- Nano Express
- Open Access
Green synthesis and synergistic catalytic effect ofAg/reduced graphene oxide nanocomposite
© Hsu and Chen; licensee Springer. 2014
- Received: 3 July 2014
- Accepted: 26 July 2014
- Published: 11 September 2014
A nanocomposite of silver nanoparticles and reduced graphene oxide (Ag/rGO) has been developed as a catalyst for the reduction of 4-nitrophenol (4-NP) to 4-aminophenol (4-AP) with sodium borohydride, owing to the larger specific surface area and synergistic effect of rGO. A facile and rapid microwave-assisted green route has been used for the uniform deposition of Ag nanoparticles and the reduction of graphene oxide simultaneously with l-arginine as the reducing agent. The resulting Ag/rGO nanocomposite contained about 51 wt% of Ag, and the Ag nanoparticles deposited on the surface of rGO had a mean diameter of 8.6 ± 3.5 nm. Also, the Ag/rGO nanocomposite exhibited excellent catalytic activity and stability toward the reduction of 4-NP to 4-AP with sodium borohydride. The reduction reaction obeyed the pseudo-first-order kinetics. The rate constants increased not only with the increase of temperature and catalyst amount but also with the increase of initial 4-NP concentration, revealing that the support rGO could enhance the catalytic activity via a synergistic effect. A mechanism for the catalytic reduction of 4-NP with NaBH4 by Ag/rGO nanocomposite via both the liquid-phase and solid-phase routes has been suggested.
- Silver nanoparticles
- Reduced graphene oxide
- Green synthesis
- Synergistic effect
The removal of 4-nitrophenol (4-NP) has received continuous attention in the past decades because it is a common organic pollutant in industrial wastewater. Many processes such as adsorption, microbial degradation, photocatalytic degradation, Fenton method, and electrochemical treatment have been developed. Furthermore, 4-NP can be utilized as a precursor of 4-aminophenol (4-AP). 4-AP is not only an intermediate in the syntheses of many analgesic/antipyretic drugs but also can be regarded as a corrosion inhibitor, photographic developer, hair-dyeing agent, and anticorrosion lubricant[2–4]. So, a great deal of efforts have been made on the reduction of 4-NP to 4-AP. Among them, the borohydride reduction of 4-NP to 4-AP by metal nanoparticles such as Au, Ag, Pt, Pd, and Pt-Ni is particularly attractive because this reaction can be performed in aqueous solution under mild condition[5–10]. However, for the sake of energy saving, safe operation, and avoiding the use of organic solvents, the development of more appropriate processes for the reduction of 4-NP to 4-AP in aqueous solutions under mild condition is still in demand.
On the other hand, graphene which is a two-dimensional single-layer carbon sheet has attracted great interest recently in various fields of science and engineering because of its unique electrical, optical, thermal, and mechanical properties[11–15]. Although a lot of methods have been developed for the preparation of graphene sheets, the most suitable and efficient approach was the solution-based chemical reduction of exfoliated graphite oxide to reduced graphene oxide (rGO) because of its low cost and facile synthetic nature in a controlled, scalable, and reproducible manner[16, 17]. Graphite oxide can be readily dispersed in water to yield the stable dispersions of graphene oxide (GO) by simple sonication, owing to the presence of oxygen-containing functional groups such as hydroxyl, epoxide, and carboxyl moieties. Furthermore, these oxygen-containing functional groups can act as nucleation centers or anchoring sites for the attachment of nanoparticles. They limited the growth of nanoparticles and improved the stability and dispersion of nanoparticles on GO or rGO. The attached nanoparticles are also helpful for enlarging the interplanar spacing of the GO or rGO in solid state, maintaining the excellent properties of individual GO or rGO sheets, and avoiding the aggregation of GO or rGO sheets into graphitic structure[20, 21]. Because of its large specific surface area and the above advantages, GO and rGO have been widely used as the supports for the attachment of nanoparticles to yield the nanocomposites for various applications.
