Temperature-dependent gas transport performance of vertically aligned carbon nanotube/parylene composite membranes
© Zhang et al.; licensee Springer. 2014
Received: 23 June 2014
Accepted: 23 August 2014
Published: 28 August 2014
A novel composite membrane consisting of vertically aligned carbon nanotubes (CNTs) and parylene was successfully fabricated. Seamless filling of the spaces in CNT forests with parylene was achieved by a low-pressure chemical vapor deposition (CVD) technique and followed with the Ar/O2 plasma etching to expose CNT tips. Transport properties of various gases through the CNT/parylene membranes were explored. And gas permeances were independent on feed pressure in accordance with the Knudsen model, but the permeance values were over 60 times higher than that predicted by the Knudsen diffusion kinetics, which was attributed to specular momentum reflection inside smooth CNT pores. Gas permeances and enhancement factors over the Knudsen model firstly increased and then decreased with rising temperature, which confirmed the existence of non-Knudsen transport. And surface adsorption diffusion could affect the gas permeance at relatively low temperature. The gas permeance of the CNT/parylene composite membrane could be improved by optimizing operating temperature.
Because of their excellent mechanical, electrical, and thermal properties, carbon nanotubes (CNTs) have been used in many areas such as conductive or electromagnetic devices, sensors, high-strength composites, and multifunctional membranes [1–4]. Single-walled carbon nanotubes (SWCNTs) or multi-walled carbon nanotubes (MWCNTs) which have atomically smooth inner surfaces could provide us with ideal systems for the investigation on the characteristics of molecular transport in the nanometer scales [5, 6]. Recently, the phenomena of gas transport through CNTs embedded in polymer matrix are of great interest. The low-cost CNT/polymer composites are promising membranes which possess high transparency and extraordinary gas permeance performance [7, 8].
CNT-based membranes have opened up a new prospect for the selective separation of gases [9, 10]. CNTs exhibit routes of fast interfacial slip for gas molecules on their inner walls since they have a large non-interacting van der Waals distance and atomically smooth surfaces that do not scatter gas molecules. In addition, CNTs may provide uniform pore structures at the nanometer scales that can be finely tailored by controlling the catalyst particle sizes. Polymer matrix membranes with CNTs as fillers have attracted great attention since they are resilient, easily fabricated, and chemically stable. Unfortunately, random aggregations and dispersions of CNTs in the polymer matrix are usually found in the CNT/polymer membranes fabricated by a conventional solution method, which deteriorate the gas permeance performances of the membranes [11, 12]. In order to synthesize high-performance membranes, a lot of efforts have been devoted to improve CNT alignments with the assistances of electrical fields, flowing gases, and surface-lattice-guided growth of CNTs or CNT sheets [13, 14]. However, it remains a challenge to fabricate composite membranes in which good CNT alignment and high porosity were achieved simultaneously for high gas permeance. To address these issues, a fabrication method was developed by infiltrating vertically aligned CNTs (VACNTs) with poly-para-xylylene (parylene-C) through a vapor deposition technique [15–18]. In this work, the poly-para-xylylene (parylene-C) was chosen as matrix material to fill the intertube gaps in VACNTs because of its mechanical robustness, chemical inertness, and low permeability to moisture and gases, which are desirable for membrane applications. Furthermore, it is easy to be vapor-deposited at room temperature while providing excellent gap filling between high aspect ratio nanostructures, as will be ideal for infiltrating CNTs without sacrificing their alignment. So far, CNT forests embedded in parylene have been reported for several applications such as electrochemical sensors  and porous membranes , but it is still necessary to fully explore usage of this polymer in composite membranes for gas separation.
In the previous studies on the non-Knudsen transport phenomena in CNT-based membranes [19, 20], the effects of temperature on the permeation behaviors have not been well elucidated. Therefore, we investigate the effects of temperature on the permeation behaviors of membranes containing VACNT . For most gases, the permeance firstly increased as the temperature rose up to 50°C and then decreased with further increasing temperature. The changed permeance with temperature and the temperature-dependent gas permeance both suggested that the gas diffusion in CNT channels does not fully conform to the Knudsen diffusion kinetics, and other diffusion mechanisms of gas molecules might exist.
