- Nano Express
- Open Access
UV Treatment of Flexible Copper Nanowire Mesh Films for Transparent Conductor Applications
Nanoscale Research Letters volume 12, Article number: 577 (2017)
Copper nanowires have the potential to reach and even exceed the indium tin oxide performances as flexible transparent conductive electrodes. However, for a large-scale production, they need to be fabricated in a high-speed, low-cost way, without degrading the flexible substrate. One of the major bottlenecks resides in the post-treatment used to remove organic residues from the surface of the nanowires after forming the transparent electrode, which is necessary to obtain high optoelectronic performances. Here, we propose an ultra-violet irradiation and a subsequent acetic acid bath as an easy, scalable, fast post-treatment. After only 2 min of ultra-violet treatment, followed by 10 min of acid bath, an Rs of 42 Ω sq−1 and a T 550 nm of 87% were measured. Besides, copper nanowire electrodes maintained their high transparency in the range 750–2500 nm, which makes them good candidates for applications such as infrared solar cells.
The use of transparent conductive electrodes (TCEs) is essential in many everyday devices such as touch screens, displays, solar cells and light-emitting diodes [1,2,3,4,5]. Requirements for that type of component are outstanding optoelectronic properties fitting the desired applications and a low-cost, large-scale production method. The TCE transparency at a wavelength of 550 nm, T 550 nm, is typically ca. 90%. Their sheet resistance, Rs, can vary from ≤ 20 Ω sq−1 for solar cells to ≥ 100 Ω sq−1 for capacitive touch screens [1,2,3,4,5].
Currently, indium tin oxide (ITO) is the most common material for TCEs but it presents several drawbacks. It is expensive due to the indium scarcity and the slow physical vapour deposition process used. Moreover, it is brittle [1,2,3,4,5], which hinders its use for organic, flexible or bendable applications. Indeed, it forms microcracks after a few bending cycles, which considerably reduces the TCE electrical conductivity [6,7,8,9,10]. To address these issues, researchers have focused on various alternative materials such as poly(3,4-ethylenedioxythiophene) poly(styrenesulfonate) [11, 12], graphene [13, 14], carbon nanotubes [15, 16], Ag nanowires (NWs) [17,18,19] and Cu NWs [3, 5]. The latter is one of the most promising materials due to Cu abundance, low cost and high electronic conductivity [3, 5]. Besides, Cu NWs can be fabricated through a low-cost, large-scale, wet chemical synthesis [20,21,22] and deposited with a low-cost, high-speed, roll-to-roll (or reel-to-reel, R2R) process [6, 9]. Finally, their high flexibility allows the TCE to maintain stable performances even after 1000 bending cycles [7, 8, 10, 23, 24].
The Cu NW chemical synthesis involves a capping agent, generally an alkylamine such as oleylamine (OM) [10, 22, 24,25,26,27], octadecylamine [28, 29], hexadecylamine [8, 20, 30, 31] or ethylenediamine [7, 21, 23, 32], which makes Cu nanoparticles (NPs) grow anisotropically. The NW aspect ratio (length/diameter) is of the utmost importance because the higher it gets, the lower the area fraction covered by the NWs needs to be to obtain a percolated network and the more transparent the TCE is [33,34,35,36]. However, those capping agents leave residues on the surface of the NWs, even after an extensive washing in various solvents. Besides, prior to the TCE formation, the NWs are often put in suspension into a nano-ink using a dispersing agent such as polyvinylpyrrolidone (PVP) [22, 23, 26, 30] or nitrocellulose [7, 32]. All those organic residues hinder the NW good contact in the mesh film, and hence, significantly decrease the TCE conductivity. Indeed, Mutiso et al. demonstrated that the sheet resistance of a NW TCE is almost equivalent to the contact resistance between the NWs .
