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Table 2 The parameters of the conduction process in SPS LLT garnet nanoceramics

From: Lithium ionic conduction and relaxation dynamics of spark plasma sintered Li5La3Ta2O12 garnet nanoceramics

T (K)

σ dc (S/cm)

ω H (Hz)

n

n c (cm −3 )

μ (cm 2V −1s −1 )

D (cm 2s −1 )

SPS-850

      

230

1.15 × 10−10

4.87 × 102

0.60

6.08 × 1020

1.18 × 10−12

2.34 × 10−14

240

4.16 × 10−10

1.68 × 103

0.60

6.62 × 1020

3.92 × 10−12

8.11 × 10−14

250

1.45 × 10−9

5.21 × 103

0.60

7.78 × 1020

1.16 × 10−11

2.51 × 10−13

260

5.32 × 10−9

1.93 × 104

0.61

7.99 × 1020

4.16 × 10−11

9.31 × 10−13

270

1.75 × 10−8

6.10 × 104

0.62

8.65 × 1020

1.26 × 10−10

2.94 × 10−12

SPS-875

      

220

1.47 × 10−10

5.90 × 102

0.61

6.13 × 1020

1.50 × 10−12

2.84 × 10−14

230

5.37 × 10−10

2.12 × 103

0.61

6.50 × 1020

5.16 × 10−12

1.02 × 10−13

240

1.83 × 10−9

6.48 × 103

0.61

7.56 × 1020

1.51 × 10−11

3.12 × 10−13

250

6.44 × 10−9

2.32 × 104

0.62

7.74 × 1020

5.19 × 10−11

1.12 × 10−12

260

2.18 × 10−8

7.33 × 104

0.62

8.64 × 1020

1.57 × 10−10

3.53 × 10−12

SPS-900

      

240

1.28 × 10−10

4.88 × 102

0.60

7.02 × 1020

1.14 × 10−12

2.35 × 10−14

250

4.63 × 10−10

1.83 × 103

0.62

7.07 × 1020

4.09 × 10−12

8.80 × 10−14

260

1.69 × 10−9

6.36 × 103

0.64

7.71 × 1020

1.37 × 10−11

3.06 × 10−13

270

5.97 × 10−9

2.30 × 104

0.66

7.81 × 1020

4.77 × 10−11

1.11 × 10−12

280

1.85 × 10−8

6.83 × 104

0.64

8.45 × 1020

1.37 × 10−10

3.30 × 10−12

  1. The values of the dc conductivity σ dc, the hopping frequency ω H, the exponent n, the concentration of mobile Li ions n c, the mobility μ, and the diffusion coefficient D are summarized for the SPS LLT garnet nanoceramics at different temperatures.

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