- Nano Express
- Open Access
Fabrication of a form- and size-variable microcellular-polymer-stabilized metal nanocomposite using supercritical foaming and impregnation for catalytic hydrogenation
© Liao et al.; licensee Springer. 2012
Received: 8 March 2012
Accepted: 31 May 2012
Published: 31 May 2012
This article presents the fabrication of size-controllable and shape-flexible microcellular high-density polyethylene-stabilized palladium nanoparticles (Pd/m-HDPE) using supercritical foaming, followed by supercritical impregnation. These nanomaterials are investigated for use as heterogeneous hydrogenation catalysts of biphenyls in supercritical carbon dioxide with no significant surface and inner mass transfer resistance. The morphology of the Pd/m-HDPE is examined using scanning electron microscopy images of the pores inside Pd/m-HDPE catalysts and transmission electron microscopy images of the Pd particles confined in an HDPE structure. This nanocomposite simplifies industrial design and operation. These Pd/m-HDPE catalysts can be recycled easily and reused without complex recovery and cleaning procedures.
Nanotechnology has resulted in research that examines a scale of matter typically between 1 and 100 nm wherein properties are dependent on the size and form. The greater surface area per mass compared with larger particles with identical chemical composition makes nanomaterials an excellent catalyst and also makes them more biologically active. When examining possible exposure routes for manufactured nanoparticles or during their production and inhalation, oral and dermal exposure are the most obvious, depending on the type of product in which nanoparticles are used. Hence, the development of green methods for the fabrication of nanomaterials has become increasingly relevant as chemists look to shape a more sustainable future.
Heterogeneous catalytic hydrogenation in supercritical fluids, especially in supercritical carbon dioxide (sc-CO2), has recently become an active research area because of its advantages over conventional organic-solvent-based systems. Sc-CO2 has proven to be an effective solvent for a wide range of homogeneous transition-metal-catalyzed reactions. The readily achievable critical point of sc-CO2 (T c = 31.1 ° C, P c = 73.7 bar) is one of its many advantages, which also include its low cost, low toxicity, no flammability, and the ability to tune the reactive properties by small variations, i.e., variation in temperature or pressure in the sc-CO2 density . Their advantages also include enhanced mass and heat transfer, adjustable salvation ability, total H2 miscibility, elimination of the gas/liquid interface, extended catalyst lifetime, ease of separation from products, and minimal organic solvent waste [2–4]. Transition metals (e.g., Pd, Rh, Ru, and Pt) supported on various matrices (e.g., activated carbon, Al2O3, SiO2, SBA-15, and MCM-48) have been prepared and applied for catalytic hydrogenation of various reactants in supercritical fluids.
Previous research showed that nanosized palladium particles (diameter = 2 to 10 nm) could be deposited uniformly in the interior of high-density polyethylene (HDPE) beads (diameter = 3 to 4 mm) using supercritical impregnation and catalyzed hydrogenation of numerous aromatic compounds in sc-CO2, including benzene and naphthalene . The principles of synthesizing and using Pd/HDPE as a heterogeneous catalyst in sc-CO2 are based on the frequent swelling of polymers in sc-CO2[6–8]. CO2-soluble metal precursors can diffuse into the CO2-swollen polymers. Following hydrogen reduction, metal ions in the precursors are reduced to zero-valence metals and aggregate until becoming nanoparticles resulting from steric confinement by the polymer structure. The metal/polymer composites swell again in sc-CO2, allowing CO2-soluble reactants to diffuse into polymer structures that contact embedded metal nanoparticles for catalytic reactions. The products, catalysts, and sc-CO2 are separated by depressurization. The examples of using Pd/HDPE as a heterogeneous catalyst in sc-CO2 are catalytic hydrodechlorination and hydrogenation of polychlorinated biphenyl (PCB). Under mild conditions (PCO2 = 100 to 200 atm, PH2 = 10 atm, and temperature = 40 to 100°C), PCBs can be converted to bicyclohexyl efficiently using consecutive reactions in sc-CO2 with static and dynamic modes [9–12]. The catalytic system fulfills green chemistry principles and economic requirements for developing advanced industrial processes.
The dispersion of porous heterogeneous catalysts in the fluid phase, external mass transfer adjacent to the catalysts, and internal mass transfer within the catalysts are three key catalyst performance factors . The uniform dispersion of catalysts and alleviation of external mass transfer resistance in a catalytic system are typically achieved by vigorous stirring during the fluid phase when the influence of internal mass transfer resistance is lowered by reducing catalyst support size to a specific value (e.g., diameter = approximately 100 μm) ; however, handling and recovering micro-powdered catalysts is not simple. Moreover, uniform dispersion of catalysts in a reactor is usually difficult to achieve by stirring, and the aggregation of numerous catalysts may affect their performance.
