Experimental and theoretical studies of nanofluid thermal conductivity enhancement: a review
© Kleinstreuer and Feng; licensee Springer. 2011
Received: 1 October 2010
Accepted: 16 March 2011
Published: 16 March 2011
The Erratum to this article has been published in Nanoscale Research Letters 2011 6:439
Nanofluids, i.e., well-dispersed (metallic) nanoparticles at low- volume fractions in liquids, may enhance the mixture's thermal conductivity, knf, over the base-fluid values. Thus, they are potentially useful for advanced cooling of micro-systems. Focusing mainly on dilute suspensions of well-dispersed spherical nanoparticles in water or ethylene glycol, recent experimental observations, associated measurement techniques, and new theories as well as useful correlations have been reviewed.
It is evident that key questions still linger concerning the best nanoparticle-and-liquid pairing and conditioning, reliable measurements of achievable knf values, and easy-to-use, physically sound computer models which fully describe the particle dynamics and heat transfer of nanofluids. At present, experimental data and measurement methods are lacking consistency. In fact, debates on whether the anomalous enhancement is real or not endure, as well as discussions on what are repeatable correlations between knf and temperature, nanoparticle size/shape, and aggregation state. Clearly, benchmark experiments are needed, using the same nanofluids subject to different measurement methods. Such outcomes would validate new, minimally intrusive techniques and verify the reproducibility of experimental results. Dynamic knf models, assuming non-interacting metallic nano-spheres, postulate an enhancement above the classical Maxwell theory and thereby provide potentially additional physical insight. Clearly, it will be necessary to consider not only one possible mechanism but combine several mechanisms and compare predictive results to new benchmark experimental data sets.
A nanofluid is a dilute suspension of nanometer-size particles and fibers dispersed in a liquid. As a result, when compared to the base fluid, changes in physical properties of such mixtures occur, e.g., viscosity, density, and thermal conductivity. Of all the physical properties of nanofluids, the thermal conductivity (knf) is the most complex and for many applications the most important one. Interestingly, experimental findings have been controversial and theories do not fully explain the mechanisms of elevated thermal conductivity. In this paper, experimental and theoretical studies are reviewed for nanofluid thermal conductivity and convection heat transfer enhancement. Specifically, comparisons between thermal measurement techniques (e.g., transient hot-wire (THW) method) and optical measurement techniques (e.g., forced Rayleigh scattering (FRS) method) are discussed. Recent theoretical models for nanofluid thermal conductivity are presented and compared, including the authors' model assuming well-dispersed spherical nanoparticles subject to micro-mixing effects due to Brownian motion. Concerning theories/correlations which try to explain thermal conductivity enhancement for all nanofluids, not a single model can predict a wide range of experimental data. However, many experimental data sets may fit between the lower and upper mean-field bounds originally proposed by Maxwell where the static nanoparticle configurations may range from a dispersed phase to a pseudo-continuous phase. Dynamic knf models, assuming non-interacting metallic nano-spheres, postulate an enhancement above the classical Maxwell theory and thereby provide potentially additional physical insight. Clearly, it will be necessary to consider not only one possible mechanism but combine several mechanisms and compare predictive results to new benchmark experimental data sets.
Nanofluids are a new class of heat transfer fluids by dispersing nanometer-size particles, e.g., metal-oxide spheres or carbon nanotubes, with typical diameter scales of 1 to 100 nm in traditional heat transfer fluids. Such colloidal dispersions may be uniform or somewhat aggregated. Earlier experimental studies reported greater enhancement of thermal conductivity, knf, than predicted by the classical model of Maxwell , known as the mean-field or effective medium theory. For example, Masuda  showed that different nanofluids (i.e., Al2O3-water, SiO2-water, and TiO2-water combinations) generated a knf increase of up to 30% at volume fractions of less than 4.3%. Such an enhancement phenomenon was also reported by Eastman and Choi  for CuO-water, Al2O3-water and Cu-Oil nanofluids, using the THW method. In the following decades, it was established that nanofluid thermal conductivity is a function of several parameters [4, 5], i.e., nanoparticle material, volume fraction, spatial distribution, size, and shape, as well as base-fluid type, temperature, and pH value. In contrast, other experimentalists [6–9], reported that no correlation was observed between knf and nanofluid temperature T. Furthermore, no knf enhancement above predictions based on Maxwell's effective medium theory for non-interacting spherical nanoparticles was obtained . Clearly, this poses the question if nanofluids can provide greater heat transfer performance, as it would be most desirable for cooling of microsystems. Some scientists argued that the anomalous knf enhancement data are caused by inaccuracies of thermal measurement methods, i.e., mainly intrusive vs. non-intrusive techniques. However, some researchers [10, 11], relying on both optical and thermal measurements, reported knf enhancements well above classical model predictions. When comparing different measurement methods, error sources may result from the preparation of nanofluids, heating process, measurement process, cleanliness of apparatus, and if the nanoparticles stay uniformly dispersed in the base fluid or aggregate . Thus, the controversy is still not over because of those uncertainties.
