Table 3 Effect of \( {C}_{{\mathrm{O}}_3}^{\mathrm{in}} \) on kinetic and stoichiometric parameters of the reaction of ozone decomposition by \( \mathrm{M}\mathrm{n}{\left(\mathrm{L}1\right)}_2/\overline{\mathrm{Si}} \) (CMn(II) = 0.6 × 10−4; CL = 7.0 × 10−4 mol/g)
\( {C}_{{\mathrm{O}}_3}^{\mathrm{in}}\times 1{0}^6,\mathrm{mol}/\mathrm{l} \) | W in × 107, mol/(g·s) | k 1 × 103, s−1 | τ 1/2, s | k 1/2 × 104, s−1 | Q exp × 105, О3 moles | Q СН × 105, О3 moles | n L | n СН, % | n Mn |
|---|---|---|---|---|---|---|---|---|---|
2.1 | 1.7 | 3.6 | 6600 | 1.0 | 30.2 | 74.7 | 2.2 | 40.0 | 25.2 |
4.2 | 3.5 | 3.8 | 4800 | 1.4 | 42.1 | 74.7 | 3.0 | 56.0 | 38.3 |
8.4 | 7.0 | 3.8 | 3900 | 1.8 | 49.7 | 74.7 | 3.6 | 66.5 | 41.4 |