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ZnO Nanoparticles/Reduced Graphene Oxide Bilayer Thin Films for Improved NH3-Sensing Performances at Room Temperature
Nanoscale Research Letters volume 11, Article number: 130 (2016)
ZnO nanoparticles and graphene oxide (GO) thin film were deposited on gold interdigital electrodes (IDEs) in sequence via simple spraying process, which was further restored to ZnO/reduced graphene oxide (rGO) bilayer thin film by the thermal reduction treatment and employed for ammonia (NH3) detection at room temperature. rGO was identified by UV-vis absorption spectra and X-ray photoelectron spectroscope (XPS) analyses, and the adhesion between ZnO nanoparticles and rGO nanosheets might also be formed. The NH3-sensing performances of pure rGO film and ZnO/rGO bilayer films with different sprayed GO amounts were compared. The results showed that ZnO/rGO film sensors exhibited enhanced response properties, and the optimal GO amount of 1.5 ml was achieved. Furthermore, the optimal ZnO/rGO film sensor showed an excellent reversibility and fast response/recovery rate within the detection range of 10–50 ppm. Meanwhile, the sensor also displayed good repeatability and selectivity to NH3. However, the interference of water molecules on the prepared sensor is non-ignorable; some techniques should be researched to eliminate the effect of moisture in the further work. The remarkably enhanced NH3-sensing characteristics were speculated to be attributed to both the supporting role of ZnO nanoparticles film and accumulation heterojunction at the interface between ZnO and rGO. Thus, the proposed ZnO/rGO bilayer thin film sensor might give a promise for high-performance NH3-sensing applications.
As air pollutions become more and more serious, the demand for high-performance and low-cost gas sensors increases. Among the toxic gases of interest, ammonia (NH3) is one of the most harmful environmental pollutants with a strong and irritating smell aroused from different sources, such as combustion of chemical materials, electronic manufacturing, medical treatment, and ammonification by nitrogen cycle [1, 2]. Generally, an acceptable level of NH3 is 8-h exposure limit at 25 ppm and a short-term (15 min) exposure level at 35 ppm [3–5]. Therefore, there is a practical meaning to develop sensitive and reliable gas sensors operated at room temperature targeting NH3. Up to now, the most typical NH3-sensing materials are metal-oxides semiconductor systems (SnO2, ZnO, TiO2, WO3, In2O3, etc.). Among them, ZnO is one of the most promising materials due to its ideal chemical and thermal stability, low-cost and good gas-sensing responses [6, 7]. However, the high working temperature (200–500 °C), low selectivity, and slow response/recovery rate of metal-oxide-based sensors limit their further application. Thus, it still remains a great challenge to improve gas-sensing performances of present metal-oxide-based NH3 sensors, and further work should be performed.
Recent research has shown that composite of metal-oxide nanomaterials with other gas-sensing materials such as reduced graphene oxide (rGO) could enhance sensing properties of individual materials [7–13]. rGO is more beneficial for gas molecule detection compared with pure graphene due to its residual oxygen functional groups that provide an increased amount of adsorption sites [6, 14, 15]. Meanwhile, rGO has also great advantages of low-cost and bulk quantity production . Up to now, different ZnO nanomaterials, such as nanoflowers [6, 9], nanoparticles [7, 16, 17], nanofibers , nanorods [11, 18, 19], and quantum dots [20, 21], were designed and used for ZnO/rGO gas-sensing hybrid materials preparation, and the enhanced sensing performances for various gases including nitrogen dioxide (NO2), hydrogen (H2), formaldehyde (HCHO), methane (CH4), and ethyl acetate have been reported and analyzed, which might be ascribed to more adsorption sites and creation of p-n heterojunctions, etc. [8–10]. However, despite their improved advantageous characteristics, these sensors still suffer from several shortcomings more or less, such as high operating temperature (more than 100 °C) [8, 11, 16–18], baseline drift , and long recovery time . Therefore, further enhancement of gas-sensing properties is still strongly required.
Recently, in our lab, a novel TiO2/rGO layered film was proposed and prepared through simple thermal treatment for HCHO detection at room temperature, and an interesting abruption of rGO sheets during the heating process was focused and discussed in details . Herein, a similar strategy was used for the development of ZnO/rGO bilayer thin film-based NH3 sensor operated at room temperature. The effect of rGO amount on sensing properties was investigated, sensing mechanism model was established, and interaction between NH3 molecules and sensor was further deciphered in the present work. The resultant bilayer film sensor might have great potential in the development of novel NH3 gas sensor.
