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New Insights into CO2 Adsorption on Layered Double Hydroxide (LDH)-Based Nanomaterials
Nanoscale Research Letters volume 13, Article number: 55 (2018)
The interlamellar spacing of layered double hydroxides (LDHs) was enlarged by dodecyl sulfonate ions firstly, and then, (3-aminopropyl)triethoxysilane (APS) was chemically grafted (APS/LDHs). The structural characteristics and thermal stability of these prepared samples were characterized by X-ray diffraction (XRD), transmission electron microscopy (TEM), reflectance Fourier transform infrared spectrometer (FTIR), thermogravimetric analysis (TG), and elemental analysis (EA) respectively. The CO2 adsorption performance was investigated adopting TG and diffuse reflectance infrared Fourier transform spectroscopy (DRIFTS). The results presented that the CO2 adsorption capacity on APS/LDHs was as high as 90 mg/g and showed no obvious reduction during a five cyclic adsorption-desorption test, indicating its superior performance stability. The DRIFTS results showed that both carbamates and weakly bounded CO2 species were generated on APS/LDHs. The weakly adsorbed species was due to the different local chemical environment for CO2 capture provided by the surface moieties of LDHs like free silanol and hydrogen bonds.
The greenhouse effect and global climate change mainly caused by the substantive CO2 emission from coal-fired power plants have aroused general public concern [1,2,3]. Thus, CO2 capture should be adopted for its subsequent storage or utilization to reduce its concentration level in the atmosphere. Various solvent- and solid-based sorbents have gained great attention for CO2 capture, especially the amine-modified porous material composites for their comparatively low energy consumption for regeneration and easy implementation over a wide range of temperatures and pressures [4,5,6].
A high and stable CO2 adsorption capacity is principal for the large-scale separation process of carbon capture from the flue gas with a large volume and low partial pressure at the temperature range of 50~100 °C . As the amino groups show affinity to CO2 molecules, various porous supports with large surface area and pore volumes were adopted to obtain composite adsorbents based on their accommodation to the impregnated amines since Song’s work in 2002 . And the highest CO2 adsorption capacity reported in literatures could achieve up to 7.9 mmol/g . However, these kinds of impregnated composites are susceptible to performance degradation during the cyclic adsorption-desorption operation, suggesting a poor stability which is also an important criterion for real applications . Furthermore, strong diffusion limitation is also generated by the agglomerated amines and coated particles for CO2 from the surface into the bulky amino groups, which would lower the amine efficiency defined as the amounts of adsorbed CO2 molecules for each mole of nitrogen atom.
To improve the thermal stability and amine efficiency of the composite adsorbents, a monolayer or less of CO2 affinity sites is formulated via grafting of aminosilanes onto the support materials based on their co-condensation reaction, which has been extensively studied adopting 3-aminopropyltrimethoxysilane (APS), 3-(trimethoxysilyl) propylethylenediamine(diamine) or 3-[2-(2-aminoethylamino)ethylamino] propyltrimethoxy-silane (triamine), etc. [2, 10,11,12]. These kinds of grafted composites show lower diffusion limitations and superior stability, even though there may be an upper bound of CO2 adsorption capacity as it is assumed that two moles of exposed amine groups were demanded to capture one mole of CO2 molecules according to the zwitterion mechanism [13, 14]. Nevertheless, the chemical nature of support materials could also affect the CO2 adsorption performance. The contributions of surface hydroxyls to CO2 capturing either through their direct weak physical force  or via its hydrogen bonding with the grafted amines [13, 16] on silica-/titania-based adsorbents have been investigated.
Layered double hydroxides (LDHs) are ordered compounds that assemble by interlamination anions and positively charged layer laminates with the general formula of [M1 − x2+M x 3+(OH)2]x+(An−)x/n·mH2O, where M2+ and M3+ represent metal cations and A is an anion . LDHs have extended applications in adsorption, catalysis, photochemistry, etc. due to their tunable structure and low cost of raw materials [6, 18,19,20], which also make it a possible candidate for post-combustion CO2 capture. Wang et al.  synthesized amine-modified LDHs via an exfoliation and grafting route and reported that these adsorbents would be useful in CO2 capture processes with a high temperature of 80 °C, while the CO2 adsorption capacity on amine-modified hexagonal mesoporous silica (HMS) decreased from 1.34 mmol/g at 25 °C to 0.45 mmol/g at 75 °C . This suggests the local chemical of LDHs as support materials might affect the CO2 adsorption in a way that is different from silica supports. However, few reports have discussed about this as far as we are acknowledged. A systematic study is necessary to investigate the LDH-based sorbents and to further understand their CO2 adsorption mechanisms.
