Table 5 Kinetic parameters for the reaction of ozone decomposition by freshly prepared and modified SCWAs (\( {C}_{{\mathrm{O}}_3}^{\mathrm{in}} = 100\ \mathrm{mg}/{\mathrm{m}}^3,{m}_{\mathrm{s}} = 0.5\ \mathrm{g} \))
Sample | W in × 108, mol/L × s | k 1 × 103, s−1 | k 1/2 × 104, s−1 | Q exp × 105, О3 moles |
---|---|---|---|---|
FP SCWA-ANO | 7.00 | 4.4 | 3.3 | 8.3 |
M SCWA-ANO | 6.51 | 3.7 | 14.4 | 4.0 |
FP SCWA-TsL | 5.76 | 2.2 | 24.0 | 0.9 |
M SCWA-TsL | 6.65 | 3.8 | 8.8 | 4.9 |
FP SCWA-UONI | 5.95 | 2.4 | 13.8 | 4.4 |
M SCWA-UONI | 4.97 | 0.8 | 6.1 | 6.0 |