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Chemical Vapor Deposition of Vertically Aligned Carbon Nanotube Arrays: Critical Effects of Oxide Buffer Layers
Nanoscale Research Letters volume 14, Article number: 106 (2019)
Vertically aligned carbon nanotubes (VACNTs) were synthesized on different oxide buffer layers using chemical vapor deposition (CVD). The growth of the VACNTs was mainly determined by three factors: the Ostwald ripening of catalyst nanoparticles, subsurface diffusion of Fe, and their activation energy for nucleation and initial growth. The surface roughness of buffer layers largely influenced the diameter and density of catalyst nanoparticles after annealing, which apparently affected the lifetime of the nanoparticles and the thickness of the prepared VACNTs. In addition, the growth of the VACNTs was also affected by the deposition temperature, and the lifetime of the catalyst nanoparticles apparently decreased when the deposition temperature was greater than 600 °C due to their serious Ostwald ripening. Furthermore, in addition to the number of catalyst nanoparticles, the density of the VACNTs was also largely dependent on their activation energy for nucleation and initial growth.
Vertically aligned carbon nanotubes (VACNTs) exhibit many excellent properties, including extraordinary mechanical properties, attractive electrical characteristics, and high thermal conductivity [1,2,3]. Therefore, VACNTs show great potential for use in a wide variety of applications, including field emitters of display, biological sensors, microelectronic devices, and hydrogen storage and thermal interface materials [4,5,6,7,8,9,10,11]. Among the existing methods, chemical vapor deposition (CVD) appears to be the most suitable for the growth of VACNTs; it offers better control of the growth parameters and the growth on predefined sites of a patterned substrate [12,13,14,15,16,17]. To achieve high-quality VACNTs by CVD, catalyst nanoparticles should be formed on and prevented from reacting with the underlying substrate . Generally, to avoid undesired metal silicide formation at high process temperatures, a buffer layer is usually deposited onto the substrate prior to deposition of the catalyst [19, 20].
Many researchers have found that the buffer layer is critical to the growth of VACNTs, and different buffer layers show various effects . The effective growth of VACNTs is largely dependent on the type, quality in terms of porosity, and stoichiometry of the buffer layer [22,23,24,25]. Lee et al. reported that metallic buffer layers were ineffective for the growth of VACNTs because they could not prevent diffusion of the catalyst into the substrate, resulting in the formation of carbide or silicide phases . Compared with metallic films, nonmetallic films such as oxide films have been found to be more beneficial for the synthesis of VACNTs. de los Arcos et al. claimed that, compared with Al, Al2O3 resulted in more efficient growth of VACNTs when used as the buffer layer [27, 28]. In addition, compared with SiO2, TiO2, and ZrO2, Al2O3 was found to be a better buffer-layer material for the growth of VACNTs when Fe was used as the catalyst . Although various oxide buffer layers have been introduced to increase the growth efficiency of VACNTs, their detailed role is unclear.
In this paper, we used CVD to synthesize VACNTs with different oxide films as the buffer layers. The activity and lifetime of catalyst nanoparticles were analyzed on different oxide buffer layers to achieve high-quality VACNTs. The possible growth mechanism of VACNTs is also discussed.
Thermally oxidized SiO2 and three types of Al2O3 thin films were used as the oxide buffer layers. The Al2O3 films were deposited onto Si substrates by atomic layer deposition (ALD), electron-beam (EB) evaporation, and sputtering. For ALD Al2O3 films, trimethylaluminum (TMA) and H2O were used as the precursor and oxygen source, respectively. The deposition temperature was set at 200 °C. The thickness of the Al2O3 and SiO2 films used as the buffer layers was 20 nm. A 1-nm-thick Fe film was deposited onto all of them by EB evaporation; it was used as the catalyst. Afterwards, the VACNTs were synthesized by CVD (AIXTRON Black Magic II). First, hydrogen was introduced into the reaction chamber, and the pressure was set at 0.2 mbar. Before the growth of VACNTs, the catalyst was annealed at 550 °C under the hydrogen. The flow rate of hydrogen was set at 700 sccm, and the period was 3 min. Second, acetylene and hydrogen were introduced into the chamber simultaneously, and VACNTs were prepared on catalyst nanoparticles. The flow rates of acetylene and hydrogen were 100 and 700 sccm, respectively. The growth temperature was increased from 500 to 650 °C, and the growth period was fixed at 30 min.
