Table 6 PV characteristics for different natural dye-sensitized solar cells
From: Dye-Sensitized Solar Cells: Fundamentals and Current Status
Dye | Result | JSC (mAcm−2) | VOC (V) | FF | η (%) | Reference |
---|---|---|---|---|---|---|
Roselle | Absorption peak of the photoanode was broader than that of the dye solution due to the binding of anthocyanin in the extract to the TiO2 surface with a shift to a higher wavelength (from 540 to 560 nm) | 0.18 | 0.47 | 0.55 | 0.046 | [278] |
Red Cabbage | Absorption band and intensity has observed to be enhanced due to the interfacial Ti–O coupling between the dye molecule and the TiO2 molecules | 4.38 | 0.47 | 0.36 | 0.73 | [406] |
Morinda lucida | Shows absorption maxima at 600 nm and 440 nm | 2.56 | 0.44 | 0.47 | 0.53 | [407] |
Sumac/Rhus | Visible absorption band shifts to higher energy, showing a maximum absorption around 400–500 nm upon adsorption onto TiO2 | 0.93 | 0.39 | 0.41 | 1.5 | [408] |
Hibiscus rosa-sinensis | – | 0.96 | 0.26 | 0.43 | 0.11 | [409] |
Mangosteen peel | Absorption spectrum of mangosteen peel dye on TiO2 showed absorption at wavelengths ranging from 350 to 550 nm | 8.70 | 0.60 | 0.50 | 2.63 | [104] |
Papaya leaves | Molar extinction coefficient was found to be 86,300 M−1 cm−1 at 660 nm | 0.402 | 0.56 | 0.41 | 0.094 | [410] |
Dragon fruit | Absorption spectrum showed peak value of 535 nm and found intermolecular H-bond, conjugate C=O stretching and esters acetates C–O–C stretching vibration, due to the component of anthocyanin | 0.20 | 0.22 | 0.30 | 0.22 | [411] |
Red rose | Maximum absorption for red rose was found at 535 nm and maximum absorption coefficient was about 15 times higher than that of the N719 dye | 4.57 | 0.48 | 0.36 | 0.81 | [412] |
Lawsonia inermis leaves | Showed absorption maxima at 518 nm due to higher solubility in ethanol | 1.87 | 0.61 | 0.58 | 0.66 | [413] |
E. conferta | Showed a broad maximum around 530–560 nm with maximum absorption at 540 nm | 4.63 | 0.37 | 0.56 | 1.00 | [414] |
G. atroviridis | Absorption peaks were observed to be between 540 and 550 nm with maximum absorption at 540 nm | 2.55 | 0.32 | 0.63 | 0.51 | [414] |
Sweet pomegranate | Maximum absorption of the dye onto TiO2 was found at 536 nm | 4.60 | 0.62 | 0.55 | 1.57 | [415] |
Cosmos | Peaks were observed at about 505 and 590 nm of wavelengths, respectively verifying the charge injection from the excited state of the natural sensitizer | 1.041 | 0.447 | 0.61 | 0.54 | [274] |
Golden trumpet | Positive shift in the absorption peak was observed after adsorption | 0.878 | 0.405 | 0.54 | 0.40 | [274] |
JDND2 | Jackfruit derived natural dye (JDND) exhibited overriding photo-absorption in a spectral range of 350–800 nm with an optical bandgap of ∼ 1.1 eV | 2.21 | 0.805 | 0.60 | 1.07 | [416] |
Indian jamun | An improvement in ideality factor (A) was observed 4.8 for Jamun dye-based DSSC | 1.56 | 0.580 | 0.58 | 1.23 | [417] |
Nephelium lappaceum | – | 3.88 | 0.404 | 0.35 | 0.56 | [418] |
Tamarillo fruit | Tamarillo pulp showed highest absorbance in the visible light wavelength of ~ 450–560 nm | 0.356 | 0.542 | – | 0.043 | [419] |
Chlorophyll | – | 0.145 | 0.585 | 0.59 | 0.055 | [310] |
Xanthophyll | Xanthophyll dye showed more stable (shows low degradation over a 24-h period) than chlorophyll under light, but concentration of the adsorbed xanthophyll pigments was found to be 2.5 × 10−4 μg/ml, much lesser than that of chlorophyll pigments (2.2 μg/ml) | 0.104 | 0.610 | 0.54 | 0.038 | [310] |
Kenaf Hibiscus | UV spectra showed a peak at 378 nm and a small hump at 554 nm, whereas dye absorbed TiO2 film showed two peaks at 385 nm and 548 nm with broad absorption spectra in the visible range as required for a solar cell | 6.6733 | 0.478 | 0.60 | 2.87 | [420] |