Similar details of experimental process on metal-oxide nanoparticles/rGO-based bilayer thin film were reported in our earlier work . GO was synthesized from natural graphite flakes through Hummer’s method. In a typical process run, as shown in Fig. 1, firstly, 2 mg/ml ZnO colloid in ethanol (purchased from Sigma-Aldrich) and 0.5 mg/ml GO aqueous solution were obtained through dilution and then sonicated, and secondly, 1 ml ZnO colloid and different amount GO solution (0.5, 1, 1.5, 2, and 2.5 ml) were deposited on gold interdigital electrodes (IDEs) in sequence by spraying process. After that, ZnO/GO bilayer thin film samples were restored to ZnO/rGO films through thermal reduction process (in nitrogen flow, 220 °C for 2 h). The corresponding sample was noted as ZnO/rGO-0.5, ZnO/rGO-1, ZnO/rGO-1.5, ZnO/rGO-2, and ZnO/rGO-2.5, respectively. Pure rGO (1 ml) film was also prepared under the same condition for comparison.
Characterization and Measurement
The surface morphology features of prepared thin films were observed using a field emission scanning electron microscope (FESEM, S-4800, Hitachi Ltd., Japan). Ultraviolet-visible (UV-vis) spectra were measured with UV-1700 pharmaSpec (Japan, Shimadzu) in the range of 190–800 nm. The X-ray photoelectron spectroscope (XPS) analysis was performed with a commercial X-ray photoelectron spectrometer (Scienta ESCA-200) using MgKα X-ray source.
The electrical properties of sensors were measured by Keithley 4200-SCS. For gas-sensing properties evaluation, the fabricated sensors were placed in a homemade gas sensor assembly (Teflon chamber), and resistance changes of sensors were recorded at room temperature by a Keithley 2700 data acquisition system connected to a computer. Mass flow controllers (MFC, MT50-4J, Beijing Metron Instruments Co. Ltd, China) were employed to vary the concentration of standard NH3 vapors (100 ppm) in dry air (carrier gas). The tested chamber was purged with dry air between each NH3 pulse to allow the film surface to recover. The sensor response (R) is defined as R% = (R gas − R air)/R air × 100, where R gas and R air are the resistance in tested gas and dry air, respectively. The response/recovery time is defined as the sensor achieved 90 % of total resistance change.
Results and Discussion
Representative FESEM micrographs of single rGO and ZnO/rGO-1 film are shown in Fig. 2. Figure 2a represents rGO nanosheets with slimsy wrinkles whereas Fig. 2b displays obvious fluctuant transparent rGO nanosheets with dispersed ZnO nanoparticles or their aggregation, which should be ascribed to the supporting function of ZnO nanoparticles under folded rGO sheets. It is conjectured that ZnO/rGO bilayer film should possess larger surface area than pure rGO one, and good adhesion between rGO and ZnO nanoparticles might also be formed with the aid of thermal reduction treatment .
Figure 3 shows UV-vis absorption spectra of prepared different films. In the absorption spectrum of ZnO/GO film, it shows both absorption peaks of GO at ca. 226 nm (π-π* transitions of C–C bonds)  and ZnO at ca. 362 nm (the intrinsic band gap absorption) , referred to pure ZnO and GO films shown in Fig. 3. The spectrum of ZnO/rGO-1 bilayer thin film also exhibits the overlapping absorption bands of ZnO and rGO (ca. 254 nm, the excitation of π-plasmon of the graphitic structure). However, the ZnO/rGO film showed a slight blue shift from 366 to 361 nm compared with pure ZnO, and from 259 to 252 nm compared with pure rGO, which might be explained by the quantum size effect of the fine structure in nanometer regime . It has been proved that the excitation energy of ZnO nanoparticles will increase with the decrease of grain diameter according to the Kubo theory ; therefore, the blue shift of ZnO absorption peak in ZnO/GO-layered film might demonstrate the decrease of ZnO nanoparticles size and further indicate certain synergistic effect between ZnO and rGO layers. Meanwhile, ZnO/rGO film exhibits an enhanced optical absorption in the UV-visible spectral region, which was also observed and reported in ref. . The reduction of GO was further investigated by XPS spectra of C elements present in GO and ZnO/rGO-1 samples, as shown in Fig. 4a, b. It can been seen that C1s spectra of both samples could be deconvoluted into three Gaussian peaks associated with C–C, C–O, and C=O, respectively. Compared with the peak intensity of C–O and C=O in GO (Fig. 4a), the peak intensities of C–O and C=O in ZnO/rGO sample decrease obviously, indicating that GO has been restored to rGO successfully with some amount of residual oxygenic groups after thermal reduction [7, 16, 24, 26], which is also consistent with UV-vis spectra results.
