Nano Express | Open | Published:
A General One-Pot Approach to Synthesize Binary and Ternary Metal Sulfide Nanocrystals
Nanoscale Research Lettersvolume 14, Article number: 19 (2019)
A general one-pot approach is developed to synthesize a series of binary metal sulfide nanocrystals (NCs) including PbS, Cu2S, ZnS, CdS, Ag2S, and ternary CuInS2 and CdS:Cu(I) NCs. This synthetic approach involves thermal decomposition of the mixture of inorganic metal salts and n-dodecanethiol (DDT) without pre-synthesis of any organometallic precursors. In this method, layered metal-thiolate compound is formed at the beginning of the reaction and then this intermediate compound is decomposed into small particles, leading to further growth as the reaction time increases. The as-obtained CdS NCs exhibits a broad but weak surface-state emission, and the Cu(I) doping leads to a red-shift of the emission band due to the Cu(I)-related emission. It is expected that this one-pot approach can be extended to prepare multinary metal sulfide NCs.
In the past few decades, colloidal inorganic NCs have attracted much attention due to their unique optical and electrical properties [1, 2], as well as their wide potential applications in light-emitting diodes [3,4,5,6], biological labels [7,8,9], solar cells [10,11,12,13], memory devices [14,15,16], and so on. As an important category of colloidal inorganic NCs, metal sulfide have exhibited distinct size-, structure-, and composition-dependent optoelectronic properties . Therefore, it is necessary to develop a general and simple synthetic approach that yields monodispersed metal sulfide, in which the size, shape, phase, and chemical composition can be controlled precisely by changing the starting materials and reaction conditions. Up to date, a variety of synthetic methods, including hydrothermal or solvothermal techniques [17, 18], hot-injection approaches [19, 20], and single-source precursor routes [21, 22], have been reported to prepare different types of high-quality colloidal inorganic NCs. However, it is difficult to control the shape and size in the hydrothermal or solvothermal methods, and the air-free manipulation and fast injection rate limits the large-scale production in the hot-injection routes. In addition, the precursors should be pre-synthesized in the thermal decomposition of single-source methods, which will add some additional steps during the synthesis . Therefore, it is still challenging to develop a more simple, low-cost, and general wet-chemical synthetic route for preparing different types of inorganic NCs. Li’s group developed a facile “dispersion-decomposition” route to synthesize high-quality metal sulfides using inorganic salts and alkylthiol as the raw materials . However, these approaches mainly focused on synthesis of binary metal sulfide NCs, and the synthesis of doped and ternary metal sulfide NCs by a simple and versatile approach is less studied. Moreover, the formation of gelification phenomena is also less discussed. Recently, our group developed a simple and versatile method for preparing a wide range of metal sulfide NCs and some heterostructured NCs [25,26,27,28]. To demonstrate the universality of this one-pot method, herein, this one-pot approach is developed to synthesize a series of binary metal sulfide NCs including PbS, Cu2S, ZnS, CdS, Ag2S and ternary CuInS2 NCs, and doped CdS:Cu(I) NCs. This process does not need any extra steps for pre-synthesis of toxic organometallic precursors, and DDT is chosen not only as sulfur source but also as a surface-capping agent without any phosphine agents. A layered metal-thiolate compound is produced upon heating the inorganic salt and DDT, which then is decomposed into nanocrystal nuclei. The metal-thiolate compounds are air-stable and become a gel at room temperature. The nucleation and growth process can be tuned by changing the reaction conditions, resulting in controllable shape, size, and chemical composition.
Synthesis of Binary Metal Sulfide NCs
For a typical synthesis of PbS nanocrystals, 3 mmol of Pb(OAc)2·3H2O and 20 mL of DDT were added into a three-necked flask at room temperature, and then the mixture was degassed by nitrogen gas following about 20 min. Afterwards, the mixture was heated to 200 °C and maintained for 60 min. After reaction, it was terminated by naturally cooling down to room temperature after removal of the heating equipment. The nanocrystals can be separated after adding some ethanol by centrifugation at 7000 rpm for 10 min. The precipitates were washed using chloroform to remove precursor and surfactant residuals. The above centrifugation and purification procedures were repeated twice, and then the samples were re-dispersed into chloroform or dried in vacuum for subsequent characterization.
For synthesis of Cu2S nanocrystals, 3 mmol of Cu(acac)2 was added into 10 mL of DDT and 20 mL of ODE in a three-necked flask, and then the mixture was heated to 200 °C and kept for 60 min.
