Effect of Extra-Framework Cations of LTL Nanozeolites to Inhibit Oil Oxidation
© Tan et al. 2015
Received: 10 April 2015
Accepted: 26 May 2015
Published: 4 June 2015
Lubricant oils take significant part in current health and environmental considerations since they are an integral and indispensable component of modern technology. Antioxidants are probably the most important additives used in oils because oxidative deterioration plays a major role in oil degradation. Zeolite nanoparticles (NPs) have been proven as another option as green antioxidants in oil formulation. The anti-oxidative behavior of zeolite NPs is obvious; however, the phenomenon is still under investigation. Herein, a study of the effect of extra-framework cations stabilized on Linde Type L (LTL) zeolite NPs (ca. 20 nm) on inhibition of oxidation in palm oil-based lubricant oil is reported. Hydrophilic LTL zeolites with a Si/Al ratio of 3.2 containing four different inorganic cations (Li+, Na+, K+, Ca2+) were applied. The oxidation of the lubricant oil was followed by visual observation, colorimetry, fourier transform infrared (FTIR) spectroscopy, 1H NMR spectroscopy, total acid number (TAN), and rheology analyses. The effect of extra-framework cations to slow down the rate of oil oxidation and to control the viscosity of oil is demonstrated. The degradation rate of the lubricant oil samples is decreased considerably as the polarizability of cation is increased with the presence of zeolite NPs. More importantly, the microporous zeolite NPs have a great influence in halting the steps that lead to the polymerization of the oils and thus increasing the lifetime of oils.
Lubricant oil is one of the most beneficial components in modern technology that can be used to prevent friction in various industries and machinery . Besides synthetic oils, vegetable oils, particularly palm oil, are becoming an important alternative to mineral oils due to their economical feasibility, low toxicity, renewability, high biodegradability, low volatility, ideal cleanliness, and satisfactory lubricating performance . Nevertheless, low resistance to oxidative degradation and poor low temperature properties are major issues for palm oils to be used as lubricant . The formation of oxidation products in palm oil, such as hydroperoxides, carbonyl compounds, high-molecular-weight polymeric hydrocarbons, and free fatty acids, is undesirable due to their potential in deteriorating the lubricating properties of the oils. Furthermore, polymerization and cyclization at high temperature lead to the formation of sludge and soot which can cause an increase in oil viscosity. These side reactions, therefore, shorten the service lifetime of lubricant oils.
Several methods such as chemical modification (hydrogenation, inter-esterification, epoxidation), blending, and organic antioxidant additivation have been developed to improve the oxidation stability of lubricant oils [4–8]. However, some of these approaches are still not applied by the industries since excess modification will alter the useful properties of base oil and, concurrently, increases the production cost of lubricants. Furthermore, some of the chemicals used for modification are harmful and can severely pollute the environment.
The use of zeolite (AlPO-18 (AEI topology), <500 nm and Na+-X (FAU topology), 60 nm) as oil purifier has been carried out in our group . The basis of this approach is that nanozeolites with high surface area and hydrophilic behavior tend to adsorb oxidation products from the lubricant oil and hence produce oil with low oxidation products. Since then, the use of nanosized K+-LTL zeolite (<400 nm) as eco-friendly antioxidant in soybean oil-based lubricant is reported . The results showed that Linde Type L (LTL) zeolite effectively controls the content of acidic oxidation products in oil, and hence the oxidation process is significantly decelerated. The effect of zeolite nanoparticles in halting oil degradation is obvious in both mineral and soybean-based lubricants. However, the study on the chemical properties of zeolites in halting oil oxidation remains unclear.
Zeolites containing alkali and alkaline earth metals as the extra-framework cations have been extensively studied and used as molecular sieves for selective separation of nitrogen and oxygen from air [10, 11]. The charge, polarizability, charge density, and cationic size of extra-framework cations tend to affect the sorption and stabilization of diffused species since these cations are able to generate strong local electrical fields [12, 13]. The effect of extra-framework cations of zeolite in oil oxidation, however, has not been studied and hence is worth to be further investigated.
