Piezo-phototronic effect enhanced UV photodetector based on CuI/ZnO double-shell grown on flexible copper microwire
- Jingyu Liu†1,
- Yang Zhang†1,
- Caihong Liu1,
- Mingzeng Peng1,
- Aifang Yu1,
- Jinzong Kou1,
- Wei Liu1,
- Junyi Zhai1Email author and
- Juan Liu2Email author
© The Author(s). 2016
Received: 16 May 2016
Accepted: 23 May 2016
Published: 3 June 2016
In this work, we present a facile, low-cost, and effective approach to fabricate the UV photodetector with a CuI/ZnO double-shell nanostructure which was grown on common copper microwire. The enhanced performances of Cu/CuI/ZnO core/double-shell microwire photodetector resulted from the formation of heterojunction. Benefiting from the piezo-phototronic effect, the presentation of piezocharges can lower the barrier height and facilitate the charge transport across heterojunction. The photosensing abilities of the Cu/CuI/ZnO core/double-shell microwire detector are investigated under different UV light densities and strain conditions. We demonstrate the I-V characteristic of the as-prepared core/double-shell device; it is quite sensitive to applied strain, which indicates that the piezo-phototronic effect plays an essential role in facilitating charge carrier transport across the CuI/ZnO heterojunction, then the performance of the device is further boosted under external strain.
Wurtzite-structured zinc oxide and gallium nitride are gaining much attention due to their exceptional optical, electrical, and piezoelectric properties which present potential applications in the diverse areas including field effect transistors, energy harvesters, photodetectors, solar cells, pressure sensors, and chemical sensors [1–14]. In particular, one-dimensional (1D) ZnO micro/nanowires have attracted great attention due to its advantages in facile synthetic procedure, long-term chemical stability, and environmental friendliness. Coupling the semiconducting and piezoelectric properties of ZnO, applying force/strain along the ZnO polar c-axis can generate piezoelectric polarization-induced piezopotential at two ends of 1D micro/nanowire, which facilitates the modulation of charge carrier transportation process . By endowing nanostructured ZnO devices with flexible capability, force/strain-modulated photoresponsing behaviors resulted from the change of Schottky barrier height (SBH) at the metal-semiconductor heterojunction or the modification of the band diagram of semiconductor composites [15, 16]. Piezo-phototronic effect utilizes external stress-induced piezopotential to modulate photo-generated carrier transport, which has promising applications for pressure-triggered sensors and human-machine interfacing . The presence of piezocharges at one side of the heterojunction can considerably regulate the behaviors of the charge carriers and tune performances of flexible electronic and optoelectronic devices by controlling external strain conditions.
Recently, considerable attention has been paid to piezotronic and piezo-phototronic nanodevices based on ZnO micro/nanowires array and their strain-modulated photoresponsing behaviors [18, 19]. However, it should be noted that the presentation of free electrons in ZnO can partially screen piezopocharges under applied strain which unavoidably reduce the performances of piezotronic and piezo-phototronic nanodevice [20, 21]. In order to suppress electron screening effect, substantial efforts had already been devoted to the synthesis of p-type ZnO or the formation of heterojunction. Previous work reported the improved performance of ZnO/Au Schottky junction-based UV detector  because the Fermi energy of Au is lower than that of ZnO, which facilitated electron transfer from the ZnO to Au via the Schottky junction. Under external strain, the enhanced photocurrent is related to charge redistribution which induced by piezoelectric polarization at the ZnO/Au heterojunction. Another strategy for efficient separation of photo-generated electrons to prevent charge carrier recombination is the formation of semiconductor heterojunction. Involving multi-step synthetic processes for constructing complex nanostructures, several reports exhibited enhanced photoresponse of ZnO nanowires achieved with CdS or Cu2O under strain conditions [19, 22]. It can avoid the problems in the synthesis of p-type ZnO, which are known as the low solubility of dopants or poor stability . Nevertheless, the as-fabricated photodetectors (PDs) exhibited the photoresponse in the visible region as well, which considerably influenced the direct detection of UV light. Therefore, p-type semiconductor with band gap close to ZnO can be considered as the idea building block for the formation of heterojunction and UV detector.
The Cu microwire-based devices have been reported such as piezoelectric nanogenerator, dye-sensitized solar cells, and directional gas collection/transportation [24–26]. The surface modification of Cu microwire with unique morphologies or nanostructured functional materials extensively broadened practical application in flexible devices. In this work, we present a facile and environmentally friendly approach for fabricating a flexible UV photodetector with a Cu/CuI/ZnO core/double-shell structure. The performances of Cu/CuI/ZnO microwire PD can be tuned by changing strain and illumination conditions, which indicated this type of PD has a potential application in flexible nanodevices. The CuI/ZnO heterojunction plays an essential role in modulating the photo-generated charge carrier transport with regard to the band alignment of wide band gap CuI and ZnO. Compared to the strain-free conditions, applying compressive strains leads to the photoresponsivity, relative changes of photoresponsivity, and the detectivity of Cu/CuI/ZnO photodetector was improved at different light intensities. Our work might provide an alternative strategy for utilizing piezo-phototronic effect for boosting photoresponsing performance of PD in a low-cost and convenient manner.
