Magnetic and electric properties of stoichiometric BiMnO3 thin films
© Lee et al. ; licensee Springer. 2015
Received: 3 December 2014
Accepted: 16 January 2015
Published: 6 February 2015
It has been suggested that BiMnO3 is a material exhibiting both ferromagnetism and ferroelectricity. Stoichiometry is rather easily achieved in a polycrystalline sample, and ferromagnetic properties have been well documented for bulk samples. Stoichiometry in thin films has been difficult to obtain, and many physical properties have exhibit wide distributions mainly due to the stoichiometry problem. Thin film studies on BiMnO3 have not shown clear evidence of ferroelectricity, while other physical properties measured for the BiMnO3 films showed wide spectra, which has been attributed to cation and/or oxygen vacancies. We fabricated BiMnO3 thin films with good stoichiometry and with ferromagnetic properties comparable to those reported for stoichiometric BiMnO3: Tc ~ 105 K and M sat ~ 3.6 μB/Mn. The charge-electric field (Q-E) curve measured at 5 K was fairly linear and free from hysteresis and showed no ferroelectric order. This finding is consistent with the centrosymmetric crystal structure recently suggested by theoretical calculations and structural studies on ceramic samples of stoichiometric BiMnO3.
BiMnO3 has received huge interest due to the possibility of coexistence of ferroelectricity and ferromagnetism [1-11]. BiMnO3 has monoclinic symmetry with lattice parameters a = 9.533 Å, b = 5.606 Å, c = 9.854 Å, and β = 110.667°. The ferromagnetism has been explained in terms of orbital ordering of Mn4+ ions, while the Bi-6s lone pair was expected to result in ferroelectricity. The existence of ferromagnetism has been confirmed for both stoichiometric and ceramic BiMnO3. Most studies of ceramic BiMnO3 showed around the same ferromagnetic transition temperature of approximately 105 K, with a saturated magnetic moment of 3.6 μB/Mn, consistent with the high spin configuration of the Mn4+ ion. However, ferroelectricity of ceramic samples has not been measured. A sizable single crystal has not been obtained, and most measurements have been performed on polycrystalline samples requiring high-pressure synthesis.
It has been very difficult to obtain good stoichiometry in thin film BiMnO3, and the physical properties measured for thin films of BiMnO3 having unsatisfactory stoichiometry are often widely distributed. Thin film studies on BiMnO3 have not detected ferroelectricity very clearly, while other physical properties measured for the films varied across a wide spectrum. The films also exhibited non-optimum magnetic properties. Ferromagnetic transition temperatures and saturated magnetic moments were smaller than those reported for stoichiometric ceramic BiMnO3; thus, multiferroicity has not yet been accurately ascertained for stoichiometric BiMnO3.
The first thin film of BiMnO3 on SrTiO3 (001) substrate had Tc ~ 105 K, and an x-ray diffraction rocking curve peak had full width at half maximum of approximately 1.1° . In that study, no measurement was made of saturated magnetic moment, M sat, and the existence of ferroelectricity was not confirmed. Son et al. reported writing polarization bits on BiMnO3 thin films with a low Tc of approximately 50 K and full width at half maximum of approximately 0.4° . Pt/SrTiO3/BiMnO3/SrTiO3/Pt and SrRuO3/SrTiO3/BiMnO3/SrTiO3/SrRuO3 capacitors were also reported to show good ferroelectric properties with a remnant polarization of around 9 to 16 μC/cm2 but in combination with a very small saturated magnetic moment, M sat < 1.0 μB/Mn . It is notable that ferroelectricity was reported to arise from SrTiO3 itself [15-17]. A clear polarization electric field hysteresis curve was observed for a BiMnO3/SrTiO3 (001) structure grown using pulsed laser deposition with a high Bi-rich target of Bi2.4MnO3 . However, the ferromagnetic properties of the film were not optimum: Tc ~ 85 K, M sat ~ 1 μB/Mn. Ferromagnetic properties measured for BiMnO3 films made using chemical solution deposition or rf-magnetron sputtering were less favorable compared to those of stoichiometric ceramic BiMnO3 [19,20]. The depression in Curie temperature can be attributed to a non-stoichiometric composition, to strain, or to size effects .