In the present paper, we report the influence of extra-framework cations on the oil oxidation. LTL-type zeolite nanoparticles containing four extra-framework basic cations (Li+, Na+, K+, and Ca2+) with different ionic radii, polarizability, and charge density are prepared and added as nano-additives during oil oxidation. The oil oxidative evolution is then characterized and followed by using analytical, spectroscopy, and thermogravimetry analyses.
Extraction of Silica from Rice Husk
Amorphous rice husk (RHA) silica was prepared as follows [14, 15]: Rice husk was initially washed with water to remove dusts and mud. The rice husk (100 g) was then soaked in HNO3 (1.0 L, 1.5 M), and the mixture was shaken for 15 h at 90 rpm. The acid-treated rice husk was washed with copious amount of distilled water until the pH of the filtrate reached 7.0. The rice husk was burnt in a muffle furnace (600 °C, 10 h) to obtain white amorphous RHA powder (98 % SiO2) as a final product.
Synthesis of Parent K-LTL Zeolite Nanocrystals
The potassium form LTL-type (K+-LTL) nanocrystals (as parent zeolite) was synthesized as follows without using any organic template : Initially, the clear silicate solution was prepared by dissolving RHA (3.93 g) in 8 mL of KOH solution (3.779 M) at 90 °C for 2 h. The clear alumina solution was obtained by dissolving the Al(OH)3 (1.02 g) in KOH solution (1.045 g, 3.779 M) at 100 °C overnight. The alumina solution was then introduced into the silicate solution under vigorous stirring to obtain the final gel molar composition of 10SiO2:Al2O3:4K2O:100H2O. The mixture was then introduced into an autoclave and allowed for crystallization at 170 °C for 24 h. The resulting zeolite solids were then purified with distilled water and freeze-dried.
Preparation of Li+-, Na+-, and Ca2+-LTL Zeolites
The Li+-, Na+-, and Ca2+-LTL zeolite nanocrystals were prepared via ion exchange treatment upon parent K+-LTL zeolite. Typically, K+-LTL zeolite nanocrystals (1.00 g) were added and magnetically stirred in the nitrate solutions (100 mL, 0.50 mol/L) of the targeted metal cations (LiNO3, NaNO3, Ca(NO3)2) at 60 °C for 6 h. The ion exchange process was repeated for five times by separating the supernatant from mother liquid, re-dispersing in the metal nitrate solutions, and carrying on with the ion exchange process to ensure the highest possible ion exchange was achieved. The zeolite nanocrystals after ion-exchanged were purified thoroughly with deionized water (pH = 7.5) prior to freeze-drying.
The palm oil-based lubricant used in this study was provided by the Malaysian Palm Oil Board (MPOB). First, 50.00 g of oil was mixed with 0.50 wt% (0.25 g) dehydrated LTL nanozeolites (Li+-, Na+-, K+-, or Ca2+-LTL). The oil mixture was allowed to oxidize at 150 °C for 400 h under reflux and stirring. Ten milliliters of oil samples were withdrawn at 100 h interval. The zeolite nanocrystals were recovered from the oils through centrifugation (25,000 rpm, 2 h). For comparison, similar amount of palm lubricant oil (50.00 g) was also oxidized using the same oxidation condition in the absence of zeolite nanocrystals and this oil sample was referred as a reference sample (Ref).
The purity and crystalline phase of zeolites were confirmed by a PANalytical X’Pert Pro X-ray diffractometer with Cu Kα monochromatized radiation (λ = 1.5418 Å, step size of 0.02°). The surface areas of zeolites were determined by a Micrometrics ASAP 2010 nitrogen adsorption analyzer. Prior to analysis, the zeolite powders were dehydrated at 250 °C under vacuum overnight. The Si/Al ratios of zeolite nanoparticles were determined by using a Varian 720-ES ICP-OES. The morphology and crystallite size of the samples were examined by a FEI Titan 80-300 transmission electron microscope (TEM) with an acceleration voltage of 300 kV.
