- Nano Express
- Open Access
Metallic conduction and large electron-phonon-impurity interference effect in single TiSi nanowires
Nanoscale Research Letters volume 7, Article number: 500 (2012)
We report on the first electrical characterizations of single-crystalline TiSi nanowires (NWs) synthesized by chemical vapor deposition reactions. By utilizing the focused-ion-beam-induced deposition technique, we have delicately made four-probe contacts onto individual NWs. The NW resistivities have been measured between 2 and 300 K, which reveal overall metallic conduction with small residual resistivity ratios in the NWs. Surprisingly, we find that the effect due to the interference processes between the elastic electron scattering and the electron-phonon scattering largely dominates over the usual Boltzmann transport even at room temperature. Such prominent electron-phonon-impurity interference effect is ascribed to the presence of large amounts of disorder and high Debye temperatures in TiSi NWs.
Physical properties of transition metal silicides are intensively investigated for their potential usefulness in many device applications. Among them, titanium silicides constitute a valuable material family that is widely utilized as gate electrodes and interconnects in ultra-large-scale integrated circuits, owing to their relatively low electrical resistivities and good thermal and chemical stability that is highly compatible with present-day silicon processes . Among all the six phases of titanium silicides reported to date, titanium monosilicide (TiSi)  has the highest mechanical hardness which, combined with its low resistivity  (≈ 60 μΩ cm in bulk form at 300 K), can be of interest for the possible engineering of micro- and nano-electromechanical systems . However, as compared to other titanium silicides, TiSi has not been much studied either in bulk form or at the nanoscale level due to the difficulties of either preparing quantities sufficient for bulk characterizations  or preparing single-phased nanostructures .
Recently, some of us have successfully synthesized single-crystalline TiSi nanowires (NWs) . The material belongs to one of the eight transition metal silicide NWs currently known . In this work, we aim to study the intrinsic electrical transport properties of this nanoscale material by measuring four-probe individual NW samples in a wide temperature range of 2 to 300 K. We demonstrate that these NWs are indeed metallic, revealing decreasing resistivity with reducing temperature. Furthermore, we observe a large electron-phonon-impurity (EPI) interference effect, which is theoretically predicted to exist in disordered conductors . Surprisingly, we find that this EPI interference effect strongly dominates over the usual Boltzmann transport even at temperatures as high as room temperature. This unique property renders the TiSi NWs useful for the investigations of the interplay among a variety of electron-scattering processes at the nanoscale level. Previously, the EPI interference effect has been found to be important in normal metals only at considerably lower temperatures [8–12].
Our TiSi NWs were synthesized via a low-pressure chemical vapor deposition process using TiCl4 and titanium powder as precursors; no templates or catalysts were needed . The growth mechanism and detailed structure and composition characterizations by high-resolution transmission electron microscopy (HRTEM), X-ray diffraction (XRD), and other techniques have been reported by Lin et al. in . Since these NWs can be readily coated by a thick (approximately 10 nm) oxide layer over the surfaces [5, 13], we choose the ‘invasive’ focused-ion-beam-induced deposition (FIBID) technique to fabricate the electrical contacts onto individual NWs. It should be stressed that the existence of the thick oxide layers prevented us from making good ohmic contacts when employing the electron-beam lithographic technique. After transferring the NWs onto the silicon substrate capped with a ≈ 500-nm thick SiO2 layer, the positions of individual NWs were first located by the scanning electron microscopy (SEM) capability of the FIB system (Model FEI Nova 200, FEI Co., Hillsboro, OR, USA). Platinum electrodes were then deposited onto the NWs using a 30-KeV, 10-pA Ga+ FIB. The Pt leads connected the individual NWs to the microelectrodes which were photolithographically pre-patterned on the SiO2/Si substrate. The substrate was thermally anchored to the sample holder mounted with a calibrated silicon diode thermometer on a standard 4He cryostat. A standard four-probe current-reversal method was applied for resistance measurements using a Keithley K-220 current source and a K-182 nanovoltmeter (Keithley Instruments Inc., Cleveland, OH, USA).
