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Table 4 Assignment of the spectral bands (cm-1) observed for Thy and Thy/GO complex

From: Coherent anti-Stokes Raman scattering enhancement of thymine adsorbed on graphene oxide

RAMAN (λex = 785 nm) spectra

CARS spectra

Assignment in Thy[3638] and GO[33]

Thy

Thy/GO

Thy

Thy/GO

-

-

-

3,300

ν (OH) in GO

-

-

-

3,167

ν (NH); ν (OH) GO

3,065

3,065

-

3,065

ν (C6H)

3,006

3,005

-

2,991

ν (CH3)

2,968

2,967

-

2,963

ν (CH3)

2,989

2,989

2,972

2,989

ν (CH3)

2,936

2,936

2,945

2,930

ν (CH3)

2,892

2,897

2,870

-

ν (CH3)

-

2,831

-

2,848

CH, GO

2,739

2,738

2,749

2,753

CH

-

2,626

-

-

2D-mode in GO

1,673

1,675

1,660

1,670

ν (C2 = O)

-

-

1,655

-

ν (C4 = O)

-

1,603

-

-

G-mode in GO

-

-

1,520

1,525

ν ring

1,489

1,490

1,482

1,483

δN1H

1,460

1,459

1,461

1,458

δas (CH3)

1,437

-

-

1,436

CH3

1,411

1,410

1,406

1,405

νC2N3, δN1H

1,368

1,368

1,355

1,365

δs (CH3), δ (N3H)

-

1,319

-

-

D-mode in GO

1,247

1,248

1,247

1,249

ν (ring)

  1. ν, stretching; δ, deformation. All bands are assigned to Thy; the bands assigned to graphene oxide are noted.

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