Epoxy resin (412813) was purchased from Sigma-Aldrich Co., Ltd. The curing agent (C1486) and diluent (E0342) were purchased from TCI Chemical Industrial Development Co., Ltd. After the growth of VACNTs, VACNT/epoxy composite films were also prepared. First, epoxy resin, curing agent, and diluents were mixed as the matrix using a high-speed dispersion mixing machine (MIX500D). Second, the VACNTs were immersed into the matrix, which was subsequently cured in a vacuum oven at 120 °C for 1 h and then at 150 °C for 1 h. The obtained composite films were peeled from the Si substrate and polished to a thickness of approximately 300 μm. The tips of VACNTs protruded from both surfaces of the composite film.
Field-emission scanning electron microscopy (FESEM; Merlin Compact) was used to characterize the diameter and distribution of the catalyst nanoparticles as well as the cross section of the VACNTs and composite films. Raman spectra of the VACNTs were recorded with an inVia Reflex spectrometer, and transmission electron microscopy (TEM; Tecnai G2 F20 S-TWIN) was used to characterize the morphology of the carbon nanotubes. The chemical composition and density of different buffer layers were characterized by X-ray photoelectron spectroscopy (XPS; ESCALAB 250Xi) and X-ray reflectivity (XRR; Bruker D8 Discover), respectively. The surface roughness of different buffer layers was analyzed by atomic force microscopy (AFM; SPM9700). Laser flash thermal analysis (Netzsch LFA 447) and differential scanning calorimetry (DSC; Mettler Toledo DSC1) were used to measure the thermal diffusivity and specific heat capacity of the composite films, respectively. The thermal conductivity was subsequently calculated using Eq. 1:
where λ, α, Cp, and ρ are the thermal conductivity (W m−1 K−1), thermal diffusivity (mm2 s−1), specific heat capacity (J kg−1 K−1), and density (kg m−3) of composite films, respectively.
Results and Discussion
Figure 1a–d shows Raman spectra of VACNTs grown on different oxide buffer layers. Generally, the G peak, which is the symmetrical vibration of the optical mode and six-ring plane expansion, was located at approximately 1580 cm−1 . The D peak, which is a vibration mode caused by the edge or defect of the microcrystal plane, was located at approximately 1360 cm−1 . In addition, the G′ peak was typically located at ~ 2700 cm−1 . For different oxide buffer layers, the ratio of ID and IG was calculated to be approximately equal to or greater than 1, and no radial breathing modes (RBMs) were observed at ~ 200 cm−1. These results indicate that all of the prepared VACNTs on different buffer layers were multiwalled. Figure 2a–d shows the morphology of VACNTs on different buffer layers, which were analyzed by TEM. The VACNTs were multiwalled on all of them, consistent with the Raman analysis results. The carbon nanotubes were triple-walled on ALD and EB Al2O3 but quadruple- or quintuple-walled on sputtered Al2O3 and SiO2.
Figure 3a–f shows the cross-sectional SEM images of VACNTs grown on different oxide buffer layers at 600 °C. The VACNTs were successfully synthesized on ALD and EB Al2O3, as shown in Fig. 3a, b, e, and f. The thickness of VACNTs on ALD Al2O3 was smaller than that on EB Al2O3, which can be explained by different lifetimes of catalyst nanoparticles on them during the growth period. The lifetime of catalyst nanoparticles, which represents the time after which the catalyst nanoparticle has basically lost its catalytic function to grow carbon nanotubes, was deduced from the thickness of VACNTs . The results show that the lifetime of catalyst nanoparticles on EB Al2O3 was longer than that on ALD Al2O3, which was largely related to Ostwald ripening of catalyst nanoparticles on the substrates. Ostwald ripening is a phenomenon whereby larger nanoparticles increase in size while smaller nanoparticles, which have greater strain energy, shrink in size, and eventually disappear via atomic interdiffusion . When a catalyst nanoparticle disappeared, or when too much catalyst was lost, the carbon nanotubes growing from it stopped . When enough carbon nanotubes stopped growing, the growth of VACNTs collectively terminated because each terminated carbon nanotube imparted a mechanical drag force on adjacent growing nanotubes because of van der Waals forces and interlocking . Therefore, the lifetime of catalyst nanoparticles was mostly dependent on their rate of Ostwald ripening. Figure 3c shows that almost no VACNTs were present on sputtered Al2O3. As shown in Table 1, the density and chemical composition of sputtered Al2O3 was almost similar to ALD and EB Al2O3, which indicated that the various Al2O3 might have a similar barrier property against Fe. Therefore, the main reason for the unsuccessful growth of VACNTs might not be the subsurface diffusion of Fe, but the serious Ostwald ripening of catalyst nanoparticles on it . As Ostwald ripening proceeds, the number of nanoparticles decreases while the average catalyst diameter increases and the nanoparticle size distribution broadens . Therefore, serious Ostwald ripening of catalyst nanoparticles would directly result in a low density of carbon nanotubes. Generally, any marginal alignment observed in CVD samples was due to a crowding effect, and carbon nanotubes support each other by van der Waals attraction . As a result, VACNTs could not be achieved on sputtered Al2O3. Compared with VACNTs on ALD and EB Al2O3, those on SiO2 were very thin, which might be caused by the subsurface diffusion of Fe, as shown in Fig. 3d .
