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Density Detection of Aligned Nanowire Arrays Using Terahertz Time-Domain Spectroscopy
Nanoscale Research Letters volume 11, Article number: 337 (2016)
A rapid technique is necessary to quantitatively detect the density of nanowire (NW) and nanotube arrays in one-dimensional devices which have been identified as useful building blocks for nanoelectronics, optoelectronics, biomedical devices, etc. Terahertz (THz) time-domain spectroscopy was employed in this research to detect the density of aligned Ni NW arrays. The transmitted amplitude of THz peaks and optical thickness of NW arrays was found to be the effective parameters to analyze the density change of NW arrays. Owing to the low multiple scattering and high order of Ni NW arrays, a linear relationship was observed for the transmitted amplitude and optical thickness regarding NW density, respectively. Therefore, THz technique may be used as a promising tool to characterize the density of one-dimensional structures in the large-scale integrated nanodevice fabrication.
Arrays of one-dimensional (1D) nanostructures such as nanowires (NWs) and nanotubes (NTs) are a very attractive option to be used as building blocks for nanoscale electronic, biosensor, chemical detector, etc. [1–3]. To realize their full potential in applications, however, NWs and NTs must be integrated efficiently into various device architectures. Many factors, such as NW/NT numbers, diameter, and alignment, should be considered in the process of developing large-scale device fabrication. To control the lateral density of NW and NT arrays, since it can influence device performance, is one of the most important challenges. A number of experimental studies have been reported to explore the impact of NW and NT density on device performance in the context of photoelectric response, nanowire electrical transport studies, gas-phase chemical sensing, and field emission [4–7]. The fundamental requirements for these studies are to obtain quantitatively meaningful relationships between the NW and NT density and device properties. Meanwhile, many approaches have been suggested to control the density of NWs [8, 9]. However, these methods only focus on the vertically grown NWs, and the NW density was controlled during the preparation of NWs.
Though there have lots of existing methods such as directed self-assembly, flow-assisted alignment, contact printing, Langmuir–Blodgett technique, and blown bubble methods [10–14] to fabricate the large-scale lateral-aligned NW/NT devices, it is still difficult to precisely control the density of NWs/NTs incorporated into each device. Especially, when the NW arrays have a high density, it is impossible to quantitatively analyze the density distribution of large-scale assembly of NWs and NTs.
Terahertz time-domain spectroscopy (THz-TDS) is a normal and significant THz method based on the THz electric field with time resolution. As a newly developed spectral technique, some spectral features can be used as the standard to qualitatively and quantitatively analyze the material structures and physical properties of tested samples. Ramanandan’s group investigated the oxidation kinetics of nanometer-thick copper films using the in situ THz transmission spectroscopy . Balci’s group investigated the complex refractive index, dielectric function, and conductivity of ZnO NWs using temperature-dependent THz-TDS combined with calculations . In this work, we investigated the relationship between the optical properties and the aligned Ni NW density using the THz-TDS technique. These results indicated that THz-TDS technique was effective to realize the detection of NW density.
In order to avoid the light scattering resulted from the disordered arrangement of NWs, the magnetic material of Ni NWs with the similar length and diameter was used and aligned by magnetic field. Nickel nanowires were fabricated by electrochemical deposition into commercially available 50-μm thick alumina filter templates (Anodisc, Whatman, Inc.) . A gold film was deposited on one side of the template to serve as a working electrode. Nickel was deposited from a solution of 20 g/L NiCl2 · 6H2O and 20 g/L H3BO3, buffered to pH 3.4 at a potential of 1.0 V. The wires were grown to be ~20 μm in length, as controlled by the deposition time. Next, the AAO membrane was dissolved in a 1-mol/L NaOH solution for 1 h at room temperature. A series of washing steps dilutes the base, and the NWs can be suspended in a number of solvents indefinitely for storage. Owing to a low absorption for the THz wave, the 2-mm thick rectangular polyethylene lamina was used as the substrate. The Ni NWs were aligned in alcohol at 50 °C by magnetic field on the polyethylene substrate with the different density range from 0.31 × 109 cm−2 to 2.17 × 109 cm−2. The magnetic field intensity was controlled in the range of ~0.6 mT. Figure 1 shows the SEM image of the aligned Ni NW arrays with the NW density of 0.31 × 109 cm−2. It can be clearly observed that the horizontally aligned Ni NW arrays spread on the substrate. The mean values of the diameter and length of NWs were calculated by a statistical evaluation of SEM micrographs. Arrays of NWs ~260 nm in diameter and lengths in the 25 μm were obtained.
The density of aligned NW arrays was investigated at room temperature by THz-TDS. The measurement system was comprised of a transmission THz-TDS setup and a diode-pump mode-locked Ti:sapphire laser (Maitai, Spectra Physics) from Zomega Terahertz Corporation as shown in Fig. 2. In brief, an 800-nm femtosecond laser beam was split into pump and probe beams. The pump beam (~100 mW) was focused onto the surface of a biased GaAs photoconductive antenna for terahertz generation. THz pulses were focused onto a sample by optical lens, and the THz beam carrying sample’s information met the probe laser beam at the ZnTe crystal in THz dector . All THz-TDS measurements are performed six times for each sample, and the average value was used to analyze the density change of Ni NW arrays. For comparison, the empty polyethylene substrate was used with the same size.