Electrical and Gas-Sensing Properties
The electrical behavior of rGO and ZnO/rGO-1 film samples was investigated at room temperature, and the corresponding current-voltage (I-V) curves were displayed in Fig. 5, in which the magnified I-V curve of ZnO/rGO-1 sample was inset. Both samples exhibit the typical p-type semiconductor and almost linear characteristics, indicating the ohmic nature of films. It is noteworthy that the resistance of ZnO/rGO bilayer thin film is two orders higher than that of rGO, and the reason for this phenomenon might be that ZnO usually has a much higher resistance at room temperature compared to rGO; meanwhile, some discontinuous ZnO nanoparticles under rGO layer are also unhelpful for charge transport in ZnO/rGO bilayer thin film.
The response-recovery behavior is one of the important properties for evaluating the characteristics of gas sensors; therefore, dynamic response curves of pristine rGO and different ZnO/rGO bilayer thin film sensors are shown in Fig. 6 when exposed to 10 and 50 ppm NH3 at room temperature. Apparently, the resistances of all sensors show an increased trend when adsorbing NH3 vapor (reducing gas), further indicating the p-type semiconductor characteristic of rGO and ZnO/rGO samples. The response values, response, and recovery times of all samples were calculated and summarized in Table 1. Obviously, ZnO/rGO bilayer thin film sensors all exhibit overall improvement including larger response values and shorter response/recovery time than those of bare rGO one, and ZnO/rGO-1.5 sample shows the highest response, almost three times higher than pure rGO one. It is also noticeable that the response values of ZnO/rGO samples increase with increasing rGO amount and then decrease with a further rise of rGO amount. The maximum response value and shorter response/recovery time were obtained when sprayed GO amount was 1.5 ml. On the basis of these results, ZnO/rGO-1.5 sample was chosen for the subsequent investigations.
The real-time response curves of ZnO/rGO-1.5 sensor are plotted in Fig. 7 when exposed to a series of NH3 concentration ranging from 10 to 50 ppm at room temperature. It shows that the response increases quickly upon exposure to NH3 and returns to its initial baseline after exposure to dry air, suggesting the good reversibility of optimized sensor in NH3 sensing. The response and recovery time were found to be within 1.5 and 4.0 min, respectively. Furthermore, the relationship of response values as a function of NH3 concentration and its fitting curve has also been investigated and inset in Fig. 7, showing a good linear characteristic of responses versus NH3 concentration with a regression coefficient (R 2) of 0.9827. The reproducibility of the sensor was also assessed for sequential four pulses of 10 ppm NH3, and the result is exhibited in Fig. 8, indicating good reproducibility with less than 10 % drift in response. Furthermore, to evaluate the selectivity of the sensor, ZnO/rGO-1.5 sensor was exposed to different interfering gases including carbon dioxide (CO2, 1000 ppm), HCHO (10 ppm), NO2 (10 ppm), and hydrogen sulfide (H2S, 10 ppm), and the transient gas-sensing response curves are shown in Fig. 9a, in which the response values versus NH3 and interfering gases are inset. As expected, the response value of ZnO/rGO-1.5 sensor towards 10 ppm NH3 presents about 2–30 times greater than that to other tested gases; meanwhile, it is obvious that response/recovery rates of sensor to NH3 are significantly quicker than those to other gases. Consequently, the sensor exhibited superior selective ability to NH3. Compared with some recent reports in ZnO [25, 27, 28] or graphene [29, 30] based NH3 sensors, the as-prepared ZnO/rGO thin film sensor in our work exhibits lower cost, better reversibility, smaller detection concentration, and quicker response/recovery rates. Meanwhile, the spraying process is also simple and feasible. However, it was found in the experiment that the resistance of prepared ZnO/rGO film sensor decreased promptly with exposure to 32.8 % RH and 75.2 % RH (7.1 % RH level was served as the baseline) and then gradually reached a relatively stable response value (ca. 20 and 32, respectively) accompanied with an incomplete recovery, as shown in Fig. 9b. It is obviously seen that the response of the sensor to water molecules is much larger (one or two orders of magnitude) than that of the sensor when exposed to NH3 or other tested interfering gases, indicating that the interference of water molecules on the prepared sensor is non-ignorable. The mechanism of this phenomenon should be ascribed to the residual oxygenic groups (high hydrophilicity) of rGO  and active sites (oxygen vacancies) of ZnO for dissociation of water molecules . Therefore, some proper techniques should be researched to eliminate the effect of moisture in the further work.