Figure 4a–d shows SEM images of catalyst nanoparticles on different oxide buffer layers after annealing at 550 °C for 3 min in the absence of C2H2. Compared with others, the nanoparticles had a much larger diameter on sputtered Al2O3 before the growth of VACNTs. Figure 4e shows the number of catalyst nanoparticles on a 200 × 200 nm2 area of different buffer layers. The number of nanoparticles was the most on EB Al2O3, and the least on sputtered Al2O3. The largest diameter and least number of nanoparticles might result in their shortest lifetime on sputtered Al2O3 due to the effect of Ostwald ripening. It also explains why almost no VACNTs grew on sputtered Al2O3 (Fig. 3c). In addition, the mean diameter and size distribution of catalyst nanoparticles were also analyzed, as shown in Fig. 5a–d. Figure 5b shows that the mean diameter of nanoparticles was the smallest on EB Al2O3, which led to the Fe catalyst showing the longest lifetime . The result in Fig. 3b confirms that the thickest VACNTs were grown on EB Al2O3. Figure 5c shows that the mean diameter of nanoparticles was the largest on sputtered Al2O3, which was confirmed by the result in Fig. 4c. Figure 5a, d shows that the mean diameter of nanoparticles on ALD Al2O3 and SiO2 was similar, whereas Fig. 3a, d shows that their thickness was quite different. Fe atoms might more easily diffuse through SiO2 and into the Si substrate than through ALD Al2O3 . The subsurface diffusion of Fe would result in few catalyst nanoparticles existing on the surface of SiO2 during the growth period, which led to the thin VACNTs.
Figure 6a–d shows the surface roughness of different buffer layers before deposition of the catalyst. The surface roughness of EB Al2O3 was the largest; its root-mean-square (RMS) roughness value was 2.53 nm, as shown in Fig. 6b and Table 1. As previously mentioned, the smallest diameter and greatest number of catalyst nanoparticles were achieved on EB Al2O3. The rough surface would result in a small diameter and high density of catalyst nanoparticles after annealing. Figure 6c shows that the surface of sputtered Al2O3, whose RMS value was 0.68 nm, was the smoothest. This result indicates that the largest diameter and lowest density of nanoparticles might also be related to the smooth surface of sputtered Al2O3. From Fig. 6a, d, the RMS value of ALD Al2O3 was larger than that of SiO2. Compared with the nanoparticles on SiO2, those on ALD Al2O3 exhibited a greater density and smaller diameter, as confirmed by the results in Figs. 4e and 5a, d. Therefore, the surface roughness of buffer layers was critical and strongly influenced the growth of VACNTs in the CVD process.
Figure 7 shows the effect of deposition temperature on the growth rate of VACNTs on EB and ALD Al2O3. At temperatures below 600 °C, the growth rate increased with increasing temperature. However, when the temperature was greater than 600 °C, the growth rate apparently decreased. This behavior might be related to serious Ostwald ripening of catalyst nanoparticles, which largely reduced the lifetime of nanoparticles and the growth rate . In addition, Fig. 7 also shows the dependence of the growth rate on 1/T; the activation energy was directly calculated from the slope of the linear fit to the data . The activation energies for the nucleation and initial growth of VACNTs on ALD and EB Al2O3 were 39.1 and 66.5 kJ mol−1, respectively. This result indicates that activation energy for nucleation and initial growth using ALD Al2O3 is much lower than that using EB Al2O3. Therefore, we could conclude that the nucleation and initial growth of VACNTs were more easily achieved on ALD Al2O3, compared with EB Al2O3. From Table 1, we could know that there were some impurities in ALD Al2O3, such as carbon, which might offer the extra sites for the nucleation of VACNTs and then reduce its activation energy.
