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Table 1 Interpretation of the absorption band IR spectra of LiClO4, DEG-1, and PEPA

From: Structural Peculiarities of Ion-Conductive Organic-Inorganic Polymer Composites Based on Aliphatic Epoxy Resin and Salt of Lithium Perchlorate

LiClO4

DEG-1

PEPA

Wave number, cm−1

Group, type fluctuations

Wave number, cm−1

Group, type fluctuations

Wave number, cm−1

Group, type fluctuations

3100–3600

–OH, ν (a water)

3100–3600

–OH, ν

3100–3600

NH2 + NH, ν

1637

LiClO4

2914

–CH2–, ν asym

2941

–CH2–, ν asym

1086, 1113, 1146

ClO4 , ν asym

2872

–CH2–, ν sym

2827

–CH2–, ν sym

941

ClO4 , ν sym

1458

–CH2–, δ

1641, 1585

NH2 + NH, δ

627

ClO4 (not associated with Li+)

1352

CH2–, δ

1462

CH2–, δ

1253

Epoxy group, ν sym

1310

CH2–, δ

1105

C–O–C, ν

1124

C–N–C, ν

910, 856

Epoxy group, ν asym

  1. ν valence vibration, ν sym and ν asym valence symmetric and asymmetric vibrations, δ bending vibration

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