Consequently, a post-treatment is necessary to remove organic residues after forming a Cu NW TCE. It is generally a high-temperature treatment under a vacuum [24, 25], inert , reducing (pure H2)  or forming (5% H2–95% inert gas) [26, 27] atmosphere. This avoids Cu oxidation while removing organic residues and fusing the NW junctions. However, this suits neither a high-rate, low-cost production nor a low-fusion temperature, flexible, polymer substrate. Therefore, alternative post-treatments have been tested and have given very promising results. Treatments using lactic , hydrochloric , propionic  or acetic [10, 29] acid, for instance, proved to be very efficient to remove organic residues from the surface of Cu NWs without damaging the polymer substrates. After an acetic acid treatment, Mayouse et al. obtained poly-ethylenenaphthalate-supported TCEs with Rs values of 9 and 55 Ω sq−1 for a respective T 550 nm of 88 and 94% . Using the same acid, Wang et al. developed TCEs on polyethylene terephthalate (PET) substrates with an Rs of 30 and 60 Ω sq−1 for respective T 550 nm values of 83 and 90% . Besides, photonic sintering using xenon flash lamp pulses allowed to fuse the NW junctions while removing undesired organics in ambient air in a few milliseconds [31, 37]. Ding et al. reported 23 Ω sq−1 for T 550 nm = 82% . Mallikarjuna et al. obtained an Rs of 110 and 170 Ω sq−1 for a T 550 nm of 90 and 95%, respectively . Hence, although photonic sintering seems very promising, further efforts must be made to obtain Rs < 100 Ω sq−1 with T 550 nm ≥ 90%.
In this work, we synthesised high aspect ratio Cu NWs using OM as a solvent, capping and reducing agent, and a nickel (II) species as a catalyst. The NWs were then dispersed in an ink and coated on flexible PET substrates to form TCEs. A post-treatment was necessary to obtain both high conductivity (42 Ω sq−1) and transparency (87% in the visible range). It involved an irradiation under an ultra-violet (UV) lamp, followed by an acetic acid bath, which are both compatible with a R2R process [6, 9, 38, 39]. The UV-treated Cu NW TCEs were compared to conventionally, thermally treated Cu NW TCEs and to commercial ITO.
Copper (II) chloride dihydrate (CuCl2·2H2O, ≥ 95.0% pure), nickel (II) acetate tetrahydrate (Ni(C2H3O2)2·4H2O, ≥ 99.0% pure), OM (C18H37N, 70% pure), anhydrous hexane (C6H14, 95.0% pure), acetic acid (C2H4O2, ≥ 99% pure), ethyl acetate (C4H8O2, ≥ 99.7% pure) and PVP ((C6H9NO) n , 10,000 g mol−1) were purchased from Sigma Aldrich UK. Isopropyl alcohol (IPA, (C3H8O, ≥ 99.5% pure), PET substrates ((C10H8O4) n , 125 ± 25 μm thick) and a glass-supported ITO TCE were purchased from Fisher Scientific UK, Goodfellow UK and Optics Balzers, Liechtenstein, respectively. All chemicals were used as received.
The Cu NW synthesis process was based on a catalytic method previously reported by Guo et al. . 0.4092 g (2.4 mmol) of CuCl2·2H2O, 0.2986 g (12 mmol) of catalytic Ni(C2H3O2)2·4H2O, 25 mL of OM and a magnetic stirrer were added in a 50-mL round bottom flask. The flask was placed in an oil bath on a magnetic stirring hotplate (model 3810000 RCT Basic IKAMAG, IKA) and connected to a reflux column with a top, in-line, oil bubbler. The solution was first heated at 90 °C for 30 min under a vigorous 800-rpm stirring and a constant N2 flow to remove O2(g) and water traces. At that stage, the solution was blue. Then, the temperature was increased to 190 °C to reduce Cu2+ ions and form Cu0 seeds, and the colour of the solution progressively became red. After 30 min, the stirring was stopped and the solution kept at 190 °C under N2 for 16 h to make the Cu NWs grow from the seeds. Finally, the heating was stopped and the solution allowed to cool down naturally.