According to the above, in this work, we attempted to fabricate the nanocomposite of Ag nanoparticles and rGO (Ag/rGO) for the catalytic reduction of 4-NP to 4-AP. Ag nanoparticles were chosen because they were cheaper as compared to other noble metal catalysts such as Au, Pt, and Pd[5–10, 22, 23]. Such a nanocomposite not only could be used in the catalytic field but also has been widely applied in antibacterial agent, electrochemical analysis, surface-enhanced Raman scattering (SERS), and so on[24–31]. Recently, we have developed a facile and rapid microwave-assisted green route to fabricate the Ag/rGO nanocomposite as a SERS substrate with high uniformity by using l-arginine as the reducing agent. The average size and content of Ag nanoparticles could be easily controlled by adjusting the cycle number of microwave irradiation. In that work, the formation of larger Ag nanoparticles which favored the enhancement of SERS intensity was desired. However, for the catalytic application, it is known that smaller nanoparticles usually exhibit higher specific catalytic activity. So, in this study, by modifying the condition of the l-arginine-based microwave-assisted green route, smaller Ag nanoparticles were uniformly deposited on rGO to fabricate the Ag/rGO nanocomposite for the catalytic reduction of 4-NP to 4-AP with sodium borohydride. As compared to other studies on the synthesis of Ag/rGO nanocomposites for catalytic reduction of 4-NP, the resulting Ag/rGO nanocomposite in this work had significantly higher content of Ag nanoparticles on rGO[24–26]. In addition, from the effect of 4-NP concentration, the synergistic effect of rGO was also demonstrated.
Graphite powder (99.9 %) was obtained from Bay Carbon (Bay City, MI, USA). Potassium manganite (VII) and sodium nitrate were purchased from J. T. Baker (Center Valley, PA, USA). Sulfuric acid was supplied by Panreac (Barcelona, Spain). Hydrogen peroxide was a product of Showa (Tokyo, Japan). Sulfuric acid was obtained from Merck (Whitehouse Station, NJ, USA). l-Arginine was supplied by Sigma-Aldrich (St. Louis, MO, USA). Silver nitrate and 4-nitrophenol were obtained from Alfa Aesar (Ward Hill, MA, USA). Sodium borohydride was the product of Aldrich. All chemicals were of guaranteed or analytical grade reagents commercially available and used without further purification. The water used throughout this work was the reagent grade water produced by a Milli-Q SP ultra-pure-water purification system of Nihon Millipore Ltd., Tokyo, Japan.
GO was prepared from purified natural graphite by a modified Hummers method. The graphite powder (1.5 g) and NaNO3 (0.75 g) were added to the concentrated H2SO4 (18 M, 37 mL) in an ice bath. KMnO4 (4.5 g) was added gradually under stirring. The mixture was then stirred at 35°C for 24 h. Then, deionized water (70 mL) was slowly added to the mixture, followed by stirring of the mixture at 98°C for 15 min. The suspension was further diluted to 110 mL and stirred for another 30 min. The reaction was terminated by adding H2O2 (3.7 mL, 35 wt%) under stirring at room temperature, followed by washing with deionized water several times.
Ag/rGO nanocomposite was synthesized by a facile, rapid and green process. Firstly, 15 mg of graphite oxide was dispersed in 20 mL of deionized water by ultrasonication to form a stable GO colloid solution, and then mixed with 10 mL of AgNO3 (180 mM) and l-arginine (60 mg/mL) solution. Next, the solution was transferred into a Teflon beaker and then reduced by three cycles of microwave irradiation (2.45 GHz, 900 W). Each cycle included 50 s ON and 10 s OFF. The product (denoted as 3C) was collected by centrifugation, then washed several times with deionized water, and finally dried in a vacuum oven at 35°C. Following the above procedures in the absence of AgNO3, rGO was prepared to confirm the reduction of GO by l-arginine and for comparison with Ag/rGO. Moreover, to investigate the effect of size and content of Ag nanoparticles on rGO, another two products 1C and 5C were also obtained under the same condition by one and five cycles of microwave irradiation, respectively.