With this in mind, (3-aminopropyl)triethoxysilane (APS)-modified LDHs (APS/LDHs) have been prepared in this paper adopting dodecyl sulfate (DS) for pre-intercalation. The structural characteristics of APS/LDHs have been addressed in details elsewhere . Yet some quantities will be reintroduced to illustrate the linkage between CO2 adsorption performance and the surface features of LDHs. The CO2 adsorption-desorption properties on APS/LDHs were explored mainly using in situ diffuse reflectance infrared Fourier transform spectroscopy measurements (DRIFTS).
All the utilized chemicals were purchased from Aladdin reagent Co., Ltd., and were A.R. grade. And these chemicals were used without further treatment.
The as-synthesized LDHs were prepared as the control sample through a co-precipitation method. A mixed solution containing 0.075 mol Mg(NO3)2·6H2O and 0.025 mol Al(NO3)3·9H2O was firstly obtained, which was then added to a Na2CO3 aqueous solution (0.5 mol/L, 100 mL) under vigorous stirring at 70 °C. The pH value of this mixture was maintained at about 10 using NaOH aqueous solution (4 M) followed by stirring for another 4 h. After that, the resulted precipitate was filtered, washed with distilled water for several times, and dried under vacuum condition at 120 °C overnight. The DS-intercalated LDHs (DS/LDHs) were synthesized 7according to a previous report . Typically, 4.00 g of Mg(NO3)2·6H2O and 1.95 g of Al(NO3)3·9H2O were dissolved in 50 ml of deionized water. The obtained solution was added dropwise into the aqueous solution of sodium dodecyl sulfate (3 g/100 mL distilled water) under continuous stirring at 70 °C. Special attentions should also be paid to the pH adjustment to around 10. The same post-treatment described above was applied to DS/LDHs too.
APS-grafted LDHs (APS/LDHs) were prepared as follows. Two grams of DS/LDHs was dissolved in a conical flask with 500 mL toluene solvent and then subjected to sonication for 5 h. Abundant white gel was gathered half an hour later. Fifteen milliliters of (3-aminopropyl)triethoxysilane was added, and the mixture solution was aged at 60 °C under a nitrogen atmosphere for 5 h. The sediment was extracted by filtration, washed repeatedly, and then dried in a vacuum oven at 120 °C overnight.
The crystal phases of the samples were analyzed by an X-ray diffractometer with CuKα radiation (XRD: model D/max RA; Rigaku Co., Japan, CuKα radiation 0.15418 nm), and data were collected for scattering angles (2θ) which ranged from 5° to 70° with a step size of 0.02°. The micromorphology were investigated by transmission electron microscopy (TEM: Tecnai G2 F20; FEI Company, USA). Elemental analysis was performed on Flash EA1112 (Thermo Finnigan, USA). Fourier transform infrared spectrometer (FTIR, IR Affinity-1; SHIMADZU, Japan) was employed to record the IR spectra of the prepared samples. Potassium bromide (KBr) plates mixed with 1/50 of sample were made by applying 20 tons of oil pressure and then scanned from 400 to 4000 cm−1 with a resolution of 0.2 cm−1. The thermal stability of solid samples was determined using thermogravimetric analysis (TG; NETZSCH STA 409 Luxx, Selb/Bavaria, Germany). The samples were heated from room temperature to 600 °C with a heating rate of 10 K/min in nitrogen atmosphere.
The information about surface species and molecular behavior on the surface of adsorbents were obtained through DRIFTS (Nicolet 6700 FT-IR spectrometer, Thermo Scientific, USA), which was equipped with a temperature control system and coupled with ZnSe windows. In the DRIFTS cell, powder adsorbents were pretreated for 1 h at 200 °C under a nitrogen flow of 30 mL/min. When the temperature was stabilized at 50 °C, a CO2 gas flow of 5 mL/min was introduced into the cell for a span of time until complete saturation was achieved. Here, the CO2 concentration (~ 14v%) in the gas mixture indicated its general concentration of the industrial flue gas. DRIFTS spectra were collected with 4 cm−1 resolution and 64 co-added sans with the consideration of the background spectra recorded just before the introduction of probe molecules.
