- Nano Express
- Open Access
Synthesis and characterization of electrically conductive polyethylene-supported graphene films
© Carotenuto et al.; licensee Springer. 2014
- Received: 5 July 2014
- Accepted: 27 August 2014
- Published: 9 September 2014
We describe a simple mechanical approach for low-density polyethylene film coating by multilayer graphene. The technique is based on the exfoliation of nanocrystalline graphite (few-layer graphene) by application of shear stress and allows to obtain thin graphene layers on the plastic substrate. We report on the temperature dependence of electrical resistance behaviors in films of different thickness. The experimental results suggest that the semiconducting behavior observed at low temperature can be described in the framework of the Efros-Shklovskii variable-range-hopping model. The obtained films exhibit good electrical conductivity and transparency in the visible spectral region.
72.80.Vp; 78.67.Wj; 78.66.Qn; 85.40.Hp
- Shear stress
- Electrical conductor
- Polyethylene-supported graphene
The development of techniques for fabricating highly conductive, transparent, and flexible electrodes is the major challenge of organic electronics, and an important topic is the search of alternative materials to replace indium tin oxide (ITO) and fluorine tin oxide (FTO) which are widely used as metal oxide window electrodes in optoelectronic devices. In particular, ITO is practically the only available transparent and electrically conductive material really adequate for industrial applications. However, there are several drawbacks for the use of this material such as, limited availability of indium, poor chemical stability to acid and bases, low near-IR transparency, and easy substrate contamination by ion diffusion. The search for electrode materials with good stability, high transparency, and excellent electrical conductivity is therefore of great importance in optoelectronics. Graphene has emerged as a valuable alternative in view of its high electrical conductivity, flexibility, and good thermal and mechanical stability [1–3]. Recently, transparent and conductive electrodes have been fabricated by including graphene layers in polystyrene or silica but their electrical conductivity was found to be quite low, between 1 and 10-3 S/cm, depending on the amount of graphene [4–8]. An alternative method which involves segregation of the graphene phase, for example, on the surface of a proper substrate allows to obtain high-quality conductive and transparent films.
We describe a simple mechanical technique which makes use of low-density polyethylene film coating by multilayer graphene (PMLG). PMLG is produced by exfoliation of nanographite, i.e., few-layer graphene (FLG), under a combination of shear and friction forces. Since the graphene layers are weakly bound to the surface of FLG , they can be easily removed by the action of a shear stress. The mechanism of rubbing a liquid suspension of FLG between two flat and parallel surfaces using a liquid suspension of FLG leads to the development of π-π interactions with graphene layers and, ultimately, to complete exfoliation of the nanocrystal in the form of graphene sheets on the substrate surface. If the amount of exfoliated FLG is enough, the surface of the substrate is completely covered by few layers of graphene. Polyolefins, being able to interact with the graphene by CH/π interactions, are ideal substrates for graphene deposition by this mechanical procedure. We demonstrate here experimentally that low-density polyethylene substrates are well suited for graphene coating by FLG under the application of shear stress, and we report a systematic investigation of the optical behavior and temperature dependence of electrical transport properties of the PMLG films as a function of the thickness. We show that the dominant transport mechanism in PMLG at low temperatures is due to Coulomb interactions in the hopping regime.
The temperature dependence of electrical transport properties was also investigated on PMLG samples of different thickness. The temperature was varied from 50 to 300 K, and the current–voltage characteristic measurements were performed in liquid helium. The electrical contacts consisted in aligned gold pads deposited on the specimen surface by evaporation technique. The samples were thermally anchored at the last stage of the probe. The measurement lines are filtered using RC filters with cut-off frequencies of about 1 MHz, thermally anchored at 4.2 K. The sample was voltage-biased with a DC source and the current is measured by a picoammeter.
The produced films are optically transparent in the visible range with a thickness ranging from 15 to 30 layers obtained by optical measurements . The transmittance of the PMLG films was measured by UV–vis spectroscopy using a PerkinElmer lambda-850 spectrophotometer.
The current as a function of voltage I(V) in Figure 6a,b,c shows a finite resistance at zero bias and exhibits a nonlinear behavior with increasing the voltage which is more evident at low temperatures and in sample of lower number of layers. At sufficiently high temperatures, we observe linear I(V) over the considered voltage measurement range. In order to investigate the dominant scattering mechanism, we employed the resistance curve derivative analysis (RCDA) to study the temperature dependence of the conductance [11, 12].
Figure 6d compares the temperature dependence of the differential conductance G d = dI/dV at zero bias (-0.01 V ≤ V ≤ 0.01 V). The differential conductance of the PMLG samples is plotted versus T1/2 on a semilogarithmic scale. We can see that the experimental results are well fitted with the Efros-Shklovskii variable-range-hopping model (ES-VRH) and suggest that electron–electron Coulomb interactions are the dominant transport mechanisms and that they are strongly dependent on temperature. The characteristic temperature dependence of hopping conduction is given by G(T) = G0 exp[-(T0/T)1/2] where G0 is a prefactor with T0 being a constant and originates from localized states induced by charge impurities [13–15].
The red dotted lines in Figure 6d are linear fits of the conductance data based on the ES-VRH model below 160, 150, and 120 K for PMLG samples of N = 18, N = 14, and N = 11 graphene layers, respectively. With decreasing the number of layers, the PMLG samples become more insulating and we find that deviations from the behavior characteristic of ES-VRH hopping occur at slightly decreasing temperature as can be seen by comparing the temperature dependence of the conductance of the three samples (linear fit from top to bottom in Figure 6d).