Results and Discussion
The reference pulse was obtained by scanning the polyethylene substrate firstly and the THz field amplitude as a function of time after the transmission of the THz pulse through the samples with different NW density as shown in Fig. 3a. It can be seen that from Fig. 3a, there are two peaks occurred in each spectrum, indicating that the THz pulse was reflected within the sample. Moreover, the amplitude of the first peak is higher than that of the second peak owing to the lower reflectance of samples. The amplitude variation of the first peak as the function of NW density is shown in Fig. 3b. Linear relationship is observed for the variation of the peak amplitude regarding the NW density and the slope of the fitting straight line is −0.155. The peak amplitude decreased with the NW density increasing.
In Fig. 3a, it is interesting to note that the location of the first peak has a right shift with NW density increasing, corresponding to the increase of the propagation time through nanowire arrays, i.e., the thickness of nanowire array increased with NW density increasing. In order to investigate the thickness variation of the aligned NW arrays regarding NW density, the optical thickness (d OT) of nanowire array is defined as the product of the speed of light in air (C) and the propagation time through nanowire array. In Fig. 3a, the first peak is the transmission directly and the second peak is formed that the THz signal through the samples was reflected two times by the back side and front side of the samples continuously. The d OT can therefore be calculated by the delay of the signal separating the peaks and is given by
where t 1 and t 0 are the delay of the two peaks in the sample with aligned NWs and in the reference sample, respectively. The d OT is plotted as the function of NW density as shown in Fig. 4. A linear relationship between the d OT and the NW density is observed, indicating that the effective refractive index of the NW arrays has no obviously change with the NW density increasing.
After the application of fast Fourier transform, the THz frequency-domain spectra (THz-FDS) were calculated in Fig. 5. When the THz frequency is smaller than 0.5 THz, the transmitted amplitude of all samples has no obvious change with NW density increasing. However, the transmitted amplitude decreased regarding NW density when the frequency is larger than 0.5 THz. Inset shows the transmitted amplitude as a function of NW density at selected frequencies of 0.6, 0.9, 1.2, and 1.5 THz. A similar change tendency in the transmitted amplitude at all selected frequencies is clearly observed; i. e., the transmitted amplitude linearly decreased with the NW density increasing.
Usually, scanning electron microscope (SEM) is an appropriate way to describe the density, diameter, and alignment of NWs and NTs in nanodevices. Li et al. have fabricated the Si NW-based field-effect transistor biosensors using nanomanipulation inside a SEM system and the number of NWs in each device is only 1, 4, and 7, respectively . The multiple In2O3 nanowire devices for gas detection have been reported by Zhang et al., and the SEM image showed that the number of NWs in a device is estimated to be 100~200 . It can be found that SEM system is difficult to detect the exact density of lateral-aligned NWs if the number of NWs in each device is higher than the order of 100 of NW density. Recently, conventional optical technology in the UV-IR region has been used to study the properties of nanostructures. However, the quantitative analysis of the NW density in NW arrays remains difficult. Because the light wavelength is approximately equal to the size of NWs, the nonlinear interaction between light and NWs is strongly dependent on the numbers, shape, and alignment of NWs induced by the multiple scattering effect. In In2S3 nanostructure arrays, it is found that the springs, screws, and vertical rods have an enhanced absorption compared to zigzags and tilted rods investigated by UV-NIR spectroscopy . Tena-Zaera et al. investigated the optical scattering effect of ZnO NW arrays in visible wavelength range and found that the increase in diameter of NWs induces a considerable redshift in the reflectance maximum . THz-TDS technique was considered to quantitatively estimate the NW density because of its advantages compared to the SEM technique and UV-NIR spectroscopy. The wavelength range of THz signal is from 30 to 1000 μm, which is much larger than the diameter of NWs and the distance between the neighboring NWs. Therefore, the multiple scattering in NW arrays has not been distinctively enhanced with NW density increasing. However, the lower NW density and alignment of NWs will influence the accuracy and measuring resolution of THz-TDS technique.
In summary, the practicability was demonstrated about the THz-TDS being applied to quantitatively measure the density of aligned NW arrays. The density variation of Ni NW arrays as the function of the transmitted amplitude and optical thicknesses of all samples was analyzed, and the linear relationship was found. It is indicated that THz-TDS represents a powerful tool for the fabrication of 1D nanoscale devices in future.