Since the NWs are readily coated with a thick oxide layer, as mentioned, we apply the FIBID technique in a delicate manner to unambiguously obtain the intrinsic electrical transport properties of the NWs. Instead of being laid across the entire NW diameter, the deposition of the Pt (especially the two voltages) electrodes were carefully brought only to the edge of the NW, which removed the outer oxide layer of the NW by invasive deposition and allowed the deposited Pt leads to be in direct contact with the fresh interior of the NW (see the schematic in the right panel of Figure 1). This approach prevents the TiSi NW from being broken into disconnected regimes as the bombardment of high-energy Ga+ ions during the FIBID could seriously damage and/or mill away the entire NW segment under the Pt electrodes, in which case a nominal four-probe measurement could become ineffective and give a two-probe result that includes the resistances of the Pt segments in the contact regions of the two voltage electrodes. (Due to the presence of Ga/C contents in the electrodes, the as-deposited ‘Pt’ electrodes are typically slightly insulating. In this work, the Pt electrodes consist of approximately 70% C, 20% Pt, and 10% Ga and have resistivity ρel(300 K)≈ 3,000 μΩ cm and resistivity ratio ρel(4 K)/ρel(300 K)≈ 1.7, which are comparable to those values reported in the literature [14–16]. Typically, in all cases, our Pt electrodes have resistances of approximately a few ten kilohms, and the contact resistances are estimated to be only a few hundred ohms.) The normalized resistance R/R(300 K) versus temperature for three single NW samples fabricated this way is shown in Figure 1. Obviously, we obtain overall metallic behavior, i.e., the resistance decreases with decreasing temperature from 300 K down to low temperature. It should be mentioned that this technical precaution has often been overlooked, and great care should be taken when applying this invasive contact technique to electrical characterizations of nanoscale conductors.
Results and discussion
Table 1 indicates that our measured ρ(300 K) ≈ 310 to 350 μΩ cm values are a few times higher than that (≈ 60 μΩ cm) reported for bulk TiSi . Our measured low residual resistivity ratios ρ(300 K)/ρ0<2 strongly suggest the presence of large amounts of defects (e.g., point defects) in the NWs, where ρ0 is the residual resistivity due to elastic electron scattering off defects. This observation is in sharp contrast to the conclusion drawn from HRTEM and XRD studies , where structure characterizations indicated good crystalline structures without noticeable lattice defects. Indeed, the electrical transport measurement is one of the most sensitive techniques for probing defects in single nanoscale structures [17–19].
In the standard electrical transport model, the temperature behavior of resistivity ρ in metals is described by Matthiessen’s rule: ρ(T)=ρ0 + ρBG(T), where the Bloch-Grüneisen term, ρBG(T), due to electron-phonon scattering in an impure metal is given by [20, 21]
where βBG is a material-dependent electron-phonon coupling parameter, and θDis the Debye temperature. Previously, the applicability of using the Bloch-Grüneisen theorem for electron-phonon resistivity in metallic NWs of diameter ≥ 15 nm has been established . In practice, however, deviations from Matthiessen’s rule are often seen in metals that contain disorder . Recently, Reizer and Sergeev  have proposed that such deviations can be theoretically explained by taking into account the various interference processes generated between the elastic electron scattering and the electron-phonon scattering. They predicted that this new EPI interference mechanism causes a new resistivity contribution 
where βint is a material-dependent electron-phonon coupling parameter. Thus, for a disordered metal, the total resistivity is
(The quantum interference weak localization and electron-electron interaction effects  that could arise at lower temperatures are ignored here. They contribute negligibly to the measured resistivity in the temperature range of interest in the present work.)
We have least-squares fitted our measured ρ(T) in the NWs to Equation 3, with ρ0, βBG, θD, and βintas adjusting parameters. Figure 2 shows the normalized resistivity, Δρ/ρ0=(ρ−ρ0)/ρ0, versus temperature for the three NW samples. Good agreement between theory and experiment is found for every NW. Our fitted θDvalues (≈ 520 to 680 K) are relatively high (Table 1) compared with, e.g., those in noble metals. Our fitted values of −10−5K−2 are in similar orders of magnitude with those previously obtained in normal metals, such as Au , Al , and AuPd . What is more interesting is that previous studies of a variety of metals have found that the EPI interference effect was important only at considerably low temperatures [8–12]. In sharp contrast, we find that in our TiSi NWs, ρint(T) can largely dominate over ρBG(T) even up to temperatures as high as room temperature. Figure 2 clearly illustrates that ρint(T) is about one order of magnitude larger than ρBG(T) in samples B and C at 300 K.