In this study, a solvent-free approach involving supercritical foaming and supercritical impregnation is used to prepare recyclable and geometrically variable microcellular high-density polyethylene-stabilized palladium nanoparticles (Pd/m-HDPE) with uniform particle dispersion and no significant mass transfer resistance in sc-CO2. Supercritical foaming is used to prepare microcellular polymer foams for numerous applications such as absorbents, biomedical materials, and lightweight structural devices [15–18]. The pore size and density can be altered by controlling pressure, temperature, depressurization rate, and other factors.
Materials and equipments
HDPE beads, palladium(II) hexafluoroacetylacetonate, hexane, and biphenyl were purchased from Aldrich (Milwaukee, WI, USA). All chemicals were used as received. Scanning electron microscopy (SEM) (Hitachi S-2400, Tokyo, Japan), transmission electron microscopy (TEM) (Hitachi H-7100), atomic absorption (AA) (Perkin Elmer AAnalyst 100, Waltham, MA, USA), ultraviolet-visible (UV/Vis) spectroscopy (GENESYS 10 S, ThermoSpectronic, Rochester, NY, USA) and gas chromatography flame ionization detection (GC/FID) (Varian CP-3800, Palo Alto, CA, USA) are used in this study.
Preparation of recyclable and geometrically variable pd/m-HDPE catalysts
The synthesis procedure for preparing recyclable and geometrically variable Pd/m-HDPE catalysts involves supercritical foaming, supercritical impregnation, and hydrogen reduction. The experimental setups for catalyst synthesis and catalytic reactivity test are described in previous literature [9, 10]. A beaker filled with 2.5 g of white HDPE beads (circular flat white beads with an average diameter, height, and weight of 3 mm, 1.5 mm, and 14 mg, respectively; Tm = 130°C) is placed in a 20-mL high-pressure reactor at 140°C and pressurized with 200 atm of CO2 for the supercritical foaming process. After 3 h, the reactor was depressurized completely in 10 s. A small section is removed from the top of the resulting m-HDPE to produce a level surface. Subsequently, 100 mg of yellow palladium (II) hexafluoroacetylacetonate, Pd(hfa)2, and a microcellular HDPE support were placed into the high-pressure reactor at 90°C and pressurized with 100 atm of CO2 for the supercritical impregnation process. After 3 h, the reactor was depressurized. The depressurization time was less than 1 min to avoid impregnated Pd(hfa)2 diffusing outside of the m-HDPE support. The Pd(hfa)2-impregnated HDPE support, the reactor, and the tubing were cleaned using hexane to recover Pd(hfa)2 outside the support for reuse. The cleaned Pd(hfa)2-impregnated HDPE support was then placed into the reactor again, and the Pd2+ in the precursors was reduced to a zero-valence state with 10 atm of hydrogen gas in 200 atm of sc-CO2 at 90°C. The resulting Pd/m-HDPE catalyst was cleaned for 1 h with sc-CO2 to remove impurities. The conversion variation test to compare agitation speed or catalyst volume was performed as follows: a small beaker containing 10 μL of biphenyl stock solution in hexane (concentration = 7.74 × 10-2 M) was placed on top of Pd/m-HDPE catalysts in a 20-mL high-pressure reactor. Following hexane evaporation and achieving the required temperature (50°C), the reactor was pressurized with CO2 at 100 atm to dissolve biphenyls in sc-CO2 in advance. In total, 200 atm of CO2 containing 10 atm of H2 was injected into the reactor from a 40-mL H2 storage cell. After 5 min, the system outlet valve was opened, and the effluent was collected in 10 mL of hexane for UV/Vis and GC/FID analysis. The collection process was continued for 30 min with a flow rate of 1 mL min-1 using identical experimental conditions (200 atm of CO2 at 50°C) to recover all reactants and products. The catalysts and high pressure system were cleaned for another 30 min following the collection process.
Results and discussion
Preparation of microcellular high-density polyethylene-stabilized pd nanoparticles (pd/m-HDPE)
Metal nanoparticles are tangled by flexible polymer chains. Under sc-CO2, polymers are swelled, and the mobility of polymer chains is enhanced significantly, allowing molecules to pass through their structures. The creation of microcellular pores further facilitates the molecule diffusion in the polymer matrix. Consequently, molecules can theoretically approach each embedded metal nanoparticle from all directions through microcellular pores and flexible swollen polymer structures. Furthermore, nanoparticles may detach from the pore surface and block nanosized pore channels during reaction, recovery, and cleaning processes, causing catalyst deactivation in the case of common supports (Figure 1a). Such polymer support issues can be prevented because nanoparticles are surrounded and sterically confined by numerous polymers. The possibility of metal nanoparticle leaching should be minimized.