The preparation of inner shell CuI was conducted by exposing the Cu microwire surface to iodine vapor. The outer shell ZnO was grown by a standard RF magnetron sputter deposition using a high purity ZnO target (99.99 %) and Ar/O2 (flow rate was fixed at 8:1) as the sputtering gases at room temperature. The morphology of the Cu microwire, Cu/CuI core/shell microwire, and Cu/CuI/ZnO core/double-shell microwire was examined by scanning electron microscope (SEM, Hitachi 8020). The X-ray diffraction (XRD) spectra of Cu/CuI and Cu/CuI/ZnO microwire were recorded on a Bede D1 ZM-SJ-001 diffractometer. The X-ray photoelectron spectroscopy (XPS) characterization was performed at Thermo Scientific ESCALAB 250Xi. Ag paste was employed to fix the end of Cu/CuI/ZnO core/double-shell microwire on the polyethylene terephthalate (PET) flexible substrate as electrodes. A thin layer of polydimethylsiloxane (PDMS) was used to protect the device during the test. The measurements of photoresponse properties were conducted by a semiconductor characterization system (Keithley 4200 SCS).
Results and Discussion
To evaluate the photosensing performance of the flexible Cu/CuI/ZnO core/double-shell microwire PDs, the as-fabricated device was measured by increasing compressive strain and the power of UV light. The change of photocurrent ΔI (ΔI = I-Idark,s, Idark,s represents the corresponding dark current under certain strains) are summarized in Fig. 4c. Under each illumination conditions, the photocurrents increase with raising compressive strains from 0 to 0.48 %. The strain-modulated photoresponse behaviors of Cu/CuI/ZnO core/double-shell microwire PD can be understood by piezo-phototronic effect. The detailed discussion will require further analysis of the key factors of photoresponsivity R and relative changes of photoresponsivity R (compressive strain conditions) with respect to R 0 (strain-free conditions) and detectivity D*, which are calculated according to the previous method; see Fig. 4d−f . The R, R/R 0 and detectivity (D*) values were recorded at different illumination and strain conditions with the electrode 1.5 V biased. We found that the improved performance of the Cu/CuI/ZnO microwire PDs can be achieved by gradually increasing compressive stain. The maximum values of R, R/R 0, and D* are 2050, 227 %, and 1.597 × 1014 Jones which obtained under a compressive strain (0.48 %) with an illumination condition (6.5 × 10−6 W/cm2). It can be understood that the mechanically generated piezocharges at the region of heterojunction plays a central role in enhancing the performance of PD under UV illumination. For low intensity UV illumination, the photoexcited electron-hole pairs are almost completely separated and redistributed by the build-in electric field, which the photocurrents were largely boosted. At the CuI/ZnO heterojunction, the existence of piezocharges can reduce the barrier height and then increase the photocurrent. While the high intensity UV illumination on the CuI/ZnO heterojunction resulted a large number of electron-hole pairs are photoexcited, the recombination of electron-hole results in photocurrent trends to saturation. Consequently, the small amount of piezocharges at heterojunction cannot further increase the photocurrent. The strain-induced piezocharges played an important role in enhancing the performance of piezotronic and piezo-phototronic effect based nanodevice . However, the free electrons in outer shell ZnO can partly screen piezocharges. The employment of p-type CuI as inner shell can effectively reduce the amount of free electrons in the ZnO. Therefore, more piezocharges can be effectively utilized by applying compressive strain to the Cu/CuI/ZnO core/double-shell microwire PD. Basing on the principle of piezo-phototronics, it can be concluded that piezocharges play an imperative role in modulating CuI/ZnO photoresponsing performance at a low light intensity and large strain conditions.
We have developed a convenient approach for preparing piezo-phototronic effect enhanced UV photodetector with Cu/CuI/ZnO core/double-shell microwire structure. The photoresponsing behaviors of the Cu/CuI/ZnO microwire can be controllably tuned by strain and illumination conditions, respectively. In comparison to other narrow band gap semiconductors used to build UV photodetector, wide band gap make CuI a promising candidate for avoiding unfavorable influence from visible light. Furthermore, inner shell CuI plays a significant role in modulating the transport of charge carrier across the heterojunction under UV illumination due to the staggered band alignment of CuI and ZnO. Under strain conditions, piezocharges are mechanically generated at the ZnO side of heterojunction which has an essential impact on the depletion width. Compared to the strain-free condition, applying compressive strains lead to the photoresponsivity, relative changes of photoresponsivity, and the detectivity of Cu/CuI/ZnO microwire photodetector was largely improved at different illumination conditions. This work provides a reliable and inexpensive method for utilizing piezo-phototronic effect for boosting the performance of UV photodetector with a low-cost, environmentally friendly and convenient technique.
1D, one-dimensional; 3D, three-dimensional; CB, conduction band; EDS, energy dispersive spectroscopy; PDMS, polydimethylsiloxane; PDs, photodetectors; PET, polyethylene terephthalate; SBH, Schottky barrier height; SEM, scanning electron microscope; UV, ultraviolet; VB, valence band; XPS, X-ray photoelectron spectroscopy; XRD, X-ray diffraction
This work was supported by NSFC 51472056, the “thousand talents” program for pioneer researcher and his innovation team, China, and the Recruitment Program of Global Youth Experts, China.
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