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Realizing Full Coverage of Stable Perovskite Film by Modified Anti-Solvent Process
Nanoscale Research Letters volume 12, Article number: 367 (2017)
Lead-free solution-processed solid-state photovoltaic devices based on formamidinium tin triiodide (FASnI3) and cesium tin triiodide (CsSnI3) perovskite semiconductor as the light harvester are reported. In this letter, we used solvent engineering and anti-solvent dripping method to fabricate perovskite films. SnCl2 was used as an inhibitor of Sn4+ in FASnI3 precursor solution. We obtained the best films under the function of toluene or chlorobenzene in anti-solvent dripping method and monitored the oxidation of FASnI3 films in air. We chose SnF2 as an additive of CsSnI3 precursor solution to prevent the oxidation of the Sn2+, improving the stability of CsSnI3. The experimental results we obtained can pave the way for lead-free tin-based perovskite solar cells (PSCs).
Organic-inorganic halide perovskite solar cells have attracted great attention in recent years. The general formula for perovskite is ABX3 (A cation, B cation, X anion). In 2012, the first all-solid-state solar cell  was introduced with a power conversion efficiency (PCE) of 9%  which is now increasing up to 22% . These perovskite solar cells are mainly based on methylammonium lead iodide (MAPbI3) [3,4,5,6,7,8] and formamidinium lead iodide (FAPbI3) [9, 10]. Different halogens are used as anions (I, Br, Cl)  and inorganic cesium (Cs) is also used as cation with methylammonium(MA) and formamidinium(FA) in perovskite solar cells (PVCs) . All of these materials have toxic lead, which is harmful to human health. This limits the commercial use of perovskite solar cells. Scientists have been looking for a non-toxic elements to replace lead in perovskites [16,17,18,19,20,21,22,23,24,25,26]. Some tried to mix the bivalent cations Sn2+ and Pb2+ as CH3NH3SnxPb(1−x)I3 [13, 14] and others mixed the monovalent A cations along with mixed bivalent cations, i.e. FA0.8MA0.2SnxPb1−xI3 , but these perovskites are still toxic. In 2014  Snaith and co-workers first developed complete lead-free perovskite solar cells based on methylammonium tin triiodide (CH3NH3SnI3) and achieved a PCE around 6%. In the same year, Kanatzidis and co-workers  investigated CH3NH3SnI3-xBrx and received almost the same PCE. MASnI3 is very unstable in air according to previous reports . Later, researchers attempted to use formamidinium tin triiodide (FASnI3) with the additive of SnF2 to delay the oxidation of Sn2+ to Sn4+ [18, 19]. They found that FASnI3 was more stable than MASnI3. Recently, Seok and co-workers  obtained a smooth and dense FASnI3 perovskite layer using SnF2-pyrazine complex as an additive. With SnF2 additives and diethyl ether dripping in a solvent engineering process to synthesize FASnI3 perovskite thin films , Dewei Zhao and co-workers  achieved an improved PCE up to 6.22% for lead-free Sn-based perovskite solar cells .
Similar as FASnI3, CsSnI3 also shows perovskite phase at room temperature. CsSnI3 has four phases at different temperatures , but only the black orthorhombic phase B-γ-CsSnI3 is the perovskite phase. Kumar et al.  fabricated solar cells using CsSnI3 as the perovskite layer between a TiO2 electron transfer layer and a Spiro-OMeTAD hole transfer layer and achieved a PCE of 2%. Zhou et al.  modulated B-γ-CsSnI3 grain sizes by employing different annealing temperatures and chose the optimal architecture for perovskite solar cells. They achieved a PCE of 3.31%. Marshall et al.  proved that the existence of SnCl2 resulted in higher film stability and they achieved a PCE of 3.56% from PSCs without any hole-selective interfacial layer. CsSnI3 can be used as the perovskite absorption layer as well as the active region in lead-free perovskite infrared LEDs . Generally, Spiro-OMeTAD is used as a hole transport material (HTM), which typically contains acetonitrile and lithium (Li) and/or cobalt (Co) salts that may change the morphology of Sn-based perovskite films and form the undesirable Cs2SnI6 polymorph [21, 22].
While SnF2-pyrazine complex  and SnF2  have been used as additives into FASnI3 solution and resulted in good performance on stability and efficiency, SnCl2 also can be used as an alternative additive. The mechanism is similar to other tin halides (SnF2, SnCl2, SnBr2, SnI2) additives which are chosen in CsSnI3-based perovskite photovoltaics . In this report, we chose SnCl2 as an additive of FASnI3 solution and SnF2 as an additive of CsSnI3 solution to investigate the stability of the perovskite films, respectively. The measurement of the evolution of absorption spectra at different time courses and other experimental results (SEM, photos etc.) showed that the stability of the films was improved by both additives. With different anti-solvent dripping during spin-coating, we obtained some new findings about the surface morphology and obtained complete coverage of perovskite films.