The solution was transferred to a 50-mL vial and washed successively with hexane, IPA, acetic acid and IPA again. In each solvent, the Cu NWs were vortexed 2 min in manual mode (model Topmix FB15024, Fisher Scientific) and then centrifuged at 4000 rpm (model AccuSpin 400, Fisher Scientific). Centrifugation lasted 20 min in hexane and 2 min in the other solvents. Finally, the Cu NWs were incorporated into an ink composed of 26 vol% of ethyl acetate and 74 vol% of IPA containing 0.5 wt% of PVP. The Cu NW ink was vortexed at 10 Hz for 30 min before storage. The Cu NW concentration in the ink was either 10 or 20 mg mL−1.
Before the coatings were carried out, the Cu NW ink was vortexed once more at 10 Hz for 5 min. To coat a 10 × 10-cm2 PET substrate, 100 μL of ink were taken with a micro-pipette and put on the substrate to form a straight liquid line parallel to the upper edge. The ink was immediately and quickly spread over the PET substrate with a Meyer rod (N°4 from Dyne Testing UK, giving a ca. 10.2-μm thick wet film). All solvents were evaporated after a few seconds at room temperature.
Two different post-treatments were implemented on the as-obtained Cu NW TCEs to remove organic residues (OM and PVP). Some TCEs underwent a thermal treatment at 200, 210, 220, 230, 240 or 250 °C during 1 h under N2 in a tubular oven (model MTF 10/25/130, Carbolite). The other ones underwent a UV irradiation in ambient air for 2, 4 or 6 min with a 430-W lamp (model UVASPOT 400/T, Honle). The lamp was equipped with a mercury vapour bulb (H type), and the distance between the bulb and the samples was 30 cm. After either thermal or UV treatments, TCEs were dipped into pure acetic acid for 10 min to further remove organics and possible oxide traces.
The structure of the Cu NWs was determined using an X-ray diffractometer (XRD, model D5005, Siemens) with a Bragg Brentano configuration chamber, a Cu anticathode (K α = 0.154184 nm) and a back monochromator. The X-ray patterns were indexed with a DIFFRAC.SUITE EVA software (Bruker AXS) containing the JCPDS files database. The microstructure and composition were characterised using a scanning electron microscope equipped with a field emission gun (FEG-SEM, model XL30 SFEG, Philips) and an in-situ energy dispersive spectrometer (EDS, Oxford Instruments-AZTEC). The TCE sheet resistance and transmittance were measured using the four-point probe technique (model 3007 A, Kulicke & Soffa) and a UV-Vis/NIR (near infrared) spectrophotometer (model V-670, JASCO), respectively.
The manufacturing parameters of various TCEs, as well as their ID, Rs and transparency, are summarised in Table 1. However, the TCEs which had an Rs so high that it could not be measured by the four-point probe technique are not included in this table and have no specific ID.
Results and Discussion
The synthesised, washed Cu NWs exhibited a high aspect ratio of ca. 1000 (average length and diameter of 70 μm and 70 nm, respectively) with very few cubic NPs, as seen in Fig. 1a. The presence of the latter suggests slow Ni2+ reduction kinetics . The XRD pattern of Fig. 1b proves that the NWs were made of Cu with a face-centred cubic structure Fm3m (in agreement with the PDF file 04-0836), without any secondary phase detected within the limit of the apparatus (ca. 5 wt%). In particular, there is no diffraction peak corresponding to a copper oxide or a Ni-containing phase. The high purity of the Cu NWs is further confirmed by the EDS spectrum in Fig. 1c. The traces of carbon and oxygen were attributed to non-crystalline OM residues as no other phase than pure Cu was revealed by XRD, and it is well-known that it is very difficult to remove all the OM without a post-treatment [10, 25, 27]. No trace of Ni was found within the detection limit of the EDS (ca. 0.1 wt%), confirming that its role during the synthesis was mainly catalytic as previously described [25, 26]. The silicon corresponds to the wafer supporting the NWs during the EDS analysis and the gold and palladium, to the metallic nano-coating used to improve the sample conductivity and therefore the analysis quality.
After forming the TCEs using a Meyer rod, either thermal or UV post-treatments were used to remove OM and PVP residues from the Cu NW surface and try to fuse them together. Figure 2 shows the surface of the TCE #3 where the NWs form a percolated network, which is necessary for the TCE to be conductive through its entire area. The NWs appear very well dispersed, without any aggregate or bundle that would decrease the TCE transparency. This confirms that the Meyer rod coating is an easy, fast and efficient process to obtain large-area, well-dispersed, percolated NW TCEs [2, 7, 32].