Experimental measurement methods
Transient hot-wire method
THW method is the most widely used static, linear source experimental technique for measuring the thermal conductivity of fluids. A hot wire is placed in the fluid, which functions as both a heat source and a thermometer [20, 21]. Based on Fourier's law, when heating the wire, a higher thermal conductivity of the fluid corresponds to a lower temperature rise. Das  claimed that during the short measurement interval of 2 to 8 s, natural convection will not influence the accuracy of the results.
For the experimental procedure, the wire is heated via a constant electric power supply at step time t. A temperature increase of the wire is determined from its change in resistance which can be measured in time using a Wheatstone-bridge circuit. Then the thermal conductivity is determined from Eq. 4, knowing the heating power (or heat flux q) and the slope of the curve ln(t) versus T.
The advantages of THW method are low cost and easy implementation. However, the assumptions of an infinite wire-length and the ambient acting like a reservoir (see Eqs. 1 and 2c) may introduce errors. In addition, nanoparticle interactions, sedimentation and/or aggregation as well as natural convection during extended measurement times may also increase experimental uncertainties [19, 23].
Other thermal measurement methods
A number of improved hot-wire methods and experimental designs have been proposed. For example, Zhang  used a short-hot-wire method (see also Woodfield ) which can take into account boundary effects. Mintsa  inserted a mixer into his THW experimental devices in order to avoid nanoparticle aggregation/deposition in the suspensions. Ali et al.  combined a laser beam displacement method with the THW method to separate the detector and heater to avoid interference.
Alternative static experimental methods include the temperature oscillation method [16, 17, 28], micro-hot-strip method , steady-state cut-bar method , 3-ω method [18, 31, 32], radial heat-flow method , photo-thermal radiometry method , and thermal comparator method [19, 35].
Summary of experimental studies on convective heat transfer properties of nanofluids
Pak and Cho 
dp = 13 nm spherical Al2O3-water
dp = 27 nm spherical TiO2-water
Nu is 30% larger than conventional base fluid and larger than Dittus-Boelter prediction
Li and Xuan 
dp < 100 nm spherical Cu-water
Nu is larger than Dittus-Boelter prediction when volume fraction φ > 0.5%
Wen and Ding 
dp = 27-56 nm spherical Al2O3-water
Nu > 4.36 for fully-developed pipe flow with constant wall heat flux
dp > 100 nm rodlike carbon nanotube-water
Nu increase more than 300% at Re = 800
dp = 20 nm spherical Al2O3-water
Nu measured is larger than Nu of pure water
dp = 46 nm spherical Al2O3-water
dp = 60 nm spherical ZrO2-water
Nu of nanofluids can be predicted by traditional correlations and models. No abnormal heat transfer enhancement was observed.
dp = 40-50 nm spherical Al2O3-water rodlike carbon nanotube-oil
Nu is apparently larger than pure based fluid
dp = 21 nm spherical TiO2-water
Pak and Cho (1998) correlation show better agreement to experimental data of Nu than Xuan and Li (2002) correlation
dp = 50 nm spherical Al2O3-water
dp = 50 nm spherical ZrO2-water
Nu of Al2O3-water nanofluid show up to 27% more than pure water, ZrO2-water displays much lower enhancement.
dp = 170 nm spherical Al2O3-water
dp = 170 nm spherical Al2O3-ethylene glycol
Nu increases with increasing the Reynolds number in laminar flow regime, appreciable enhancement of Nu is measured
Nu increases with increasing the Peclet number and φ, Brownian motion may play role in convective heat transfer enhancement
Actually, "convective" knf values are not directly measured. Instead, wall temperature Tw and bulk temperature Tb are obtained and the heat transfer coefficient is then calculated as h = qw/(Tw - Tb). From the definition of the Nusselt number, knf = hD/Nu where generally D is the hydraulic diameter. With h being basically measured and D known, either an analytic solution or an iterative numerical evaluation of Nu is required to calculate knf. Clearly, the accuracy of the "convective measurement method" largely depends on the degree of uncertainties related to the measured wall and bulk temperatures as well as the computed Nusselt number.
