Table 1 X-ray spectral parameters and the phase composition of SCWA-ANO
Phase Ref. | Freshly prepared sample | Modified sample | ||||||
---|---|---|---|---|---|---|---|---|
2θ, ° | I N | d (Ǻ) | 2θ, ° | I N | d (Ǻ) | |||
Exp. | Ref. | Exp. | Ref. | |||||
(Mn,Fe)(Cr,V)2O4 | 18.212 | 85 | 4.867 | 4.85 | 18.362 | 219 | 4.828 | 4.85 |
36.654 | 70 | 2.449 | 2.44 | – | – | – | – | |
– | – | – | – | 42.784 | 210 | 2.112 | 2.12 | |
56.402 | 121 | 1.630 | 1.63 | 56.453 | 197 | 1.629 | 1.63 | |
61.727 | 149 | 1.502 | 1.50 | – | – | – | – | |
– | – | – | – | 62.402 | 369 | 1.487 | 1.50 | |
Fe3O4 | 35.389 | 1000 | 2.534 | 2.55 | 35.546 | 999 | 2.524 | 2.55 |
36.978 | 87 | 2.429 | 2.42 | 37.204 | 222 | 2.415 | 2.42 | |
43.027 | 297 | 2.100 | 2.10 | 43.186 | 344 | 2.093 | 2.10 | |
53.414 | 58 | 1.714 | 1.71 | – | – | – | – | |
57.001 | 219 | 1.614 | 1.61 | 57.015 | 295 | 1.614 | 1.61 | |
62.587 | 463 | 1.483 | 1.483 | 62.724 | 528 | 1.480 | 1.483 | |
73.957 | 75 | 1.281 | 1.279 | 74.154 | 121 | 1.278 | 1.279 | |
79.004 | 22 | 1.211 | 1.210 | 78.943 | 70 | 1.212 | 1.210 | |
Mn3O4 | 53.638 | 57 | 1.707 | 1.70 | 53.712 | 147 | 1.705 | 1.70 |
K2CO3 | 34.189 | 95 | 2.620 | 2.61 | Not detected | |||
Na2CO3 | 56.058 | 90 | 1.639 | 1.62 | Not detected | |||
62.071 | 250 | 1.494 | 1.48 | Not detected | ||||
63.278 | 62 | 1.470 | 1.48 | Not detected | ||||
K2CrO4 | 38.826 | 38 | 2.317 | 2.32 | Not detected | |||
K2Cr2O7 | 30.809 | 75 | 2.900 | 2.85 | Not detected | |||
53.091 | 48 | 1.724 | 1.73 | Not detected | ||||
(Mn,Fe)(Cr,V)2O4; | 30.033 | 328 | 2.973 | 2.99 | 30.159 | 439 | 2.961 | 2.99 |
Fe3O4; | 2.97 | 2.97 | ||||||
K2CrO4 | 2.96 | 2.96 |