Many researchers have reported improvement in gas-sensing properties due to heterojunction formation between metal oxide and rGO for their hybrids [7–11, 16, 18–21]. Meanwhile, for metal-oxide nanoparticles/rGO-layered thin film sensor, a preliminary sensing mechanism has also been discussed in our previous report , in which the supporting and catalytical roles of lower TiO2 nanoparticles were proposed. Based on the above reports, the enhanced NH3-sensing performances of ZnO/GO film sensor at room temperature are proposed in this present work, which should be ascribed to two aspects, one is the supporting role of ZnO nanoparticles layer (as illustrated in ref 22) and the other is the formed accumulation heterojunction at interface between rGO and ZnO. Furthermore, the effect of upper rGO amount on sensing properties is also focused. A schematic illustration of sensing mechanism is shown in Fig. 10.
For bare rGO layer, as shown in Fig. 10a, the electrons transfer from reducing NH3 gas molecules to p-type rGO nanosheets and result in a decrease of charge carriers concentration (the resistance increases). After an appropriate amount of rGO nanosheets are deposited on the surface of ZnO nanoparticles film, we suggest two kinds of adsorption sites, being related to rGO nanosheets surface and ZnO/rGO interfaces, exist in bilayer thin film at room temperature, in which the latter one might be responsible for the enhancement of sensing properties compared with pure rGO film. It is noteworthy that although O2− could be produced on the surface of ZnO nanoparticles even at room temperature (see Fig. 10b), the catalytic oxidation ability of O2− is not powerul enough to convert NH3 as the final product (N2 and H2O) when the temperature is lower than 373 K . However, since the work function of p-rGO (4.75 eV) is lower than that of n-ZnO (5.20 eV), a considerable amount of local accumulation heterojunctions at interfaces between rGO nanosheets and ZnO nanoparticles might be formed at ZnO/rGO interfaces , in which more holes and electronics could accumulate in rGO and ZnO regions of heterojunction, respectively, as shown in the magnified view of Fig. 10b. In the present case, rGO becomes more p-type than the original state, and thus, the energy barrier between absorbed NH3 molecules and rGO is further reduced , resulting in the higher response values and shorter response times. However, in case of ZnO/rGO-2.0 and ZnO/rGO-2.5 samples, it is possible that an excess of rGO might weaken the supporting role of lower ZnO nanoparticles film and further reduce the probability of target NH3 gas molecules adsorption at heterointerfaces between ZnO and rGO films, leading to a decline in sensor responses, as shown in Fig. 10c.
In summary, ZnO/rGO bilayer sensitive thin film was produced through a two-step process. In the first step, ZnO nanoparticle film and GO layer were sprayed on gold interdigital electrodes in sequence, and then GO was successfully restored to rGO by the thermal reduction method at 220 °C for 2 h, as proved by the UV-vis spectra and XPS analyses. The experimental results showed that ZnO/rGO bilayer sensing film exhibited a comprehensive enhancement of room-temperature NH3-sensing performances compared with pure rGO one, including higher response values (~threefold better than that of rGO) and shorter response/recovery time (ca. 30/90 s was shorten). Meanwhile, the sensing properties were influenced significantly by the sprayed rGO amount, and the optimized amount of rGO was found to be 1.5 ml. The reason for the sensing property improvement was interpreted from the views of supporting roles of ZnO nanoparticle layer and accumulation heterojunctions at ZnO/rGO interfaces. Furthermore, the optimal sensor possessed short response time (<1.5 min), excellent linear characteristic, reversibility, reproducibility, and selectivity upon exposure to NH3 at room temperature. This sensor shows great potential for applications as room temperature operated NH3 gas sensor.