Characterization—Palm Lubricant Oils
Colorimetric measurement of oil samples were carried out using a Shimadzu UV-2600 spectrophotometer with a wavelength scan at 530 nm where fresh palm lubricant oil was used as a reference. Fourier transform infrared (FTIR) spectroscopy was performed with a Perkin Elmer System 2000 spectrometer where the scans were taken with a spectral resolution of 4 cm−1. The total acid number (TAN) of oil samples was determined by a Cole-Parmer Aquamax titrator. The viscosity of the oils was measured by a Malvern Kinexus Rheometer. The water content in oil sample was measured via a volumetric Karl Fischer titrator (Metrohm 870 KF Titrino plus). 1H NMR analysis was carried out by using a Bruker AVIII spectrometer 400 MHz. Prior to analysis, the oil sample (225 mg) was dissolved with CDCl3 (450 mg) in a NMR tube.
Results and Discussion
Characterization of LTL Zeolite Nanocrystals
Properties of LTL zeolite nanocrystals containing different extra-framework cations 
Effective ionic radii (Å)
Charge density (e/Å3)
Polarizability of cation (10−24 cm3)
where p, q, r, and s are the number of atoms of the basic elements of LTL zeolite, and S denotes the electronegativity of the atom. From the calculation, the basicity follows the order Ca2+-LTL (3.98) < Li+-LTL (3.68) < Na+-LTL (3.66) < K+-LTL (3.53), where Ca2+-LTL is divalent cation-exchanged zeolite [17, 18].
Characterization of Palm Lubricant Oils
Visual Observation and Colorimetry Analysis
Total Acid Number Analysis
The effect of extra-framework cations on the oxidation of palm lubricant oil was also studied by performing the TAN analysis, by which the acidity in oil was contributed by the acidic oxidized compounds such as alcohols, aldehydes, ketones, carboxylic acids, and esters [25, 26]. The trend of TAN analysis (Fig. 5b) was found to be similar to the colorimetry observation. For example, the reference oil showed a slow increase in TAN values before 200 h, and its acidity increased abruptly after 200 h until the highest TAN value was recorded after 400 h (42.83 mg KOH/g oil). In contrary, the extra-framework cations effectively lowered down the TAN values of the oils. The acidity of the oils was significantly reduced by four to seven times compared to that of the reference oil after 400 h of oxidation. Typically, Na+-, K+-, and Ca2+-LTL had comparable performance in controlling the TAN values (6.72–8.75 mg KOH/g oil) whereas Li-LTL, which possessed the lowest cation polarizability (0.03 × 10−24 cm3), had the lowest effect in halting oil oxidation (13.92 mg KOH/g oil of TAN was recorded after 400 h).
The viscosity of the palm lubricant oils was studied by rheometry analysis as a function of oxidation time. The results demonstrated that the viscosity in the zeolite additivated oils especially with Ca2+-LTL and K+-LTL nanozeolites increased very slowly, and an increase in the viscosity value from ca. 0.05 to ca. 0.14 Pa⋅s was recorded throughout 400 h of oxidation (Fig. 5c). This result showed that the polymerization of oil to form viscous fluid takes place in a very limited extent along the oxidation process in both additivated oils. On the other hand, the oil samples oxidized with Li+-LTL and Na+-LTL possessed slightly higher viscosity values but still considered much lower when compared to the reference oil. As shown, the viscosity of zeolite additivated oil samples was about four to six times less than the reference sample after 400 h of oxidation. This observation provided strong evidence that extra-framework cations in LTL zeolite nanocrystals were able to retard the oxidation and polymerization processes in palm lubricant oil and concurrently maintained its quality for long term lubricating application.
On the other hand, small broadening of carbonyl IR bands was observed for the additivated oils (Fig. 6). For the palm lubricant oils oxidized with Li+-LTL and Na+-LTL zeolites, moderate increment in the peak width corresponding to carbonyl species was observed (Fig. 6). In contrast, LTL nanozeolites containing K+ and Ca2+ extra-framework cations were found to be the best oxidation inhibitor among the four types nanozeolites investigated. This data agreed with the TAN and colorimetry results, where low amount of oxidation products (mainly are lactones, esters, and carboxylic acids) was present in the oils oxidized with K+-LTL and Ca2+-LTL zeolite nanocrystals (Fig. 5a, b). These observations suggested that the anti-oxidation behavior of zeolite nanocrystals was depending on the type of extra-framework cation where highly polarizable Ca2+ and K+ effectively slowed down the formation of oxidation products in the palm oil.