For synthesis of ZnS nanocrystals, 3 mmol of Zn(acac)2 was added into 5 mL of DDT and 25 mL of ODE in a three-necked flask, and then the mixture was heated to 240 °C and kept for 180 min.
For synthesis of CdS nanocrystals, 5 mmol of Cd(acac)2 and 30 mL of DDT were added into a three-necked flask, and then the mixture was heated to 200 °C and kept for 23 h.
For synthesis of Ag2S nanocrystals, 3 mmol of Ag(OAc) and 20 mL of DDT were added into a three-necked flask at room temperature, and then the mixture was heated to 205 °C and kept for 100 min.
Synthesis of Ternary Metal Sulfide NCs
For synthesis of CdS:Cu(I) nanocrystals, 4.5 mmol of Cd(acac)2 and 0.5 mmol Cu(acac)2 were added into 30 mL of DDT in a three-necked flask, and then the mixture was heated to 200 °C and kept for 23 h.
For synthesis of CuInS2 nanocrystals, 3.1 mmol of Cu(acac)2, 1.9 mmol of In(acac)3, 5 mL of DDT and 25 mL of ODE were added into a three-necked flask, and then the mixture was heated to 240 °C and kept for 60 min.
All the detailed experimental conditions for different products in our work are summarized in Table 1.
The size and shape of the samples were examined by using a transmission electron microscope (TEM; Hitachi-7650) with the accelerating voltage of 100 kV and high-resolution transmission electron microscope (HRTEM; JEM-2010) operating at an accelerating voltage of 200 kV. The crystalline structure of the as-obtained products was determined by using a Bruker D8 Advance X-ray Diffractometer (XRD) with Cu Kα radiation (λ = 1.54056 Å). The chemical composition and valance-state of the samples were measured using a VG Scientific ESCALab220i-XL X-ray photoelectron spectrometer (XPS) with a 300 W Al Kα radiation source. All binding energies for different elements were calibrated with respect to C1s line at 284.8 eV from the contaminant carbon. The UV-Vis absorption spectra measurements of the samples in chloroform solution were carried out using a Shimadzu-UV 3101 spectrophotometer and the fluorescent spectra were recorded using a Varian Cary Eclipse fluorescence spectrophotometer.
Results and Discussion
A schematic general synthetic procedure of different metal sulfide NCs is illustrated in the top panel of Fig. 1. The bottom panel of Fig. 1 shows the digital photographs of chloroform solutions of different products synthesized in our work. These samples can be well dispersed in chloroform to form homogenous colloidal solutions and exhibit different colors at room temperature. In this one-pot reaction, DDT acted as not only the sulfur source, but also the capping-agent and reaction media, even it was used as the reducing agent in the synthesis of binary and ternary metal sulfide NCs. ODE was used as a reaction media to allow the reaction to be performed. Generally, gelification phenomena were observed from the aliquots extracted at the initial reaction stages after they were cooled down to room temperature. When the gel was heated to above 100 °C, the gel became fluid. Unexpectedly, the aliquots became gels again at room temperature. We take Cu2S NCs as a typical example, the digital pictures of the states of matter for aliquot extracted at 180 °C are given in Fig. 2. As stated in previous reports that an intermediate compound was formed at a relatively low reaction temperature during this reaction, and then decomposed into nuclei to promote the growth of the NCs . In the synthesis of Cu2S NCs, the colors of the aliquots changed from yellow to dark-brown as the reaction proceeded, and the gelification phenomena disappeared after reaction for 10 min at 200 °C, which indicates that the formation of the gels is closely related with the intermediate compounds.
To further study the formation mechanism and structure of the intermediate compounds, some aliquots of the representative samples were extracted from the initial stage, and the corresponding XRD patterns are shown in Fig. 3a–c, respectively. A series of narrow and sharp diffraction peaks are clearly observed, which can be ascribed to the successive (0 k0) orders of reflections from a layered structure. According to Bragg’s law, the mean interlayer spacing between the two sharp diffraction peaks for the three representative samples is calculated to be about double-layer of DDT molecules and one layer of metal ions. The schematic illustration of the stacked structure for the metal-thiolate compound is depicted in Fig. 2d. Some small discrepancy between the calculated values and theoretical values for the three samples may result from the difference of diameters of metal ions and no interpenetration at the interface between layers. The aforementioned results indicate that the intermediate compounds formed at initial stage are layered metal-thiolate compound with polymeric structures, which can be demonstrated by the gelification phenomena .