Experimental data show that upon increasing the temperature, the conductance increases but the transport cannot be described by ES-VRH over the whole temperature measurement range. In higher temperature regime, the conductance tends to decrease slightly with increasing temperature, indicating metallic behavior of these films. The sheet resistance Rs of PMLG of 11 graphene layers is as high as about Rs = 4.5MΩ/sq but it decreases significantly with increasing the number of graphene layers. It is about 1.7MΩ/sq in films of 14 layers. The lowest Rs = 53KΩ/sq with transmittance (at 550 nm) of about 60% was obtained for PMLG of 18 graphene layers. These results demonstrate the fabricated PMLG films exhibit good electrical conductivity and that there is a trade-off between the conductivity and optical transparency with increasing graphene content.
In summary, we have described a simple mechanical technique for low-density polyethylene film coating by multilayer graphene. This technique is based on the exfoliation of nanocrystalline graphite by application of shear stress and allows to obtain thin graphene layers on the plastic substrate. The temperature dependence of the electrical resistance of PMLG samples of different graphene layers was investigated. The experimental results suggest that Coulomb interaction plays an essential role and we showed that Efros-Shklovskii variable-range-hopping is the dominant transport mechanism at low temperatures. The advantage of this approach is it is a cheap and simple fabrication procedure. The obtained films exhibit good electrical conductivity and transparency in the visible spectral region which can be of interest for their use as transparent and conductive films alternative to metal oxides in optoelectronic devices.
GC is a senior researcher of the Italian National Research Council, Institute for Polymers, Composites and Biomaterials. His present research interests are in the field of advanced functional materials based on polymer-embedded and polymer-supported organic and inorganic nanostructures. In particular, his research activity concerns graphene and graphene-based materials (graphene aerogels, carbon nanoscrolls, graphene oxide, etc.). Both the development of new methods for the production of graphene-based materials and techniques for the graphene chemical modification in addition to morphological, structural, and spectroscopic characterization methods are studied. He has authored 150 research articles published in international journals, ten patents, and many conference papers. He is the editor of two Wiley books devoted to metal-polymer nanocomposites and is a member of the editorial board of different scientific journals.
SDN got the degree in physics (1082) at ‘Federico II’ University of Naples, Italy. From 1983 to 1987, he was a system analyst at Elettronica S.pA. (Rome) and Alenia S.p.A. (Naples). Since 1988, he has been a staff researcher at the Institute of Cybernetics ‘E. Caianiello’ of the National Research Council (CNR). Currently, he is a senior researcher of the Italian National Research Council, Institute for Superconductors, Oxide Materials and Devices. He has been a scientific coordinator of the research project ‘Imaging Techniques for Studying and Analyzing Microstructured Materials’ of the Department of Physics Sciences and Matter Technologies (DSFTM) of the National Research Council. He has authored about 300 research articles in peer-reviewed international journals, book chapters, and conference proceedings and 7 patents. He has served in program committees of several international conferences and has been a referee for various journals in the field of optics and theoretical physics. His research interests include the development of quantum methodologies to the description of coherent phenomena in many body systems, quantum tomography, theoretical modeling for studying dynamical effects in mesoscopic systems and nanostructured polymeric materials, electronic coherent transport in nonconventional superconductors and graphene, and interaction of optical and electron beams in nonlinear media and plasma.
LN is the president of the National Research Council of Italy, a professor emeritus at the University of Naples ‘Federico II’, and an adjunct professor at the Universities of Connecticut in Storrs and Washington in Seattle. He has a prepost of the Schools of Science, Engineering, and Architecture of the University of Naples ‘Federico II’. He is the author of more than 500 papers in scientific journals and 35 patents and is also the editor of 15 books. He is a member of the editorial boards of many scientific journals. He was awarded the Society for the Advancement of Materials Technology (SAMPE) honor certificate, the ‘G. Dorsi’ and ‘Scanno’ prizes, and the gold medal of the Academy of the Forty. LN significantly contributed to the development of knowledge in the field of composite materials, rheology, energy and mass diffusion through polymers, and materials for biomedical application.
DM has a post doc position at the Physics Department of Università degli Studi di Napoli Federico II. His research involves the study of thermal and quantum properties of superconducting devices, with special focus on Josephson junctions. He has authored of about twenty articles published in international journals and the main results have been achieved in the study of escape dynamics of high critical temperature and hybrid Josephson junctions.
GA got the degree in Physics (1997) and PhD degree in Materials Engineering (2004) at ‘Federico II’ University of Naples, Italy. He is currently a researcher at ‘Federico II’ University of Naples, Italy. His main research topics are the production, characterization and application of amorphous magnetic materials, elastomagnetic composites, and nanostructures obtained by chemical synthesis and femtosecond laser ablation. The results of his research activity are reported on more than 80 papers published on international scientific journals, in three papers published on international scientific books, and in two patents.
GPP is an associate professor of the University of Napoli Federico II and deputy director of the Italian National Research Council, Institute for Superconductors, Oxide Materials and Devices. His present research interests are in the field of superconducting materials and devices, particularly on hybrid heterostructures and their characterization in terms of transport and optical properties down to very low temperatures. The application of superconducting materials to advanced photodetectors for visible and infrared single photons by nanowires is one of the main topics of actual interest. Recently, he devoted his scientific interest also to the investigation of functionalized nanomaterials for novel sensing devices by focusing on their optical responses in nonequilibrium conditions. He has authored more than 130 research articles published in many international journals, one patent, and many conference papers presented often as an invited speaker. He is member of the Advisory Board of the European Society for Applied Superconductivity (ESAS), of the Scientific Committee of the International Superconductive Electronics Conference (ISEC), and editor for superconducting nanoelectronics of the Superconducting News Forum of the IEEE Council of Superconductivity.
This work has been partially supported by Regione Campania through ‘POR Campania FSE 2007/2013, progetto MASTRI CUP B25B09000010007'.
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