The particle size and composition were determined by transmission electron microscopy (TEM) and energy dispersive X-ray (EDX) spectroscopy on a high-resolution field emission transmission electron microscopy (HRTEM, JEOL Model JEM-2100 F, JEOL Ltd., Tokyo, Japan). The high-resolution TEM (HRTEM) image and selected area electron diffraction (SAED) pattern were obtained by a JEOL Model JEM-2100 F electron microscope at 200 kV. The Ag content of Ag/rGO nanocomposite was also determined by dissolving the sample in a concentrated HCl solution and analyzing the solution composition using a GBC Model SDS-270 atomic absorption spectrometer (AAS; GBC Scientific, Braeside, Australia). The UV–vis absorption spectra of the resultant colloid solutions were monitored by a JASCO model V-570 UV/VIS/NIR spectrophotometer (JASCO, Tokyo, Japan). The crystalline structures were characterized by X-ray diffraction (XRD) analysis on a Shimadzu model RX-III X-ray diffractometer (Shimadzu Corporation, Kyoto, Japan) at 40 kV and 30 mA with CuKα radiation (λ = 0.1542 nm). Raman scattering was performed on a Thermo Fisher Scientific DXR Raman microscope using a 532-nm laser source (Thermo Fisher Scientific, Waltham, MA, USA). The X-ray photoelectron spectroscopy (XPS) measurements were performed on a Kratos AXIS Ultra DLD photoelectron spectrophotometer (Kratos Analytical Ltd, Manchester, UK) with an achromatic Mg/Al X-ray source at 450 W. Unless otherwise specified, the above characterization was done for the Ag/rGO nanocomposite 3C.
For the catalytic reduction of 4-nitrophenol, in general, an appropriate amount of Ag/rGO nanocomposite was added to the aqueous solution containing 4-NP and NaBH4 at the desired temperature to start the reaction. The bright yellow color of the solution gradually vanished, indicating the reduction of 4-NP. The variation of 4-NP concentration with time was monitored spectrophotometrically at a wavelength of 400 nm. The initial concentration ratio of NaBH4 to 4-NP was fixed at 100 so that the concentration of NaBH4 could be considered as a constant during the reaction. For the reusability study, the Ag/rGO nanocomposite was collected by centrifugation, washed with deionized water, and then reused. Unless otherwise specified, the Ag/rGO nanocomposite used for the catalytic reduction of 4-NP was the product 3C.
The Raman spectra of GO, rGO, and Ag/rGO nanocomposite are shown in Figure 4b. Two prominent peaks corresponding to the G and D bands of graphene were observed clearly. The G band is usually assigned to the E2g phonon of C sp2 atoms, while the D band originates from a breathing κ-point phonon with A1g symmetry and relates to local defects and disorders[38–40]. The intensity ratio of D band to G band (ID/IG) is correlative with the average size of sp2 domains. Higher ID/IG ratio means the smaller size of sp2 domains. From Figure 4b, the ID/IG ratios for GO, rGO, and Ag/rGO were 0.78, 1.07, and 1.11, respectively. It was reasonable that the ID/IG ratios of rGO and Ag/rGO nanocomposite were larger than that of GO because the conjugated graphene network (sp2 carbon) would be re-established after chemical reduction of GO but the size of the re-established graphene network was usually smaller than the original graphite layer, leading to the increase of ID/IG ratio. Thus, it could be concluded that silver ions and GO were reduced simultaneously by l-arginine. In addition, it was noted that the intensities of the D band and G band for Ag/rGO were larger than those for rGO. This was due to the Ag nanoparticles deposited on rGO which enhanced the Raman signal via SERS effect[31, 32]. Also, the ID/IG ratio of Ag/rGO was slightly larger than that of rGO. This might be due to the increase in the number of defects after the deposition of Ag nanoparticles on rGO.
Pseudo-first-order rate constants and TOF for reduction of 4-NP with NaBH 4 in the presence of Ag/rGO nanocomposite
Figure 7b indicates the catalytic reduction of 4-NP (0.05 mM) with NaBH4 at 25°C by different amounts of Ag/rGO nanocomposite (0.125 to 0.5 mg/100 mL). It was obvious that the reduction rate increased with the increase of the catalyst amount. The corresponding pseudo-first-order rate constants, R2, and turnover frequencies are also listed in Table 1. Because the pseudo-first-order rate constant increased linearly with the catalyst amount as indicated in the inset of Figure 7b, the role of Ag/rGO nanocomposite as the catalyst for the reduction of 4-NP with NaBH4 could be confirmed.