The synthesis method of FASnI3 follows reference : 372 mg of SnI2 (Sigma-Aldrich) and 172 mg of formamidinium iodide (FAI) were dissolved in 800 μl anhydrous dimethylformamide (DMF, Sigma-Aldrich) and 200 μl anhydrous dimethyl sulfoxide (DMSO, Sigma-Aldrich). For this precursor solution, 10 mol% SnCl2 was added and then stirred. Via spray pyrolysis at 500 °C, a compact layer of TiO2 substrate was deposited on FTO glass. The films were annealed at 500 °C for 15 min and then cooled down to room temperature. The mesoporous TiO2 scaffold was spin-coated at 4500 rpm for 20 s and then heated at 500 °C for 1 h. FASnI3 films were synthesized by spin-coating the precursor solution with SnCl2 additives at 4000 rpm for 60 s in a glove box. During the process of spin-coating, the anti-solvent (diethyl ether, toluene, chlorobenzene) was dripped and then the perovskite films were annealed at 70 °C for 20 min.
The synthesis method of CsSnI3 is described in a previous paper : 0.6 M of CsSnI3 that contained equimolar quantities of CsI and SnI2 without or with 10 mol% SnF2 additives, respectively, was added to DMSO and stirred overnight at 70 °C. Sixty microliters of the precursor solution was spin coated onto the TiO2 substrate at 4000 rpm. The substrates were then annealed at 70 °C for 10 min, and mirror-like black perovskite films were formed.
Results and Discussion
Under the effect of different anti-solvent dripping, the FASnI3 films with 10 mol% SnCl2 additives exhibit different film morphologies. Figure 1 shows the SEM images of FASnI3 perovskite films on TiO2 with different anti-solvents dripped. Figure 1a shows discontinuous nucleation, partial coverage and the presence of pinholes on the surface of the FASnI3 film without (w/o) any anti-solvent dripped. Dripping with diethyl ether (Fig. 1b), the formed FASnI3 film likes a net which has a lot of holes on it and spreads on the TiO2 substrate. Dripping with toluene or chlorobenzene (Fig. 1c and d, respectively), the surface morphology of the FASnI3 film has been further improved, and the film is highly uniform and dense with full coverage on the substrate. Using toluene as the anti-solvent, the average size of crystal particles is bigger than that of films fabricated by using chlorobenzene as the anti-solvent. These results are consistent with those reported in other articles [20, 21]. Without anti-solvent dripped, the film does not change color during spin-coating, and after continuous annealing at 70 °C, the film turns to black immediately and leads to the formation of a rough surface. When the film is dripped with diethyl ether, toluene or chlorobenzene, it changes into a reddish color immediately. After thermal annealing at 70 °C for 20 min, the film turns whitish with diethyl ether dripping and black (the left insert in Fig. 1d) with toluene or chlorobenzene dripping. No matter what kind of anti-solvent is dripped, films from the back view of the FTO glasses are brownish red (the right insert in Fig. 1d).
To investigate whether the anti-solvents dripping would lead to any crystal phase transition or not, we measured the XRD patterns. As shown in Fig. 2, all of the FASnI3 films that were formed on TiO2 crystallize in the orthorhombic structure and random orientation, which is consistent with other reports [20, 21].
Figure 3a shows the scanning electron microscopy (SEM) images of TiO2 substrates. The cross-sectional SEM image (Fig. 3b) of a structure of FTO/compact TiO2/mesoporous TiO2/FASnI3 clearly displays the stacked layers. From the figure, the thickness of FASnI3 is about 250 nm.
The optical absorption spectra of the FASnI3 perovskite thin film with 10 mol% SnCl2 additives under the effect of different anti-solvent dripping are shown in Fig. 4a. The absorption onset occurs at 900 nm, and this result is consist with that reported by other groups . As shown in Fig. 4, there are various absorption peaks of the films prepared by dripping with different anti-solvents. The absorption strength can indirectly reflect the quality of perovskite films. It is known that FASnI3 can automatically degrade to FA2SnI6 in air, [18, 21] and the absorption coefficient of the latter in the visible spectrum is smaller than that of the former. Degradation of the film in air with respect to time can be measured from absorption spectra. As shown in Fig. 4b, UV-vis absorption as a function of time was measured. The changed intensity of absorption reflected the process of degradation. Note that, relative humidity of the environment was about 46% and the room temperature was 15 °C. From optical pictures, we can see that FASnI3 degrades quickly during the first few hours. After 17 h, the absorption peak corresponding to FA2SnI6 becomes obvious. This result confirms that FASnI3 can degrade to FA2SnI6 in air.
