Table 1 Rate constants for oxidation process in RC. Exposure time 90 s, excitation light intensity 0.2–6 mW/cm2
I, mW/sm2 | k 12, s−1 | k 21, s−1 | k 23, s−1 | k 32, s−1 | k 34, s−1 | k 43, s−1 | k 13, s−1 | k 31, s−1 | k 24, s−1 | k 42, s−1 | k 14, s−1 | k 41, s−1 |
---|---|---|---|---|---|---|---|---|---|---|---|---|
0.2 | 0.471 | 0.9995 | 5.01E−04 | 1.10E−06 | 1.10E−06 | 5.49E−02 | 0.0012 | 1.00E−06 | 6.16E−03 | 4.94E−02 | 1.00E−06 | 1.00E−06 |
0.5 | 1.5085 | 1.49375 | 7.70E−04 | 4.87E−02 | 2.17E−02 | 5.58E−04 | 0.02554 | 7.51E−04 | 1.59E−04 | 1.10E−06 | 1.00E−06 | 1.00E−06 |
1 | 3.94725 | 1.40738 | 6.01E−04 | 1.10E−06 | 1.10E−06 | 5.83E−02 | 0.01884 | 1.39E−04 | 5.35E−03 | 1.11E−01 | 0.007 | 6.89E−03 |
2 | 6.66 | 1.81312 | 0.07201 | 0.15489 | 7.07E−03 | 1.09E−05 | 0.01526 | 1.01E−05 | 1.06E−05 | 1.07E−05 | 0.024 | 1.03E−05 |
4 | 23.59125 | 6.22 | 0.05276 | 0.2087 | 1.08E−05 | 3.38E−03 | 0.09032 | 7.07E−03 | 3.79E−03 | 1.07E−05 | 0.01974 | 1.03E−05 |
6 | 40.81 | 5.01 | 0.07701 | 0.14101 | 2.50E−02 | 1.09E−05 | 1.00E−05 | 1.60E−02 | 1.06E−05 | 1.07E−05 | 0.01981 | 1.03E−05 |