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Table 1 XPS core-level spectra curve-fitting results and VBM positions used to calculate VBO of the Ga 2 O 3 /GaN heterostructure

From: Valence band offset of β-Ga2O3/wurtzite GaN heterostructure measured by X-ray photoelectron spectroscopy

Sample

State

Binding energy (eV)

Bonding

FWHM (eV)

Ga2O3

Ga 3d

20.22

Ga-O

1.35

O1s

531.15

Ga-O

1.58

VBM

3.10

  

GaN

Ga3d

19.89

Ga-N

1.35

N1s

397.18

Ga-N

1.18

 

395.61

Ga Auger

1.89

 

393.44

Ga Auger

2.95

VBM

2.22

  

Ga2O3/GaN

Ga3d

20.56

Ga-O

1.23

 

19.57

Ga-N

1.03

O1s

531.27

Ga-O

1.72

N1s

396.93

Ga-N

1.75

 

395.36

Ga-Auger

2.36

 

393.19

Ga-Auger

3.02

  1. FWHM, full width at half maximum.

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