Figure 8a, b shows the cross-sectional SEM images of the composite films prepared by filling the matrix in VACNTs. The VACNTs and matrix were fully contacted, and the VACNT-based composite films were successfully synthesized. Their longitudinal thermal conductivities were subsequently analyzed, as shown in Fig. 9. Compared with the pure epoxy resin, VACNTs obviously improved the thermal conductivity of the composite films. In addition, the composite film had higher thermal conductivity with the VACNTs grown on ALD Al2O3 compared with that on EB Al2O3. Generally, the thermal conductivity of epoxy resin was much lower than that of multiwall carbon nanotubes, whose experimental thermal conductivity has been reported to be greater than 3000 W m−1 K−1 at room temperature . Each carbon nanotube was a pathway of thermal dissipation in composite films, and a higher thermal conductivity means more pathways of thermal dissipation. The results indicate that a larger quantity of carbon nanotubes and more dense VACNTs could be achieved on ALD Al2O3. Commonly, each catalyst nanoparticle could produce at most one carbon nanotube, and the catalyst nanoparticle count might provide an upper limit prediction of the density of VACNTs [35, 38]. However, not all of the catalyst nanoparticles could achieve the formation of a carbon nanotube because the activation energy must be overcome for its nucleation and initial growth. Although the EB Al2O3 contained a greater number of catalyst nanoparticles than ALD Al2O3, as mentioned in Fig. 4e, the number of carbon nanotubes on EB Al2O3 was still less than that on ALD Al2O3. This result might be explained by a lower activation energy for the nucleation and initial growth of VACNTs on ALD Al2O3, as shown in Fig. 7. Therefore, in addition to the number of catalyst nanoparticles, the density of VACNTs was still largely dependent on the activation energy for their nucleation and initial growth.
In this study, we investigated the growth of VACNTs on different oxide buffer layers and their possible growth mechanism. The lifetime of catalyst nanoparticles and the thickness of prepared VACNTs were largely dependent on the diameter and density of the nanoparticles after annealing. The smallest diameter and highest density of nanoparticles were achieved on EB Al2O3, and the thickest VACNTs were also prepared on this substrate. Conversely, the largest diameter and lowest density of nanoparticles were achieved on sputtered Al2O3, and almost no VACNTs were prepared on it. These observations might be explained by serious Ostwald ripening of catalyst nanoparticles on sputtered Al2O3. Compared with EB and ALD Al2O3, the prepared VACNTs were much thinner on SiO2, which might be related to the subsurface diffusion of Fe. In addition, the surface roughness of buffer layers largely influenced the diameter and density of catalyst nanoparticles. Compared with the surface of sputtered Al2O3, the rough surface of EB Al2O3 favored a small diameter and high density of catalyst nanoparticles.
Furthermore, the growth of VACNTs was largely dependent on the deposition temperature. At a temperature above 600 °C, the growth rate of VACNTs apparently decreased, which might be caused by serious Ostwald ripening of catalyst nanoparticles, reducing their lifetime. Compared with the activation energy on EB Al2O3, that on ALD Al2O3 was much lower, suggesting that the nucleation and initial growth of VACNTs were more easily achieved on it. This lower activation energy might result in more dense VACNTs on ALD Al2O3, which was confirmed by the higher longitudinal thermal conductivity of the composite film including them. Therefore, in addition to the number of catalyst nanoparticles, the activation energy for the nucleation and initial growth of VACNTs still strongly influenced their density.
