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Table 1 HOMO and LUMO levels of PCBM changed by electron irradiation as a function of electron fluence

From: Tuning the electronic band structure of PCBM by electron irradiation

 

Ep, red(1)

E on, red (1)

LUMO

E p, ox

E on, ox

HOMO

PCBM

-1.11

-0.98

-3.70

1.76

1.50

-6.18

PCBM (3.6 × 1016 cm-2)

-1.22

-1.09

-3.59

1.79

1.55

-6.23

PCBM (7.2 × 1016 cm-2)

-1.41

-1.18

-3.50

1.86

1.56

-6.24

PCBM (1.44 × 1017 cm-2)

-1.49

-1.28

-3.40

1.94

1.57

-6.25

  1. The first reduction and oxidation peak potentials (voltage vs. Ag/Ag+), onset potentials, and LUMO and HOMO level (electron volts) of electron-irradiated PCBM at different fluences.

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