Optical measurement methods
In recent years, optical measurement methods have been proposed as non-invasive techniques for thermal conductivity measurements to improve accuracy [6–9, 13, 11, 27, 37]. Indeed, because the "hot wire" is a combination of heater and thermometer, interference is unavoidable. However, in optical techniques, detector and heater are always separated from each other, providing potentially more accurate data. Additionally, measurements are completed within several microseconds, i.e., much shorter than reported THW-measurement times of 2 to 8 s, so that natural convection effects are avoided.
For example, Rusconi [6, 38] proposed a thermal-lensing (TL) measurement method to obtain knf data. The nanofluid sample was heated by a laser-diode module and the temperature difference was measured by photodiode as optical signals. After post-processing, the thermal conductivity values were generated, which did not exceed mean-field theory results. Similar to the TL method, FRS have been used to investigate the thermal conductivity of well-dispersed nanofluids [8, 39]. Again, their results did not show any anomalous enhancement either for Au-or Al2O3-nanofluids. Also, based on their data, no enhancement of thermal conductivity with temperature was observed. In contrast, Buongiorno et al.  presented data agreement when using both the THW method and FRS method. Another optical technique for thermal conductivity measurements of nanofluids is optical beam deflection [7, 40]. The nanofluid is heated by two parallel lines using a square current. The temperature change of nanofluids can be transformed to light signals captured by dual photodiodes. For Au-nanofluids, Putnam  reported significantly lower knf enhancement than the data collected with the THW method.
However, other papers based on optical measurement techniques showed similar enhancement trends for nanofluid thermal conductivities as obtained with the thermal measurement methods. For example, Shaikh et al.  used the modern light flash technique (LFA 447) and measured the thermal conductivity of three types of nanofluids. They reported a maximum enhancement of 161% for the thermal conductivity of carbon nanotube (CNT)-polyalphaolefin (PAO) suspensions. Such an enhancement is well above the prediction of the classical model by Hamilton and Crosser . Also, Schmidt et al.  compared experimental data for Al2O3-PAO and C10H22-PAO nanofluids obtained via the Transient Optical Grating method and THW method. In both cases, the thermal conductivities were greater than expected from classical models. Additionally, Bazan  executed measurements by three different methods, i.e., laser flash (LF), transient plane source, and THW for PAO-based nanofluids. They concluded that the THW method is the most accurate one while the LF method lacks precision when measuring nanofluids with low thermal conductivities. Also, no correlation between thermal conductivity and temperature was observed. Clearly, materials and experimental methods employed differ from study to study, where some of the new measurement methods were not verified repeatedly [6, 7]. Thus, it will be necessary for scientists to use different experimental techniques for the same nanofluids in order to achieve high comparable accuracy and prove reproducibility of the experimental results.
Nearly all experimental results before 2005 indicate an anomalous enhancement of nanofluid thermal conductivity, assuming well-dispersed nanoparticles. However, more recent efforts with refined transient hot-wire and optical methods spawned a controversy on whether the anomalous enhancement beyond the mean-field theory is real or not. Eapen et al.  suggested a solution, arguing that even for dilute nanoparticle suspensions knf enhancement is a function of the aggregation state and hence connectivity of the particles; specifically, almost all experimental knf data published fall between lower and upper bounds predicted by classical theories.
In summary, knf is likely to improve with nanoparticle volume fraction and temperature as well as particle diameter, conductivity, and degree of aggregation, as further demonstrated in subsequent sections.