Overall, the growth of BiMnO3 thin films with correct stoichiometry, free from vacancies, and with ferromagnetic properties similar to those measured in bulk samples has not yet been reported. Thin film growth of BiMnO3 suffers from high Bi volatility. To study the pertinent problem of multiferroicity in BiMnO3, we fabricated thin films of BiMnO3 with magnetic properties and stoichiometry matching those reported for high-pressure fabricated stoichiometric BiMnO3. Using these films, we investigated the existence of ferroelectricity in stoichiometric BiMnO3.
We fabricated BiMnO3 thin films on a SrTiO3 (001) substrate using a pulsed laser deposition method [21-24]. A KrF excimer laser with repetition rate of 4 Hz was used, and the optimum growth temperature was found to be very narrow: around approximately 500°C with oxygen partial pressure of approximately 10 mTorr. We used a freshly ground surface of Bi1.2MnO3 as the target. Note that the Bi overstoichiometry is rather small; together with the precise growth conditions, these characteristics of the target are one reason for the wide spectrum of physical properties reported in films. The number of pulses required per monolayer of BiMnO3 was about 13.6. The thickness was estimated to be around t ~ 88 nm, using field emission scanning electron microscope. We performed a detailed x-ray diffraction study of the epitaxial structure of the BiMnO3 films using high-resolution x-ray diffraction. For electrical transport studies, we used a physical property measurement system (Quantum Design, PPMS, San Diego, USA). Magnetic properties were determined using a superconducting quantum interference device (Quantum Design, MPMS, San Diego, USA). Ferroelectric characterization measurement with capacitance geometry was done on Nb-doped SrTiO3 substrate\BiMnO3\Au sample using a cryogenic probe station (Lake Shore Cryotronics, Inc., Westerville, USA) and semiconductor parameter analyzer (Agilent Technologies, Santa Clara, USA). The area of Au top electrode was approximately 100 μm × 100 μm.
Results and discussion
The reciprocal space maps shown in Figure 1b confirm nearly coherent growth of a BiMnO3 film on an SrTiO3 (001) substrate with an in-plane lattice constant of 3.909 Å. The calculated volume of one unit cell of BiMnO3 (V film = 60.89 Å3) in the film was 98.9% that of bulk monoclinic BiMnO3 (V bulk = 61.58 Å3). The roughly 1% volume reduction is mostly due to compressive strain from the SrTiO3 substrate. The slightly smaller unit cell volume measured for the film demonstrates that our stoichiometric BiMnO3 has negligible cation or oxygen vacancies.
Finally, we measured the charge-electric field (Q-E) curve to obtain evidence of ferroelectricity in the stoichiometric BiMnO3 film. Figure 3b shows Q-E curves at 5 K, where leakage problems, as shown in Figure 3a, do not occur. The Q-E curve measured at 5 K was fairly linear and free from hysteresis, and no ferroelectric order was observed. The absence of ferroelectric order in our stoichiometric film seems to be strengthened by the observation that the unit cell volume supports stoichiometry, that crystallinity is excellent, and ferromagnetic properties are as good as those reported for stoichiometric BiMnO3 samples.
Recently, there has been doubt about observations of ferroelectricity in some BiMnO3 films. It was reported theoretically that the ground state for BiMnO3 either with or without strain should be a centrosymmetric structure [29,30]. Rigorous structural studies on ceramic samples using transmission electron microscope and neutron diffraction data showed that BiMnO3 crystallizes in the centrosymmetric space group C2/c at 300 K . It was suggested that the weak ferroelectric polarizations measured on BiMnO3 samples originated from an ordered oxygen deficiency .
In summary, we investigated the existence of ferroelectricity in stoichiometric BiMnO3. We produced high-quality thin films with good stoichiometry and with magnetic properties - such as Tc and saturated magnetic moment - comparable to those reported for bulk stoichiometric BiMnO3. The structural quality was evidenced by narrow full width at half maximum for XRD peaks and good reciprocal space mapping data. Since vacancies in perovskite oxide film affect transport properties more than ferromagnetic properties, we believe that our stoichiometric BiMnO3 films should have sufficient quality for ascertaining the existence of ferroelectricity in stoichiometric BiMnO3. We found that the resistivity of the film demonstrates semiconducting behavior, with ρ(T = 300 K) ~ 4 × 104 Ω⋅cm. The Q-E curve measured at 5 K was fairly linear and free from hysteresis, and no ferroelectric order was observed. This finding is consistent with the centrosymmetric crystal structure recently suggested by theoretical calculations and structural studies on ceramic samples of stoichiometric BiMnO3. If ferroelectricity does exist in both stoichiometric BiMnO3 and non-stoichiometric BiMnO3, then Bi-6s lone pair scenario should be the best answer for the origin. Summarizing our work and other works, the existence of ferroelectricity seems to depend on the stoichiometry very sensitively. Then, other origin should be considered at least together since Bi-6s lone pair exists both for stoichiometric BiMnO3 without showing FE and non-stoichiomeric BiMnO3 showing FE.