Figure 3 shows thermally treated TCEs, with fused (Fig. 3a) and PET-encapsulated (Fig. 3b) Cu NWs. Indeed, during the thermal treatment, NW fusion and encapsulation are two phenomena in competition. On one hand, the heat induces the fusion of the Cu NW junctions, which is expected to greatly increase the TCE conductivity by decreasing the contact resistance between the NWs. On the other hand, due to its low glass transition temperature (70 °C), the PET is softened during the thermal treatment. This causes the Cu NWs embedding inside the polymer substrate and, hence, a loss of conductivity. The challenge is thus to operate at a temperature where the fusion exceeds the encapsulation phenomenon, which will overall increase the TCE conductivity. It was found that fusion and encapsulation phenomena were dominating at 220 °C (TCE #1) and 230 °C (TCE #2), respectively. After a thermal treatment at 200 or 210 °C, no conductivity could be measured because there were still too many organic residues around the Cu NWs and they were not fused together. As a consequence, the contact resistance between the NWs was still very high. And after a thermal treatment at 240 or 250 °C, no conductivity could be measured because the encapsulation phenomenon was too important.
The micrograph of Fig. 4 presents the high-magnification, top view of the TCE #3. The Cu NW surface appears clean and non-encapsulated, proving that the OM and PVP traces have been removed without softening and damaging the PET substrate. However, the NW junctions are not fused, which is likely due to a lower energy delivered by the UV lamp used in this study, compared to the high-power Xe flash lamps utilised by other authors [31, 37]. Besides, the Cu NW surface is slightly rough, which may be due to a beginning of oxidation. Reducing the distance between the UV lamp bulb and the TCE could allow to transmit a higher energy in a shorter time, and hence, to achieve the Cu NWs fusion while avoiding their oxidation.
Table 1 shows the sheet resistance Rs and the transmittance values T 550 nm, T 350–750 nm (visible range) and T 750–2500 nm (IR range) of various Cu NW TCEs and of a commercial ITO TCE taken as reference. The transmittance spectra between 300 and 2500 nm are given in Fig. 5. For all the Cu NW TCEs, T 550 nm and T 350–750 nm are almost identical, proving that T 550 nm represents very well the average transmittance of a Cu NW TCE in the entire visible range. However, there is a difference of 6% between the two parameters for ITO/ref., which means that using T 550 nm instead of T 350–750 nm leads to an overestimated transparency in the visible range for that kind of transparent oxide.
An Rs of 25 and 743 Ω sq−1, for a T 350–750 nm of 61 and 46% was measured for the TCEs #1 and #2, respectively. This confirms that the NW fusion prevails over their encapsulation inside the PET substrate at 220 °C, thus decreasing Rs. The opposite occurs at 230 °C. Moreover, two reasons can explain the low T 350–750 nm values obtained for the TCEs #1 and #2, compared to 84% for ITO/ref. Firstly, the high concentration of Cu NWs in the ink (20 mg mL−1) lead to a high area fraction coverage. Secondly, the PET substrate was damaged during the thermal treatments.