A fast check for the presence of water can be usually made by looking at 3500–3350 cm−1 . However, moisture analysis in this region is not sensitive when the moisture content is less than 200 ppm, and the interpretation is becoming complicated due to spectral interferences from other O–H containing constituents such as alcohols, phenols, carboxylic acids, and hydroperoxides and confounded further by hydrogen bonding effects . Thus, the moisture content can be roughly inspected at 1655 cm−1. As indicated in Fig. 6, the reference oil had the largest amount of moisture compared to the other four zeolite additivated oil samples, which could be proven by a sharp baseline rise (Fig. 6c, d) at 1600 cm−1 whereas the additivated palm oil samples especially with K+-LTL and Ca2+-LTL zeolites had the lowest moisture content (Fig. 6d) after 400 h of oxidation. This observation was further supported by more precise Karl Fischer titration analysis.
1H NMR Spectroscopy
Karl Fischer Titration for Quantitative Moisture Analysis
Characterization of Zeolite Nanoparticles After Oil Oxidation
After oil oxidation, several peaks emerged indicating the presence of adsorbed organic species in the LTL zeolites. The signals at 2927 and 2855 cm−1 were assigned to the C–H stretching modes while the ones at 1461 and 1378 cm−1 were due to the C–H bending modes of the aliphatic hydrocarbons . In addition, the OH band at 3437 cm−1 was shifted to 3472 cm−1 and the shape of the band also changed indicating that besides water, the zeolites also adsorbed compounds containing OH group such as alcohols, hydroperoxides, and carboxylic acids . As shown, the degree of adsorption of these hydroxyl species and other carbonyl oxidation compounds (esters, 1744 cm−1, aldehydes and carboxylic acids, 1712 cm−1 ) varied depending on the type of extra-framework cations. The LTL containing the least polarizable Li+ cation (0.03 × 10−24 cm3) mostly adsorbed less polar esters (1744 cm−1) and aliphatic compounds (1461 and 1378 cm−1) whereas LTL zeolite containing highly polarized K+ (0.84 × 10−24 cm3) and Ca2+ (0.47 × 10−24 cm3) cations generally adsorbed more polar oxidation compounds such as carboxylic acids (1712 cm−1), water, alcohols, and hydroperoxides (3472 cm−1).
In addition, the IR spectrum of Ca2+-LTL also detected a signal at 1568 cm−1 which corresponded to (RCOO−)2Ca2+  This indicated that the deceleration of oxidative oil degradation in the presence of Ca2+-LTL zeolite could also be due to acid-base neutralization effect. In contrast, little to no signal was observed at 1568 cm−1 for the IR spectra of Li+-, Na+-, and K+-LTL. All the LTL nanozeolites also adsorbed hydroperoxides based on the two bands at 881 and 865 cm−1, which corresponded to the bending motions of O–O–H (inset of Fig. 9) [35, 36].
High concentration of solid particles in the lubricating oils with a relatively high hardness, size (≥10 μm), and particular shape is harmful to machinery as it may cause abrasive wear [37–39]. However, recent investigations reported on the nanoparticles (e.g., metal oxides and SiO2) with size less than 100 nm and a concentration of 2.0 wt% (20,000 ppm) are found to have negligible abrasive wear function on oil [40, 41]. Thus, it can be predicted that the zeolite nanocrystals (size less than 50 nm) added in trace amount (0.50 wt%) as nano-additives will not behave as abrasive.
Proposed Mechanism of Halting Oil Oxidation by LTL Zeolite Nanocrystals
The effect of extra-framework alkali metal and alkali earth metal cations on hindering the palm oil oxidation is demonstrated. A mechanism of halting the oil oxidation by ion-exchanged LTL zeolites is proposed based on the chemical and spectroscopy results obtained.
