Table 2 Rate constants for reduction process in RC. Exposure time 90 s, excitation light intensity 0.2–6 mW/cm2
I, mW/sm2 | k 12, s−1 | k 21, s−1 | k 23, s−1 | k 32, s−1 | k 34, s−1 | k 43, s−1 | k 13, s−1 | k 31, s−1 | k 24, s−1 | k 42, s−1 | k 14, s−1 | k 41, s−1 |
---|---|---|---|---|---|---|---|---|---|---|---|---|
0.2 | 0 | 0.921 | 9.33E−02 | 5.60E−03 | 2.81E−02 | 1.32E−03 | 0 | 1.62E−02 | 3.20E−02 | 7.15E−03 | 0 | 1.00E−06 |
0.5 | 0 | 0.99287 | 1.05E−02 | 2.40E−02 | 1.10E−06 | 6.98E−05 | 0 | 9.39E−04 | 1.10E−06 | 1.40E−03 | 0 | 2.42E−03 |
1 | 0 | 0.15523 | 1.00E−06 | 1.10E−06 | 4.14E−04 | 4.50E−03 | 0 | 1.03359 | 1.99E−01 | 1.10E−06 | 0 | 1.00E−06 |
2 | 0 | 0.02543 | 0.00749 | 0.00568 | 1.10E−06 | 1.10E−06 | 0 | 1.00E−06 | 1.10E−06 | 1.10E−06 | 0 | 1.08E−06 |
4 | 0 | 1.091 | 0.00418 | 0.1914 | 1.10E−06 | 3.74E−03 | 0 | 1.69E−01 | 1.10E−06 | 1.10E−06 | 0 | 1.00E−06 |
6 | 0 | 0.0314 | 0.0085 | 0.0051 | 1.10E−06 | 7.45E−02 | 0 | 1.00E−06 | 1.10E−06 | 1.10E−06 | 0 | 1.02 |