malaysia (grant Vot. No. 07H56) for the financial support received during the investigation.
Centre for Artificial Intelligence and Robotics (CAIRO), Universiti Teknologi Malaysia
Institute of High Voltage & High Current, Faculty of Electrical Engineering, Universiti Teknologi Malaysia
Faculty of Mechanical Engineering, Universiti Teknologi Malaysia
Department of Chemistry, Faculty of Science, Universiti Teknologi Malaysia
Institute of Advanced Photonics Science, Nanotechnology Research Alliance, Universiti Teknologi Malaysia
Faculty of Computing, Universiti Teknologi Malaysia (UTM)
Akbari E, Ahmadi MT, Kiani MJ, Feizabadi HK, Rahmani M, Khalid M: Monolayer graphene based CO2 gas sensor analytical model. J Comput Theor Nanosci 2013, 10(6):1301–1304. 10.1166/jctn.2013.2846View Article
Haberle RM, Forget F, Colaprete A, Schaeffer J, Boynton WV, Kelly NJ, Chamberlain MA: The effect of ground ice on the Martian seasonal CO2 cycle. Planetary and Space Scine 2008, 56(2):251–255. 10.1016/j.pss.2007.08.006View Article
Akbari E, Yousof R, Ahmadi MT, Kiani MJ, Rahmani M, Abadi HF, Saeidmanesh M: The Effect of Concentration on Gas Sensor Model Based on Graphene Nanoribbon. Neural Comput & Applic 2014, 24(1):143–146. 10.1007/s00521-013-1463-2View Article
Cole BE, Zook DJ: Carbon Nanotube Sensor. Google Patents; 2006. U.S. Patent No. 7,057,402. Washington, DC: U.S. Patent and Trademark Office; 2006.
Li J, Lu Y, Ye Q, Cinke M, Han J, Meyyappan M: Carbon nanotube sensors for gas and organic vapor detection. Nano Lett 2003, 3(7):929–933. 10.1021/nl034220xView Article
Star A, Ding M: Detection of Hydrogen Sulfide Gas Using Carbon Nanotube-Based Chemical Sensors. U.S. Patent Application 13/251,811, filed October 3, 2011 U.S. Patent Application 13/251,811, filed October 3, 2011
Sayago I, Fernandez MJ, Fontecha JL, Horrillo MC, Terrado E, Seral-Ascaso A, Munoz E: Carbon nanotube-based SAW sensors. Electron Devices (CDE) 2013. Spanish Conference on. (pp. 127–130).IEEE; 2013 Spanish Conference on. (pp. 127-130).IEEE; 2013
Kiani MJ, Ahmadi MT, Akbari E, Karimi H, Che Harun FK: Graphene nanoribbon based gas sensor. Key Eng Mater 2013, 553: 7–11.View Article
Novoselov K, Fal VI, Colombo L, Gellert PR, Schwab MG, Kim K: A roadmap for graphene. Nature 2012, 490(7419):192–200. 10.1038/nature11458View Article
Akbari E, Akbari E, Buntat Z, Ahmad MH, Enzevaee A, Yousof R, Iqbal SMZ, Karimi H: Analytical calculation of sensing parameters on carbon nanotube based gas sensors. Sensors 2014, 14(3):5502–5515. 10.3390/s140305502View Article
Valentini L, Armentano I, Kenny JM, Cantalini C, Lozzi L, Santucci S: Sensors for sub-ppm NO 2 gas detection based on carbon nanotube thin films. Appl Phys Lett 2003, 82(6):961–963. 10.1063/1.1545166View Article
Battie Y, Ducloux O, Thobois P, Dorval N, Lauret JS, Attal-Trétout B, Loiseau A: Gas sensors based on thick films of semi-conducting single walled carbon nanotubes. Carbon 2011, 49(11):3544–3552. 10.1016/j.carbon.2011.04.054View Article
Adjizian J-J, Leghrib R, Koos AA, Suarez-Martinez I, Crossley A, Wagner P, Ewels CP: Boron-and nitrogen-doped multi-wall carbon nanotubes for gas detection. Carbon 2014, 66: 662–673.View Article
Iqbal SMZ: Decomposition of Methane Into Carbonaceous Material Using Arc Discharge Method. 2014.
Muradov N: Catalysis of methane decomposition over elemental carbon. Catal Commun 2001, 2(3):89–94.View Article
Akbari E, Buntat Z, Enzevaee A, Ebrahimi M, Yazdavar AH, Yusof R: Analytical Modelling and Simulation of IV Characteristics in Carbon Nanotube Based Gas Sensors Using ANN and SVR Methods. Chemometrics and Intelligent Laboratory Systems. Elsevier; 2014.
Moon YK, Lee J, Lee JK, Kim TK, Kim SH: Synthesis of length-controlled aerosol carbon nanotubes and their dispersion stability in aqueous solution. Langmuir 2009, 25(3):1739–1743. 10.1021/la8031368View Article
Lee EK, Lee SY, Han GY, Lee BK, Lee T-J, Jun JH, Yoon KJ: Catalytic decomposition of methane over carbon blacks for CO2-free hydrogen production. Carbon 2004, 42(12–13):2641–2648. 10.1016/j.carbon.2004.06.003View Article
Zhang J, Jin L, Li Y, Si H, Qiu B, Hu H: Hierarchical porous carbon catalyst for simultaneous preparation of hydrogen and fibrous carbon by catalytic methane decomposition. Int J Hydrog Energy 2013, 38(21):8732–8740. 10.1016/j.ijhydene.2013.05.012View Article
Patel N, Bazzanella RFN, Miotello A: Enhanced Hydrogen Production by Hydrolysis of NaBH4 Using “Co-B nanoparticles supported on Carbon film” Catalyst Synthesized by Pulsed Laser Deposition. Elsevier, Catalysis Today 170; 2011:20–26.
Fantini C, Jorio A, Souza M, Strano MS, Dresselhaus MS, Pimenta MA: Optical transition energies for carbon nanotubes from resonant Raman spectroscopy: environment and temperature effects. Phys Rev Lett 2004, 93(14):147406.View Article
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