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Table 3 Electronic transitions in absorption spectra of neodymium compounds

From: Synthesis, Characterization, and Luminescent Properties of Polymer Complexes of Nd(III) with β-Dicarbonyl Ligands

transition

Nd(mphpd)3, cm−1

[Nd(mphpd)3]n, cm−1

[Nd(mphpd)3]n⋅[VK]m, cm−1

[Nd(mphpd)3]n⋅[styrene]m, cm−1

4I9/2 → 2P1/2

23,255

23,150

23,474

4I9/2 → 4G9/2

19,530

19,520

19,420

19,880

4I9/2 → 4G7/2

19,080

19,040

18,800

4I9/2 → 2G7/2, 4G5/2

17,215

17,150

17,070

17,240

4I9/2 → 2H11/2

15,650

15,480

15,700

15,950

4I9/2 → 4F9/2

14,700

14,590

14,540

14,800

4I9/2 → 4F7/2

13,420

13,400

13,370

13,460

4I9/2 → 4H9/2

12,490

12,400

12,320

12,470

4I9/2 → 4F3/2

11,480

11,415

11,440, 11,390

11,495

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