CO2 adsorption capacity was also determined by TG. About 10 mg of samples was pretreated at 120 °C for 1 h under nitrogen atmosphere at 100 ml/min. After cooling down to the adsorption temperature, pure CO2 flow was switched in until to the dynamic adsorption equilibrium. The final gained weight was regarded as its CO2 adsorption capacity. Saturated samples were regenerated under the pretreatment conditions. This adsorption-regeneration procedure was repeated five times to evaluate the performance stability of modified adsorbent materials.
Results and Discussion
As it is shown in Fig. 1, there emerged a series of typical peaks due to the layered structures for the as-synthesized LDHs at 2θ = 11.5°, 23.0°, 34.5°, and 60.5°, which were ascribed to (003), (006), (009), and (110) lattice planes, respectively, according to the previous literatures [23, 24]. It should be noted that a lower angle Bragg reflection (003), in addition to the well order (00l) series, appeared for DS/LDHs generated by the expanded structure as the intercalation of organic anions into the laminated plates of LDHs. This expanded interlayer, suggesting high exposure of surface hydroxyl groups and low diffusion limitation, enabled DS/LDHs to be a precursor for the subsequent introduction of APS. APS grafting reduced the crystallinity dramatically. Yet the hydrotalcite-like structure of the host was conserved for the observed (110) reflection. This was confirmed by the TEM image of APS/LDHs (Fig. 2) as the aggregates of irregular flaky particles were demonstrated.
The molar ratio of C/N is 9 in APS molecule (C9H23NO3Si). Correspondingly, the molar ratios of C/N would be 7, 5, or 3 if 1, 2, or 3 ethoxysilane groups condense with the surface hydroxyl groups on the LDH laminates respectively . Here, the molar ratio of C/N (Table 1) was adopted to further confirm the successful grafting of APS. As the C/N molar ratio of 6.59 was obtained, thus, at least one ethoxysilane group in each APS molecule was tethered to the metal layers while the others presented as the intact ethoxysilane groups or free silanol bonds after hydrolysis.
TG-DTG (DTG is the derivative curve of TG) study was carried out to investigate the thermal stability of modified LDHs. As it is presented in Fig. 3, DS/LDHs underwent three steps of mass loss, which were ascribed to the removal of adsorbed water below 150 °C; the dehydroxylation during the temperature range from 150 to 300 °C with a prominent loss occurred at 240 °C, as well as the further dehydroxylation and decomposition of dodecyl sulfate over 300 °C [24, 25]. Thermal decomposition behavior of APS/LDHs was significantly different (Fig. 4). It was noted that the weight loss of APS/LDHs due to the dehydroxylation (150~300 °C) was about 10%, much less than that of DS/LDHs (approximately 30%). This mainly could be attributed to the consumption of −OH on the LDH laminates after APS grafting through the condensation reaction as interpreted in Fig. 5. Furthermore, a weight loss peaked at even a higher temperature at 321 °C emerged due to the delayed dehydroxylation on APS/LDHs which might benefit from the hydrogen bonding between the terminal –NH2 of APS molecules and the surface hydroxyls on LDH laminates.
IR spectra of modified LDHs are shown in Fig. 6. For LDHs, the strong broad peak centered at 3460 and the band at 1650 cm−1 was related to stretching and bending vibrations of hydroxyl groups from the surface and/or interlayer respectively. The absorption bands at 1370 cm−1 were assigned to both monodentate carbonate and intercalated NO3− in the interlayer space of LDHs. An overtone of lattice Mg–O vibrations as well as Al–O modes overlay the spectrum ranging from 800 to 400 cm−1. The DS molecules in DS/LDHs showed a group of characteristic bands at 2920 (stretching vibration of –CH3 groups), 2852 (stretching vibration of –CH2 groups), 1465 (C–H bending bond of the organic skeleton), and 1217/1075 cm−1 (the asymmetric and symmetric stretching vibrations of –SO32− groups). However, the intensities of these characteristic bands were substantially weakened after the grafting of APS while new bands related to N–H and N–C bonds in APS molecules were observed, e.g., the vibration of N–H2 in the primary amine groups (RNH2) at 1570/1468 cm−1 and the C–N bending vibration of C–N at 1124 cm−1 [13, 23].
Even though part of surface −OH groups on LDH laminates were consumed through its condensation reaction with the silanols of APS as it was abovementioned, the bands located at 3460 and 1650 cm−1 were somewhat enhanced. It was reported that non-uniform distribution of grafted APS would occur, like clustering of amino groups via their intermolecular hydrogen bonding  and protonation of amine species (RNH3+) generated under the existence of water , with surface hydroxyls or with free silanol groups. It was also held that the basic molecules or groups could be hydrogen-bonded onto the surface hydroxyls of LDHs even though this bonding was rather weak . Thus, here, the enhancement of these absorption bands was attributed to the bounded –NH2 groups overlapped with the –OH group at the same IR region , indicating a rather different local environment for CO2 adsorption.
