Abstract
This work reports on a novel controlled nanocomposite fabrication technique which is applicable for material design via a micro- and nano-assembly method. The principle is based on the use of electrostatic adsorption of the surface charge-modified particles via layer-by-layer assembly. The polarity and the zeta potential of the surface charge was controlled using polycation and polyanion, while the zeta potential strength was controlled via the number of alternating coating layers which was determined using zeta potential measurement. A systematic study was conducted to demonstrate the feasibility of composite material assembly via electrostatic adsorption using alumina (Al2O3) and silica (SiO2) composite as a study model, which was carried out as a function of surface zeta potential, surface coverage percentage, and processing time. The considerable potential of this technique for composite material design is also further demonstrated with controlled assembly involving different materials in various structural forms such as fiber, whisker, nanosheets, and even irregular-shaped foam-like structured urethane. The composite materials designed using this EA method possess good potentials to be utilized for various applications such as mechanical property control, composite ceramic films formation, selective laser sintering, and rechargeable metal-air battery.
Introduction
In the nanoscale-focused society nowadays, nano-architecture design and fabrication have never been more crucial and have seen rapid development in recent years. Bottom-up assemblies such as self-assembled monolayers and a layer-by-layer (LbL) assembly technique utilizing electronic adsorption have attracted significant interest from researchers [1,2,3]. This has led to a new concept known as nano-architectonics where an integration of hybrid polymer and inorganic nano-architecture is used for nanoscale morphological design [4]. Since the discovery by Decher et al., most of the reported work involved the formation of one or multiple layer of films (coatings) on the surfaces and focusing on surface molecular engineering [5, 6], conjugate polymers, bio-components, graphene, and fullerene [7]. LbL method has opened up significant potential for the development of advanced materials that require precise design such as core-shells for drug delivery and photonic crystals as well as selective functional molecules [8, 9]. However, controlled assembly of micro- and nanoparticles using an electrostatic adsorption technique is rarely reported [10]. Mo et al. demonstrated the assembly of ZnO nanorod-based hollow hemisphere assembly using hydrothermal thermolysis of Zn precursor in the presence of 2 g long chain polymer with a large side group, poly(sodium 4-styrenesulfonate) (PSS) [11]. They mentioned that the presence of a water-soluble long chain with a large side group is crucial for the formation of the unique assembled structure that consists of hollow hemispheres. The long chain is said to promote clustering of secondary colloidal particles that would lead to subsequent space-limited crystallization and dissolution. Using the similar concept, it is also demonstrated to be possible to fabricate three-dimensional polymer shells using cores that consisted of soluble colloidal template by Decher [12, 13] and Caruso et al. [14]. Their works have laid the foundation toward more material design using the EA method. It is also reported that the size and density of a material’s nanostructures applied during bio-engineering could specifically induce the desired biological properties [15, 16]. Visalakshan et al. have reported on a versatile and scalable controlled formation of covalently bonded Au particles on a plasma-deposited polymethlyoxazoline interlayer with a well-defined nano-topography that could be applied to biomaterial engineering-related technologies [15]. In another work reported by Li et al., they have demonstrated the feasibility to obtain bifunctional microspheres that consisted of Fe2O3 (core) and SiO2 (shell) with Au nanoparticles adsorbed on the surface through interaction with polyethyleneimine via LbL method. The bifunctional hybrid composite exhibited excellent catalytic performance in organic and inorganic reduction while possessing superparamagnetic property that enabled efficient separation using magnetic field [17]. The abovementioned works have further emphasized the importance of micro- and nano-assembly toward the generation of desired properties for various advanced functional applications. Looking forward toward large scale fabrication, Hueckel and Sacanna reported on a mix-and-melt reaction method that enables rapid