Evaluation of different conductive nanostructured particles as filler in smart piezoresistive composites
© Stassi et al.; licensee Springer. 2012
Received: 9 January 2012
Accepted: 15 May 2012
Published: 21 June 2012
This work presents a comparison between three piezoresistive composite materials based on nanostructured conductive fillers in a polydimethylsiloxane insulating elastomeric matrix for sensing applications. Without any mechanical deformation upon an applied bias, the prepared composites present an insulating electric behavior, while, when subjected to mechanical load, the electric resistance is reduced exponentially. Three different metal fillers were tested: commercial nickel and copper spiky-particles and synthesized highly-pointed gold nanostars. These particles were chosen because of their high electrical conductivity and especially for the presence of nanosized sharp tips on their surface. These features generate an enhancement of the local electric field increasing the tunneling probability between the particles. Different figures of merit concerning the morphology of the fillers were evaluated and correlated with the corresponding functional response of the composite.
In the last decades, piezoresistive composite materials have found extensive potential application in the fields of micro-sensors [1, 2], electromechanical devices, circuit breakers , touchable sensitive screens, and tactile sensors for robotics , providing cheaper, faster, and more accurate alternatives than the commercially available devices. The properties of these materials could be tuned by varying the nature and the morphology of the particles, used as functional filler and the type of matrix . Several papers report on composites prepared by incorporating different conductive fillers, mostly carbon structures (carbon black and nanotubes) and metal particles in an insulating polymer matrix (e.g., silicones, polyurethane, acrylics, etc.) [6, 7]. By varying the type and amount of fillers, the composite can assume the electrical properties of an insulator up to those of a good conductor. In the piezoresistive composites based on tunneling conduction mechanism, a small variation of the external load induces a huge change of the electrical conductivity [8–10]. In these materials, each conductive particle is separated from the others by a thin layer of insulating polymer representing the tunneling barrier . Under the effect of an applied pressure, a mechanical deformation is induced, and the polymer thickness reduces, thus decreasing the tunneling barrier. As a consequence, the probability of tunneling phenomena increases, resulting in a large reduction of the bulk electrical resistance. In these composites, the shape and dimension of the filler particles become as important as the filler nature and amount. In particular, the composites prepared with conductive particles presenting sharp and nanostructured tips on the surface exhibit a huge variation of the electrical conduction in response to a mechanical strain. In fact, this morphology is responsible for a local electric field enhancement  that considerably increases the tunneling probability through the insulating barrier.
In this work, we report on the use of three different metal conductive spiky particles into silicone-based polymeric matrix for piezoresistive composites based on tunneling conduction mechanism. These composites were prepared and studied as functional materials for tactile sensors application because of their large sensitivity . The aim of the present work is to understand how the morphological features of the nanostructured particles influence the minimum required amount of the fillers to obtain similar piezoresistive performances among the different composites. In this way, it could be possible to select the best filler and to easily tune the functional properties of the composites in order to reach the required sensor sensitivity.
The nickel powder used in this work was supplied by Vale Inco Ltd. (type 123, Toronto, Canada.), copper was obtained from Pometon (LT10, Maerne, Italy) and the bi-component polydimethylsiloxane (PDMS) was purchased by Dow Corning Corporation (SYLGARD 184, Midland, MI, USA). For the synthesis of the gold nanoparticles, all the chemicals were obtained from Sigma Aldrich (St. Louis, MO, USA) and used as received without any further purification.
We have reported in a previous publication , the synthetic procedure to prepare shape-controlled, highly pointed, and nanometric-sized gold nanostars. For the composite preparation, the gold nanostars were dispersed in ethanol, and then, the PDMS copolymer was added to the solution . The blend was mixed in an ultrasound bath at 70°C until all the ethanol was evaporated. In the case of nickel and copper filler, the composites were prepared by dispersing the metallic powders in the PDMS by gently mixing, in order to avoid the destruction of the tips on the surface of the particles . The filler to polymer ratio is optimized according to the discussion below. The curing agent was then added to the viscous mixture in a weight ratio of 1:10 with respect to the co-polymer, and the solution was gently mixed at RT. The resulting pastes were outgassed under vacuum for 1 h, poured in PMMA moulds, and then cured in oven at 75°C for 10 h. All the prepared square samples had a footprint of 10 × 10 mm2 and the thickness of 1 mm. The resistance of the nickel and copper composite was circa 1 GΩ, in the absence of an applied pressure, while for the gold composite was around 100 GΩ.