Atomic force microscopy
Atomic layer deposition
Chemical vapor deposition
Differential scanning calorimeter
Field-emission scanning electron microscopy
Laser flash thermal analyzer
Radial breathing modes
Transmission electron microscopy
Vertically aligned carbon nanotubes
X-ray photoelectron spectroscopy
Lin W, Zhang RW, Moon KS, Wong CP (2010) Synthesis of high-quality vertically aligned carbon nanotubes on bulk copper substrate for thermal management. IEEE T Adv Packag 33:370–376
Yang DJ, Zhang Q, Chen G, Yoon SF, Ahn J, Wang SG, Zhou Q, Wang Q, Li JQ (2002) Thermal conductivity of multi-walled carbon nanotubes. Phys Rev B 66:165440
Tong T, Zhao Y, Delzeit L, Kashani A, Meyyappan M, Majumdar A (2007) Dense vertically aligned multi-walled carbon nanotube arrays as thermal interface materials. IEEE Trans Compon Packag Manuf Technol 30:92–100
Bandaru PR (2007) Electrical properties and applications of carbon nanotube structures. J Nanosci Nanotechnol 7:1239–1267
Modi A, Koratkar N, Lass E, Wei B, Ajayan PM (2003) Miniaturized gas ionization sensors using carbon nanotubes. Nature 34:171–174
Fan SS, Liang WJ, Dang HY, Franklin N, Thomas T, Chapline M, Dai HJ (2000) Carbon nanotube arrays on silicon substrates and their possible application. Phys E 8:179–183
Jung YJ, Kar S, Talapatra S, Soldano C, Viswanathan G, Li XS, Yao ZL, Ou FS, Avadhanula A, Vajtai R, Curran S, Nalamasu O, Ajayan PM (2006) Aligned carbon nanotube−polymer hybrid architectures for diverse flexible electronic applications. Nano Lett 6:413–418
Jonge ND, Lamy Y, Schoots K, Oosterkamp TH (2002) High brightness electron beam from a multi-walled carbon nanotube. Nature 420:393–395
Fennimore AM, Yuzvinsky TD, Han WQ, Fuhrer MS, Cumings J, Zettl A (2003) Rotational actuators based on carbon nanotubes. Nature 424:408–410
Huang WJ, Taylor S, Fu K, Lin Y, Zhang DH, Hanks TW, Rao AM, Sun YP (2002) Attaching proteins to carbon nanotubes via diimide-activated amidation. Nano Lett 2:311–314
Liu C, Fan YY, Liu M, Cong HT, Cheng HM, Dresselhaus MS (1999) Hydrogen storage in single-walled carbon nanotubes at room temperature. Science 286:1127–1129
Ajayan PM, Ebbesen TW, Ichihashi T, Iijima S, Tanigaki K, Hiura H (1993) Opening carbon nanotubes with oxygen and implications for filling. Nature 362:522–525
Penza M, Rossi R, Alvisi M, Serra E (2010) Metal-modified and vertically aligned carbon nanotube sensors array for landfill gas monitoring applications. Nanotechnology 21:105501
Kong J, Cassell AM, Dai H (1998) Chemical vapor deposition of methane for single-walled carbon nanotubes. Chem Phys Lett 292:567–574
Wal RLV, Ticich TM (2001) Comparative flame and furnace synthesis of single-walled carbon nanotubes. Chem Phys Lett 336:24–32
Laplaze D, Bernier P, Maser WK, Flamant G, Guillard T, Loiseau A (1998) Carbon nanotubes: the solar approach. Carbon 36:685–688
De IAT, Garnier MG, Seo JK, Oelhafen P, Thommen V, Mathys D (2004) The influence of catalyst chemical state and morphology on carbon nanotube growth. J Phys Chem B 108:7728–7734
de los Arcos T, Vonau F, Garnier MG, Thommen V, Boyen HG, Oelhafen P (2002) Influence of iron-silicon interaction on the growth of carbon nanotubes produced by chemical vapor deposition. Appl Phys Lett 80:2383
Merkulov VI, Melechko AV, Guillorn MA, Lowndes DH, Simpson ML (2002) Effects of spatial separation on the growth of vertically aligned carbon nanofibers produced by plasma-enhanced chemical vapor deposition. Appl Phys Lett 80:476–478
Teo KBK, Chhowalla M, Amaratunga GAJ, Milne WI, Pirio G, Legagneux P, Wyczisk F, Olivier J, Pribat D (2002) Characterization of plasma-enhanced chemical vapor deposition carbon nanotubes by Auger electron spectroscopy. J Vac Sci Technol B 20:116–121
