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Table 3 Results from the GPC analysis of degrafted PMMAM nth = ([M]o/[I]o)(M wof Methyl methacrylate)(conversion)/100 = 1.5 × 105(g/mol)

From: Grafting of Poly(methyl methacrylate) Brushes from Magnetite Nanoparticles Using a Phosphonic Acid Based Initiator by Ambient Temperature Atom Transfer Radical Polymerization (ATATRP)

Sl. no

Time (h)

M n × 103(g/mol)

PDI

% weight lossa

Grafting densityb

Initiator efficiency

1

3

17.6

2.46

75

0.85

0.43

2

6

27

2.39

80

0.74

0.40

3

9

32

2.36

87

1.07

0.55

4

12

42

1.94

88

0.89

0.45

5

15

50

2.00

90

0.92

0.47

  1. aDetermined by thermogravimetric analysis
  2. bGrafting density calculated using Eq. 1 in chains/nm2

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