The crystal structures of the as-obtained products were confirmed by the XRD patterns. Figure 4 shows the XRD patterns of PbS, Cu2S, ZnS, CdS:Cu(I), Ag2S, and CuInS2 NCs. As shown in Fig. 4a, the as-observed diffraction peaks can be assigned the face-centered-cubic (fcc) structure of PbS (JCPDS 77-0422), and no other phases are present in the patterns. The XRD pattern of Cu2S shown in Fig. 4b is consistent with the standard pattern of hexagonal Cu2S (JCPDS no. 26-1116). For ZnS NCs (shown in Fig. 4c), the three major diffraction peaks confirm the cubic zinc blende structure according to the standard pattern of the bulk ZnS (JCPDS 80-0020). The broadening of the XRD peaks indicates the nature of small size. Similarly, Fig. 4d depicts the XRD patterns of the CdS and CdS:Cu(I) NCs, and their positions and relative diffraction intensities match well with those from the standard patterns of CdS (JCPDS 10-0454), demonstrating that the CdS:Cu(I) NCs possess a zinc blende structure similar to CdS NCs. There is little difference observed in the XRD patterns of CdS and CdS:Cu(I) NCs, indicating the incorporation of Cu(I) ions into CdS lattice has little influence on the crystal structure. Figure 4e depicts the XRD pattern of Ag2S NCs, all the diffraction peaks are consistent with the standard pattern of monoclinic Ag2S (JCPDS card no. 14-0072), which indicates that the as-obtained samples are in pure Ag2S phase. It is well known that the Ag NCs can be obtained in the presence of DDT due to the reducing ability; however, the nucleophilic attack of DDT also contributes to the formation of Ag2S NCs, which was studied comprehensively in our previous work. In the case of this work, pure Ag2S NCs could be obtained by directly heating the Ag(OAc) in the pure DDT without any surfactant at 200 °C. For the CuInS2 NCs shown in Fig. 4f, all the diffraction peaks match well with the wurtzite phase. As a matter of fact, the crystal structure of the ternary CuInS2 NCs could be tuned by varying the In sources and the Cu/In precursor ratios .
Due to the complexity of the valence states of Cu ions, it is worthy to figure out the valence state of Cu ion in CdS:Cu samples. XPS spectra were used to characterize the chemical composition and the valence state of Cu ions in the samples, and Fig. 5 shows the XPS results of CdS:Cu NCs. The survey XPS spectrum of the samples shown in Fig. 5a demonstrates the presence of Cd, S, and Cu components in the as-obtained samples. By analyzing the XPS signal of Cu 2p shown in Fig. 5c, it is found that two peaks are located at 952 eV and 932.4 eV, corresponding to Cu 2p1/2 and Cu 2p3/2 signals, respectively. This result suggests the presence of Cu ion in + 1 state according to previous reports . As the “shake-up” peak is absent between the Cu 2p3/2 and Cu 2p1/2 signals at around 942 eV, the possibility of + 2 state for Cu ion can be ruled out . Therefore, the analysis mentioned above supports that Cu ion exists in + 1 state in CdS:Cu(I) NCs.
TEM technique was employed to ascertain the morphology and size of the as-obtained NCs. Figure 6 shows the TEM images of Cu2S, PbS, CdS, ZnS, Ag2S, CdS:Cu(I), and CuInS2 NCs. As shown in Fig. 6a, b, the as-obtained Cu2S NCs exhibit a spherical shape with a mean diameter of 8.0 nm and the size distribution is less than 7%, and the samples reveal a self-assembly behavior of hexagonal close-packed array. The selected-area electron diffraction (SAED) pattern depicted in the inset of Fig. 6a exhibits polycrystalline diffraction rings that can be indexed to hexagonal Cu2S (JCPDS no. 26-1116), which is in good agreement with the XRD result. Clear lattice fringes visible in the HRTEM image (inset of Fig. 6b) confirm their good crystallinity, and the interplanar spacing of 0.34 nm corresponds to (002) planes of a hexagonal Cu2S phase. Figure 6c, d displays the TEM images of PbS NCs. At first glance, the NCs are hexagonal in shape (shown in Fig. 6c). As a matter of fact, however, they are hexagonal projections of octahedrons with a mean diameter of 93.6 nm. The corresponding SAED pattern depicted in the inset of Fig. 6c demonstrates the nature of single crystals. For a typical HRTEM image of octahedral PbS NCs, we can observe obvious lattice fringes with interplanar spacings of 0.337 and 0.298 nm, which are ascribed to (111) and (200) planes of a fcc PbS phase, respectively. Figure 6e–g are the TEM images of CdS and ZnS NCs, and the samples are quasi-spherical shape with the average size less than 5 nm. The corresponding SAED patterns confirm their cubic zinc blende structure. The TEM image of Ag2S NCs is shown in Fig. 6h, and the NCs are spherical in shape with a mean diameter of about 7 nm. The SAED shown in the inset of Fig. 6h indicates polycrystalline diffraction rings that can be indexed to the monoclinic structure of Ag2S, which is in consistent with the XRD result. Figure 6i depicts the TEM image of CdS:Cu(I) NCs, and the shape is quasi-spherical and the mean size is less than 5 nm, and the SAED shown in the inset can be indexed to pure cubic phase structure. The HRTEM image (in Fig. 6j) of CdS:Cu(I) NCs shows the resolved lattice fringe with the interplanar spacing of 0.335 nm assigned to the (111) plane of cubic structured CdS. The great difference in size and shape of these metal sulfide nanocrystals may arise from the different decomposition rates of metal-thiolate compounds. Figure 6k presents the low-magnified TEM images of ternary CuInS2 NCs, and all the samples exhibit a bullet shape. The corresponding HRTEM image shown in Fig. 6l indicates that the interplanar distance is about 0.32 nm, which accords with the plane distance of (002) in wurtzite CuInS2 phase.
