- Nano Express
- Open Access
Transmission electron microscope observation of organic–inorganic hybrid thin active layers of light-emitting diodes
© Jitsui and Ohtani; licensee Springer. 2012
- Received: 16 July 2012
- Accepted: 12 October 2012
- Published: 25 October 2012
We performed transmission electron microscope (TEM) observation of organic–inorganic hybrid thin films fabricated by the sol–gel reaction and used as the active layers of organic light-emitting diodes. The cross-sectional TEM images show that the films consist of a triple-layer structure. To evaluate the composition of these layers, the distribution of atoms in them was measured by energy-dispersive X-ray fluorescence spectroscopy. As a result, most of the organic emissive material, poly(9,9-dioctyl-fluorene-co-N-4-butylphenyl-diphenylamine (TFB), was found to be distributed in the middle layer sandwiched by SiO and SiO2 layers. The surface SiO layer was fabricated due to the lack of oxygen. This means that the best sol–gel condition was changed due to the TFB doping; thus, the novel best condition should be found.
- Organic light-emitting diodes
- Hybrid thin films
Organic light-emitting diodes (OLEDs) have been energetically investigated for application to flat-panel displays and illumination light sources[1–6]. However, the operation lifetime of OLEDs is shorter than that of inorganic LEDs because OLEDs are strictly affected by the oxidant effect. Very recently, we fabricated organic–inorganic hybrid LEDs in which the active layers consisted of organic emissive materials dispersed in SiO2[7, 8]. These novel LEDs exhibit very long operation lifetime because the organic emissive materials in SiO2 are protected against the oxidant effect. However, the structures of the fabricated organic–inorganic hybrid active layers are still unknown. In this research, we observe them by transmission electron microscope (TEM).
The organic–inorganic hybrid thin films were fabricated by sol–gel method. Poly(9,9-dioctyl-fluorene-co-N-4-butylphenyl-diphenylamine) (TFB) was used as an organic emissive material, while perhydropolysilazane (PHPS) was used as a sol–gel reaction accelerator. The ratio of TFB to PHPS was changed from 1 to 50 wt.%. They were dissolved together in xylene at a density of 3.5 wt.%. Then, a thin film of the TFB-PHPS solution was fabricated on a sufficiently cleaned SiO2 substrate by spin-coating method. Next, the samples were annealed to remove the xylene. Finally, the thin film was turned into the organic–inorganic hybrid material by humidity treatment of 90% RH at 50°C for 180 min. This temperature and humidity constituted the best condition for the sol–gel reaction of PHPS recommended by a chemical company, Sanwa Kagaku Corp. (Nagoya, Japan).
TEM observation was performed using JEM2100F (JEOL, Tokyo, Japan). To evaluate the distributions of atoms in the organic–inorganic films, energy-dispersive X-ray fluorescence spectroscopy (EDS) observation was additionally performed using JEM2100F. The samples were irradiated using an N2 laser for the photoluminescence (PL) measurement. PL spectra were measured using a multi-channel spectroscope (USB-2000, Ocean Optics, Dunedin, FL, USA). PL measurements were performed in atmosphere and at room temperature.
Mass distributions of the three atoms, carbon, oxygen, and silicon in the three layers
Organic–inorganic hybrid thin films fabricated by sol–gel reaction were investigated in detail by TEM and EDS observations. They consisted of triple-layer structures; most of the organic emissive material TFB was distributed in the middle layer sandwiched by SiO and SiO2 layers. The surface SiO layer was formed due to the lack of oxygen. This means that the best sol–gel condition was changed due to the TFB doping; thus, the novel best condition should be found.
The authors would like to thank Miwako Toda and Junko Morita for their cooperation in the TEM observation.
- Tang CW, VanSlyke SA: Organic electroluminescent diodes. Appl Phys Lett 1987, 51: 913–915. 10.1063/1.98799View ArticleGoogle Scholar
- Kido J, Ikeda W, Kimura M, Nagai K: White-light-emitting organic electroluminescent device using lanthanide complexes. Jpn J Appl Phys 1996, 35: L394-L396. 10.1143/JJAP.35.L394View ArticleGoogle Scholar
- Burroughes JH, Bradley DDC, Brown AR, Marks RN, Mackay K, Friend RH, Burns PL, Holmes AB: Light-emitting diodes based on conjugated polymers. Nature 1990, 347: 539–541. 10.1038/347539a0View ArticleGoogle Scholar
- Adachi C, Baldo MA, Thompson ME, Forrest SR: Nearly 100% internal phosphorescence efficiency in an organic light emitting device. Appl Phys Lett 2001, 90: 5048–5050.Google Scholar
- Wong W-Y, Ho C-L: Functional metallophosphors for effective charge carrier injection/transport: new robust OLED materials with emerging applications. J Mat Chem 2009, 19: 4437–4640.View ArticleGoogle Scholar
- Chen S, Deng L, Xie J, Peng L, Xie L, Fan Q, Huang W: Recent developments in top-emitting organic light-emitting diodes. Adv Mater 2010, 22: 5227–5239. 10.1002/adma.201001167View ArticleGoogle Scholar
- Kimura S, Jitsui Y, Ohtani N: Fabrication of organic light-emitting diodes containing SiO2 layer in active region. In 5th International Conference on Optical, Optoelectronic and Photonic Materials and Applications (ICOOPMA 2012), 3P-64;June 2012; NaraGoogle Scholar
- Jitsui Y, Kimura S, Ohtani N: Organic light-emitting diodes consisting of SiO2 active layer in which emissive organic materials are dispersed. In 31st International Conference on the Physics of Semiconductors (ICPS2012), 32.3. Zurich: ETH; 2012.Google Scholar
- Sato T, Fujikawa H, Taga Y: Influence of indium tin oxide electrodes deposited at room temperature on the properties of organic light-emitting devices. Appl Phys Lett 2005, 87: 143503. 10.1063/1.2077835View ArticleGoogle Scholar
This article is published under license to BioMed Central Ltd. This is an Open Access article distributed under the terms of the Creative Commons Attribution License (http://creativecommons.org/licenses/by/2.0), which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.