It was noted that the size and content of Ag nanoparticles on rGO should also influence the catalytic ability of Ag/rGO nanocomposite. Figure 7c shows the catalytic reduction of 4-NP (0.05 mM) with NaBH4 at 25°C by Ag/rGO nanocomposites 1C, 3C, and 5C (0.25 mg/100 mL). It was found that the catalytic activities of Ag/rGO nanocomposites increased in the following sequence: 1C < 5C < 3C. This revealed that the catalytic ability indeed depended on both the size and content of Ag nanoparticles on rGO. It is known that the specific activities of metal catalysts usually decrease with the increase of their size. Although increasing Ag content might increase the catalytic activity, too high Ag content might lead to the decrease of catalytic activity owing to the larger particle size and slight particle aggregation. So, in this work, the Ag/rGO nanocomposite 3C was found to be a better product for the catalytic reduction of 4-NP.
Figure 7d shows the effect of initial 4-NP concentration on the catalytic reduction of 4-NP (0.04 to 0.1 mM) with NaBH4 by Ag/rGO nanocomposite (0.25 mg/100 mL) at 25°C. The corresponding pseudo-first-order rate constants, R2, and turnover frequencies are listed in Table 1. It was found that the reaction rate increased with the increase of the initial 4-NP concentration. This phenomenon was different from some earlier studies and suggested that the use of rGO as the catalyst support might be helpful for the increase of catalytic activity, showing a synergistic effect. The synergistically enhanced catalytic activity might be explained as follows[44, 45]: Because 4-NP was π-rich in nature, it was expected that 4-NP could be adsorbed onto the surface of rGO via π-π stacking interaction, providing a higher 4-NP concentration near the Ag nanoparticles on the surface of rGO and therefore leading to the more efficient contact between them. For the earlier studies, the catalysts and/or the catalyst supports were usually present in the form of particles[1, 5–10]. Also, the adsorption of 4-NP on the surface of catalyst support was not significant like that on the surface of rGO. So, the reaction occurred mainly via the collision of 4-NP molecules between catalyst particles, leading to a slower reaction rate.
All the above observations demonstrated that the resulting Ag/rGO nanocomposite exhibited good catalytic activity toward the catalytic reduction of 4-NP to 4-AP with NaBH4, and the support rGO also enhanced the catalytic activity via a synergistic effect. As compared to previous works, the catalytic ability of the Ag/rGO nanocomposite obtained in this work was superior or comparable to most of them although different materials and conditions were used[1, 5–7, 9, 10, 20, 24–27, 35, 44]. This revealed that the Ag/rGO nanocomposite developed in this work could be used as a highly effective catalyst for the reduction of 4-NP with NaBH4.
Ag/rGO nanocomposite has been fabricated successfully via a rapid and facile green process. By the use of l-arginine and microwave irradiation, Ag nanoparticles were deposited uniformly on the surface of rGO. The Ag/rGO nanocomposite showed excellent catalytic activity and stability for the reduction of 4-NP to 4-AP with NaBH4. Also, the catalytic activity depended on both the size and content of Ag nanoparticles on rGO, and their appropriate controls were required. In addition, a mechanism for the catalytic reduction of 4-NP with NaBH4 by Ag/rGO nanocomposite via both the liquid-phase and solid-phase routes was suggested to describe the synergistic effect of rGO. Such a product could be used in the industrial wastewater treatment and the conversion of 4-NP to 4-AP in aqueous solution under mild condition.
KCH is currently a PhD student of the National Cheng Kung University (Taiwan). DHC is a distinguished professor of Chemical Engineering Department at National Cheng Kung University (Taiwan).
This work was performed under the auspices of the National Science Council of the Republic of China, under contract number NSC 102-2221-E-006-221-MY3, to which the authors wish to express their thanks.