CO2 adsorption performance of amine-modified LDHs was investigated by TGA at different testing temperatures. As it is shown in Fig. 7, CO2 adsorption amounts on APS/LDHs increased dramatically within the first 30 min, followed by a slow saturation stage. A CO2 adsorption capacity as high as 2.09 mmol/g during this saturation stage was obtained, much higher than that of LDHs (typically less than 1.0 mmol/g [29,30,31]). Therefore, the incorporated amino groups contributed to CO2 capturing significantly. It should be noted that APS/LDHs exhibited a CO2 adsorption amount of 1.55 mg/g at 25 °C while it showed a rather stable adsorption capacity at a temperature range from 30 to 75 °C. APS begins to react with CO2 from 28 °C . Thus, the higher viscosity of APS at 25 °C would generate greater mass transfer limitation and further weaken its function for CO2 capturing.
It was the accessibility of amino groups and the proximity of adjacent amino pairs that essentially determined the CO2 adsorption capacity for amine-modified materials. The impregnated amines would like to agglomerate in the pores of supports which generated strong diffusion limitation for CO2 molecules from surface into bulk [2, 9, 25, 32]. However, the accessibility of active sites in APS/LDHs might also be affected adversely by the hydrocarbon chains intercalated between the LDH laminates, which reduced the mobility and relative proximity of amino pairs. This was unfavorable to the amine efficiency of APS/LDHs presumably, which yet turned out to be slightly higher than 0.5 that was the maximum value based on the zwitterion mechanism (Table 1). Thus, it was deduced there may be a different adsorption mechanism here contributing to the amine efficiency.
DRIFTS measurement was adopted to investigate the CO2 adsorption mechanism on APS/LDHs (Fig. 8). Exposure to CO2/N2 gas mixture led to the appearance of several typical absorption peaks, which were due to the N–H deformation in RNH3+ at 1629 and 1489 cm−1, the asymmetric stretching mode of COO− at 1567 cm−1, and the NCOO skeletal vibration at 1428 and 1326 cm−1 . Obviously, CO2 adsorption onto the primary amines happened via the zwitterion mechanism with a two-step sequence, i.e., the formation of a zwitterion firstly and the subsequent proton transfer [13, 14].
Especially, the emerged band at 1703 cm−1 needed further identification. As it disappeared completely under mild regeneration conditions while the generated carbamates decomposed under a higher temperature, this band might be related to a weakly bound CO2 species around the bounded −NH2 group  which provided a different local environment for adsorption. CO2 molecules could be captured onto these amino groups via hydrogen bonding. Wu et al.  attributed the absorption band at 1706 cm−1 to the hydrogen-bonded CO2 species generated by its adsorption near the protonated amine groups. Danon et al.  also found that the SBA-15 surface play a significant role in the specific interactions between CO2 and moieties tethered to the surface of SBA-15.
Stable cyclic adsorption/desorption performance of adsorbents is especially desired for practical separation process. The cyclic performance of APS/LDHs was obtained (Fig. 9) through its exposure to CO2 at different adsorption temperatures and then regeneration at 120 °C repeatedly. The CO2 adsorption capacity fluctuated around its initial adsorption amount during these five cycles at these testing temperatures, showing excellent cyclic performance. This provided APS/LDHs great feasibility to capture CO2 from fossil fuel-based thermal power plants . Firstly, energy saving for regeneration could be achieved compared with the calcined LDH samples that needed activation at elevated temperatures, e.g., 400 °C . What is more, the CO2 adsorption on calcined LDH samples decreased with the increasing number of thermal adsorption/desorption cycles due to irreversible chemisorption caused by the poor thermal stability and agglomeration of particles , while APS/LDHs here showed superior performance stability.
A monolayer of terminal amino groups of APS was grafted onto LDHs (APS/LDHs) for CO2 capture. It was found that the enlarged layer spacing pillared by dodecyl sulfonate was beneficial to APS introduction. APS was tethered to the LDH laminates through covalent interaction. The incorporated amino groups contributed a lot to CO2 capturing on APS/LDHs both through the zwitterion mechanism and weak bonding as confirmed by DRIFTS results. The CO2 adsorption capacity stabilized at about 90 mg/g during the five cycles of adsorption-desorption, showing a great application potential in the temperature swing adsorption processes.
