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Nonlinear thermooptical properties of twolayered spherical system of gold nanoparticle core and water vapor shell during initial stage of shell expansion
Nanoscale Research Letters volumeÂ 6, ArticleÂ number:Â 448 (2011)
Abstract
Nonlinear thermooptical properties of twolayered spherical system of gold nanoparticle core and water vapor shell, created under laser heating of nanoparticle in water, were theoretically investigated. Vapor shell expansion leads to decreasing up to one to two orders of magnitude in comparison with initial values of scattering and extinction of the radiation with wavelengths 532 and 633 nm by system while shell radius is increased up to value of about two radii of nanoparticle. Subsequent increasing of shell radius more than two radii of nanoparticle leads to rise of scattering and extinction properties of system over initial values. The significant decrease of radiation scattering and extinction by system of nanoparticlevapor shell can be used for experimental detection of the energy threshold of vapor shell formation and investigation of the first stages of its expansion.
PACS: 42.62.BE. 78.67. BF
Background
Metal nanoparticles (NPs) and other nanostructures are widely used in nanotechnology, physical chemistry, catalysis, biology, and laser nanomedicine for different purposes during past 10 years [1â€“15] (also see the references in these papers). The determination of sizes, concentrations, and placements of NPs in different media is carried out by different methodstransmission electron microscopy, smallangle Xray scattering, laser scanning microscopy, optical diagnostics, etc. [1â€“15]. In many cases, optical detection and diagnostics of NPs via scattering have the advantages in comparison with others and can be carried out on the base of detection of radiation scattered from NPs placed in some medium (liquid). However, as NP radius r _{0} decreases, the scattered intensity drops as r _{0} ^{6} and, as result, the detection difficulties will be increased [16]. Effective strategy for solving of this difficulty could be the use of nonlinear thermooptical effects as a result of NP optical absorption and heating.
Nonlinear thermooptical effects can be achieved under the action of laser radiation on NP, absorption of laser energy, NP heating, heat exchange with surrounding liquid, and its explosive vaporization. The liquid evaporates around rapidly heated NP, and spherical vapor shell (bubble) is formed near to an NP surface. It is possible to determine the temperature of heated NP, or determine the thermal refractive index change of ambient medium or formation of vapor shell (bubble) in the heated vicinity of absorbing NP [8, 17]. The formation and expansion of vapor nanobubbles is attractive tool for diagnostics and applications in laser nanotechnology [8, 18â€“26]. The resulting shell around laserheated NP can cause spatial confined and highly localized thermomechanical damage to the surrounding medium. This feature should be taken into account for practical applications. The process is observed by means of the detection of transmission and scattering of the probe laser beam with wavelength 633 nm [19, 22â€“26].
Nonlinear thermooptical properties of twolayered spherical system of gold nanoparticle core and water vapor shell, created under laser heating of nanoparticle in water, were theoretically investigated in this paper.
Results and discussion
At fairly short pulses of intense radiation, heating of NP and surrounding liquid medium (water) can occur at the rates of 10^{12} to 10^{14} K/s and more. Intense heat exchange in the surface layer of the NP drops the surface temperature of the NP and raises the temperature of the surrounding layers of water to a value of the order of the explosive ebullition (boiling) temperature of water [27] and higher. The nucleus vapor bubble originated in overheated water around the particle with achievement of threshold temperature in the range of 373 to 647 K (critical temperature for water) [27]. Thereafter, a very rapid (explosive) ebullition of the water occurs and the system goes into an equilibrium state characterized by the generation of a new phasewater vapor. A vapor shell formed around NP has an initial saturated water vapor pressure of about approximately 1 to10^{2} atm at temperature of 100 to 500 C which induces a subsequent rapid expansion of the vapor shell [8].
