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Table 1 Surface groups and quantitative composition for the samples of the functionalized porous silicon

From: Impact of Water Adsorption on Nonlinear Optical Properties of Functionalized Porous Silicon

No

Treatment

Sample

Surface layer

f Si, %

f R, %

f por, %

1

Aged

PS

SiH x, O3SiH, SiOH

31.5

68.5

1’

Refreshed

PS-ref

SiH x

22.6

77.4

2

Alkylation

PS-C10

-(CH2)9CH3

22.2

9.7

68.1

3

 

PS-C18

-(CH2)17CH3

22.6

18.4

59.0

4

Chem. oxidized

PS-ox

SiO2 (SiOH)

28.8

6.1

65.1

  

PS-ox-H2O

SiO2 (SiOH)

28.8

6.1

65.1 a

  1. aPore fraction 65.1% consists 48.2% of H2O and 16.9% of voids
  2. The f Si, f R, and f por are the volume fractions of the Si, functional groups and empty pores correspondingly

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