C. U. Jung was supported by the Hankuk University of Foreign Studies Research Fund of 2014. The others were supported by the Basic Science Research Program through the National Research Foundation of Korea (NRF) funded by the Ministry of Education, Science and Technology (2012R1A1A2008595, 2012R1A1A2008845, and 2013R1A2A2A01067415).
- Prellier W, Singh MP, Murugavel P. The single-phase multiferroic oxides: from bulk to thin film. J Phys Conden Matter. 2005;17:R803–R832.View ArticleGoogle Scholar
- Sugawara F, Iida S, Syono Y, Akimoto S-I. New magnetic perovskites BiMnO3 and BiCrO3. J Phys Soc Jpn. 1965;20:1529.View ArticleGoogle Scholar
- Bokov VA, Myl’nikova IE, Kizhaev SA, Bryzhina MF, Grigorian NA. Structure and magnetic properties of BiMnO3. Sov Phys Solid State. 1966;7:2993–2994.Google Scholar
- Sugawara F, Iida S, Syono Y, Akimoto S-I. Magnetic properties and crystal distortions of BiMnO3 and BiCrO3. J Phys Soc Jpn. 1968;25:1553–1558.View ArticleGoogle Scholar
- Chiba H, Atou T, Syono Y. Magnetic and electrical properties of Bi1−xSrxMnO3. J Solid State Chem. 1997;132:139–143.View ArticleGoogle Scholar
- Faqir H, Chiba A, Kikuchi M, Syono Y, Mansori M, Satre P, et al. High-temperature XRD and DTA studies of BiMnO3 perovskite. J Solid State Chem. 1999;142:113–119.View ArticleGoogle Scholar
- Kimura T, Kawamoto S, Yamada I, Azuma M, Takano M, Tokura Y. Magnetocapacitance effect in multiferroic BiMnO3. Phys Rev B. 2003;67, R180401.View ArticleGoogle Scholar
- Atou T, Chiba H, Ohoyama K, Yamaguichi Y, Syono Y. Structure determination of ferromagnetic perovskite BiMnO3. J Solid State Chem. 1999;145:639–642.View ArticleGoogle Scholar
- Santos AM, Cheetham AK, Atou T, Syono Y, Yamaguchi Y, Ohoyama K, et al. Orbital ordering as the determinant for ferromagnetism in biferroic BiMnO3. Phys Rev B. 2002;66:064425.View ArticleGoogle Scholar
- Santos AM, Parashar S, Raju AR, Zhao YS, Cheetham AK, Rao CNR. Evidence for the likely occurrence of magnetoferroelectricity in the simple perovskite, BiMnO3. Solid State Commun. 2002;122:49–52.View ArticleGoogle Scholar
- Sharan A, Lettieri J, Jia Y, Tian W, Pan X, Schlom DG, et al. Bismuth manganite: a multiferroic with a large nonlinear optical response. Phys Rev B. 2004;69:214109.View ArticleGoogle Scholar
- Santos AFM, Cheetham AK, Tian W, Pan X, Jia Y, Murphy NJ, et al. Epitaxial growth and properties of metastable BiMnO3 thin films. Appl Phys Lett. 2004;84:91–93.View ArticleGoogle Scholar
- Son JY, Kim BG, Kim CH, Cho JH. Writing polarization bits on the multiferroic BiMnO3 thin film using Kelvin probe force microscope. Appl Phys Lett. 2004;84:4971–4973.View ArticleGoogle Scholar
- Son JY, Shin Y-H. Multiferroic BiMnO3 thin films with double SrTiO3 buffer layers. Appl Phys Lett. 2008;93:062902.View ArticleGoogle Scholar
- Haeni JH, Irvin P, Chang W, Uecker R, Reiche P, Li YL, et al. Room-temperature ferroelectricity in strained SrTiO3. Nature. 2004;430:758–761.View ArticleGoogle Scholar
- Schlom DG, Chen L-Q, Eom C-B, Rabe KM, Streiffer SK, Triscone J-M. Strain tuning of ferroelectric thin films. Annu Rev Mater Res. 2007;37:589–626.View ArticleGoogle Scholar