Experimental investigations of vapor shell (bubble) formation and its dynamics in water under action of laser pulses on NP were carried out in [18â€“26]. It used gold NPs with diameters10 to 250 nm [18, 19], 9 to 100 nm [20, 21], 250 nm [22, 23], and 30 nm [24â€“26] under laser pulse action with wavelengths Î» = 400 nm [20, 21], 532 and 527 nm [22â€“26], and 900 and 1,064 nm [18, 19]. Continuous probe laser (Î» = 633 nm) was used for monitoring of optical transmission through NPshell area and for diagnostics of optical properties of NPs with surrounding vapor shells. Smallangle scattering method of the Xray pulses was used for investigation of bubble properties in [20, 21]. Formation and expansion of vapor bubble with radii of about 3r _{0} and more led to decreasing of transmission of probe laser radiation in mentioned above experiments. Experimental investigations of initial stage of vapor shell expansion did not carry out.
Nonlinear thermooptical properties of twolayered spherical system of gold nanoparticle core and water vapor shell arising under laser heating of nanoparticle in water are theoretically investigated in this paper. The basic attention was given to the research of initial and following stages of bubble expansion. The investigation was performed on the base of theoretical modeling of absorption, scattering, and extinction of laser radiation with wavelengths Î» = 532, 633, and 780 nm by system of NP corevapor shell. It was assumed that the twolayered spherical system consists of a spherical homogeneous core of radius r _{0} with the complex refractive index m _{0} = n _{0}iÎº _{0} of core material (gold), enveloped by the spherically symmetric homogeneous shell of radius r _{1} with the complex refractive index m _{1} = n _{1}iÎº _{1} of water vapor shell. The particle is located in the homogeneous nonabsorbing medium with a refractive index n _{ m } (water). Absorption , scattering , and extinction efficiency cross sections were numerically calculated, where K _{abs}, K _{sca}, and K _{ext} are efficiency factors of absorption, scattering, and extinction of radiation [16] by spherical system NPcore and vaporshell (bubble) with outer shell radius r _{1}.
Refractive index m _{1} of water vapor is presented in [28] in the ranges of radiation wavelengths 404 to 706 nm, temperature 100Â°C to 500Â°C and pressure 1 to 200 bar of water vapor. Analysis of presented values of m _{1} shows that the change of refractive index of water vapor m _{1} in the interval of wavelengths 404 to 780 nm on refractive index m _{1} of water vapor is equal to approximately 0.01% to 0.04% and can be neglected. For computer modeling of optical properties of shell, we choose one average value m _{1} â‰ˆ 1.001i 0. This value of refraction index of water vapor refraction m _{1}[28] can be used in the ranges of pressure approximately 5 to 20 bar and temperatures approximately 100Â°C to 500Â°C with deviation approximately 1%. Such parameters of water vapor are realized in experiments in real situation of formation and dynamics of bubble under action of moderate intensity (energy density) of laser pulses. Investigations of optical properties of pure gas (vapor) bubbles were carried out in [29]. Optical parameters of gold were taken from [30] and for surrounding water from [31].
Figure 1 presents efficiency cross sections of absorption Ïƒ _{abs}, scattering Ïƒ _{sca}, and extinction Ïƒ _{ext} of laser radiation with wavelength 532 nm by twolayered spherical system gold NP core and water vapor shell, placed in water for the range of NP radii r _{0} = 5 to 100 nm and radii of system r _{1} = r _{0} (pure gold NP), r _{1} = r _{0} + 0.1r _{0}, r _{1} = r _{0} + 1r _{0}, r _{1} = r _{0} + 2r _{0}, r _{1} = r _{0} + 3r _{0}, and r _{1} = r _{0} + 4r _{0}, and for homogeneous vapor bubble with radius r _{0} = 5 to 100 nm. Increasing of vapor shell thickness leads to substantial monotonous decreasing of Ïƒ _{abs} from two to eight times for all range of 5 < r _{0} < 100 nm and for the interval of shell vapor thicknesses Î”r _{1} < r _{0}, Î”r _{1} = r _{1}r _{0}. Further increasing of vapor shell thickness weakly influences the Ïƒ _{abs}. It means that the absorbance of laser radiation by the NP is sharply decreased at formation of thin shielded vapor shell and then it is weakly changed for thick shells. Cross section of absorption Ïƒ _{abs} for pure vapor bubble is much smaller than Ïƒ _{abs} for system NPshell and does not present at Figures 1 and 2.