Water-assisted chemical vapor deposition (CVD) technique was employed to synthesize VACNTs at 815°C using high-purity ethylene (99.9%) as carbon source. Al2O3 (approximately 40 nm)/Fe (1.4 nm) bilayer films were evaporated on Si (100) substrate as catalysts. Mixture of pure argon (99.999%) and H2 (99.999%) with a total flow rate of 600 sccm was used as the carrier gas. Water vapor was employed as catalyst preserver and enhancer and was supplied by passing a portion of the carrier gas Ar through a water bubbler [22, 23]. Typically, the growth of CNT forests was carried out with ethylene (100 sccm) under a water concentration of 100 to 200 ppm for 10 s . And CNT forests of 8 to 10 μm in height were obtained.
To fabricate VACNT/parylene membranes, parylene was used to impregnate the spaces among VACNTs through a low-pressure CVD method. The as-synthesized VACNTs on Si substrates were placed in a deposition instrument (Parylene Coating System-2060 V, Shanghai PAL Chetech Co. Ltd, Shanghai, P.R. China). In a vacuum of 0.1 Torr, para-xylene monomer was polymerized to form parylene films on the CNT arrays, which was kept at room temperature. Ten-micrometer-thick parylene films were deposited, and the deposition rate was kept at 1.2 μm/h. After parylene deposition, the composite membranes were heated up and held at 375°C for 1 h in Ar atmosphere to allow the parylene to reflow. Subsequently, a planar surface of the membrane was formed. The membrane was then cooled at room temperature at a cooling rate of 1°C min-1.
After polymer infiltration and annealing, an Ar/O2 plasma etching process was carried out to remove the excessive parylene and open up the CNT tips [25–27]. The Ar/O2 plasma oxidation processing of the samples was accomplished using a homemade plasma-enhanced CVD (PECVD) apparatus. The operating power was 100 W, and the typical etching time was 90 min. Plasma treatment on the composite membrane was performed at 100 Pa at room temperature. A 13.56-MHz RF power supply (CESAR 136, Advanced Energy Industries, Inc., CO, USA) was used to generate plasma. Ar (99.999%) and O2 (99.999%) were employed as feed gases, and the background vacuum of the equipment was 1 × 10-4 Pa. The composite membrane with opened CNT channels was then immersed in a 50% hydrogen fluoride acid solution for 24 h to remove the CNT/parylene membrane from the silicon substrate. The freestanding composite membrane  was washed with deionized water, followed by drying. The bottom or untreated surface of the membrane was also treated shortly by plasma etching to expose CNTs. Finally, a through-hole membrane was obtained.
It is important to exclude the gas leakage within the polymer matrix when the gas permeances through the CNTs in the composite membranes are measured. The gas leakage in the CNT/parylene composite membrane was characterized through H2 permeation measurement before it was treated by plasma etching. The freestanding CNT/parylene composite membrane was first sealed between two pieces of aluminum adhesive tapes with pre-punched holes (3 mm in diameter). Then, the membrane was mounted in the gas line of a permeation testing apparatus, which was purged with the target gas for several times to avoid any possible impurities. Finally, pure H2, He, N2, Ar, O2, and CO2 (99.999%) were introduced to the upstream side of the membrane  for permeation measurements. A pressure or flow controller (MKS 250E, MKS Instruments, MA, USA) was connected to the upstream and downstream sides of the composite membrane to control the relative gas pressures by automatically tuning the gas feeding rates. The permeabilities at a variety of pressures (10 to 80 Torr) were measured using a mass flow meter connected at the downstream side. The measurements were carried out at different temperatures. The pore density and porosity of the membranes were measured using KCl diffusion through the membrane .