Since the EPI interference effect is governed by the various interference processes generated between the elastic electron scattering and the electron-phonon scattering, our observation may be understood as follows. For a given material characterized by the same βBG, θD, and βint values, when the amount of disorder (ρ0) contained in the sample increases, the number of electronic waves generated from the elastic scattering off defects increases correspondingly. This can consequently enhance the strength of the EPI interference effect, giving rise to an increasingly pronounced ρint(T), as dictated by Equation 2. Furthermore, a metal with a high θDvalue means that the number of phonons that can participate in the electron-phonon scattering is relatively large. (Note that the upper limits of the integrals in Equations 1 and 2 are given by θD.) This can also lead to an enhanced EPI interference effect. As both the ρ0 and θD values in our TiSi NWs are higher than those in normal metals, a significant contribution due to such an effect hence can result.
The importance of the EPI interference effect can also be directly checked by plotting Δρ/ρ 0 versus T2. Theoretically, the integral in Equation 2 approaches Π2/6 at , and thus, Equation 2 reduces to a simple power-law form: . This T2temperature characteristic would extend to higher temperatures in metals that possess higher θD values and contain larger amounts of disorder (ρ0), as mentioned previously. Figure 3 clearly demonstrates that this T2 law prevails in a wide temperature range of approximately 50 to 140 K in our most disordered sample, C. In sample B, the T2 law is seen between approximately 40 and 120 K.
Inspection of Table 1 indicates that our extracted βBG,θD, and βint parameters vary among samples. Such variations cannot be explained in terms of current theoretical concepts. According to the current theoretical understanding, the two electron-phonon coupling parameters βBG and βint are expected to be independent of disorder for a given material in the weakly disordered regime . On the other hand, whether the value of θD should vary with disorder (or sound velocity which could be disorder dependent) is less clear . These issues deserve further theoretical and experimental investigations.
In summary, we have measured the temperature-dependent resistivity of single TiSi NWs between 2 and 300 K. We demonstrated that as-grown TiSi NWs are metallic. Furthermore, we found a large electron-phonon-impurity interference effect, which strongly dominates the total resistivity up to temperatures as high as room temperature. This is ascribed to originating from large Debye temperatures and high levels of disorder (e.g., point defects) in as-grown TiSi NWs. Our observations suggest that TiSi NWs can serve as a useful system for studying the rich electron scattering processes at the nanoscale level.
Chen LJ (Ed): Silicide Technology for Integrated Circuits. London: IET; 2004.
Maex K, Van Rossum M (Eds): Properties of Metal Silicides. London: IEE; 1995.
Murarka SP, Fraser DB: Silicide formation in thin cosputtered (titanium + silicon) films on polycrystalline silicon and Si02. J Appl Phys 1980, 51: 350. 10.1063/1.327379
Ekinci KL, Roukes ML: Nanoelectromechanical systems. Rev Sci Instrum 2005, 76: 061101. 10.1063/1.1927327
Lin HK, Cheng HA, Lee CY, Chiu HT: Chemical vapor deposition of TiSi nanowires on C54 TiSi2 thin film: an amorphous titanium silicide interlayer assisted nanowire growth. Chem Mater 2009, 21: 5388. 10.1021/cm901726s
Schmitt AL, Higgins JM, Szczech JR, Jin S: Synthesis and applications of metal silicide nanowires. J Mater Chem 2010, 20: 223. 10.1039/b910968d
Reizer MY, Sergeev AV: The effect of the electron-phonon interaction of the conductivity of impure metals. Sov Phys JETP 1987, 65: 1291.
Echternach PM, Gershenson ME, Bozler HM: Evidence of interference between electron-phonon and electron-impurity scattering on the conductivity of thin metal films. Phys Rev B 1993, 47: 13659. 10.1103/PhysRevB.47.13659
Ptitsina NG, Chulkova GM, Il’in KS, Sergeev AV, Pochinkov FS, Gershenzon EM, Gershenson ME: Electron-phonon interaction in disordered metal films: the resistivity and electron dephasing rate. Phys Rev B 1997, 56: 10089. 10.1103/PhysRevB.56.10089
Lin JF, Bird JP, Rotkina L, Sergeev A, Mitin V: Large effects due to electron-phonon-impurity interference in the resistivity of Pt/C-Ga composite nanowires. Appl Phys Lett 2004, 84: 3828. 10.1063/1.1745108
Yeh SS, Lin JJ, Jing XN, Zhang DL: Electron-phonon-impurity interference effect in disordered Au56 Pd44 and IrO2 thick films. Phys Rev B 2005, 72: 024204.
