Table 1 Interpretation of the absorption band IR spectra of LiClO4, DEG-1, and PEPA
LiClO4 | DEG-1 | PEPA | |||
---|---|---|---|---|---|
Wave number, cm−1 | Group, type fluctuations | Wave number, cm−1 | Group, type fluctuations | Wave number, cm−1 | Group, type fluctuations |
3100–3600 | –OH, ν (a water) | 3100–3600 | –OH, ν | 3100–3600 | NH2 + NH, ν |
1637 | LiClO4 | 2914 | –CH2–, ν asym | 2941 | –CH2–, ν asym |
1086, 1113, 1146 | ClO4 −, ν asym | 2872 | –CH2–, ν sym | 2827 | –CH2–, ν sym |
941 | ClO4 −, ν sym | 1458 | –CH2–, δ | 1641, 1585 | NH2 + NH, δ |
627 | ClO4 − (not associated with Li+) | 1352 | CH2–, δ | 1462 | CH2–, δ |
– | – | 1253 | Epoxy group, ν sym | 1310 | CH2–, δ |
– | – | 1105 | C–O–C, ν | 1124 | C–N–C, ν |
– | – | 910, 856 | Epoxy group, ν asym | – | – |