Even appearance of vapor shells with thickness Î”r _{1} â‰¤ r _{0} leads to decrease of Ïƒ _{sca} from 10 to 30 times in the NP radius interval 5 < r _{0} < 50 nm. When Î”r _{1} becomes vastly larger than r _{0} (Î”r _{ 1 } â‰ˆ 4r _{0}), values of Ïƒ _{sca} grow from 10 to 50 times for all values of r _{0} in comparison with initial value Ïƒ _{sca} for pure NP. As to Ïƒ _{ext}, the dependences of the extinction of laser radiation of such system NP corewater vapor shell on r _{0} and vapor shell thickness Î”r _{1} resemble that in the case of scattering. Values of Ïƒ _{ext} decrease for all values of r _{0} in the interval of vapor shell thicknesses Î”r _{1} â‰¤ r _{0} and then grow at first for large values of core radii and thereafter in all intervals of the core sizes. We see nonlinear dependence of Ïƒ _{sca} and Ïƒ _{ext} on vapor shell thickness during bubble formation, and increase of Î”r _{1} till Î”r _{1} â‰¤ r _{0} leads to significant decrease of Ïƒ _{sca} and Ïƒ _{ext}. Following increase of Î”r _{1} > r _{0} leads to increase of Ïƒ _{sca} and Ïƒ _{ext}.
Figure 2 presents efficiency cross sections of absorption Ïƒ _{abs}, scattering Ïƒ _{sca}, and extinction Ïƒ _{ext} of probe laser radiation with wavelength 633 nm by twolayered spherical system gold NP core and water vapor shell for the range of NP radii r _{0} = 5 to 100 nm and different radii of system and for homogeneous vapor bubble with r _{0}. Influence of vapor shell thickness on thermooptical properties of system NPvapor shell for probe radiation with wavelength 633 nm is analogical one as for the case of laser radiation with wavelength 532 nm. It is especially extended to the cross sections of absorption Ïƒ _{abs} of considered NPs. In the case of the cross sections of scattering and extinction character of dependences Ïƒ _{sca}(r _{0}) and Ïƒ _{ext}(r _{0}) for different values of Î”r _{1} are similar. Furthermore, when increasing Î”r _{1} (Î”r _{1} â‰ˆ 4r _{0}), values of Ïƒ _{sca} grow from 100 to 10 times in the dependence on the r _{0}. Notice that the scattering and extinction cross sections of homogeneous water vapor bubbles of different sizes in water are very small and is 23 orders less than for pure gold and twolayered system NPvapor shell (line 7, Figures 1 and 2).
It is well known that the formation of vapor bubble in liquid leads to significant increasing of radiation scattering, and extinction by bubble and bubble itself can be visible [16, 32]. Nonlinear behavior mentioned above (decreasing of Ïƒ _{abs}, Ïƒ _{sca}, and Ïƒ _{ext} during increasing of Î”r _{1} till Î”r _{1} â‰¤ r _{0}) leads to bleaching of medium during initial stage of vapor shell expansion. This behavior exists for different values of m _{1}.
Figure 3 presents efficiency cross sections of absorption Ïƒ _{abs}, scattering Ïƒ _{sca}, and extinction Ïƒ _{ext} of laser radiation with wavelength 780 nm by twolayered spherical system gold NP core and water vapor shell with refractive index of vapor m _{1} = 1,001i 0. The increase of vapor shell thickness till Î”r _{1} < r _{0} for Î» = 780 nm leads to insignificant decrease of efficiency cross sections of absorption Ïƒ _{abs} (10% Ã· 15%), and then, at increase in a shell thickness to five times, absorption grows almost in 10 times (Figure 3a). In the case of scattering and extinction of NPs (Figure 3b,c), the dependencies of Ïƒ _{sca}(r _{0}) and Ïƒ _{ext}(r _{0}) for wavelength 780 nm are similar as for other considered wavelengths.