As for the UV-treated TCEs, two main features were observed. Firstly, increasing the Cu NW concentration from 10 to 20 mg mL−1 decreased both the sheet resistance and transparency. After a 2-min UV treatment, Rs decreased from 42 to 31 Ω sq−1 and the corresponding T 350–750 nm, from 87 to 67%. After a 4-min UV treatment, Rs decreased from 103 to 49 Ω sq−1 and the corresponding T 350–750 nm, from 89 to 71%. This is in agreement with both theoretical and experimental results previously reported: increasing the area fraction covered by the NWs decreases both the sheet resistance and the transparency of a TCE [33,34,35,36]. Secondly, increasing the UV irradiation time increased significantly Rs but only slightly the transparency. For instance, with an ink concentration of 20 mg mL−1, the TCEs #5 (2 min), #6 (4 min) and #7 (6 min) had an Rs of 31, 49 and 236 Ω sq−1, with corresponding T 350–750 nm values of 67, 71 and 73%, respectively. And with an ink concentration of 10 mg mL−1 for the TCEs #3 and #4, Rs increased from 42 to 103 Ω sq−1, with corresponding T 350–750 nm values of 87 and 89%. It is worth noting that those performances are quite similar to Wang et al.’s acid-treated TCEs (30 and 60 Ω sq−1 with a corresponding T 550 nm of 83 and 90%) . They are also close to Mallikarjuna et al.’s flash lamp-treated TCEs (110 and 170 Ω sq−1 with a respective T 550 nm of 90 and 95%) . The TCEs obtained from inks with concentrations of 10 and 20 mg mL−1 became non-conductive after UV treatments longer than 4 and 6 min, respectively. Regardless of the ink concentration, a low Rs was obtained after 2 min of UV irradiation. This means that most of the organics were removed and that, despite the absence of fusion, the Cu NWs were in intimate contact. This was confirmed by the fact that the transparency after 2 min was very close to the one obtained after longer UV treatments. When the UV irradiation duration in ambient air increased, it is likely that oxidation occurred due to a temperature increase. The oxide layer on the NW surface grew thicker, thus increasing their contact resistance. However, it remained thin enough not to lower the transparency significantly. The quite stable transparency over the time range 2–6 min also means that the PET substrates were not degraded during the UV treatments. Consequently, only the high area fraction covered by the NWs on the TCEs #6 and #7 (20 mg mL−1 ink) was responsible for the T 350–750 nm values lower than for the ITO/ref. Indeed, with an ink concentration of 10 mg mL−1, T 350–750 nm for the TCEs #3 (87%) and #4 (89%) was slightly higher than for the ITO/ref. (84%).
Furthermore, it is worth noting that T 750–2500 nm is significantly higher for every Cu NW TCE than for the ITO/ref. (50%). This can be observed for the thermally treated TCEs #1 (65%) and #2 (57%), despite the PET substrates degradation. This is even more interesting for UV-treated TCEs, in particular #3 and #4, which have T 750–2500 nm values of 89 and 91%, respectively. This means that Cu NW TCEs suit applications such as IR imaging and sensing, electromagnetic shielding, telecommunications or IR solar cells much better than ITO, known to have a poor transmittance in the IR range [1, 7, 25, 29].
Finally, the comparison between the results obtained for thermally and UV-treated Cu NW TCEs highlights the advantages of the latter process. Quite close performances were measured for the thermally treated TCE #1 (25 Ω sq−1 with T 350–700 nm = 61%) and the UV-treated TCE #3 (31 Ω sq−1 with T 350–700 nm = 67%). However, the UV irradiation lasted 30 times less than the thermal treatment, and neither damaged the PET substrate nor required a controlled atmosphere. Furthermore, a UV treatment in ambient air is compatible with an industrial R2R process. Further work will consider a high-speed, low-cost, large-scale production using an R2R platform, a slot die, a UV lamp and an acid bath [38, 39]. Preliminary tests have already been realised at laboratory scale with a syringe pump injecting 15 mL h−1 of Cu NW ink in a slot die and a table moving a PET substrate at 10 mm s−1. So far, the results obtained on 2 × 5-cm2 coatings have suggested an optimal shim width of 100 μm and a slot die-substrate gap of 80 μm.
High aspect ratio (length/diameter = 1000) Cu NWs were synthesised through a wet chemical, catalyst-assisted route. Then, they were used to fabricate TCEs on flexible PET substrates using the Meyer rod technique. A UV treatment and an acid bath were carried out to remove organic residues from the NW surface and obtain both low sheet resistance and high transparency. This method gave better results than a conventional thermal treatment, 30 times faster, and without needing a controlled atmosphere. Forty-two and 103 Ω sq−1, with corresponding T 350–750 nm of 87 and 89%, were the best performances obtained for UV-treated TCEs, which fits the requirements for flexible capacitive touchscreens. A very interesting result is that the transparency values of the Cu NW TCEs were maintained in the IR range, where the reference ITO TCE had a very low T 750–2500 nm of 50%. Hence, the Cu NW TCEs fabricated for this study are a very promising alternative to oxide TCEs for applications such as IR imaging and IR solar cells. Finally, the Cu NW ink and PET substrate, as well as the UV and acetic acid post-treatments used in this study, are compatible with an industrial, scalable, high-speed, low-cost, R2R process.