- Chiou JR, Lai BH, Hsu KC, Chen DH: One-pot green synthesis of silver/iron oxide composite nanoparticles for 4-nitrophenol reduction. J Hazard Mater 2013, 248: 394–400.View ArticleGoogle Scholar
- Corbett JF: An historical review of the use of dye precursors in the formulation of commercial oxidation hair dyes. Dyes Pigments 1999, 41: 127–136. 10.1016/S0143-7208(98)00075-8View ArticleGoogle Scholar
- Rode CV, Vaidya MJ, Chaudhari RV: Synthesis of p -aminophenol by catalytic hydrogenation of nitrobenzene. Org Process Res Dev 1999, 3: 465–470. 10.1021/op990040rView ArticleGoogle Scholar
- Zhang B, Xu P, Xie X, Wei H, Li Z, Mack NH, Han X, Xu H, Wang H-L: Acid-directed synthesis of SERS-active hierarchical assemblies of silver nanostructures. J Mater Chem 2011, 21: 2495. 10.1039/c0jm02837aView ArticleGoogle Scholar
- Chang YC, Chen DH: Catalytic reduction of 4-nitrophenol by magnetically recoverable Au nanocatalyst. J Hazard Mater 2009, 165: 664–669. 10.1016/j.jhazmat.2008.10.034View ArticleGoogle Scholar
- Ghosh SK, Mandal M, Kundu S, Nath S, Pal T: Bimetallic Pt-Ni nanoparticles can catalyze reduction of aromatic nitro compounds by sodium borohydride in aqueous solution. Appl Catal A Gen 2004, 268: 61–66. 10.1016/j.apcata.2004.03.017View ArticleGoogle Scholar
- Hayakawa K, Yoshimura T, Esumi K: Preparation of gold-dendrimer nanocomposites by laser irradiation and their catalytic reduction of 4-nitrophenol. Langmuir 2003, 19: 5517–5521. 10.1021/la034339lView ArticleGoogle Scholar
- Lu Y, Mei Y, Schrinner M, Ballauff M, Moller MW: In situ formation of Ag nanoparticles in spherical polyacrylic acid brushes by UV irradiation. J Phys Chem C 2007, 111: 7676–7681. 10.1021/jp070973mView ArticleGoogle Scholar
- Naik B, Hazra S, Prasad VS, Ghosh NN: Synthesis of Ag nanoparticles within the pores of SBA-15: an efficient catalyst for reduction of 4-nitrophenol. Catal Commun 2011, 12: 1104–1108. 10.1016/j.catcom.2011.03.028View ArticleGoogle Scholar
- Yamamoto H, Yano H, Kouchi H, Obora Y, Arakawa R, Kawasaki H: N, N-Dimethylformamide-stabilized gold nanoclusters as a catalyst for the reduction of 4-nitrophenol. Nanoscale 2012, 4: 4148–4154. 10.1039/c2nr30222eView ArticleGoogle Scholar
- Balandin AA, Ghosh S, Bao WZ, Calizo I, Teweldebrhan D, Miao F, Lau CN: Superior thermal conductivity of single-layer graphene. Nano Lett 2008, 8: 902–907. 10.1021/nl0731872View ArticleGoogle Scholar
- Geim AK: Graphene: status and prospects. Science 2009, 324: 1530–1534. 10.1126/science.1158877View ArticleGoogle Scholar
- Geim AK, Novoselov KS: The rise of graphene. Nat Mater 2007, 6: 183–191. 10.1038/nmat1849View ArticleGoogle Scholar
- Kim KS, Zhao Y, Jang H, Lee SY, Kim JM, Kim KS, Ahn JH, Kim P, Choi JY, Hong BH: Large-scale pattern growth of graphene films for stretchable transparent electrodes. Nature 2009, 457: 706–710. 10.1038/nature07719View ArticleGoogle Scholar
- Stankovich S, Dikin DA, Dommett GHB, Kohlhaas KM, Zimney EJ, Stach EA, Piner RD, Nguyen ST, Ruoff RS: Graphene-based composite materials. Nature 2006, 442: 282–286. 10.1038/nature04969View ArticleGoogle Scholar
- Dreyer DR, Park S, Bielawski CW, Ruoff RS: The chemistry of graphene oxide. Chem Soc Rev 2010, 39: 228–240. 10.1039/b917103gView ArticleGoogle Scholar
- Eda G, Fanchini G, Chhowalla M: Large-area ultrathin films of reduced graphene oxide as a transparent and flexible electronic material. Nat Nanotechnol 2008, 3: 270–274. 10.1038/nnano.2008.83View ArticleGoogle Scholar