Figure 4 presents angular distributions (optical indicatrixes) of radiation intensity I _{sca} with wavelengths Î» = 532, 633, and 780 nm scattered by twolayered spherical system gold NP core and water vapor shell for the NP radius r _{0} = 20 nm and different radii of system r _{1}. The increase of vapor shell thickness till Î”r _{1} â‰¤ r _{0} for Î» = 532, 633, and 780 nm leads to decrease of scattered radiation intensity in approximately 50 Ã· 300 times in all scattered directions. Only at Î”r _{1} â‰ˆ 2r _{0} scattering intensity is approximately equal initial distribution of scattered radiation from pure NP. Then, further growth of vapor shell thickness tends to essential increase of scattered radiation intensity (in 20 Ã· 100 times for Î”r _{1} = 4r _{0}) in comparison to the case of pure Au NP. This fact is well correlated with the behavior of Ïƒ _{sca} (Figures 1 and 2). With growth of Î”r _{1}, optical indicatrixes become essentially extended in the forward direction (angle 0Â°). We have to note that mathematical modeling of optical indicatrixes of scattered radiation was independently carried out on the base of optical constants without use of calculated values of Ïƒ _{sca}. This behavior of indicatrixes of scattered radiation is additional evidence of nonlinear (decreasing and increasing) properties of system NP core and vapor shell during initial stages of bubble expansion till r _{1} â‰¤ 2r _{0}.
Figure 5 presents cross sections Ïƒ _{abs} and Ïƒ _{sca} of laser radiation with wavelength 532 nm by twolayered spherical system gold NP core and water vapor shell for the radii r _{0} = 10, 20, 40, 60, 80, and 100 nm as a function of the radii relations r _{1}/r _{0} in the interval of radii r _{1} = (1 to 10)r _{0}. As shown in Figure 4a, absorption cross sections Ïƒ _{abs} are decreased for all range of 1 < r _{1}/r _{0} < 10 and for the interval of core radii 10 nm â‰¤ r _{0} â‰¤ 100 nm. At first, this decrease is reasonably sharp from two to four times, and then after achievement of value Î”r _{1} â‰¤ r _{0}, Ïƒ _{abs} slowly reduces. It is determined by the shielded effect of vapor shell when irradiation cannot reach the absorbing core. The growth of the core radii results in essential increase of absorption cross sections Ïƒ _{abs} as long as r _{0} â‰¤ 60 nm. For r _{0} â‰¤ 60 nm, the dependence of Ïƒ _{abs}(r _{0}) becomes oscillating and undergoes less effect of core radius. Scattering cross sections of Ïƒ _{sca} are also lowered in the interval of 1 < r _{1}/r _{0} < 2 (Figure 4b). Then, Ïƒ _{sca} is sharply increased in the interval r _{1}/r _{0} = 2 to 10. Scattering cross section Ïƒ _{sca} is decreased up to one to two orders of magnitude depending on r _{0}, for example, for r _{0} = 20 nm is decreased from Ïƒ_{sca} = 2.5 Ã— 10^{12} cm^{2} (r _{1}/r _{0} = 1) to Ïƒ _{sca} = 8.5 Ã— 10^{14} cm^{2} (r _{1}/r _{0} = 2) for Î» = 532 nm. After achievement of minimal value, Ïƒ _{sca} increases and at r _{1} = (2 to 3.5) r _{0} cross section Ïƒ _{sca} achieves initial value of Ïƒ _{sca}(r _{1} = r _{0}). It means that the scattering property of system NPvapor shell is equal initial value of Ïƒ _{sca} for pure NP at this value of r _{1}. After this moment, the increase of r _{1}/r _{0} leads to growth of Ïƒ _{sca} up to values two to four orders of magnitude greater than initial values of this one. This effect is due to the complicated twolayered spherical system, and the fact that the growth of vapor shell leads to change of median complex refractive index of twolayered NP: the real part of the complex refractive index increases and the imaginary part is decreased. Therefore, at first, the scattering cross sections of NPs fall and then begin to grow when expanding the vapor shell thickness and value of r _{1}/r _{0} increases.
