- Nano Express
- Open Access
Laser etching of groove structures with micro-optical fiber-enhanced irradiation
© LIU et al.;licensee BioMed Central Ltd. 2012
- Received: 28 February 2012
- Accepted: 23 May 2012
- Published: 19 June 2012
A microfiber is used as a laser-focusing unit to fabricate a groove structure on TiAlSiN surfaces. After one laser pulse etching, a groove with the minimum width of 265 nm is manufactured at the area. This technique of microfabricating the groove in microscale is studied. Based on the near-field intensity enhancement at the contact area between the fiber and the surface during the laser irradiation, simulation results are also presented, which agree well with the experimental results.
In the past 10 years, with the important role of microdevices in industrial applications, fabrication technologies on the micron and nanometer scales are attracting more attentions. Recently, developed lithographic technologies like ion beam, electron beam, and near-field optics have been investigated and regarded as potential methods for microfabrication[1–4]. Due to the light diffraction limit, traditional laser optical manufacture is not available to fabricate the further microsturctures. Many groups offered approaches to overcome the limit by using near-field effects through surface pattern designs. These are carried out by delivering a laser beam through a near-field tip or illuminating the tip with a pulsed laser. Huang et al. used single-pulse 248 nm KrF laser radiation to fabricate nano bump arrays. Hong et al. reported that femtosecond laser (400 nm, 100 fs) irradiation went through a near-field scanning optical microscope and sub-50 nm feature size was created. The near-field enhanced laser irradiation with 248 and 355 nm UV lasers was applied to pattern a silicon surface in a massively parallel fashion. However, these approaches need the expensive equipment with the related complex system. Zhang et al. used a 248 nm excimer laser with a pulse duration of 23 ns and obtained 100 nm hillocks at the original particle positions. These glass microballs can only be used for processing micro-dimple structures. Zhou et al. also tried a low-cost method, in which an optical fiber was used as a focusing unit to etch parallel microgrooves with 2 to 6 μm width and 0.7 to 1.4 μm depth on Si surface. This resolution still needed to be improved to overcome the diffraction limit. Meanwhile, it is necessary for the micro and nanofabrication to develop the low-cost and fast speed laser processing. To further reduce the resolution to the nanometer scale, methods of near-field laser irradiation with the combination of advanced processing tools such as SPM, NSOM, transparent, and metallic particles are applied for the sizes as small as 20 nm. Laser interference lithography is also capable of fabricating sub-100 nm periodic structures for large area, maskless, and noncontact nanofabrications. In this work, we report a low-cost microprocessing technique, based on a microfiber-enhanced irradiation to fabricate groove structures under the diffraction limit.
In the groove manufacture process, the micro-fiber is placed on the TiAlSiN surface. The fiber contacts with the surface directly, which makes the gap between the fiber and the surface at nanometer scales. Light intensity at the sample surface is adjusted at 440 mJ/cm2. The laser perpendicularly irradiates on TiAlSiN through the fiber and etches the surface. After one laser pulse etching, a groove on the TiAlSiN surface is created. It is observed under both SEM and atomic force microscopy (AFM).
RF module of Comsol 3.5 is used to simulate optical fields. Here, it is required to calculate the energy distribution behind the fiber. The calculations are based on finite element analysis to solve Maxwell equations with the boundary conditions. The calculation results are compared to the groove characters.
This etching technique of the microfiber-enhanced irradiation is also attemped to process grooves on Si. A inhomogeneous groove with a minimum size of around 300 nm is also observed on the laser treated surface. As the fiber changes in the diameters, the groove dimension is relatively altered. However, the further investment needs to find out the fabrication technique and etching mechanism.
Two mechanisms of Rayleigh scattering and Mie scattering are proposed to explain the enhancement by the laser irradiation of particles. The intensity distribution changes dramatically as the particle sizes and the interaction distance decreased. Laser procession through a small particle is different from a sphere lens focusing in a far field. In our work, the microfiber is considered as a kind of one-dimension optical component in microscale. Rayleigh scattering takes place when the fiber diameter is less than the wavelength of the light. It enhances the electric field at its sides along the direction of polarization of the incident light. Furthermore, when the diameter is equal to or greater than the incident wavelength, Mie scattering is used to examine this phenomenon. In contrast, the electric field is enhanced by several times towards the forward area of the sphere. The intensity distribution shows that Mie scattering is the main reason for the enhancement of the fiber system. It is a potential application of the microfiber in microstructure fabrications. According to finite element analysis, choosing a suitable fiber size, wavelength, and incident light can produce the higher resolution in the etching process.
A novel laser etching technique, in which a quartz fiber at a diameter of about 5 μm is placed on the TiAlSiN surface in order to induce the light intensity enhancement near the contact line, is investigated. We have demonstrated that the laser etching with microfiber-enhanced irradiation can be used to fabricate a groove. Its minimum width is about 265 nm. This technique is found to have advantages of simple setup and low cost. Meanwhile, the experimental results are consistent with computational simulations.
DL is a lecturer in State Key Laboratory of Tribology, Tsinghua University. JL is a PHD student. HW is a research assistant. TS is a professor of State Key Laboratory of Tribology, Tsinghua University.
The authors would thank the National Natural Science Foundation of China (Grant No.90923018), the National Natural Science Foundation of China (Grant No.51105222) and the Tribology Science Fund of State Key Laboratory of Tribology (SKLT10B02) for the financial support.
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