- Buchsteiner A, Lerf A, Pieper J: Water dynamics in graphite oxide investigated with neutron scattering. J Phys Chem B 2006, 110: 22328–22338. 10.1021/jp0641132View ArticleGoogle Scholar
- Jasuja K, Berry V: Implantation and growth of dendritic gold nanostructures on graphene derivatives: electrical property tailoring and Raman enhancement. ACS Nano 2009, 3: 2358–2366. 10.1021/nn900504vView ArticleGoogle Scholar
- Ji ZY, Shen XP, Zhu GX, Zhou H, Yuan AH: Reduced graphene oxide/nickel nanocomposites: facile synthesis, magnetic and catalytic properties. J Mater Chem 2012, 22: 3471–3477. 10.1039/c2jm14680kView ArticleGoogle Scholar
- Zhou XZ, Huang X, Qi XY, Wu SX, Xue C, Boey FYC, Yan QY, Chen P, Zhang H: In situ synthesis of metal nanoparticles on single-layer graphene oxide and reduced graphene oxide surfaces. J Phys Chem C 2009, 113: 10842–10846. 10.1021/jp903821nView ArticleGoogle Scholar
- Li C, Yamauchi Y: Facile solution synthesis of Ag@Pt core–shell nanoparticles with dendritic Pt shells. Phys Chem Chem Phys 2013, 15: 3490–3496. 10.1039/c3cp44313bView ArticleGoogle Scholar
- Ataee-Esfahani H, Liu J, Hu M, Miyamoto N, Tominaka S, Wu KCW, Yamauchi Y: Mesoporous metallic cells: design of uniformly sized hollow mesoporous Pt–Ru particles with tunable shell thicknesses. Small 2013, 9: 1047–1051. 10.1002/smll.201202539View ArticleGoogle Scholar
- Jeon EK, Seo E, Lee E, Lee W, Um M-K, Kim B-S: Mussel-inspired green synthesis of silver nanoparticles on graphene oxide nanosheets for enhanced catalytic applications. Chem Commun 2013, 49: 3392–3394. 10.1039/c3cc00115fView ArticleGoogle Scholar
- Mao A, Zhang D, Jin X, Gu X, Wei X, Yang G, Liu X: Synthesis of graphene oxide sheets decorated by silver nanoparticles in organic phase and their catalytic activity. J Phys Chem Solids 2012, 73: 982–986. 10.1016/j.jpcs.2012.03.013View ArticleGoogle Scholar
- Qu J-C, Ren C-L, Dong Y-L, Chang Y-P, Zhou M, Chen X-G: Facile synthesis of multifunctional graphene oxide/AgNPs-Fe3O4 nanocomposite: a highly integrated catalysts. Chem Eng J 2012, 211–212: 412–420.View ArticleGoogle Scholar
- Fernández-Merino MJ, Villar-Rodil S, Paredes JI, Solís-Fernández P, Guardia L, García R, Martínez-Alonso A, Tascón JMD: Identifying efficient natural bioreductants for the preparation of graphene and graphene-metal nanoparticle hybrids with enhanced catalytic activity from graphite oxide. Carbon 2013, 63: 30–44.View ArticleGoogle Scholar
- Hu Y, Perello D, Yun M, Kwon D-H, Kim M: Variation of switching mechanism in TiO2 thin film resistive random access memory with Ag and graphene electrodes. Microelectron Eng 2013, 104: 42–47.View ArticleGoogle Scholar
- Tang J, Chen Q, Xu L, Zhang S, Feng L, Cheng L, Xu H, Liu Z, Peng R: Graphene oxide-silver nanocomposite as a highly effective antibacterial agent with species-specific mechanisms. ACS Appl Mater Interfaces 2013, 5: 3867–3874. 10.1021/am4005495View ArticleGoogle Scholar
- Li J, Kuang D, Feng Y, Zhang F, Xu Z, Liu M, Wang D: Green synthesis of silver nanoparticles-graphene oxide nanocomposite and its application in electrochemical sensing of tryptophan. Biosens Bioelectron 2013, 42: 198–206.View ArticleGoogle Scholar
- Qian Z, Cheng Y, Zhou X, Wu J, Xu G: Fabrication of graphene oxide/Ag hybrids and their surface-enhanced Raman scattering characteristics. J Colloid Interface Sci 2013, 397: 103–107.View ArticleGoogle Scholar