Figure 6 shows the scattering Ïƒ _{sca} and extinction Ïƒ _{ext} cross sections of probe laser radiation with wavelength 633 nm by twolayered spherical system gold NP core and water vapor shell for the radii r _{0} = 10, 20, 40, 60, 80, and 100 nm as a function of the radii relations r _{1}/r _{0} in the interval of radii r _{1} = (1 to 10) r _{0}. Influence of vapor shell thickness on scattering properties of system NPvapor shell for probe radiation with wavelength 633 nm is analogical as for the laser radiation with wavelength 532 nm. Character of dependences Ïƒ _{sca}(r _{0}) and Ïƒ _{ext}(r _{0}) for different values of r _{0} are similar. Extinction cross section Ïƒ _{ext} is decreased from 2 to 20 times depending on r _{0}, for example, for r _{0} = 40 nm is decreased from Ïƒ _{ext} = 6.2 Ã— 10^{10} cm^{2} (r _{1}/r _{0} = 1) to Ïƒ _{ext} = 3 Ã— 10^{11} cm^{2} (r _{1}/r _{0} = 2) for Î» = 633 nm.
Conclusions
We found the general trends of nonlinear behavior of NPvapor shell systemdecrease of absorption and decrease and subsequent increase of scattering and extinction with increasing of shell radius, beginning from the initial period of shell expansion. Vapor shell formation can produce one to two orders of magnitude of decreasing of scattered radiation during initial stage of shell expansion till radius r _{1} â‰¤ 2r _{0}. The amplification of scattering intensity is mainly due to increasing of shell radius r _{1} > 2r _{0}.
Such behavior of thermooptical properties of spherical system gold NP core and water vapor shell depending of shell thickness Î”r _{1}, NP radius r _{0}, wavelength, and optical properties of vapor (pressure and temperature of vapor) can open new options for optical detection of the moment of vapor shell formation and investigation of the initial stage of its dynamics with small thickness of vapor shell.
Different situations can be realized. Optical detection of single NP is usually realized by irradiation of probe laser radiation and optical detection of scattered radiation and extinction by NP. Suppose that single NP can be visualized using of probe radiation without laser pump irradiation and vapor shell formation, it means that optical scattering of radiation by pure single NP is enough to be detected. After laser pump irradiation and shell formation and during initial stage of shell dynamics with Î”r _{1} â‰¤ r _{0}, intensity of scattered radiation by system NPshell will be decreased (see Figures 1, 2, 3 and 4), and this system could not be visualized. Only after substantial increasing of Î”r _{1} up to Î”r _{1} â‰ˆ (2 to 3) r _{0} and more and increasing of intensity of scattered radiation by system NPshell it will be possible to visualize this system.
Optical detection of system of NPs in some medium is based on the detection of transmitted radiation through this dispersed medium. The formation of vapor shells with small thicknesses on NPs under pump laser irradiation leads to substantial decreasing of Ïƒ _{ext} for probe radiation 633 nm (see Figures 1, 2, and 3). It means that the moment of initial formation of nanoshells around NPs can be detected by increasing of transmitted probe radiation intensity. Then, after substantial increasing of Î”r _{1} > r _{0} up to Î”r _{1} â‰ˆ (2 to 5) r _{0} transmitted probe intensity will be decreased.
Applications of laserinduced vapor nanoshells are proposed for selective tissue damage on the cellular level, anticancer therapy, when selective destruction of cells containing NPs can be triggered due to these ones [3â€“8]. Vapor nanoshells formed around laserheated NPs can serve as contrast agents in optical diagnostics and optoacoustic tomography, etc. Vapor bubble formation around NPs and its expansion can be used for optical limiting and switching in suspensions.
The significant decrease of radiation scattering and extinction by system of nanoparticlevapor shell can be used for experimental detection of the energy threshold of bubble formation and investigation of the first stages of its expansion.
Methods
We used modified Mie theory developed for twolayer spherical system particleshell [33, 32, 34, 35] to model absorption, scattering, and extinction of pump Î» = 532 and 780 nm and probe Î» = 633 nm radiations by spherical system of gold NP core and water vapor shell. The expressions for the optical characteristics of twolayered sphere (efficiency cross sections of absorption, scattering, and extinction) are presented in terms of the amplitude coefficients given by the theory of diffraction of electromagnetic radiation on twolayered spherical particle [33, 32, 34, 35].
