Table 4 Kinetic and stoichiometric parameters of the reaction of ozone decomposition by \( \mathrm{M}\mathrm{n}{\left(\mathrm{L}\right)}_2/\overline{\mathrm{Si}} \) complexes \( \left({C}_{{\widehat{\mathrm{O}}}_3}^{\mathrm{in}}=4,2\times {10}^{-6}\mathrm{mol}/\mathrm{l}\right) \)
Sample | k 1 × 103, s−1 | τ 1/2, s | k 1/2 × 104, s−1 | Q exp × 105, О3 moles | Q CH × 105, О3 moles | n L | n CH, % | n Mn |
|---|---|---|---|---|---|---|---|---|
L1 | 3.8 | 1800 | 3.8 | 11.1 | 74.7 | 0.8 | 15.0 | – |
Mn(L1) | 3.8 | 4800 | 1.4 | 42.1 | 74.7 | 3.0 | 56.0 | 38.3 |
L2 | 2.8 | 960 | 7.2 | 10.6 | 72.3 | 0.8 | 15.0 | – |
Mn(L2) | 2.4 | 600 | 11.5 | 6.4 | 72.3 | 0.5 | 9.0 | 4.0 |
L3 | 3.2 | 1600 | 4.3 | 12.3 | 116.7 | 0.9 | 10.5 | – |
Mn(L3) | – | 13,800 | 0.5 | 127.2 | 116.7 | 9.1 | 109.0 | 374.1 |
L4 | 6.2 | 3300 | 2.2 | 26.0 | 86.4 | 1.8 | 30.0 | – |
Mn(L4) | 6.0 | 1680 | 4.1 | 101.0 | 86.4 | 7.0 | 117.0 | 63.1 |
L5 | 1.3 | 240 | 28.8 | 13.2 | 45.0 | 1.8 | 29.0 | – |
Mn(L5) | 1.6 | 1080 | 6.4 | 35.3 | 45.0 | 4.7 | 78.0 | 15.0 |
L6 | 5.6 | 2820 | 2.4 | 19.6 | 84.0 | 1.4 | 23.0 | – |
Mn(L6) | 5.1 | 10,200 | 0.7 | 93.7 | 84.0 | 6.7 | 111.0 | 66.8 |