Indium tin oxide
Transparent conductive electrode
Hecht DS, Hu L, Irvin G (2011) Emerging transparent electrodes based on thin films of carbon nanotubes, graphene, and metallic nanostructures. Adv Mater 23(13):1482–1513. Available at. DOI:10.1002/adma.201003188
Ye S, Rathmell AR, Chen Z, Stewart IE, Metal WBJ (2014) Nanowire networks: the next generation of transparent conductors. Adv Mater 26(39):6670–6687. Available at. DOI:10.1002/adma.201402710
Kumar DVR, Woo K, Moon J (2015) Promising wet chemical strategies to synthesize Cu nanowires for emerging electronic applications. Nano 7(41):17195–17210. Available at. DOI:10.1039/C5NR05138J
Guo CF, Ren Z (2015) Flexible transparent conductors based on metal nanowire networks. Mater Today 18(3):143–154. Available at. DOI:10.1016/j.mattod.2014.08.018
Nam VB, Lee D (2016) Copper nanowires and their applications for flexible, transparent conducting films: a review. Nano 6(3):47. Available at. DOI:10.3390/nano6030047
Kang M-G, Joon PH, Hyun AS, Jay Guo L (2010) Transparent Cu nanowire mesh electrode on flexible substrates fabricated by transfer printing and its application in organic solar cells. Sol Energy Mater Sol Cells 94(6):1179–1184. Available at. DOI:10.1016/j.solmat.2010.02.039
Rathmell AR, Wiley BJ (2011) The synthesis and coating of long, thin copper nanowires to make flexible, transparent conducting films on plastic substrates. Adv Mater 23(41):4798–4803. Available at. DOI:10.1002/adma.201102284
Won Y, Kim A, Lee D, Yang W, Woo K, Jeong S et al (2014) Annealing-free fabrication of highly oxidation-resistive copper nanowire composite conductors for photovoltaics. NPG Asia Materials 6(6):e105. Available at. DOI:10.1038/am.2014.36
Deng B, Hsu P-C, Chen G, Chandrashekar BN, Liao L, Ayitimuda Z et al (2015) Roll-to-roll encapsulation of metal nanowires between graphene and plastic substrate for high-performance flexible transparent electrodes. Nano Lett 15(6):4206–4213. Available at. DOI:10.1021/acs.nanolett.5b01531
Wang R, Ruan H (2016) Synthesis of copper nanowires and its application to flexible transparent electrode. J Alloys Compd 656:936–943. Available at. DOI:10.1016/j.jallcom.2015.09.279
Kim N, Kee S, Lee SH, Lee BH, Kahng YH, Jo Y-R et al (2014) Highly conductive PEDOT:PSS nanofibrils induced by solution-processed crystallization. Adv Mater 26(14):2268–2272. Available at. DOI:10.1002/adma.201304611
Singh R., Tharion J., Murugan S., Kumar A. ITO-free solution-processed flexible electrochromic devices based on PEDOT:PSS as transparent conducting electrode. ACS Applied Materials & Interfaces. 27 October 2016; Available at: DOI:10.1021/acsami.6b09476 (Accessed: 5 Jan 2017)
Kim KS, Zhao Y, Jang H, Lee SY, Kim JM, Kim KS et al (2009) Large-scale pattern growth of graphene films for stretchable transparent electrodes. Nature 457(7230):706–710. Available at. DOI:10.1038/nature07719
Sun J, Chen Z, Yuan L, Chen Y, Ning J, Liu S et al (2016) Direct chemical-vapor-deposition-fabricated, large-scale graphene glass with high carrier mobility and uniformity for touch panel applications. ACS Nano 10(12):11136–11144. Available at. DOI:10.1021/acsnano.6b06066
Yu Z, Niu X, Liu Z, Pei Q (2011) Intrinsically stretchable polymer light-emitting devices using carbon nanotube-polymer composite electrodes. Adv Mater 23(34):3989–3994 Available at: DOI:10.1002/adma.201101986