Authors' information
VKP is a professor of Belarusian National Technical University, Independence pr. 65, Minsk, 220013, Belarus. LGA is a chief scientist of B.I. Stepanov Institute of Physics, National Academy of Sciences of Belarus, Independence pr. 68, 220072, Minsk, Belarus.
Abbreviations
 NPs:

nanoparticles.
References
Adleman JR, Boyd DA, Goodwin DG, Psaltis D: Heterogeneous catalysis mediated by plasmon heating. Nano Lett 2009, 9: 4417â€“4420. 10.1021/nl902711n
Narayanan R, ElSayed MA: Some aspects of colloidal nanoparticle stability, catalytic activity, and recycling potential. Topics in Catalysis 2008, 47: 15â€“23. 10.1007/s1124400790290
Halas N: The photonic nanomedicine revolution: let the human side of nanotechnology emerge. Nanomedicine 2009, 4: 369â€“375. 10.2217/nnm.09.26
Liu Z, Hung W, Aykol M, Valley D, Cronin S: Optical manipulation of plasmonic nanoparticles, bubble formation and patterning of SERS aggregates. Nanotechnology 2010, 21: 105304. (5 pp) (5 pp) 10.1088/09574484/21/10/105304
Huang X, Jain P, ElSayed MA: Plasmonic photothermal therapy (PPTT) using gold nanoparticles. Lasers Med Sci 2008, 23: 217â€“221. 10.1007/s101030070470x
Jain P, Lee K, ElSayed I, ElSayed M: Calculated absorption and scattering properties of gold nanoparticles of different size, shape and composition: applications in biological imaging and biomedicine. J Phys Chem B 2006, 110: 7238â€“7243. 10.1021/jp057170o
Kim JW, Shashkov E, Galanzha E, Kotarigi V, Zharov V: Photothermal antimicrobial nanotherapy and nanoidiagnostics with selfassembling carbon nanotube clusters. Lasers Surg Med 2007, 39: 622â€“629. 10.1002/lsm.20534
Pustovalov VK, Smetannikov AS, Zharov VP: Photothermal and accompanied phenomena of selective nanophotothermolysis with gold nanoparticles and laser pulses. Laser Phys Lett 2008, 5: 775â€“792. 10.1002/lapl.200810072
Muto H, Miajima K, Mafune F: Mechanism of laserinduced size reduction of gold nanoparticles as studied by laser pulse excitation. J Phys Chem C 2008, 112: 5810â€“5815. 10.1021/jp711353m
Hu M, Petrova H, Chen J, McLellan JM, Siekkinen AR, Marquez M, Li X, Xia Y, Hartland GV: Ultrafast laser studies of the photothermal properties of gold nanocages. J Phys Chem B Lett 2006, 110: 1520â€“1524.
Watanabe M, Takamura H, Sugai H: Preparation of ultrafine FePt alloy and Au nanoparticle colloids by KrF excimer laser solution photolysis. Nanoscale Res Lett 2009, 4: 565â€“571. 10.1007/s1167100992812
Xiao X, Lu J, Li Y: LiMn _{ 2 } O _{ 4 } microspheres: synthesis, characterization and use as a cathode in lithium ion batteries. Nano Res 2010, 3: 733â€“737. 10.1007/s1227401000371
Stalmashonak A, Podlipensky A, Seifert G, Graener H: Intensity driven laser induced transformation of Ag nanospheres to anisotropic shapes. Appl Phys B 2009, 94: 459â€“465. 10.1007/s0034000833097
Wang L, Zhao W, Tan W: Bioconjugated silica nanoparticles: development and applications. Nano Res 2008, 1: 99â€“115. 10.1007/s1227400880183
Khan S, Yuan Y, Abdolvand A, Schmidt M, Crouse P, Li L, Liu Z, Sharp N, Watkins KJ: Generation and characterization of NiO nanoparticles by continuous wave fiber laser ablation in liquid. Nanopart Res 2009, 11: 1421â€“1427. 10.1007/s1105100895309
Bohren CF, Huffman DR: Absorption and Scattering of Light by Small Particles. New York: Wiley; 1983.
Zharov VP, Lapotko DO: Photothermal imaging of nanoparticles and cells. Sel Top Quant Electron 2005, 11: 733â€“751.