mass production of anisotropic core-shell colloids using electrostatic self-assembly [18]. In the LbL method, despite the possible application of uncharged particles/colloids, the charged ones still remain the commonly used method through the assembly of multilayer polyelectrolyte [19]. Other than polyelectrolyte utilization, the zeta potential can also be controlled using pH adjustment depending on the material used in the composite formation [20, 21]. The sequential application of oppositely charged polyelectrolyte could increase the surface charge strength as well as stability of the polyelectrolyte coatings which can be determined using zeta potential measurement [13, 22]. When the zeta potential of a surface-charge modified particle is equivalent or more than +/− 40 mV, it is reported to be sufficient to obtain a good stable electrostatic interaction to avoid agglomeration and remain in colloidal form [21, 23]. Despite the advancement and development of the LbL method, its utilization for materials and composites design are rarely reported despite its huge potential. Therefore, in this work, we not only demonstrated a facile and more superior method to obtain a homogeneous materials mixture using the EA method but have also realized the feasibility of composite material design that crosses the boundaries between materials and shape. The potential of EA method was further expanded by demonstrating the feasibility of this method for decoration of desired additives onto irregular-structured materials such as urethane foam, sheet-like boron nitride (BN), and rod-like structured materials. As for conventional mixing methods such as mechanical milling, it is often the case where the structure of the precursor is either degenerated or altered due to volatile impact and heat generation. Moreover, agglomeration of the mixture also occurs which would then affect the final properties of the composite materials [21, 24, 25]. To overcome this issue, a method for precise nanoscale design of materials is indispensable to boost toward advanced precision manufacturing. Figure 1 is a schematic that shows the comparison of the microstructures that could be obtained via a conventional mechanical milling method with the aggregation occurrence compared to a novel homogenous decoration of composite materials via the EA method. A well-distributed microstructure could be obtained using the homogenously decorated composite materials to generate the desired properties from a functional composite material. In a recent reported work, a homogeneous decoration of indium tin oxide (ITO) nanoparticles on the surface of poly(methyl methacrylate) (PMMA) was demonstrated using the EA method. The ITO-PMMA composite powders obtained were then used to fabricate a pellet with good transparency in the visible-light region and a controllable IR light-shielding effect [21]. Therefore, a clear overview of the EA method for micro- and nano-assembly is vital to emphasize the feasibility and potential of this technique for material design. The fundamental principle for this novel work is illustrated in Fig. 2 where the control of surface charge is carried out using polyelectrolytes (polycation and polyanion) in order to enable homogenous decoration of desired additive particles on the primary/mother particle. By utilizing the attractive force, nanocomposites with significant homogeneity could be achieved regardless of structural complexity. The preservation of the primary and secondary nanostructures such as nanofibers and nanorods could be achieved compared to the conventional mechanical milling method which would destroy their original morphological structure. In terms of fabrication cost, the EA method is also a more cost-effective method. Freymann et al. also emphasized that the EA method is an excellent bottom-up assembly method for photonic crystals fabrication as opposed to the extremely expensive top-down approaches [8]. The demonstrated feasibility of the nano-architectural composite design demonstrated in this novel work could be a useful platform for various applications due to its cost-competitiveness and simplicity. Room temperature formation and the superior homogeneity of this method hold significant advantage for precise powder-based fabrication technology such as aerosol deposition [25], ceramic 3D printing technology, and additive manufacturing laser sintering[26, 27]. The applicability of this EA method toward useful practical applications is also demonstrated in our recently reported work for IR light shielding [21], mechanical property control of carbon-based alumina composite [24], and rechargeable Fe-air battery [20].