Lin YH, Sun YC, Jian WB, Chang HM, Huang YS, Lin JJ: Electrical transport studies of individual IrO2 nanorods and their nanorod contacts. Nanotechnology 2008, 19: 045711. 10.1088/0957-4484/19/04/045711
Lin HK: Growth and characterization of titanium silicide nanostructures. PhD thesis. National Chiao Tung University, Department of Applied Chemistry; 2010 National Chiao Tung University, Department of Applied Chemistry; 2010
Marzi GD, Iacopino D, Quinn AJ, Redmond G: Probing intrinsic transport properties of single metal nanowires: direct-write contact formation using a focused ion beam. J Appl Phys 2004, 96: 3458. 10.1063/1.1779972
Peñate-Quesada L, Mitra J, Dawson P: Non-linear electronic transport in Pt nanowires deposited by focused ion beam. Nanotechnology 2007, 18: 215203. 10.1088/0957-4484/18/21/215203
Fernández-Pacheco A, Teresa JMD, Córdoba R, Ibarra MR: Metal-insulator transition in Pt-C nanowires grown by focused-ion-beam-induced deposition. Phys Rev B 2009, 79: 174204.
Chiu SP, Chung HF, Lin YH, Kai JJ, Chen FR, Lin JJ: Four-probe electrical-transport measurements on single indium tin oxide nanowires between 1.5 and 300 K. Nanotechnology 2009, 20: 105203. 10.1088/0957-4484/20/10/105203
Lien AS, Wang LY, Chu CS, Lin JJ: Temporal universal conductance fluctuations in RuO2 nanowires due to mobile defects. Phys Rev B 2011, 84: 155432.
Yang PY, Wang LY, Hsu YW, Lin JJ: Universal conductance fluctuations in indium tin oxide nanowires. Phys Rev B 2012, 85: 085423.
Ziman JM: Electrons and Phonons. Oxford: Clarendon; 1960.
Al’shuler BL: Temperature dependence of impurity conductivity of metals at low temperatures. Sov Phys JETP 1978, 48: 670.
Bid A, Bora A, Raychaudhuri AK: Temperature dependence of the resistance of metallic nanowires of diameter ≥ 15 nm: applicability of Bloch-Grüneisen theorem. Phys Rev B 2006, 74: 035426.
Bass J, Pratt WP, Schroeder PA: The temperature-dependent electrical resistivities of the alkali metals. Rev Mod Phys 1990, 62: 645. 10.1103/RevModPhys.62.645
Al’tshuler BL, Aronov AG: Electron-electron interaction in disordered conductors. In Electron-Electron Interactions in Disordered Systems. Edited by: Efros AL, Pollak M. Amsterdam: North-Holland; 1985:1–1.
Kästle G, Müller T, Boyen HG, Klimmer A, Ziemann P: Resistivity and phonon softening in ion-irradiated epitaxial gold films. J Appl Phys 2004, 96: 7272. 10.1063/1.1818713
This work was supported by the Taiwan National Science Council through grant nos. NSC 100-2120-M-009-008 (JJL) and NSC 100-2113-M-009-003-MY3 (HTC), and by the MOE ATU Program.
The authors declare that they have no competing interests.
WCH conducted the electrical measurements. CCC realized the FIBID contacts. They both participated in the experiment design. YHL analyzed the results and wrote the manuscript. HKL and HTC carried out the synthesis and structure and composition characterizations of the NWs. JJL coordinated and supervised the overall study and helped draft the manuscript. All authors read and approved the final manuscript.
About this article
Cite this article
Hsu, WC., Chen, CC., Lin, YH. et al. Metallic conduction and large electron-phonon-impurity interference effect in single TiSi nanowires. Nanoscale Res Lett 7, 500 (2012). https://doi.org/10.1186/1556-276X-7-500
- Chemical vapor deposition reaction
- TiSi nanowire
- Electron-phonon scattering
- Electron-phonon-impurity interference
- Focused-ion-beam-induced deposition