- Hsu KC, Chen DH: Microwave-assisted green synthesis of Ag/reduced graphene oxide nanocomposite as a surface-enhanced Raman scattering substrate with high uniformity. Nanoscale Res Lett 2014, 9: 193. 10.1186/1556-276X-9-193View ArticleGoogle Scholar
- Li J, Liu C-Y: Ag/graphene heterostructures: synthesis, characterization and optical properties. Eur J Inorg Chem 2010, 2010: 1244–1248. 10.1002/ejic.200901048View ArticleGoogle Scholar
- Guardia L, Villar-Rodil S, Paredes JI, Rozada R, Martínez-Alonso A, Tascón JMD: UV light exposure of aqueous graphene oxide suspensions to promote their direct reduction, formation of graphene–metal nanoparticle hybrids and dye degradation. Carbon 2012, 50: 1014–1024. 10.1016/j.carbon.2011.10.005View ArticleGoogle Scholar
- Li J, Liu CY, Liu Y: Au/graphene hydrogel: synthesis, characterization and its use for catalytic reduction of 4-nitrophenol. J Mater Chem 2012, 22: 8426–8430. 10.1039/c2jm16386aView ArticleGoogle Scholar
- Beyene HT, Tichelaar FD, Peeters P, Kolev I, van de Sanden MCM, Creatore M: Hybrid sputtering-remote PECVD deposition of Au nanoparticles on SiO2 layers for surface plasmon resonance-based colored coatings. Plasma Process Polym 2010, 7: 657–664. 10.1002/ppap.201000003View ArticleGoogle Scholar
- Noguez C: Surface plasmons on metal nanoparticles: the influence of shape and physical environment. J Phys Chem C 2007, 111: 806–3819.View ArticleGoogle Scholar
- Ferrari AC, Meyer JC, Scardaci V, Casiraghi C, Lazzeri M, Mauri F, Piscanec S, Jiang D, Novoselov KS, Roth S, Geim AK: Raman spectrum of graphene and graphene layers. Phys Rev Lett 2006, 97: 187401.View ArticleGoogle Scholar
- Stampfer C, Molitor F, Graf D, Ensslin K, Jungen A, Hierold C, Wirtz L: Raman imaging of doping domains in graphene on SiO2. Appl Phys Lett 2007, 91: 241907. 10.1063/1.2816262View ArticleGoogle Scholar
- Tuinstra F, Koenig JL: Raman spectrum of graphite. J Chem Phys 1970, 53: 1126–1130. 10.1063/1.1674108View ArticleGoogle Scholar
- Stankovich S, Dikin DA, Piner RD, Kohlhaas KA, Kleinhammes A, Jia Y, Wu Y, Nguyen ST, Ruoff RS: Synthesis of graphene-based nanosheets via chemical reduction of exfoliated graphite oxide. Carbon 2007, 45: 1558–1565. 10.1016/j.carbon.2007.02.034View ArticleGoogle Scholar
- Xu C, Wang X, Zhu JW: Graphene-metal particle nanocomposites. J Phys Chem C 2008, 112: 19841–19845. 10.1021/jp807989bView ArticleGoogle Scholar
- Waterhouse GIN, Bowmaker GA, Metson JB: Oxidation of a polycrystalline silver foil by reaction with ozone. Appl Surface Sci 2001, 183: 191–204. 10.1016/S0169-4332(01)00561-XView ArticleGoogle Scholar
- Zhang YW, Liu S, Lu WB, Wang L, Tian JQ, Sun XP: In situ green synthesis of Au nanostructures on graphene oxide and their application for catalytic reduction of 4-nitrophenol. Catal Sci Technol 2001, 1: 1142–1144.View ArticleGoogle Scholar
- Yeh CC, Chen DH: Ni/reduced graphene oxide nanocomposite as a magnetically recoverable catalyst with near infrared photothermally enhanced activity. Appl Cat B Environ 2014, 150–151: 298–304.View ArticleGoogle Scholar
- Leary R, Westwood A: Carbonaceous nanomaterials for the enhancement of TiO2 photocatalysis. Carbon 2011, 49: 741–772. 10.1016/j.carbon.2010.10.010View ArticleGoogle Scholar
This article is published under license to BioMed Central Ltd. This is an Open Access article distributed under the terms of the Creative Commons Attribution License (http://creativecommons.org/licenses/by/4.0), which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly credited.