- Kim YS, Kim DJ, Kim TH, Noh TW, Choi JS, Park BH, et al. Observation of room-temperature ferroelectricity in tetragonal strontium titanate thin films on SrTiO3 (001) substrates. Appl Phys Lett. 2007;91:042908.View ArticleGoogle Scholar
- Jeen H, Singh-Bhalla G, Mickel PR, Voigt K, Morien C, Tongay S, et al. Growth and characterization of multiferroic BiMnO3 thin films. J Appl Phys. 2011;109:074104.View ArticleGoogle Scholar
- Naganuma H, Kovacs A, Harima T, Shima H, Okamura S, Hirotsu Y. Structural analysis of interfacial strained epitaxial BiMnO3 films fabricated by chemical solution deposition. J Appl Phys. 2009;105:07D915.Google Scholar
- Grizalez M, Delgado E, Gómez ME, Prieto P. Magnetic and electrical properties of BiMnO3 thin films. Phys Stat Sol (c). 2007;4:4203–4208.View ArticleGoogle Scholar
- Jung CU, Yamada H, Kawasaki M, Tokura Y. Magnetic anisotropy control of SrRuO3 films by tunable epitaxial strain. Appl Phys Lett. 2004;84:2590–2592.View ArticleGoogle Scholar
- Lee B, Kwon O-U, Shin RH, Jo W, Jung CU. Ferromagnetism and Ru-Ru distance in SrRuO3 thin film grown on SrTiO3 (111) substrate. Nano Res Lett. 2014;9:8.View ArticleGoogle Scholar
- Lee BW, Jung CU, Kawasaki M, Tokura Y. Tuning of magnetism in SrRuO3 thin films on SrTiO3 (001) substrate by control of the twin and strain amount in the buffer layer. J Appl Phys. 2008;104:103909.View ArticleGoogle Scholar
- Lee BW, Jung CU. Modification of magnetic properties through the control of growth orientation and epitaxial strain in SrRuO3 thin films. Appl Phys Lett. 2010;96:102507.View ArticleGoogle Scholar
- Hawley ME, Brown GW, Yashar PC, Kwon C. H-dependent magnetic domain structures in La0.67Sr0.33MnO3 thin films. J of Crystal. Growth. 2000;211:86–92.View ArticleGoogle Scholar
- Gajek M, Bibes M, Barthélémy A, Bouzehouane K, Fusil S, Valera M, et al. Spin filtering through ferromagnetic BiMnO3 tunnel barriers. Phys Rev B. 2005;72:020406.View ArticleGoogle Scholar
- Eerenstein W, Morrison FD, Scott JF, Mathur ND. Growth of highly resistive BiMnO3 films. App Phys Lett. 2005;87:101906.View ArticleGoogle Scholar
- Koster G, Klein L, Siemons W, Rijnders G, Dodge JS, Eom CB, et al. Structure, physical properties, and applications of SrRuO3 thin films. Rev Mod Phys. 2012;84:253–298.View ArticleGoogle Scholar
- Baettig P, Seshadri R, Spaldin NA. Anti-polarity in ideal BiMnO3. J Am Chem Soc. 2007;129:9854–98555.View ArticleGoogle Scholar
- Hatta AJ, Spaldin NA. Strain effects on the electric polarization of BiMnO3. J Eur Phys J B. 2009;71:435–437.View ArticleGoogle Scholar
- Belik AA, Iikubo S, Yokosawa T, Kodama K, Igawa N, Shamoto S, et al. Origin of the monoclinic-to-monoclinic phase transition and evidence for the centrosymmetric crystal structure of BiMnO3. J Am Chem Soc. 2007;129:971–977.View ArticleGoogle Scholar
- Yang H, Chi ZH, Jiang JL, Feng WJ, Dai JF, Jin CQ, et al. Is ferroelectricity in BiMnO3 induced by superlattice? J Mater Sci. 2008;43:3604–3607.View ArticleGoogle Scholar
This is an Open Access article distributed under the terms of the Creative Commons Attribution License (http://creativecommons.org/licenses/by/4.0), which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly credited.