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Table 1 GPC and 1 H NMR data of (PCL) 2 (PDEA- b -PPEGMA) 2 polymers

From: pH-responsive micelles based on (PCL)2(PDEA-b-PPEGMA)2 miktoarm polymer: controlled synthesis, characterization, and application as anticancer drug carrier

Entry Samplea M n, GPC b Mw/Mnb M n, NMR c M n, RealIR d
1 (PCL24)2(PDEA16-b-PPEGMA19)2 14,888 1.28 29,617 28,200
2 (PCL24)2(PDEA37-b-PPEGMA15)2 12,692 1.19 33,977 34,300
3 (PCL38)2(PDEA26-b-PPEGMA11)2 18,302 1.19 29,530 28,524
4 (PCL38)2(PDEA17-b-PPEGMA9)2 13,586 1.35 24,480 24,614
5 (PCL32)2(PDEA25-b-PPEGMA22)2 19,389 1.41 37,766 38,114
6 (PCL32)2(PDEA20-b-PPEGMA19)2 18,707 1.37 32,907 32,120
  1. aThe subscripts of PCL, PDEA and PPEGMA were the DP of PCL (x), PDEA (y) and PPEGMA (z) calculated from 1H NMR spectrum; bmeasured by GPC in THF; ccalculated by the equations Mn, NMR = (114 × x + 185 × y + 475 × z ) × 2 + 434; dcalculated by monomer conversion from the ReactIR.