Zharov VP, Letfullin RR, Galitovskaya EN: Microbubblesoverlapping mode for laser killing of cancer cells with absorbing nanoparticle clusters. J Phys D Appl Phys 2005, 38: 2571â€“2581. 10.1088/00223727/38/15/007
Akchurin G, Khlebtsov B, Tuchin V, Zharov V, Khlebtsov N: Gold nanoshell photomodification under a singlenanosecond laser pulse accompanied by colorshifting and bubble formation phenomena. Nanotechnology 2008, 18: 015701.
Kotaidis V, Plech A: Cavitation dynamics on the nanoscale. Appl Phys Lett 2005, 87: 213102. 10.1063/1.2132086
Kotaidis V, Dahmen C, von Plessen G, Springer F, Plech A: Excitation of nanoscale vapor bubbles at the surface of gold nanoparticles. J Chem Phys 2006, 124: 184702. 10.1063/1.2187476
Neumann J, Brinkmann R: Boiling nucleation on melanosomes and microbeads transiently heated by nanosecond and microsecond laser pulses. J Biomed Opt 2005, 10: 024001. 10.1117/1.1896969
Neumann J, Brinkmann R: Selflimited growth of laserinduced vapor bubbles around single microabsorbers. Appl Phys Lett 2008, 93: 033901. 10.1063/1.2957030
Lapotko D: Pulsed photothermal heating of the media during bubble generation around gold nanoparticles. Int J Heat Mass Transfer 2009, 52: 1540â€“1543. 10.1016/j.ijheatmasstransfer.2008.08.010
Lapotko D: Optical excitation and detection of vapor bubbles around plasmonic nanoparticles. Optics Express 2009, 17: 2538â€“2556. 10.1364/OE.17.002538
LukianovaHleb E, Hanna E, Hafner J, Lapotko D: Tunable plasmonic nanobubbles for cell theranostics. Nanotechnology 2010, 21: 085102. 10.1088/09574484/21/8/085102
Scripov VP: Metastable liquids. Berlin: Wiley; 1974.
Thormahlen I, Straub J, Grigull U: Refractive index of water and its dependence on wavelength, temperature and density. J Phys Chem Ref Data 1985, 14: 933â€“945. 10.1063/1.555743
Kokhanovsky A: Optical properties of bubbles. J Opt A Pure Appl Opt 2003, 5: 47â€“53. 10.1088/14644258/5/1/307
Johnson PB, Christy RW: Optical constants of the noble metals. Phys Rev B 1972, 6: 4370â€“4379. 10.1103/PhysRevB.6.4370
Zuev VE: Propagation of visible and infrared waves in atmosphere. Moscow: Sov. Radio; 1970.
Babenko VA, Astafyeva LG, Kuzmin VN: Electromagnetic Scattering in Disperse Media. BerlinChichester: SpringerPraxis; 2003.
Kattawar GW, Hood DA: Electromagnetic scattering from a spherical polydispersion of a coated spheres. Appl Opt 1976, 15: 1996â€“1999. 10.1364/AO.15.001996
Bhandari R: Scattering coefficients for a multilayered sphere: analytic expressions and algorithms. Appl Opt 1985, 24: 1960â€“1967. 10.1364/AO.24.001960
Pustovalov V, Astafyeva L, Jean B: Computer modeling of the optical properties and heating of spherical gold and silicagold nanoparticles for laser combined imaging and photothermal treatment. Nanotechnology 2009, 20: 225105. 10.1088/09574484/20/22/225105
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VKP and LGA carried out all investigations together. All authors read and approved the final manuscript.
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Pustovalov, V.K., Astafyeva, L.G. Nonlinear thermooptical properties of twolayered spherical system of gold nanoparticle core and water vapor shell during initial stage of shell expansion. Nanoscale Res Lett 6, 448 (2011). https://doi.org/10.1186/1556276X6448
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DOI: https://doi.org/10.1186/1556276X6448
Keywords
 Vapor Bubble
 Complex Refractive Index
 Probe Radiation
 Extinction Cross Section
 Optical Indicatrixes