UV-Vis absorption and fluorescence emission spectroscopy has often been employed to study quantum-confinement effect in semiconductor NCs. In addition, the fluorescence emission spectroscopy is also used to probe the defects or surface traps in the NCs. It is reported previously that some defects were introduced into the semiconductor NCs using DDT as sulfur source [30, 31]. Figure 7a shows the photographs of CdS and CdS:Cu(I) NCs before and after 365 nm UV irradiation. It is clearly observed that the colloidal solution of CdS NCs exhibits green emission under UV illumination, and the relative photoluminescence quantum yield (PLQY) is estimated to be about 10%. After doping Cu (I) ions into CdS NCs, the colloidal solution exhibits a relatively strong red emission, which demonstrates that the Cu (I) doping into CdS NCs can effectively tune the optical property of the semiconductor NCs. The UV-Vis absorption spectra of CdS and CdS:Cu(I) NCs are plotted in Fig. 7b. The absorption spectrum of CdS NCs shows a distinct absorption maximum at 364 nm, which is blue-shifted than bulk CdS (the band gap is 2.4 eV). In contrast, the absorption maximum of CdS:Cu(I) NCs shifts to 384 nm, exhibiting a clear red-shift as compared to that of pure CdS NCs. Due to the similar particle size of CdS and CdS:Cu(I) NCs from the TEM results, the red-shift of absorption maximum is not associated with the size of the NCs but is closely related with the doping Cu(I) ions into CdS NCs. The fluorescence emission spectra of CdS and CdS:Cu(I) NCs are given in Fig. 7c. The fluorescence emission spectrum of CdS NCs exhibits a broad band at 548 nm, which is attributed to the trapped surface state’s emission .The trapped surface state’s emission may originate from the localized surface states of the samples, which presumably are formed by the lack of bonding to S2− due to the excess amount of DDT used in our experiment. For the fluorescence emission spectrum of CdS:Cu(I) NCs, a red-emissive maximum of 642 nm is observed, and the relative PLQY is estimated to be about 16%, which can be attributed to Cu (I)-related emission due to the recombination of an excited electron in the conduction band of the CdS NCs and a hole from the d-orbital of Cu ions . The Cu(I) doping level plays an important role in the optical properties of CdS:Cu(I) NCs, and thus different CdS:Cu(I) NCs were synthesized by using different feeding ratios Cd/Cu precursors, such as 7:3, 9:1, and 19:1. The actual percentage of [Cu]/[Cu + Cd] can be estimated to be 12.3%, 6.8%, and 2.8% based on the XPS results shown in Additional file 1: Figure S1, which depicts the survey XPS spectra and Cu 2p signal of the CdS:Cu(I) NCs synthesized in the presence of different amount of Cu precursors. The corresponding absorption and PL spectra are given in Fig. 8a, b, and the absorption maximum shifts to longer wavelength with an increase of Cu(I) doping level (Fig. 8a). Moreover, such a red-shift is also observed in the PL maximum with an increase of Cu doping level from 2.8% to 12.3% (Fig. 8b). It should be noted that the PL emission band at 710 nm becomes dominant for the CdS:Cu(I) synthesized in the presence of Cd/Cu feeding ratio of 7:3, which indicates that the luminescence mainly derives from deep donor-acceptor recombination due to the incorporation of more Cu(I) ions into the CdS core.