Figure 5a shows a cross-sectional SEM image of the FASnI3 PSCs with a structure of FTO/cp-TiO2/mp-TiO2/FASnI3/Spiro-OMeTAD/Au. Figure 5b shows the J-V curves measured with different anti-solvent effects. Although the PCEs of these PSCs are quite low, some characteristics still offer new insights of the fabrication of lead-free perovskites. From Fig. 1a, we know that the nucleation of the film without anti-solvent dripping is discontinuous, which leads to nano-radiative recombination of electrons and holes and causes a large leakage current between TiO2 and FASnI3. The result of the films used diethyl ether as the anti-solvent was approximately the same as the untreated sample. The leakage current is large, but the coverage of the film is improved. With toluene and chlorobenzene as anti-solvents, the coverage of the film has been further improved, and larger crystal particles can create less grain boundaries to enhance the charge separation and collection of electrons and holes, thus leading to the highest PCE.
There are several challenges that hinder performance improvement of CsSnI3 perovskite solar cells: (1) Sn2+ oxidizes to Sn4+ easily, which seriously affects the photoelectric properties of CsSnI3 perovskite solar cells. (2) It is difficult to synthesize uniform and fully covered lead-free Sn-based thin films. Even with different additives, there are many pinholes existing on the crystallite surface which may short electron transfer layer and hole transport layer, leading to an enormous leakage current. (3) Lead-free Sn-based PSCs are often prepared in regular cell structures [18, 23]. In the following content, we have made some preliminary studies on the CsSnI3 films.
Without any additives, the color of CsSnI3 precursor solution was more yellowish than the solution with 10 mol% SnF2 additive, as presented in Fig. 6. This indicates that oxidation occurred more easily for pure CsSnI3.
We also plotted the evolution of absorption spectra at different time courses to investigate the degradation of CsSnI3 thin films with and without additives in air. As shown in Fig. 7, the black vertical line indicates the direction of change with increasing time in ambient air. Without additives, the CsSnI3 thin films degraded quickly when it was exposed to air at relative humidity of 57% and temperature of 13 °C. The degradation rate of the film was very fast in the beginning, but it slowed down a lot after 1 h. The degeneration process of CsSnI3 with 10 mol% SnF2 additive showed some difference. During the first few minutes, the film was quite stable and no oxidation occurred. Meanwhile the absorption peaks were at the same position. Few minutes later the oxidation rate accelerated and slowed down after an hour. Therefore, it can be deduced that the stability of the film is improved by the addition of SnF2.
In summary, we have studied the different morphology characteristics of FASnI3 films prepared by using different anti-solvents and 10 mol% SnCl2. The aforementioned experimental results show that toluene and chlorobenzene are the best anti-solvents for improving the quality of the films and allow the film to completely cover the substrate. Using toluene as anti-solvent, we can gain the highest PCE of PSCs. The stability of FASnI3 can be kept for several hours, while CsSnI3 can only be stable for few minutes. So if we want to develop alternative Pb-free Sn-based perovskite films, the most critical issue is to stabilize the material, namely, suppressing the oxidation of Sn2+ within the crystal. This will enhance the long-term stable operation of perovskite films. This technique may offer a promising approach to fabricate the high efficiency of Pb-free Sn-based perovskite solar cell over the next few years.
Kim HS, Lee CR, Im JH et al (2012) Lead iodide perovskite sensitized all-solid-state submicron thin film mesoscopic solar cell with efficiency exceeding 9%. Sci Rep 2(8):591
(2016) REL Chart. http://www.nrel.gov/ncpv/images/efficiency_chart.jpg. Accessed 13 June 2016.
Burschka J, Pellet N, Moon SJ et al (2013) Sequential deposition as a route to high-performance perovskite-sensitized solar cells. Nature 499(7458):316–319
Heo JH, Han HJ, Kim D, et al (2015) Hysteresis-less inverted CH NH PbI planar perovskite hybrid solar cells with 18.1% power conversion efficiency. J Energy Environ Sci 8(5):1602-1608
Li S, Zhang P, Chen H et al (2017) Mesoporous PbI2 assisted growth of large perovskite grains for efficient perovskite solar cells based on ZnO nanorods. J Power Sources 342:990–997
Li S, Zhang P, Wang Y, et al (2016) Interface engineering of high efficiency perovskite solar cells based on ZnO nanorods using atomic layer deposition. Nano Res 10:1–12.