At high temperature (150 °C), thermal oxidation process is first initiated by the cleavage of C–H bond that adjacent to a C=C bond of unsaturated triglycerides to form free radical species . Further oxidation of these free radicals by air produces highly unstable hydroperoxides (ROOH) as the primary oxidation product. The reaction continues with the decomposition of the hydroperoxides into alkoxyl, hydroxyl, or peroxyl radicals, which later attack the unsaturated C=C bonds of triglycerides and form secondary oxidation products such as aldehydes and carboxylic acids. The autoxidation reaction of palm oil ends with polymerization and radical recombination processes at termination stage.
In contrast, autoxidation pathway is interrupted when LTL zeolite nanocrystals are added into palm oil. As demonstrated in the previous sections, slower oxidative degradation was achieved and lower amount of secondary oxidation products was detected in the palm oils additivated with LTL zeolite nanocrystals than the reference oil after 400 h of oxidation (Figs. 4, 5, 6, 7, and 8). The anti-oxidation activity of nanosized LTL zeolite can be explained by three phenomena, namely adsorption of oxidation products, stabilization of oxidation intermediates, and neutralization effect by extra-framework cations.
In addition, LTL zeolite is a porous material with one-dimensional open channels. The main channel of LTL zeolite has the smallest free diameter of about 0.71 nm, while the largest diameter inside is 1.26 nm . Hence, in order to allow the oxidation products to diffuse and adsorb in the pores of the zeolites, the oxidation products must (i) have a molecular size smaller than 0.71 nm and (ii) diffuse in a proper orientation (align parallel to the channel)  (Fig. 10b). In addition, LTL zeolite nanocrystals also contain high external surface area (ca. 25 % of the total surface area, Table 1) by which it facilitates adsorption of small (<0.71 nm) or bulk (>0.71 nm) oxidation products molecules on the external surface without considering diffusion in the pores of zeolite . Typically, the LTL zeolite nanocrystals containing highly polar cations (e.g., K+ and Ca2+) are able to adsorb more polar oxidation products than Li+-LTL and Na+-LTL via their external and internal surface area as revealed by the IR spectroscopy data (Fig. 9).
Furthermore, zeolites also function as acid neutralizers in oil. This characteristic is only exhibited by the alkaline earth Ca2+-LTL which has bidentate capability (Fig. 10c). As shown by IR spectroscopy, the Ca2+ cations in LTL zeolite are able to interact with the acidic carboxylate compounds and form COO−(Ca2+)1/2 species (Fig. 9). As a result, the acidity of the oil is reduced and the oil degradation is slowed down. The monovalent alkali metal cations exchanged zeolites, on the other hand, have limited effect on neutralizing the acidity of oil which can be proven by the presence of little to no signal at 1568 cm−1, a signal which is attributed to RCOO−M+ (M = Li, Na, K).
This work reports the effect of extra-framework cations (Li+, Na+, K+, Ca2+) in LTL zeolite nanocrystals on the oxidation of palm oil lubricant. The results show that the efficiency of zeolite nanocrystals in halting the oil oxidation is related to the cations polarizability. Ca2+-LTL and K+-LTL zeolite nanoparticles with high cation polarizability are the best candidate to hinder oil oxidation. In contrast, LTL nanozeolite containing slightly polarizable Li+ has the lowest oxidative inhibition activity.
The nanosized zeolites manage to reduce the oxidation level of oil by slowing down the rate of formation of oxidation products through stabilization of peroxides and adsorption of oxidation products. For Ca2+-X zeolite nanocrystals, the bidentate capability of Ca2+ is also able to reduce the acidity of the oil by neutralizing the acidic carboxylate compounds to form COO−(Ca2+)1/2 species as proven by IR spectroscopy. Aluminosilicate zeolite particularly the Ca2+-LTL and K+-LTL nanoparticles are thus a promising eco-friendly antioxidant that are able to slow down oil oxidation, and hence prolonging the lifetime of palm oil lubricants.
The authors would like to acknowledge the Bio-Asia Program, University Short Term (304/PKIMIA/6313047) and FRGS (203/PKIMIA/6711362) research grants for the financial support. KHT and HYC would also like to thank the MyBrain and USM fellowship for the scholarship provided.
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