Experimental Procedures
Formation of Al2O3-SiO2 Composite Particles
The experiments were carried out using commercially available monodispersed spherical SiO2 particles (average particle diameter 8.8 μm, Ube EXSYMO) and alumina (Al2O3) particles (average particle size 100 nm, Taimei Chemical Co., Ltd.). The polycation and polyanion used were polydiallyldimethylammonium chloride (PDDA) (average molecular weight 100,000 to 200,000, Sigma-Aldrich) and polysodium styrenesulfonate (PSS) (average molecular weight 70,000, Sigma-Aldrich), respectively. The primary SiO2 particles were immersed into the polyelectrolytes in the order of PDDA, PSS, PDDA, and PSS to induce a negative surface charge. As for the Al2O3 particles, the surface charge was prepared by immersion in PSS and PDDA in order to obtain a positive surface charge. The surface zeta potential was controlled by repetitive multiple-layer coating by LbL process [12, 13, 28]. Finally, the suspension of SiO2 and Al2O3 particles with the opposite zeta potential were mixed together. The pH of the solution prepared was within the vicinity of 7–8 (neutral). When PDDA or PSS was added into an aqueous solution, the pH of the solution changed to approximately 5.5 and 6.8, respectively. After the addition of PDDA and PSS, the solutions were then washed and rinsed several times (up to four times) to remove the excessive PDDA and PSS from the solution. After washing and rinsing, the pH returned to an original pH of approximately 7–8. Although the suspension obtained was stable for several days, they were used for the electrostatic assembly a few hours upon preparation. Smaller electrostatically charged particles (secondary) were attracted toward and attached onto the larger particles (primary) forming the nano/micro-composite particles. The schematic of the overall fabrication process of the Al2O3-SiO2 composite particles is shown in Fig. 3. The Al2O3 and SiO2 composite particles were mixed and stirred for up to 180 min to allow complete adsorption. In the investigation of coverage control, the amount of particle adsorption was adjusted by changing the mixing ratio of the precursors using the formula below:
Wa is the added particle amount (g), C is the coverage ratio of the secondary particles on the primary particles (C = Sa/Sm; Sa is the cross-sectional area [m2] of the additive particles while Sm is the surface area of the primary particles [m2]), Vais the volume of one additive particle [m3], ρa is the density of additive particles [g/m3], Wm is the amount of the primary particles [g], ρm is the density of the primary particles [g/m3], and Vm is the volume of one primary particle [m3]. In this study, the amount of additive particles was adjusted to 25, 50, and 75% surface coverages of a constant amount of primary SiO2 particles. The coverage estimation of the Al2O3-SiO2 composite obtained was also calculated from the SEM images and tabulated in Table 1. In a different study on the effect of deposition time during the reaction process, the duration for Al2O3 and SiO2 composite particle formation was investigated at intervals of 5, 15, and 60 min with a constant coverage of 25%.
Formation of SiO2-SiO2 Composite Particles with Size Control
In this investigation, in order to demonstrate the feasibility of designing a composite that consists of the same material but of different sizes, SiO2 with particle sizes of 1, 4, and 16 μm (Ube EXYMO) were used. As for the primary 16-μm SiO2 particles, an LbL coating of PDDA/PSS/PDDA/PSS was carried out while as for the secondary smaller 1- and 4-μm SiO2 particles, LbL coating of PDDA/PSS/PDDA was performed. The suspensions were then mixed and stirred accordingly.
Formation of Various Composite Combination Using EA Method
In order to further demonstrate the feasibility and flexibility of this novel method in composite design involving various materials and shapes, materials such as Al2O3, polymethyl methacrylate (PMMA), carbon nanotube (CNT), boron nitride (BN), carbon fiber, and silicon carbide (SiC) in the structural form of fiber, whisker, nanosheet, and an irregular foam-like structure were used to form the composites via the EA method. Depending on the material, the surface charge modification differs. For Al2O3 and SiO2 that possess positive and negative surface charge, respectively, PSS and PDDA were used to induce the opposite charge until the zeta potential is higher than +/− 40 mV prior to electrostatic assembly. For materials that exhibit low or negligible zeta potential such as PMMA, carbon microspheres, CNT, BN, carbon fiber, SiC, and urethane, an initial layer of surfactant, sodium deoxycholate (SDC), was used to coat and induce a negative surface charge on the surface followed by PDDA. Multiple alternating layers of PDDA and PSS were adjusted until the zeta potential is higher than +/− 40 mV prior to mixing to allow electrostatic assembly. For example, in order to obtain composite that consist of carbon-microsphere-Al2O3, the surface of primary particle Al2O3 was surface-charged modified using PSS to induce a negative surface charge. As for the secondary carbon microspheres, an initial coating of SDC was carried out and followed by PDDA in order to generate a positive zeta surface potential. If the zeta potential is less than + 40 mV, alternating coating of PSS/PDDA is carried out to obtain a higher and more stable surface potential for the electrostatic assembly. Then, the surface-charged modified Al2O3 and carbon microsphere aqueous solution were mixed and stirred in order to promote the electrostatic adsorption process. A similar approach was applied to PMMA, CNT, BN, carbon fiber, SiC, and urethane prior to electrostatic assembly process.