In summary, we reported a simple and general one-pot approach to synthesize binary and ternary metal sulfide NCs including Cu2S, PbS, ZnS, CdS, Ag2S, CdS:Cu(I), and CuInS2, in which no pre-synthesis organometallic precursors were required. In this reaction, layered metal-thiolate compounds were formed at the early stage, which effectively acted as the precursors to promote the growth of the NCs. The size and shape of the products could be controlled easily. Importantly, a high red-emissive CdS:Cu(I) was successfully synthesized through this one-pot route, which greatly reduced the operational complexity and offered an alternative method to prepare doped NCs. We believe that this versatile and simple one-pot strategy would open a new methodology for synthesis of other ternary or multinary metal sulfide NCs. More importantly, the different NCs synthesized using this approach exhibited different absorption regions and had distinct photoluminescence properties, making them good candidates for applications in photovoltaic devices and light-emitting devices.
High-resolution transmission electron microscope
- PL QY:
Photoluminescence quantum yield
Transmission electron microscope
X-ray photoelectron spectrometer
Alivisatos AP (1996) Perspectives on the physical chemistry of semiconductor nanocrystals. J Phys Chem 100(31):13226–13239
Talapin DV, Lee JS, Kovalenko MV, Shevchenko EV (2010) Prospects of colloidal nanocrystals for electronic and optoelectronic applications. Chem Rev 110(1):389–458
Chen F, Guan ZY, Tang AW (2018) Nanostructure and device architecture engineering for high-performance quantum-dot light-emitting diodes. J Mater Chem C 6(39):10958–10981
Qian L, Zheng Y, Xue JG, Holloway PH (2011) Stable and efficient quantum-dot light-emitting diodes based on solution-processed multilayer structures. Nat Photon 5(9):543–548
Liu Z, Zhao K, Tang AW, Xie Y, Qian L, Cao W, Yang Y, Chen Y, Teng F (2016) Solution-processed high-efficiency cadmium-free Cu-Zn-In-S-based quantum-dot light-emitting diodes with low turn-on voltage. Org Electron 36:97–102
Chen F, Liu ZY, Guan ZY, Liu ZM, Li X, Deng ZB, Teng F, Tang AW (2018) chloride-passivated mg-doped ZnO nanoparticles for improving performance of cadmium-free, quantum-dot light-emitting diodes. ACS Photonics 5(9):3704–3711
Li YL, Jing LH, Qiao RR, Gao MY (2011) Aqueous synthesis of CdTe nanocrystals: progresses and perspectives. Chem Comm 47:9293–9311
Chen XQ, Liu Y, Ma Q (2018) Recent advances in quantum dot-based electrochemiluminescence sensors. J Mater Chem C 6(5):942–959
Wu P, Yan XP (2013) Doped quantum dots for chemo/biosensing and bioimaging. Chem Soc Rev 42(12):5489–5521
Huynh WU, Dittmer JJ, Alivisatos AP (2002) Hybrid nanorod-polymer solar cells. Science 295:2425–2427
Tang AW, Teng F, Wang Y, Hou YB et al (2008) Investigation on photovoltaic performance based on matchstick-like Cu2S–In2S3 heterostructure nanocrystals and polymer. Nanoscale Res Lett 3(12):502–507
Zhang YN, Gu MF, Li N, Xu YL et al (2018) Realizing solution-processed monolithic PbS QDs/perovskite tandem solar cells with high UV stability. J Mater Chem A 6(48):24693–24701
Yi L, Liu Y, Yang N et al (2013) One dimensional CuInS2–ZnS heterostructured nanomaterials as low-cost and high-performance counter electrodes of dye-sensitized solar cells. Energy Environ Sci 6(3):835–840
Tang AW, Teng F, Hou YB, Wang YS et al (2010) Optical properties and electrical bistability of CdS nanoparticles synthesized in dodecanethiol. Appl Phys Lett 96:163112 1–3
Tang AW, Teng F, Liu J, Wang YC et al (2011) Electrical bistability and charge-transport mechanisms in cuprous sulfide nanosphere-poly(N-vinylcarbazole) composite films. J Nanopar Res 13(12):7263–7269