Zhang X, Aitola K, Hägglund C, Kaskela A, Johansson MB, Sveinbjörnsson K et al (2016) Dry-deposited transparent carbon nanotube film as front electrode in colloidal quantum dot solar cells. ChemSusChem 9:1–9. Available at. DOI:10.1002/cssc.201601254
Anh DD, Nam HK, San HK, Singh J, Kumar P, Silver ZW (2013) Nanowires: a promising transparent conducting electrode material for optoelectronic and electronic applications. Rev Adv Sci Eng 2(4):1–22. Available at. DOI:10.1166/rase.2013.1048
Jiu J, Sugahara T, Nogi M, Araki T, Suganuma K, Uchida H et al (2013) High-intensity pulse light sintering of silver nanowire transparent films on polymer substrates: the effect of the thermal properties of substrates on the performance of silver films. Nano 5(23):11820–11828. Available at. DOI:10.1039/C3NR03152G
Scheideler WJ, Smith J, Deckman I, Chung S, Claudia Arias A, Subramanian V (2016) A robust, gravure-printed, silver nanowire/metal oxide hybrid electrode for high-throughput patterned transparent conductors. J Mater Chem C 4(15):3248–3255. Available at. DOI:10.1039/C5TC04364F
Mohl M, Pusztai P, Kukovecz A, Konya Z, Kukkola J, Kordas K et al (2010) Low-temperature large-scale synthesis and electrical testing of ultralong copper nanowires. Langmuir 26(21):16496–16502. Available at. DOI:10.1021/la101385e
Xu C, Wang Y, Chen H, Zhou R, Liu Y (2014) Large-scale synthesis of ultralong copper nanowires via a facile ethylenediamine-mediated process. J Mater Sci Mater Electron 25(5):2344–2347. Available at. DOI:10.1007/s10854-014-1882-6
Li S, Chen Y, Huang L, Pan D (2014) Large-scale synthesis of well-dispersed copper nanowires in an electric pressure cooker and their application in transparent and conductive networks. Inorg Chem 53(9):4440–4444. Available at. DOI:10.1021/ic500094b
Rathmell AR, Bergin SM, Hua Y-L, Li Z-Y, Wiley BJ (2010) The growth mechanism of copper nanowires and their properties in flexible, transparent conducting films. Adv Mater 22(32):3558–3563. Available at. DOI:10.1002/adma.201000775
Yin Z, Lee C, Cho S, Yoo J, Piao Y, Facile KYS (2014) Synthesis of oxidation-resistant copper nanowires toward solution-processable, flexible, foldable, and free-standing electrodes. Small 10(24):5047–5052. Available at. DOI:10.1002/smll.201401276
Guo H, Lin N, Chen Y, Wang Z, Xie Q, Zheng T et al (2013) Copper nanowires as fully transparent conductive electrodes. Sci Rep 3:2323. Available at. DOI:10.1038/srep02323
Zhu Z, Mankowski T, Balakrishnan K, Shikoh AS, Touati F, Benammar MA et al (2015) Ultrahigh aspect ratio copper-nanowire-based hybrid transparent conductive electrodes with PEDOT:PSS and reduced graphene oxide exhibiting reduced surface roughness and improved stability. ACS Appl Mater Interfaces 7(30):16223–16230. Available at. DOI:10.1021/acsami.5b01379
Hwang C, An J, Doo CB, Kim K, Jung S-W, Baeg K-J et al (2016) Controlled aqueous synthesis of ultra-long copper nanowires for stretchable transparent conducting electrode. J Mater Chem C 4(7):1441–1447. Available at. DOI:10.1039/C5TC03614C
Shi Y, Li H, Chen L, Huang X (2005) Obtaining ultra-long copper nanowires via a hydrothermal process. Sci Technol Adv Mater 6(7):761–765. Available at. DOI:10.1016/j.stam.2005.06.008
Mayousse C, Celle C, Carella A, Simonato J-P (2014) Synthesis and purification of long copper nanowires. Application to high performance flexible transparent electrodes with and without PEDOT:PSS. Nano Res 7(3):315–324. Available at. DOI:10.1007/s12274-013-0397-4