Thermal conductivity knfvs. volume fraction φ
Most experimental observations of nanofluids with just small nanoparticle volume fractions showed that knf will significantly increase when compared to the base fluid. For example, Lee and Choi  investigated CuO-water/ethylene glycol nanofluids with particle diameters 18.6 and 23.6 nm as well as Al2O3-water/ethylene glycol nanofluids with particle diameters 24.4 and 38.4 nm and discovered a 20% thermal conductivity increase at a volume fraction of 4%. Wang  measured a 12% increase in knf for 28-nm-diameter Al2O3-water and 23 nm CuO-water nanofluids with 3% volume fraction. Li and Peterson  provided thermal conductivity expressions in terms of temperature (T) and volume fraction (φ) by using curve fitting for CuO-water and Al2O3-water nanofluids. For non-metallic particles, i.e., SiC-water nanofluids, Xie  showed a knf enhancement effect. Recently, Mintsa  provided new thermal conductivity expressions for Al2O3-water and CuO-water nanofluids with particle sizes of 47, 36, and 29 nm by curve fitting their in-house experimental data obtained by the THW method. Murshed  measured a 27% increase in 4% TiO2-water nanofluids with particle size 15 nm and 20% increase for Al2O3-water nanofluids. However, Duangthongsuk  reported a more moderate increase of about 14% for TiO2-water nanofluids. Quite surprising, Moghadassi  observed a 50% increment of thermal conductivity for 5% CuO-monoethylene glycol (MEG) and CuO-paraffin nanofluids.
Thermal conductivity knfvs. temperature T
Das  systematically discussed the relationship between thermal conductivity and temperature for nanofluids, noting significant increases of knf (T). More recently, Abareshi et al.  measured the thermal conductivity of Fe3O4-water with the THW method and asserted that knf increases with temperature T. Indeed, from a theoretical (i.e., kinetics) view-point, with the increment of the nanofluid's bulk temperature T, molecules and nanoparticles are more active and able to transfer more energy from one location to another per unit time.
In contrast, many scientists using optical measurement techniques found no anomalous effective thermal conductivity enhancement when increasing the mixture temperature [[6–9, 29, 30, 37, 49], etc.]. Additionally, Tavman et al.  measured SiO2-water, TiO2-water, and Al2O3-water by the 3-ω method and claimed, without showing actual data points, that there is no anomalous thermal conductivity enhancement with increment of both volume fraction and temperature. Whether anomalous enhancement relationship between knf and temperature T exist or not is still open for debate.
Dependence of knfon other parameters
Potentially influential parameters on thermal conductivity, other than volume fraction and temperature, include pH value, type of base fluid, nanoparticle shape, degree of nanoparticle dispersion/interaction, and various additives. For example, Zhu et al.  showed that the pH of a nanofluid strongly affects the thermal conductivity of suspensions. Indeed, pH value influence the stability of nanoparticle suspensions and the charges of the particle surface thereby affect the nanofluid thermal conductivity. For pH equal to 8.0-9.0, the thermal conductivity of nanofluid is higher than other situations  Of the most common base fluids, water exhibits a higher thermal conductivity when compared to ethylene glycol (EG) for the same nanoparticle volume fraction [43, 44, 51–53]. However, thermal conductivity enhancement of EG-based nanofluids is stronger than for water-based nanofluids [42, 43]. Different particle shapes may also influence the thermal conductivity of nanofluids. Nanoparticles with high aspect ratios seem to enhance the thermal conductivity further. For example, spherical particles show slightly less enhancement than those containing nanorods , while the thermal conductivity of CuO-water-based nanofluids containing shuttle-like-shaped CuO nanoparticles is larger than those for CuO nanofluids containing nearly spherical CuO nanoparticles . Another parameter influencing nanofluid thermal conductivity is particle diameter. Das , Patel  and Chon  showed the inverse dependence of particle size on thermal conductivity enhancement, considering three sizes of alumina nanoparticles suspended in water. Beck et al.  and Moghadassi et al.  reported that the thermal conductivity will increase with the decrease of nanoparticle diameters. However, Timofeeva et al.  reported that knf increases with the increment of nanoparticle diameter for SiC-water nanofluids without publishing any data. Other factors which may influence the thermal conductivity of nanofluids are sonification time  and/or surfactant mass fraction  to obtain well-dispersed nanoparticles.