Results and discussion
After annealing (at 375°C), the extra parylene covering tips of CNTs on the membrane surfaces was removed by Ar/O2 plasma-enhanced oxidation. Plasma etching was performed at 100 W for 90 min by using 71.4% O2 in the feed gas. Figure 2c shows SEM image of the top surface of VACNT/parylene composite after plasma etching. Large numbers of bright spots were found, which were believed to be the extending CNT tips agglomerated together, sine parylene was etched faster than CNTs by oxidative plasma [9–11]. HRTEM observation (Figure 3d) confirms the protruding of CNTs from the above of the composite surface after plasma treatment. Furthermore, the marked area highlighted the opened CNT tips, which provides a direct proof for the opening of the exposed CNTs by oxidative plasma. Subsequently, HF acid was used to remove the VACNT/parylene composite from the Si substrate to produce a freestanding membrane. Another 5-min plasma etching was performed on the backside to expose the CNTs from the bottom surface. After these procedures, freestanding composite membranes with vertically aligned CNTs embedded in the parylene matrix were successfully fabricated.
where PKn is the Knudsen permeation (mol m-2 s-1 Pa-1), ϵp is the porosity, τ is the tortuosity, Φ is the inner diameter of CNT (m), L is the layer thickness (m), M is the molecular mass (kg mol-1) of the gas molecule, and T is the absolute temperature (K).The constant experimental permeances of the gases irrespective of the pressure gradient are consistent with the Knudsen model, which provide indirect but important evidence that the gas molecules do transport through the nanoscale interior channel of CNTs rather than the relatively large cracks in the membranes. This finding agrees well with the good impregnation of CNTs with the parylene, which has been demonstrated in Figure 3b.
Parameters of VACNT/parylene membranes
Thickness I (μm)
CNT diameter Φ (nm)
CNT tortuosity factor (τ)
Areal porosity (ϵp)
Interestingly, the enhancement factors of each gas show a similar dependence on temperature with the permeance. For most gases, the enhancement factor firstly increased as the temperature rose up to 50°C and then decreased with further increasing temperature. The changed enhancement factor with temperature and the temperature-dependent gas permeance both suggested that the gas diffusion in CNT channels does not fully conform to the Knudsen diffusion kinetics, and other diffusion mechanisms of gas molecules might exist. It is well established that the surface-adsorption-based diffusion in microporous membranes is an activation process, following the Arrhenius-type equation [33, 34]. Therefore, the increased permeance and enhancement factor with the temperature below 50°C indicated that surface diffusion might also play an important role in the total gas diffusion through our CNT/parylene membranes. Since the surface diffusion is thermally activated, its contribution to the total diffusivity was expected to rise with increasing temperature, which could lead to the increase in gas permeance and enhancement factor. However, when the temperature was over 50°C, gas adsorption on the CNT walls was attenuated and thus the contribution of surface diffusion to overall permeance decreased gradually with the temperature increment. Accordingly, the gas permeance and the enhancement factor over Knudsen kinetics decreased with further increasing temperature.
Figure 7b shows selectivity of hydrogen relative to other gases (He, Ar, N2, O2, CO2). Based on Knudsen diffusion, the gas selectivity is inversely proportional to the square root of the molecular weight ratio. For different gas pairs, the selectivity values are scattered around the Knudsen selectivity regime. However, the different selectivities at various temperatures demonstrated a derivation from the Knudsen kinetics, indicating the presence of other diffusion mechanisms beside Knudsen, such as surface diffusion.
In summary, an effective method to prepare flexible and robust VACNT/parylene composite membranes has been successfully developed by infiltrating CNT forests with parylene and exposing CNT tips through plasma etching. Transport properties of six gases across the composite membrane were explored, and gas permeances were found to be over 60 times higher than the Knudsen model prediction, which was attributed to the atomically smooth inner walls of CNTs. Investigation on temperature dependence of the gas permeances showed a tendency of first increase and subsequent decrease, and the permeance peaks around 50°C. H2 selectivity relative to other gases was around the Knudsen regime but also dependent on temperature. Discrepancy in the temperature dependences of the gas permeance and the selectivity with the Knudsen model indicates the existence of non-Knudsen transport and thermally activated surface diffusion. Further modeling and experimental investigations are still necessary to elucidate the non-Knudsen diffusion in the CNT composite membranes.
LZ is a carbon research scientist and a postgraduate of the University of Shanghai for Science and Technology. JY is a carbon research scientist and the head of the Advanced Carbon Materials Team at the University of Shanghai for Science and Technology.
The authors gratefully acknowledge the financial support from NSFC (51072118, 51272157), the 973 program (2010CB234609), Shanghai Shuguang Project (09SG46), the Innovation Fund Project for Graduate Student of Shanghai (JWCXSL1201), and SRF for ROCS, SEM.
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