reduced graphene oxide
Wang LL, Huang H, Xiao SH, Cai DP, Liu Y, Liu B, Wang DD, Wang CX, Li H, Wang YR, Li QH, Wang TH (2014) Enhanced sensitivity and stability of room-temperature NH3 sensors using core-shell CeO2 nanoparticles@cross-linked PANI with p-n heterojunctions. ACS Appl Mater & Inter 6:14131–14140
Wang J, Wei XW, Wangyang PH (2015) Gas-sensing devices based on Zn-doped NiO two-dimensional grainy films with fast response and recovery for ammonia molecule detection. Nanoscale Res Lett 10:461
Lee S-K, Chang D, Kim SW (2014) Gas sensors based on carbon nanoflake/tin oxide composites for ammonia detection. J Hazard Mater 268:110–114
Chen T-Y, Chen H-I, Hsu C-S, Huang C-C, Wu J-S, Chou P-C, Liu W-C (2015) Characteristics of ZnO nanorods-based ammonia gas sensors with a cross-linked configuration. Sens Actuators B 221:491–498
Sukhananazerin A, Thalakkotur LM, Biji P (2015) Highly sensitive, room temperature gas sensor based on polyaniline-multiwalled carbon nanotubes (PANI/MWCNTs) nanocomposite for trace-level ammonia detection. Sens Actuators B 221:1523–1534
Zhang S, Chen H-S, Matras-Postolekc K, Yang P (2015) ZnO nanoflowers with single crystal structure towards enhanced gas sensing and photocatalysis. Phys Chem Chem Phys 17:30300–30306
Liu S, Yu B, Zhang H, Fei T, Zhang T (2014) Enhancing NO2 gas sensing performances at room temperature based on reduced graphene oxide-ZnO nanoparticles hybrids. Sens Actuators B 202:272–278
Abideen ZU, Kim J-H, Kwon YJ, Kim HW, Kim SS (2015) Excellent gas detection of ZnO nanofibers by loading with reduced graphene oxide nanosheets. Sens Actuators B 221:1499–1507
Li X, Wang J, Xie D, Xu JL, Dai RX, Xiang L, Zhu HW, Jiang YD (2015) Reduced graphene oxide/hierarchical flower-like zinc oxide hybrid films for room temperature formaldehyde detection Sens. Actuators B 221:1290–1298
Mu HC, Zhang ZQ, Zhao XJ, Liu F, Wang KK, Xie HF (2014) High sensitive formaldehyde graphene gas sensor modified by atomic layer deposition zinc oxide films. Appl Phys Lett 105:033107
Anand K, Singh O, Singh MP, Kaur J, Singh RC (2014) Hydrogen sensor based on graphene/ZnO nanocomposite. Sens Actuators B 195:409–415
Feng QX, Li XG, Wang J, Gaskov AM (2016) Reduced graphene oxide (rGO) encapsulated Co3O4 composite nanofibers for highly selective ammonia sensors. Sens Actuators B 222:864–870
Mao S, Cui SM, Lu GH, Yu KH, Wen ZH, Chen JH (2012) Tuning gas-sensing properties of reduced graphene oxide using tin oxide nanocrystals. J Mater Chem 22:11009–11013
Yang YJ, Li SB, Yang WY, Yuan WT, Xu JH, Jiang YD (2014) In situ polymerization deposition of porous conducting polymer on reduced graphene oxide for gas sensor. ACS Appl Mater Interfaces 6:13807–13814
Yang YJ, Li SB, Zhang LN, Xu JH, Yang WY, Jiang YD (2013) Vapor phase polymerization deposition of conducting polymer/graphene nanocomposites as high performance electrode materials. ACS Appl Mater Interfaces 5:4350–4355
Kumar N, Srivastava AK, Patel HS, Gupta BK, Varma GD (2015) Facile synthesis of ZnO-reduced graphene oxide nanocomposites for NO2 gas sensing applications. Eur J Inorg Chem 2015:1912–1923
Uddin ASMI, Chung G-S (2014) Synthesis of highly dispersed ZnO nanoparticles on graphene surface and their acetylene sensing properties. Sens Actuators B 205:338–344
Zhang DZ, Yin NL, Xia BK (2015) Facile fabrication of ZnO nanocrystalline-modified graphene hybrid nanocomposite toward methane gas sensing application. J Mater Sci Mater Electron 26:5937–5945