For other new experimental data, Wei X. et al.  reported nonlinear correlation between knf and synthesis parameters of nanoparticles as well as temperature T. Li and Peterson  showed natural convection deterioration with increase in nanoparticle volume fraction. This may be because the nanoparticle's Brownian motion smoothen the temperature gradient leading to the delay of the onset of natural convection. Also, higher viscosity of nanofluids can also induce such an effect. Wei et al.  claimed that the measured apparent thermal conductivity show time-dependent characteristics within 15 min when using the THW method. They suggested that measurements should be made after 15 min in order to obtain accurate data. Chiesa et al.  investigated the impact of the THW apparatus orientation on thermal conductivity measurements; however, that aspect was found not to be significant. Shalkevich et al.  reported no abnormal thermal conductivity enhancement for 0.11% and 0.00055% of gold nanoparticle suspensions, which are rather low volume fractions. Beck et al.  and Teng et al.  provided curve-fitted results based on their in-house experimental data, reflecting correlations between knf and several parameters, i.e., volume fraction, bulk temperature and particle size. Both models are easy to use for certain types of nanofluids. Ali et al.  proposed hot wire-laser probe beam method to measure nanofluid thermal conductivity and confirmed that particle clustering has a significant effect on thermal conductivity enhancement.
Significant differences among published experimental data sets clearly indicate that some findings were inaccurate. Theoretical analyses, mathematical models, and associated computer simulations may provide additional physical insight which helps to explain possibly anomalous enhancement of the thermal conductivity of nanofluids.
Classical models for effective thermal conductivity of mixtures
Dynamical models and comparisons with experimental data
When using the classical models, it is implied that the nanoparticles are stationary to the base fluid. In contrast, dynamic models are taking the effect of the nanoparticles' random motion into account, leading to a "micro-mixing" effect . In general, anomalous thermal conductivity enhancement of nanofluids may be due to:
heat-resistance lowering liquid-molecule layering at the particle surface;
higher heat conduction in metallic nanoparticles;
preferred conduction pathway as a function of nanoparticle shape, e.g., for carbon nanotubes;
augmented conduction due to nanoparticle clustering.
Up front, while the impact of micro-scale mixing due to Brownian motion is still being debated, the effects of nanoparticle clustering and preferred conduction pathways also require further studies.
Oezerinc et al.  systematically reviewed existing heat transfer mechanisms which can be categorized into conduction, nano-scale convection and/or near-field radiation , thermal waves propagation [67, 72], quantum mechanics , and local thermal non-equilibrium .
For a better understanding of the micro-mixing effect due to Brownian motion, the works by Leal  and Gupte  are of interest. Starting with the paper by Koo and Kleinstreuer , several models stressing the Brownian motion effect have been published . Nevertheless, that effect leading to micro-mixing was dismissed by several authors. For example, Wang  compared Brownian particle diffusion time scale and heat transfer time scale and declared that the effective thermal conductivity enhancement due to Brownian motion (including particle rotation) is unimportant. Keblinski  concluded that the heat transferred by nanoparticle diffusion contributes little to thermal conductivity enhancement. However, Wang  and Keblinski  failed to consider the surrounding fluid motion induced by the Brownian particles.
Kumar  proposed a "moving nanoparticle" model, where the effective thermal conductivity relates to the average particle velocity which is determined by the mixture temperature. However, the solid-fluid interaction effect was not taken into account.
Summary and future work
Nanofluids, i.e., well-dispersed metallic nanoparticles at low volume fractions in liquids, enhance the mixture's thermal conductivity over the base-fluid values. Thus, they are potentially useful for advanced cooling of micro-systems. Still, key questions linger concerning the best nanoparticle-and-liquid pairing and conditioning, reliable measurements of achievable knf values, and easy-to-use, physically sound computer models which fully describe the particle dynamics and heat transfer of nanofluids. At present, experimental data and measurement methods are lacking consistency. In fact, debates are still going on whether the anomalous enhancement is real or not, and what are repeatable correlations between knf and temperature, nanoparticle size/shape, and aggregation state. Clearly, additional benchmark experiments are needed, using the same nanofluids subject to different measurement methods as well as variations in nanofluid characteristics. This would validate new, minimally intrusive techniques and verify the reproducibility of experimental results.
Concerning theories/correlations which try to explain thermal conductivity enhancement for all nanofluids, not a single model can predict a wide range of experimental observations. However, many experimental data sets may fit between the lower and upper mean-field bounds originally proposed by Maxwell , where the static nanoparticle configurations may range between the two extremes of a dispersed phase to a continuous phase. Dynamic knf models postulate an enhancement above the classic Maxwell theory and thereby provide additional physical insight. Clearly, it will be necessary to consider not only one possible mechanism but combine several mechanisms and compare predictive results to new benchmark experimental data sets.
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