Liu D, Li S, Zhang P et al (2017) Efficient planar heterojunction perovskite solar cells with Li-doped compact TiO2 layer. Nano Energy 31:462–468
Wang Y, Li S, Zhang P et al (2016) Solvent annealing of PbI2 for the high-quality crystallization of perovskite films for solar cells with efficiencies exceeding 18%. Nanoscale 8(47):19654–19661
Yang WS, Noh JH, Jeon NJ et al (2015) SOLAR CELLS. High-performance photovoltaic perovskite layers fabricated through intramolecular exchange. Science 348(6240):1234
Pang S, Hu H, Zhang J et al (2016) NH2CH = NH2PbI3: an alternative organolead iodide perovskite sensitizer for mesoscopic solar cells. Chem Mater 26(3):1485–1491
Liu M, Johnston MB, Snaith HJ (2013) Efficient planar heterojunction perovskite solar cells by vapour deposition. Nature 501(7467):395
Saliba M, Matsui T, Seo JY et al (2016) Cesium-containing triple cation perovskite solar cells: improved stability, reproducibility and high efficiency. Energy Environ Sci 9(6):1989
Mosconi E, Umari P, Angelis FD (2015) Electronic and optical properties of mixed Sn–Pb organohalide perovskites: a first principles investigation. J Mater Chem A 3(17):9208–9215
Ogomi Y, Morita A, Tsukamoto S et al (2014) CH3NH3SnxPb(1–x)I3 perovskite solar cells covering up to 1060 nm. J Phys Chem Lett 5(6):1004–1011
Patrini M, Quadrelli P, Milanese C, et al (2016) FA0.8MA0.2SnxPb1–xI3 Hybrid perovskite solid solution: toward environmentally friendly, stable, and near-IR absorbing materials. Inorg Chem 55:12752-12757
Noel NK, Stranks SD, Abate A et al (2014) Lead-free organic–inorganic tin halide perovskites for photovoltaic applications. Energy Environ Sci 7(9):3061-–3068
Hao F, Stoumpos CC, Cao DH et al (2014) Lead-free solid-state organic-inorganic halide perovskite solar cells. Nat Photonics 8(8):489–494
Koh TM, Krishnamoorthy T, Yantara N et al (2015) Formamidinium tin-based perovskite with low Eg for photovoltaic applications. J Mater Chem A 3(29):14996–15000
Wang F, Ma J, Xie F et al (2016) Organic cation-dependent degradation mechanism of organotin halide perovskites. Adv Funct Mater 26(20):3417–3423
Lee SJ, Shin SS, Kim YC, et al (2016) Fabrication of efficient formamidinium tin iodide perovskite solar cells through SnF2-pyrazine complex. J Am Chem Soc 138(12):3974-3977
Liao W, Zhao D, Yu Y et al (2016) Lead-free inverted planar formamidinium tin triiodide perovskite solar cells achieving power conversion efficiencies up to 6.22. Adv Mater 28(42):9333–9340
Chung I, Song JH, Im J et al (2012) CsSnI3: semiconductor or metal? High electrical conductivity and strong near-infrared photoluminescence from a single material. High hole mobility and phase-transitions. J Am Chem Soc 134(20):8579–8587
Kumar MH, Dharani S, Leong WL et al (2014) Lead-free halide perovskite solar cells with high photocurrents realized through vacancy modulation. Adv Mater 26(41):7122
Wang N, Zhou Y, Ju M, et al (2016) Heterojunction-depleted lead-free perovskite solar cells with coarse-grained B-γ-CsSnI3 thin films. Adv Energy Mater 6:24
Marshall KP, Walker M, Walton RI, et al (2016) Enhanced stability and efficiency in hole-transport-layer-free CsSnI3 perovskite photovoltaics. J Nature Energy 1:16178
Hong WL, Huang YC, Chang CY et al (2016) Efficient low-temperature solution-processed lead-free perovskite infrared light-emitting diodes. Adv Mater 28(36):8029–8036
This work was supported by National Natural Science Foundation of China under Grant Nos. 61421002, 61574029, and 61371046. This work was also partially supported by University of Kentucky.
LJ, TY, and YW were mainly responsible for the experimental operation. The main work of PZ and DL were material analysis and characterization. SL and ZC helped to draft the manuscript. All authors read and approved the final manuscript.
The authors declare that they have no competing interests.
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Ji, L., Zhang, T., Wang, Y. et al. Realizing Full Coverage of Stable Perovskite Film by Modified Anti-Solvent Process. Nanoscale Res Lett 12, 367 (2017). https://doi.org/10.1186/s11671-017-2117-6
- Lead-free perovskite solar cells
- Solvent engineering
- Anti-solvent dripping