The morphological characterization was carried out by a field emission scanning electron microscope (FESEM, Zeiss SupraTM 40, Oberkochen, Germany). For each metal filler, circa 100 particle tips where measured from the FESEM images in term of radius of curvature (Rtip) and aspect ratio between the tip height (Htip) and its full width at half maximum (FWHM). In order to evaluate the sharpness of the spiky particles, the ratio between the Htip and the core particle diameter (Dcore) was also calculated.
Results and discussion
Figures of merit of the nanoshaped-spiky fillers
Filler: PDMS weight ratio
The three selected particles have different size and shape, ranging from spiky micrometric-sized nickel particles (average diameter, 4.5 μm, Figure 2a), to elongated multi-branched copper ones (average diameter, 12 μm, Figure 2b) up to gold nanosized stars (average diameter, 450 nm, Figure 2c). It was already reported in the literature  that highly pronounced and elongated tips at the particle surface increase the electric conductance throughout the composite, amplifying the electric field and, thus, the tunneling probability among the spiky fillers. It is therefore clear that the lower the curvature radius of the conductive tips, the higher the tunneling conductance effect in the composite.
Considering the obtained values of electric resistance, one can observe a strong relationship between the morphological data calculated here and the used filler amount in the final composite. First, the copper and gold-based composites have both shown remarkable tunneling conduction values at lower filler amount (1.75:1 for Cu: PDMS and 1:1 for Au: PDMS) with respect to the weight ratio used for the nickel-based composite (3:1). We attribute this effect to the higher Htip/Dcore ratio obtained for both copper and gold with respect to the nickel one.
Additionally, another morphological parameter was calculated, that is the aspect ratio between the Htip and its FWHM. Higher is this value, sharper and more slender is the tip. We note that both copper and gold fillers have a higher Htip/FWHM ratio than the nickel one.
The combination of both parameters, i.e., high Htip/FWHM and Htip/Dcore ratios, implies the presence of sharp tips showing a pronounced height with respect to the core size of the particles. This means that a lower amount of material in weight is required for obtaining similar conductance values, since the probability of the tip to form a tunneling conduction is higher with respect to massive, spherical shaped nanoparticles with the same size.
In addition, the gold-based composite requires an even lower filler amount (1:1) than the copper one (1.75:1) to obtain similar tunneling conductance values. We note, however, that the Htip/Dcore ratio of gold is slightly smaller (0.34) than those of copper (0.37) as well as the Htip/FWHM ratios (2.3 for gold versus 3.6 for copper). Thus, the lower radius of curvature of the gold tip shows to play here a predominant role in the tunneling conduction enhancement. Indeed, the Rtip of gold is about 60× smaller than that of copper. It is therefore clear that, in the case of gold, the presence of either high Htip/Dcore and Htip/FWHM ratios and small Rtip is a fundamental prerequisite for obtaining high tunneling conductance value with a low filler to polymer weight ratio. We note in addition that the use of gold has several advantages with respect to the copper and the nickel fillers. First, it was synthesized and ad-hoc prepared, whereas both Cu and Ni-particles were obtained commercially. This allows a full control on the size and shape of the gold nanostars with a very good reproducibility, which cannot be reached with the other two metals. Despite higher cost of the starting precursor chemical, its nanometric size and tip nanostructuration allow the use of gold fillers in small amounts in the composite, thus obtaining comparable piezoresistive performances than the other composites with commercial fillers. Furthermore, gold is a safe material (whereas nickel particles were reported to be carcinogenic ) and shows higher resistance to oxidation with respect to both nickel and copper. In addition, thanks to the small content of the filler required and its nanometric size, the gold nanostars can be used to prepare very flexible, light, and thin composites, ideal for the integration in MEMS-like technology in tactile sensor applications.
We have reported on the influence of the filler morphological features on the piezoresistive performances of three different conductive spiky-particle polymeric composites. Based on our previous experience, we have tested different weight ratios of the filler in the PDMS matrix. The aim was to find the minimum amount of nickel, copper, and gold for obtaining comparable tunneling conductance values of the piezoresistive composite as a function of the applied mechanical pressure. We have experimentally observed a strong dependence of the minimum filler amount (for tunneling conduction mechanism of the composite) from the morphological figures of merit. We have found out that particles with sharp tip and small core size, i.e., high Htip/Dcore and Htip/FWHM, together with a small curvature radius of the tip (Rtip), present strong enhancement of the tunneling conduction. Thus, our synthesized gold nanostars showed very good performances in terms of tunneling conductance at a low weight ratio in the composites. Thanks to their nanometer size and nanostructured shape, it is possible to obtain flexible, thin, and light-weight performing piezoresistive composites, which will be well adaptable to tactile sensor application.
The help of Dr. Angelica Chiodoni and Dr. Diego Manfredi for scanning electron microscopy is gratefully acknowledged. The authors also thank Alessandro Nesca for the mould fabrication.
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