Yi J, Lee JM, Park WI (2011) Vertically aligned ZnO nanorods and graphene hybrid architectures for high-sensitive flexible gas sensors. Sens Actuators B 155:264–269
Huang QW, Zeng DW, Li HY, Xie CS (2012) Room temperature formaldehyde sensors with enhanced performance, fast response and recovery based on zinc oxide quantum dots/graphene nanocomposites. Nanoscale 4:5651–5658
Ameen S, Akhtar MS, Seo H-K, Shin HS (2014) ZnO quantum dots engrafted graphene oxide thin film electrode for low level detection of ethyl acetate. Mater Lett 136:379–383
Ye ZB, Tai HL, Xie T, Yuan Z, Liu CH, Jiang YD (2016) Room temperature formaldehyde sensor with enhanced performance based on reduced graphene oxide/titanium dioxide. Sens Actuators B 223:149–156
Ding JJ, Wang MQ, Deng JP, Gao WY, Yang Z, Ran CX, Zhang XY (2014) A comparison study between ZnO nanorods coated with graphene oxide and reduced graphene oxide. J Alloys Compd 582:29–32
Peng C, Guo JJ, Yang WK, Shi CK, Liu MR, Zheng YX, Xu J, CHen PQ, Huang TT, Yang YQ (2016) Synthesis of three-dimensional flower-like hierarchical ZnO nanostructure and its enhanced acetone gas sensing properties. J Alloys Compd 654:371–378
Kubo R (1962) Electronic properties of metallic fine particles. J Phys Soc Jpn 17(6):975–986
Wang C, Zhu JW, Liang SM, Bi HP, Han QF, Liu XH, Wang X (2014) Reduced graphene oxide decorated with CuO–ZnO hetero-junctions: towards high selective gas sensing property to acetone. J Mater Chem A 2:18635–18643
Xu S, Kan K, Yang Y, Jiang C, Gao J, Jing LQ, Shen PK, Li L, Shi KY (2015) Enhanced NH3 gas sensing performance based on electrospun alkaline-earth metals composited SnO2 nanofibers. J Alloys Compd 618:240–247
Li C-F, Hsu C-Y, Li Y-Y (2014) NH3 sensing properties of ZnO thin films prepared via sol-gel method. J Alloys Compd 606:27–31
Tiwari DC, Atri P, Sharma R (2015) Sensitive detection of ammonia by reduced graphene oxide/polypyrrole nanocomposites. Synth Met 203:228–234
Yoo SJ, Li X, Wu Y, Liu WH, Wang XL, Yi WH (2014) Ammonia Gas Detection by Tannic Acid Functionalized and Reduced Graphene Oxide at Room Temperature. J Nanomater 2014:497384-1-6
Yao Y, Chen XD, Guo HH, Wu ZQ, Li XY (2012) Humidity sensing behaviors of graphene oxide-silicon bi-layer flexible structure. Sens Actuators, B 161:1053–1058
Horzum N, Tascıoglu D, Okur S, Demir MM (2011) Humidity sensing properties of ZnO-based fibers by electrospinning. Talanta 85:1105–1111
This work was financially supported by the National Science Funds for Creative Research Groups of China (Grant No. 61421002), Program for New Century Excellent Talents in University (Grant No. NCET-13-0096), and the Open Foundation of State Key Laboratory of Electronic Thin Films and Integrated Devices (Grant No. KFJJ201413).
The authors declare that they have no competing interests.
HLT and XSD conceived and designed the experiments. ZBY and WJZ performed the experiments. ZY and CHL analyzed the data. HLT and ZY wrote the paper. XSD supervised the whole work. All authors have read and approved the final manuscript.
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Tai, H., Yuan, Z., Zheng, W. et al. ZnO Nanoparticles/Reduced Graphene Oxide Bilayer Thin Films for Improved NH3-Sensing Performances at Room Temperature. Nanoscale Res Lett 11, 130 (2016) doi:10.1186/s11671-016-1343-7
- Reduced graphene oxide (rGO)
- Thermal reduction