Patolsky F, Timko BP, Yu G, Fang Y, Greytak AB, Zheng G, Lieber CM (2006) Detection, stimulation, and inhibition of neuronal signals with high-density nanowire transistor arrays. Science 313:1100–1104
Stern E, Klemic JF, Routenberg DA, Wyrembak PN, Turner-Evans DB, Hamilton AD, LaVan DA, Fahmy TM, Reed MA (2007) Laber-free immunodetection with CMOS-compatible semiconducting nanowires. Nature 445:519–522
Fan Z, Lu JG (2006) Chemical sensing with ZnO nanowire Field-Effect Transistor IEEE Trans. Nanotechnol 5:393–396
Bai S, Wu WW, Qin Y, Cui NY, Bayerl DJ, Wang XD (2011) High-performance integrated ZnO nanowire UV sensors on rigid and flexible substrates. Adv Func Mater 21:4464–4469
Black CT (2005) Self-aligned self assembly of multi-nanowire silicon field effect transistors. Appl Phys Lett 87:163113
Zhang D, Liu Z, Li C, Tang T, Liu X, Han S, Lei B, Zhou C (2004) Detection of NO2 down to ppb levels using individual and multiple In2O3 nanowire devices. Nano Lett 4:1919–1924
Ma T, Guo M, Zhang M, Zhang Y, Wang X (2007) Density-controlled hydrothermal growth of well-aligned ZnO nanorod array. Nanotechnology 18:035605
Banerjee D, Jo SH, Ren ZF (2004) Enhanced field emission of ZnO nanowires. Adv Mater 16:2028–2032
Liu J, She J, Deng S, Chen J, Xu N (2008) Ultrathin seed-layer for tuning density of ZnO nanowire arrays and their field emission characteristics. J Phys Chem C 112:11685–11690
Smith PA, Nordquist CD, Jackson TN, Mayer TS (2000) Electric-field assisted assembly and alignment of metallic nanowires. Appl Phys Lett 77:1399–1401
Huang Y, Duan X, Wei Q, Lieber CM (2001) Directed assembly of one-dimensional nanostructures into functional networks. Science 291:630–633
Fan Z, Ho JC, Takahashi T, Yerushalmi R, Takei K, Ford AC, Chueh YL, Javey A (2009) Toward the development of printable nanowire electronics and sensors. Adv Mater 21:3730–3743
Jin S, Whang D, McAlpine MC, Friedman RS, Wu Y, Lieber CM (2004) Scalable interconnection and integration of nanowire devices without registration. Nano Lett 4:915–919
Yu G, Cao A, Lieber CM (2007) Large-area blown bubble films of aligned nanowires and carbon nanotubes. Nat Nanotechnol 2:372–377
Ramanandan GKP, Ramakrishnan G, Planken PCM (2012) Oxidation kinetics of nanoscale copper films studied by terahertz transmission spectroscopy. J Appl Phys 111:123517
Balci S, Baughman W, Wilbert DS, Shen G, Kung P, Kim SM (2012) Characteristics of THz carrier dynamics in GaN thin film and ZnO nanowires by temperature dependent terahertz time domain spectroscopy measurement. Solid-State Electron 78:68–74
He L, Liao Z, Wu H, Tian X, Xu D, Cross GLW, Duesberg GS, Shvets IV, Yu D (2011) Memory and threshold resistance switching in Ni/NiO core–shell nanowires. Nano Lett 11:4601–4606
Löffler T, Hahn T, Thomson M, Jacob F, Roskos HG (2005) Large-area electro-optic ZnTe terahertz emitters. Opt Express 13:5353–5362
Li J, Zhang Y, To S, You L, Sun Y (2011) Effect of nanowire number diameter, and doping density on nano-FET biosensor sensitivity. ACS Nano 5:6661–6668
Cansizoglu H, Cansizoglu MF, Finckenor M, Karabacak T (2013) Optical absorption properties of semiconducting nanostructures with different shapes. Adv Optical Mater 1:158–166
Tena-Zaera R, Elias J, Lévy-Clément C (2008) ZnO nanowire arrays: optical scattering and sensitization to solar light. Appl Phys Lett 93:233119
This work was supported by the National Nature Science Foundation of Beijing (4142047), Beijing Higher Education Young Elite Teacher Project (YETP0684), and Excellent Young Teachers Program of China University of Petroleum (ZX20150108).
WFX and XW designed and planned all the experiments. XW performed the NW synthesis and THz measurements. XW and WFX performed the characterization of samples, analyzed the results, and prepared the manuscript. YL, JQZ, and KZ helped in the preparation of the manuscript. WFX and KZ developed the conceptual framework, supervised the whole work, and finalized the manuscript. All authors discussed the results and reviewed the manuscript. All authors read and approved the final manuscript
The authors declare that they have no competing interests.
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Xiang, W., Wang, X., Liu, Y. et al. Density Detection of Aligned Nanowire Arrays Using Terahertz Time-Domain Spectroscopy. Nanoscale Res Lett 11, 337 (2016) doi:10.1186/s11671-016-1551-1
- Nanowire density
- Terahertz time-domain spectroscopy
- Transmitted amplitude
- Optical thickness