For LDH-based oxide adsorbents, the gradually reduced CO2 uptakes could be observed primarily due to the increasingly lack of availability of the basic sites. However, APS/LDHs are more robust to a variety of treatment conditions as it based on the chemical combination of (3-aminopropyl)triethoxysilane and the metal layers. This effectively prevents the significant loss of adsorption capacity due to the organic leaching out of the solids during the cyclic testing. And the captured CO2 could be completely desorbed under 120 °C on APS/LDHs, which is a rather safe operation temperature to avoid the amine degradation or thermal conformational alteration.
Diffuse reflectance infrared Fourier transform spectroscopy
Reflectance Fourier transform infrared spectrometer
Hexagonal mesoporous silica
Layered double hydroxides
Transmission electron microscopy
Thermogravimetric analysis-derivative curve of TG
Samanta A, Zhao A, Shimizu GKH, Sarkar P, Gupta R (2012) Post-combustion CO2 capture using solid sorbents: a review. Ind Eng Chem Res 51:1438–1463
Bollini P, Didas SA, Jones CW (2011) Amine-oxide hybrid materials for acid gas separations. J Mater Chem 21:15100–15120
Kuwahara Y, Kang D-Y, Copeland JR, Brunelli NA, Didas SA, Bollini P, Sievers C, Kamegawa T, Yamashita H, Jones CW (2012) Dramatic enhancement of CO2 uptake by poly(ethyleneimine) using zirconosilicate supports. J Am Chem Soc 134:10757–10760
Hong S-M, Kim SH, Lee KB (2013) Adsorption of carbon dioxide on 3-aminopropyl-triethyoxysilane modified graphite oxide. Energy Fuel 27:3358–3363
Gray ML, Champagne KJ, Fauth D, Baltrus JP, Pennline H (2008) Performance of immobilized tertiary amine solid sorbents for the capture of carbon dioxide. Int J Greenhouse Gas Control 2:3–8
Zhang H (2015) Ultrathin two-dimensional nanomaterials. ACS Nano 9:9451–9469
Xu X, Song C, Andresen JM, Miller BG, Scaroni AW (2002) Novel polyethylenimine-modified mesoporous molecular sieve of MCM-41 type as high capacity adsorbent for CO2 capture. Energy Fuel 16:1463–1469
Qi G, Wang Y, Estevez L, Duan X, Anako N, Park A-HA, Li W, Jones CW, Giannelis EP (2011) High efficiency nanocomposite sorbents for CO2 capture based on amine-functionalized mesoporous capsules. Energy Environmental Science 4:444–452
Liu J, Liu Y, Wu Z, Chen X, Wang H, Weng X (2012) Polyethyleneimine functionalized protonated titanate nanotubes as superior carbon dioxide adsorbents. J Colloid Interface Sci 386:392–397
Zhao Y, Shen Y, Bai L (2012) Effect of chemical modification on carbon dioxide adsorption property of mesoporous silica. J Colloid Interface Sci 379:94–100
Harlick PJE, Sayari A (2007) Applications of pore-expanded mesoporous silica. 5. Triamine grafted material with exceptional CO2 dynamic and equilibrium adsorption performance. Ind Eng Chem Res 46:446–458
Gatti G, Costenaro D, Vittoni C, Paul G, Crocella V, Mangano E, Brandani S, Bordiga S, Cossi M, Marchese L, Bisio C (2017) CO2 adsorption on different organo-modified SBA-15 silicas: a multidisciplinary study on the effects of basic surface groups. Phys Chem Chem Phys 19:14114–14128
Liu Y, Liu J, Yao W, Cen W, Wang H, Weng X, Wu Z (2013) The effects of surface acidity on CO2 adsorption over amine functionalized protonated titanate nanotubes. RSC Adv 3:18803–18810
Danckwerts PV (1979) The reaction of CO2 with ethanolamines. Chem Eng Sci 34:443–446
Fisher JC II, Tanthana J, Chuang SSC (2009) Oxide-supported tetraethylenepentamine for CO2 capture. Environ Prog Sustain Energy 28:589–598
Danon A, Stair PC, Weitz E (2011) FTIR study of CO2 adsorption on amine-grafted SBA-15: elucidation of adsorbed species. J Phys Chem C 115:11540–11549
Vodyanitskii YN, Shoba SA (2015) Ephemeral Fe(II)/Fe(III) layered double hydroxides in hydromorphic soils: a review. Eurasian Soil Sci 48:240–249