Lee KM, Han HJ, Choi SH, Park KH, Oh SG, Lee S, Koh KH (2003) Effects of metal buffer layers on the hot filament chemical vapor deposition of nanostructured carbon films. J Vac Sci Technol B 21:623–626
Nagaraju N, Fonseca A, Konya Z, Nagy JB (2002) Alumina and silica supported metal catalysts for the production of carbon nanotubes. J Mol Catal A-Chem 181:57–62
Dadyburjor DB (1988) Catalyst supports and supported catalysts: theoretical and applied concepts. AICHE J 34:174–175
Amama PB, Pint CL, Kim SM, McJilton L, Eyink KG, Stach EA, Hauge RH, Maruyama B (2010) Influence of alumina type on the evolution and activity of alumina-supported Fe catalysts in single-walled carbon nanotube carpet growth. ACS Nano 4:895–904
Quinton BT, Leedy KD, Lawson JW, Tsao B, Scofield JD, Merrett JN, Zhang Q, Yost K, Mukhopadhyay SM (2015) Influence of oxide buffer layers on the growth of carbon nanotube arrays on carbon substrates. Carbon 87:175–185
Delzeit L, Chen B, Cassell A, Stevens R, Nguyen C, Meyyappan M (2001) Multilayered metal catalysts for controlling the density of single-walled carbon nanotube growth. Chem Phys Lett 348:368–374
de los Arcos T, Wu ZM, Oelhafen P (2003) Is aluminum a suitable buffer layer for carbon nanotube growth? Chem Phys Lett 380:419–423
Ohashi T, Kato R, Tokune T, Kawarada H (2013) Understanding the stability of a sputtered Al buffer layer for single-walled carbon nanotube forest synthesis. Carbon 57:401–409
Wal RLV, Ticich TM, Curtis VE (2001) Substrate-support interactions in metal-catalyzed carbon nanofiber growth. Carbon 39:2277–2289
Rao AM, Jorio A, Pimenta MA, Dantas MSS, Saito R, Dresselhaus G, Dresselhaus MS (2000) Polarized Raman study of aligned multiwalled carbon nanotubes. Phys Rev Lett 84:1820–1823
de los Arcos T, Garnier MG, Oelhafen P, Mathys D, Seo JW, Domingo C, Vicente Garcia-Ramos J, Sanchez-Cortes S (2004) Strong influence of buffer layer type on carbon nanotube characteristics. Carbon 42:187–190
Amama PB, Pint CL, McJilton L, Kim SM, Stach EA, Murray PT, Hauge RH, Maruyam B (2009) Role of water in super growth of single-walled carbon nanotube carpets. Nano Lett 9:44–49
Kim SM, Pint CL, Amama PB, Zakharov DN, Hauge RH, Maruyama B, Stach EA (2010) Evolution in catalyst morphology leads to carbon nanotube growth termination. J Phys Chem Lett 1:918–922
Meyyappan M, Delzeit L, Cassell A, Hash D (2003) Carbon nanotube growth by PECVD: a review. Plasma Sources Sci Technol 12:205–216
Amama PB, Pint CL, Mirri F, Pasquali M, Hauge RH, Maruyama B (2012) Catalyst-support interactions and their influence in water-assisted carbon nanotube carpet growth. Carbon 50:2396–2406
Hofmann S, Ducati C, Robertson J (2003) Low-temperature growth of carbon nanotubes by plasma-enhanced chemical vapor deposition. Appl Phys Lett 83:135–137
Wang M, Chen HY, Lin W, Li Z, Li Q, Chen MH, Meng FH, Xing YJ, Yao YG, Wong CP, Li QW (2014) Crack-free and scalable transfer of carbon nanotube arrays into flexible and highly thermal conductive composite film. ACS Appl Mater Inter 6:539–544
Sinnott SB, Andrews R, Qian D, Rao AM, Mao Z, Dickey EC, Derbyshire F (1999) Model of carbon nanotube growth through chemical vapor deposition. Chem Phys Lett 315:25–30
The authors thank Dr. Yong Zhang from the School of Automation and Mechanical Engineering, Shanghai University, for the useful discussions.
This work was financially supported by the National Natural Science Foundation of China (Nos. 61704102 and 51861135105).
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Li, H., Yuan, G., Shan, B. et al. Chemical Vapor Deposition of Vertically Aligned Carbon Nanotube Arrays: Critical Effects of Oxide Buffer Layers. Nanoscale Res Lett 14, 106 (2019). https://doi.org/10.1186/s11671-019-2938-6
- Atomic layer deposition
- Chemical vapor deposition
- Vertically aligned carbon nanotubes
- Oxide buffer layers