Method, Morphological Observation, and Measurement
An ultrasonic homogenizer (QSonica, LLC., Q 700) was used to disperse the agglomerated particles in a solution. A freeze dryer (FDU-1200, Tokyo Science Instrument Co., Ltd.) was used for drying the composite particle suspension obtained. The morphologies obtained after EA were observed using an S-4800 Field Emission Scanning Electron Microscope (FE-SEM, Hitachi S-4800). The zeta potential was measured using measurement equipment from Otsuka Electronics Co. Ltd., ELSZ-1 and Micro Tech Nission, ZEECOM Co. Ltd.
Results and Discussion
Figure 4 shows the SEM images of the obtained Al2O3-SiO2 composite particles with the different coverages of 25, 50, and 75%, respectively. It can be clearly observed that the Al2O3 nanoparticles are distributed homogenously across the surface of the SiO2 particle. From the SEM images, the amount of Al2O3 particles adsorbed onto the surface of the SiO2 particles was calculated and is summarized in Table 1. From the results obtained, the values of estimated coverage measured are approximate to the intended target coverages of 25, 50, and 75%. This result shows that by using this novel EA method, the coverage could be controlled by adjusting the amount of additive particles while maintaining a very good homogenous coverage where the secondary Al2O3 particles are distributed evenly on the surface of primary SiO2 particle without any sign of agglomeration or concentrated patches. In the separate study of reaction time during the mixing and stirring, the SEM images of the composite particles (25% coverage) obtained after 5, 15, and 60 min are shown in Fig. 5. The amount of additive particles deposited on the primary SiO2 particle was observed to increase with time. It is noteworthy that even at a short mixing and stirring time of 5 min, the additive particles are seen to be distributed evenly on the surface of SiO2 particles (not agglomerated). With prolonged mixing and stirring times of 15 and 60 min, the amount of deposited Al2O3 increased accordingly. Upon 60 min, the amount of Al2O3 particles obtained on SiO2 is similar to that obtained in the abovementioned 25% distribution coverage. This shows that the particle deposition of the EA method is dependent on the reaction time (mixing and stirring). The overall time dependence behavior of Al2O3 adsorption on SiO2 for different coverage ratios as well as the zeta potential measured are summarized in Fig. 6. From Fig. 6a, in order to obtain coverage of 25%, the time required to achieve a deposition plateau is 60 min while those with higher surface coverage required a prolonged time up to 180 min. The deposition delay is caused by the increase of Al2O3 particle suspension leading to the increased Al2O3 adsorption on SiO2 that subsequently resulted in the occurrence of a steric hindrance effect [5, 29]. From Fig. 6b, it can be seen that the apparent zeta potential of Al2O3-SiO2 composite gradually shifted from negative to positive with increasing additive Al2O3 particle coverage. As the amount of positively charged Al2O3 particles adsorbed onto SiO2 increased, the positive zeta potential of the surface also increased which generated a shielding effect preventing the subsequent Al2O3 to be adsorbed onto SiO2 and causes the deposition delay. The homogenous distribution of positively charged Al2O3 particles across the surface of SiO2 at almost the same distance between each Al2O3 particle resulted in the generation of the steric effect that is thought to be equivalent to that of the negatively charged SiO2 particle. Hence, this results in the achievement of iso-electric point. In the work reported by Xu et al., they have reported an almost similar observation where, by controlling the charge density of polyelectrolyte, the membrane film roughness and distance variation from the substrate as well as the importance of steric restrictions to the ion to ion spacing in polyelectrolyte pairing were shown [30].