The supercritical foaming process, temperature, CO2 pressure, and depressurization rate are three parameters that can tune the pore size and density of HDPE easily. Previous research on foaming of polystyrene and poly (D,L-lactic acid) using sc-CO2 (Tsivintzelis et al.) shows that pore density increases and pore size decreases with decreasing temperature, thereby increasing CO2 pressure and the depressurization rate .
For comparison, a control catalyst resembling the original Pd/HDPE catalysts  was prepared following the same mentioned procedure, except for the supercritical foaming process. The control catalyst and Pd/m-HDPE catalysts synthesized under different CO2 pressures were then halved to observe their interior structure. Figure 2d shows the control catalyst cross section. Only the surface (approximately 1 mm) turned black and the rest remained white, indicating that the sc-CO2 swelling phenomenon cannot impregnate Pd(hfa)2 deep into the HDPE structure when the HDPE support is increased from millimeter  to centimeter range. The cross section of three Pd/m-HDPE catalysts prepared at 50, 100, and 200 atm (Figures 2e-g) were almost completely black. Increasing CO2 pressure caused a decrease in pore sizes, an increase in pore density, and an increase in Pd/m-HDPE volume at a fixed temperature because of the increase in pore density. The remaining white area following the hydrogen reduction process is described by the following: no foaming > 50, >100, and > 200 atm. The visual observation indicates that the microcellular structure created by supercritical foaming enhances the internal mass transfer of molecules in HDPE support significantly and Pd/m-HDPE catalysts prepared at the CO2 pressure of 200 atm appear to possess the most efficient molecule diffusion within its structure. Higher CO2 pressure was not tested because of safety reasons, although it may achieve a more significant result with respect to internal mass transfer.
Characterization of microcellular pd/HDPE
Reusability of pd/m-HDPE catalysts
No reduction in conversion was observed following more than 50 trials of reusability of Pd/m-HDPE catalysts. Following each experiment, the catalyst was cleaned with sc-CO2 for 30 min with a flow rate of 1 mL/min under the same experimental conditions, which is relatively simple compared with other catalyst cleaning procedures. Unlike powdered catalysts that lose or block and contaminate the experimental equipment during reaction and recovery processes, the monolithic Pd/m-HDPE catalyst is free of these problems. Furthermore, the HDPE supports with simple molecular structures that contain only C and H are non-toxic, economical, do not absorb molecules easily, and may cause difficulty in product recovery and catalyst cleaning.
Other advantages of pd/m-HDPE heterogeneous catalyst
The preliminary experimental data demonstrate that supercritical foaming and impregnation can be used as a solvent-free technique to prepare Pd/m-HDPE as a heterogeneous catalyst for catalytic hydrogenation in sc-CO2 without significant mass transfer resistance. Compared with other sc-CO2 catalysts, the advantages of these Pd/m-HDPE catalysts include a) the pre-dispersion of metal nanoparticles in the polymer matrix that resembles a homogeneous system and, consequently, does not require vigorous stirring to achieve uniform dispersion; b) the microcellular HDPE support structure coupled with the sc-CO2 polymer swelling property allows simple reactant diffusion inside the polymers, facilitating internal mass transfer; c) large sizes and various shapes of catalysts can be prepared, simplifying experimental or industrial design and operation; d) the catalysts are recyclable and reusable without complex recovery and cleaning procedures; and e) the fabrication of Pd/m-HDPE catalysts using this method is in a closed system; thus, the potential hazards of nanoparticles to the environment resulting from system leakage is avoidable.
By taking advantage of sc-CO2 characteristics, a green solvent and microcellular high-density polyethylene-stabilized palladium nanoparticles are successfully developed as heterogeneous catalysts in sc-CO2. In a large cylinder (2.0 cm height × 1.8 cm diameter) with pore sizes between 20 and 60 μm, Pd nanoparticles with an average diameter of 10.5 ± 3.5 nm are randomly dispersed. The conversion variations are almost constant with increasing agitation speed or decreasing catalyst volume, implying the presence of nonsignificant external and internal mass transfer resistance on the catalyst surface and within the catalyst structure. The CO2-swollen microcellular HDPE support enhances molecule diffusion inside its structure significantly, facilitating heterogeneous catalytic reactions. The findings in this study show novel advances in the field of heterogeneous catalysis, as well as potential application in environmental remediation. The presented supercritical techniques may serve as a simple and environmentally friendly approach for the preparation of various microcellular-polymer-stabilized metal nanoparticles for heterogeneous catalytic reactions in supercritical fluids. Additionally, as the field of nanotechnology expands into consumer markets, manufacturing nanoparticles by using efficient, low-cost approaches is essential, one which must be socially responsible to minimize their environmental impact on the environment.
This research was supported by the National Science Council (NSC 98-2811-M-259-004). We gratefully acknowledge Chih-Yuan Tang of National Taiwan University for SEM and TEM images.
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