Kevin MR, Lim GY, Ho GW (2015) Facile control of copper nanowire dimensions via the Maillard reaction: using food chemistry for fabricating large-scale transparent flexible conductors. Green Chem 17(2):1120–1126. Available at. DOI:10.1039/C4GC01566E
Mallikarjuna K, Hwang H-J, Chung W-H, Kim H-S (2016) Photonic welding of ultra-long copper nanowire network for flexible transparent electrodes using white flash light sintering. RSC Adv 6(6):4770–4779. Available at. DOI:10.1039/C5RA25548A
Ye S, Rathmell AR, Stewart IE, Ha Y-C, Wilson AR, Chen Z et al (2014) A rapid synthesis of high aspect ratio copper nanowires for high-performance transparent conducting films. Chem Commun 50(20):2562–2564. Available at. DOI:10.1039/C3CC48561G
Catrysse PB, Fan S (2010) Nanopatterned metallic films for use as transparent conductive electrodes in optoelectronic devices. Nano Lett 10(8):2944–2949. Available at. DOI:10.1021/nl1011239
Bergin SM, Chen Y-H, Rathmell AR, Charbonneau P, Li Z-Y, Wiley BJ (2012) The effect of nanowire length and diameter on the properties of transparent, conducting nanowire films. Nano 4(6):1996–2004. Available at. DOI:10.1039/C2NR30126A
Khanarian G, Joo J, Liu X-Q, Eastman P, Werner D, O’Connell K et al (2013) The optical and electrical properties of silver nanowire mesh films. J Appl Phys 114(2):024302. Available at. DOI:10.1063/1.4812390
Mutiso RM, Sherrott MC, Rathmell AR, Wiley BJ, Winey KI (2013) Integrating simulations and experiments to predict sheet resistance and optical transmittance in nanowire films for transparent conductors. ACS Nano 7(9):7654–7663. Available at. DOI:10.1021/nn403324t
Ding S, Jiu J, Tian Y, Sugahara T, Nagao S, Suganuma K (2015) Fast fabrication of copper nanowire transparent electrodes by a high intensity pulsed light sintering technique in air. Phys Chem Chem Phys 17(46):31110–31116. Available at. DOI:10.1039/C5CP04582G
Graham A., Morantz P., Comley P. Ultra-Precision Control of a Reel-to-Reel Process. Poster presented in the EPSRC Centre for Innovative Manufacturing in Ultra Precision Steering Meeting Committee; 24 February 2016; Cranfield University, UK. https://doi.org/10.17862/cranfield.rd.5533033.
Graham A., Morantz P., Comley P. Production of Electronics and Photovoltaics Using a Reel-to-Reel Process. Proceedings of the 16th International Conference of the European Society for Precision Engineering and Nanotechnology (EUSPEN), 30 May - 3 June 2016, Nottingham, UK. pp. 457–458. Available at: https://dspace.lib.cranfield.ac.uk/handle/1826/10602. Accessed 28 Apr 2017.
The authors thank the EPSRC and Innovate UK (Energy Catalyst, LOCUST-132141) for their financial support (grant EP/N50984X/1).
The authors thank the MSc students Raffaele D’Addario, Adriana Karcz, Ansab Khalid, Luis Rubio García, Leslie Wang and John Kamau, as well as Dr. Paul Comley and Dr. Xianwei Liu, for their technical support.
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The dataset supporting the conclusions of this article can be accessed at https://doi.org/10.17862/cranfield.rd.5528098.
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Lonne, Q., Endrino, J. & Huang, Z. UV Treatment of Flexible Copper Nanowire Mesh Films for Transparent Conductor Applications. Nanoscale Res Lett 12, 577 (2017). https://doi.org/10.1186/s11671-017-2343-y
- Copper nanowires
- Transparent conductive electrodes
- Ultra-violet treatment