In the demonstration of composite particles formation that consist of the same material but of different sizes, it is also important to adjust the surface zeta potential by adjusting the number of alternating polyelectrolyte coatings. Additional file 1: Figure S1 shows the gradual increase of zeta potential with the number of alternating PDDA and PSS coatings. The zeta potential increased one fold from approximately − 30 to − 60 mV after four layers of coating. The SEM images of the SiO2 composite particles are shown in Fig. 7, which show an excellent distribution of sub-micro SiO2 particles on a 16-μm SiO2 particle. In Fig. 7a, sub-microsized SiO2 particles of approximately 1 μm are seen homogenously distributed across the surface of a 16 μm SiO2 particle while in Fig. 7b, larger SiO2 microparticles of approximately 4 μm are seen to be well distributed in a similar fashion. This shows that by adjusting the strength of the surface charge, larger additive particles could be also utilized for the fabrication of composite materials via the EA method. To further demonstrate the feasibility and applicability of this novel method, various materials such as Al2O3, PMMA, CNT, BN, carbon fiber, SiC, and urethane involving various forms such as fiber as well as whisker and irregular-structured foam were used for the formation of composite. The morphologies of the composites obtained are shown in Fig. 8 indicating homogenous decoration of desired additive particles onto various primary particles and frameworks via the EA method. In Fig. 8a–c, the decoration of different structures such as carbon microspheres, high aspect ratio CNT, and BN nanosheets on different materials that consist of Al2O3, PMMA, and SiO2 microsphere are shown respectively. On the other hand, the homogenous decoration of SiO2 and Al2O3 nanoparticles on non-spherical and irregular structures was demonstrated on carbon fiber, SiC whisker, and urethane foam, as shown in Fig. 8d–f respectively. Therefore, this unique work has demonstrated a novel technique of controlled micro- and nano-assembly that has a huge potential for material design covering various materials as well as morphological dimensions which could offer influential impact toward the development and design of composite materials for precision manufacturing technologies. The limitations of EA method are prerequisite aqueous preparation of material that has a density higher than water (1 g/cm3), the difficulty in large scale production, and the requirement of multiple times cleansing in order to remove the excess polyelectrolytes from the solution. However, from this project, an advanced large-scale precursors’ surface charge-modifying system has been developed for a scale-up production of advanced material nano-assembly using a customized equipment with real-time monitoring. This equipment enables the control and alteration of surface charge zeta potential (positive/negative) of a large volume aqueous solution (approximately 10 l) containing the designated starting precursor materials. After achieving the desired zeta potential, the surface-charged modified starting materials are mixed to promote the subsequent electrostatic adsorption to generate the desired composite material.
Using the EA method reported in this work, various composite materials have been fabricated and reported by our group for applications such as controlled mechanical properties of alumina-based carbon composite [24], rapid room temperature formation of composite ceramic films by aerosol deposition [25], controlled IR light-shielding property of PMMA-ITO polymer composite [21], and rechargeable Fe-air battery [20]. In a recent work involving the fabrication of PMMA polymer matrix composite with ITO nanoparticles, PMMA-ITO composite pellet that demonstrated a good transparency in the visible light region while allowing the control of IR light-shielding effect by controlling the amount of ITO nanoparticle incorporation has been reported [21]. Therefore, besides inorganic materials, this shows that the electrostatic assembly method can be applied for polymeric materials as well.
Conclusions
The feasibility to control the additive particle’s coverage on a primary particle in a composite fabrication is demonstrated in this novel work. The fundamental experimental work was carried out by decoration of Al2O3 nanoparticles on SiO2 microparticles as a function of surface coverage and reaction time. Control decoration with surface coverages of 25, 50, and 75% were also demonstrated by adjusting the amount of additive and EA time. Toward the advancement of nanoscale material design, we have also demonstrated the feasibility to achieve micro- and nano-assembly of particle composites on a wide range of materials with various morphological structures at room temperature using an EA method. A superior homogeneity with controllable surface coverage is also demonstrated in this novel work. The possible applications of the fabricated composite materials using the EA method are selective laser sintering, aerosol deposition of composite ceramic films, IR-shielding materials, and rechargeable metal-air battery. The systematic findings of this work could lay a platform for nanoscale material design toward more sophisticated nanofabrication in the future.
Availability of Data and Materials
All data generated or analyzed during this study are included in this published article [and its supplementary information files].