Li JT, Tang AW, Li X, Wang M, Hu YF, Hou YB, Teng F (2016) Oxygen effects on performance of electrically bistable devices based on hybrid silver sulfide poly(N-vinylcarbazole) nanocomposites. Nanoscale Res Lett 11:63
Liu XL, Ma CC, Yan Y, Yao GX et al (2013) Hydrothermal synthesis of CdSe quantum dots and their photocatalytic activity on degradation of Cefalexin. Ind Eng Chem Res 52(43):15015–15023
Deng H, Li XL, Peng Q, Wang X et al (2005) Monodisperse magnetic single-crystal ferrite microspheres. Angew Chem Int Ed 44(18):2782–2785
Murray CB, Noms DJ, Bawendi MG (1993) Synthesis and characterization of nearly monodisperse CdE (E = sulfur, selenium, tellurium) semiconductor nanocrystallites. J Am Chem Soc 115(19):8706–8715
Parobek D, Dong YT, Qiao T, Son DH (2018) Direct hot-injection synthesis of Mn-doped CsPbBr3 nanocrystals. Chem Mater 30(9):2939–2944
Du YP, Xu B, Fu T, Cai M et al (2010) Near-infrared photoluminescent Ag2S quantum dots from a single source precursor. J Am Chem Soc 132(5):1470–1471
Shen SL, Zhang YJ, Peng L, Du YP, Wang QB (2011) Matchstick-shaped Ag2S–ZnS heteronanostructures preserving both UV/blue and near-infrared photoluminescence. Angew Chem Int Ed 50(31):7115–7118
Tang AW, Qu SC, Li K, Hou YB et al (2010) One-pot synthesis and self-assembly of colloidal copper(I) sulfide nanocrystals. Nanotechnology 21:285602 1–9
Zhuang ZB, Lu XT, Peng Q, Li YD (2011) A facile “dispersion–decomposition” route to metal sulfide nanocrystals. Chem Eur J 17(37):10445–10452
Ye HH, Tang AW, Huang LM, Wang Y et al (2013) Facile one-step synthesis and transformation of cu(I)-doped zinc sulfide nanocrystals to Cu1.94S−ZnS heterostructured nanocrystals. Langmuir 29:8728–8735
Ye HH, Tang AW, Hou YB, Yang CH et al (2014) Tunable near-infrared localized surface plasmon resonances of heterostructured Cu1.94S-ZnS nanocrystals. Opt Mater Express 4(2):220–226
Tang AW, Hu ZL, Yin Z, Ye HH, Yang CH, Teng F (2015) One-pot synthesis of CuInS2 nanocrystals using different anions to engineer their morphology and crystal phase. Dalton Trans 44:9251–9259
Liu ZM, Tang AW, Liu J, Zhu DX et al (2018) Non-injection synthesis of L-shaped wurtzite cu–Ga–Zn–S alloyed nanorods and their advantageous application in photocatalytic hydrogen evolution. J Mater Chem A 6:18649–18659
Meulenberg RW, van Buuren T, Hanif KM et al (2004) Structure and composition of cu-doped CdSe nanocrystals using soft X-ray absorption spectroscopy. Nano Lett 4(11):2277–2285
Yang H, Holloway PH (2004) Efficient and photostable ZnS-passivated CdS:Mn luminescent nanocrystals. Adv Funct Mater 14(2):152–156
Zhong HZ, Zhou Y, Ye MF, Wang X et al (2008) Controlled synthesis and optical properties of colloidal ternary chalcogenide CuInS2 nanocrystals. Chem Mater 20(20):6434–6443
Quan ZW, Wang ZL, Yang PP, Lin J et al (2007) Synthesis and characterization of high-quality ZnS, ZnS:Mn2+, and ZnS:Mn2+/ZnS (core/shell) luminescent nanocrystals. Inorg Chem 46(4):1354–1360
Tang AW, Yi LX, Han W, Teng F et al (2010) Synthesis, optical properties and superlattice structure of Cu(I)-doped CdS nanocrystals. Appl Phys Lett 97:033112 1–3
This work is partly supported by the National Natural Science Foundation of China (No. 61674011), the research project of “333 high-level talents training project” in Jiangsu Province of China (No. BRA2016111), the Science and Technology Program of Changzhou (No. CE20175031), the Jiangsu Province key R & D projects (No. BE2016200). The author (A. W.) appreciates the support from Beijing Natural Science Foundation (No.4172050).
Availability of Data and Materials
All relevant data are within the paper.
The authors declare that they have no competing interests.
Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.
Figure S1. The XPS signals of (a) Full-scan and (b) Cu 2p for CdS:Cu NCs with different Cu doping levels. (DOCX 162 kb)