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Table 3 Comparison of the catalytic activities of green-synthesized AuNPs in the 4-NP reduction reaction

From: Catalytic reduction of 4-nitrophenol with gold nanoparticles synthesized by caffeic acid

Entry

Reducing agent used for synthesis of AuNPs

Particle size (nm)

Shape

Rate constant (s-1)

4-NP (mM)a

NaBH4 (mM)a

Au atoms (mM)a,b

Refs

1

Caffeic acid (cf-CA-AuNPs)

38.61 ± 6.21

Spherical

5.73 × 10-3

0.1

10 (100 equiv.)

0.05 (0.5 equiv.)

In the present study

2

Punica granatum juice

23.1–35.8

Spherical

3.67 × 10-3

0.05

15 (300 equiv.)

0.0135 (0.27 equiv.)

[24]

3

Saraca indica bark extract

17.97

Spherical

4.83 × 10-3

0.05

15 (300 equiv.)

0.021 (0.42 equiv.)

[25]

4

Aerva lanata leaf extract

18.62

Spherical

2.78 × 10-3

0.053

10 (189 equiv.)

0.1383 (2.61 equiv.)

[26]

5

Prunus domestica extract

20 ± 6

Spherical

1.90 × 10-3

0.094

11.268 (120 equiv.)

0.019 (0.2 equiv.)

[27]

6

catechin

16.6

Diverse shapes

1.52 × 10-3

0.034

2.269 (67 equiv.)

0.075 (2.22 equiv.)

[28]

7

Bupleurum falcatum root extract

10.5 ± 2.3

Spherical

0.82 × 10-3

0.07

7 (100 equiv.)

0.1 (1.43 equiv.)

[29]

  1. aMolarity of the final volume of solutions
  2. bCalculated by initial molarity of HAuCl4∙3H2O to synthesize AuNPs

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