Gopalakrishna BLK, Subramanyam S, Chengala MD, Olivera S, Venkatesh K (2015) Progress in hydrotalcite like compounds and metal-based oxides for CO2 capture: a review. J Clean Prod 103:171–196
Li C, Wei M, Evans DG, Duan X (2014) Layered double hydroxide-based nanomaterials as highly efficient catalysts and adsorbents. Small 10:4469–4486
Gunjakar JL, Kim IY, Hwang S-J (2015) Efficient hybrid-type CO2 adsorbents of reassembled layered double hydroxide 2D nanosheets with polyoxometalate 0D nanoclusters. Eur J Inorg Chem 2015:1198–1202
Wang J, Stevens LA, Drage TC, Wood J (2012) Preparation and CO2 adsorption of amine modified Mg-Al LDH via exfoliation route. Chem Eng Sci 68:424–431
Knowles GP, Delaney SW, Chaffee AL (2006) Diethylenetriamine [propyl(silyl)]-functionalized (DT) mesoporous silicas as CO2 adsorbents. Ind Eng Chem Res 45:2626–2633
Wang S-L, Wang P-C (2007) In situ XRD and ATR-FTIR study on the molecular orientation of interlayer nitrate in Mg/Al-layered double hydroxides in water. Colloids Surf A Physicochem Eng Asp 292:131–138
Kanezaki E (1998) Thermal behavior of the hydrotalcite-like layered structure of Mg and Al-layered double hydroxides with interlayer carbonate by means of in situ powder HTXRD and DTA/TG. Solid State Ionics 106:279–284
Liu J, Cheng D, Liu Y, Wu Z (2013) Adsorptive removal of carbon dioxide using polyethyleneimine supported on propanesulfonic-acid-functionalized mesoporous SBA-15. Energy Fuel 27:5416–5422
Gartmann N, Schütze C, Ritter H, Brühwiler D (2010) The effect of water on the functionalization of mesoporous silica with 3-aminopropyltriethoxysilane. J Phys Chem Lett 1:379–382
Prinetto F, Ghiotti G, Durand R, Tichit D (2013) Investigation of acid−base properties of catalysts obtained from layered double hydroxides. J Phys Chem B 104:11117–11126
Young PD, Notestein JM (2011) The role of amine surface density in carbon dioxide adsorption on functionalized mixed oxide surfaces. Chem Sus Chem 4:1671–1678
Radha S, Navrotsky A (2014) Energetics of CO2 adsorption on Mg-Al layered double hydroxides and related mixed metal oxides. J Phys Chem C 118:29836–29844
Min YJ, Hong S-M, Kim SH, Lee KB, Jeon SG (2014) High-temperature CO2 sorption on Na2CO3-impregnated layered double hydroxides. Korean J Chem Eng 31:1668–1673
Dantas TCM, Fernandes Junior VJ, dos Santos APB, Bezerra FA, Araujo AS, Alves APM (2015) CO2 adsorption on modified Mg-Al-layered double hydroxides. Adsorption Sci Technol 33:165–173
Ma X, Wang X, Song C (2009) “Molecular basket” sorbents for separation of CO2 and H2S from various gas streams. J Am Chem Soc 131:5777–5783
Bacsik Z, Ahlsten N, Ziadi A, Zhao G, Garcia-Bennett AE, Martín-Matute B, Hedin N (2011) Mechanisms and kinetics for sorption of CO2 on bicontinuous mesoporous silica modified with n-propylamine. Langmuir 27:11118–11128
Manohara GV (2014) Exfoliation of layered double hydroxides (LDHs): a new route to mineralize atmosphere CO2. RSC Adv 4:46126–46132
Rossi TM, Campos JC, Souza MMVM (2016) CO2 capture by Mg–Al and Zn–Al hydrotalcite-like compounds. Adsorption 22:151–158
This study was supported by the Science and Technology Department of Sichuan Province (2014JY0178), the Scientific Research Foundations of China Southern Power Grid (K-GD2014-0591), and the Talent Introduction project of Chengdu University of Information Technology (KYTZ201411).
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Tang, N., He, T., Liu, J. et al. New Insights into CO2 Adsorption on Layered Double Hydroxide (LDH)-Based Nanomaterials. Nanoscale Res Lett 13, 55 (2018). https://doi.org/10.1186/s11671-018-2471-z
- Modified LDHs
- Weakly adsorption
- CO2 capture