Abbreviations
- BN:
-
Boron nitride
- CNT:
-
Carbon nanotube
- EA:
-
Electrostatic adsorption
- PDDA:
-
Polydiallyldimethylammonium chloride
- PMMA:
-
Polymethyl methacrylate
- PSS:
-
Polysodium styrenesulfonate
- SEM:
-
Scanning electron microscope
- SiC:
-
Silicon carbide
References
Ariga K, Lee MV, Mori T, Yu XY, Hill JP (2010) Two-dimensional nanoarchitectonics based on self-assembly. Adv Colloid Interface Sci 154(1-2):20–29
Tang Q, Wu J, Li Q, Lin J (2008) High conducting multilayer films from poly(sodium styrenesulfonate) and graphite nanoplatelets by layer-by-layer self-assembly. Polymer 49(24):5329–5335
Wen L-L, Shen Q (2018) Fabrication, characterization and application of layered graphene oxide films via layer-by-layer electric-assembly. Mater Chem Phys 213:455–460
Fenoy GE, Van der Schueren B, Scotto J, Boulmedais F, Ceolín MR, Bégin-Colin S, Bégin D, Marmisollé WA, Azzaroni O (2018) Layer-by-layer assembly of iron oxide-decorated few-layer graphene/PANI:PSS composite films for high performance supercapacitors operating in neutral aqueous electrolytes. Electrochimica Acta 283:1178–1187
Zhang X, Chen H, Zhang H (2007) Layer-by-layer assembly: from conventional to unconventional methods. Chem Commun (Camb) 14:1395–1405
Wu C, Aslan S, Gand A, Wolenski JS, Pauthe E, Van Tassel PR (2013) Porous nanofilm biomaterials via templated layer-by-layer assembly. Adv Funct Mater 23(1):66–74
Ariga K, Nakanishi T, Hill JP (2007) Self-assembled microstructures of functional molecules. Curr Opin Colloid Interface Sci 12(3):106–120
von Freymann G, Kitaev V, Lotsch BV, Ozin GA (2013) Bottom-up assembly of photonic crystals. Chem Soc Rev 42(7):2528–2554
Ariga K, Lvov YM, Kawakami K, Ji Q, Hill JP (2011) Layer-by-layer self-assembled shells for drug delivery. Adv Drug Deliv Rev 63(9):762–771
Chen K, Pei X, Tang L, Cheng H, Li Z, Li C, Zhang X, An L (2018) A five-component entropy-stabilized fluorite oxide. Journal of the European Ceramic Society 38(11):4161–4164
Mo M, Yu JC, Zhang L, Li SKA (2005) Self-assembly of ZnO nanorods and nanosheets into hollow microhemispheres and microspheres. Advanced Materials 17(6):756–760
Decher G (1997) Fuzzy nanoassemblies: toward layered polymeric multicomposites. Science 277(5330):1232–1237
Decher G, Hong JD, Schmitt J (1992) Buildup of ultrathin multilayer films by a self-assembly process: III. Consecutively alternating adsorption of anionic and cationic polyelectrolytes on charged surfaces. Thin Solid Films 210-211:831–835
Caruso F, Lichtenfeld H, Giersig M, Möhwald H (1998) Electrostatic self-assembly of silica nanoparticle−polyelectrolyte multilayers on polystyrene latex particles. J Am Chem Soc 120(33):8523–8524
Visalakshan RM, MacGregor MN, Cavallaro AA, Sasidharan S, Bachhuka A, Mierczynska-Vasilev AM, Hayball JD, Vasilev K (2018) Creating nano-engineered biomaterials with well-defined surface descriptors. ACS Appl Nano Mater 1(6):2796–2807
Angelatos AS, Katagiri K, Caruso F (2006) Bioinspired colloidal systems vialayer-by-layer assembly. Soft Matter 2(1):18–23
Li H, Gao S, Zheng Z, Cao R (2011) Bifunctional composite prepared using layer-by-layer assembly of polyelectrolyte–gold nanoparticle films on Fe3O4–silica core–shell microspheres. Cat Sci Technol 1:7
Hueckel T, Sacanna S (2018) Mix-and-melt colloidal engineering. ACS Nano 12(4):3533–3540
Delcea M, Mohwald H, Skirtach AG (2011) Stimuli-responsive LbL capsules and nanoshells for drug delivery. Adv Drug Deliv Rev 63(9):730–747
Tan WK, Asami K, Maeda Y, Hayashi K, Kawamura G, Muto H, Matsuda A (2019) Facile formation of Fe3O4-particles decorated carbon paper and its application for all-solid-state rechargeable Fe-air battery. Appl Surf Sci 486:257–264
Tan WK, Yokoi A, Kawamura G, Matsuda A, Muto H (2019) PMMA-ITO composite formation via electrostatic assembly method for infra-red filtering. Nanomaterials 9(6)
Lvov Y, Ariga K, Ichinose I, Kunitake T (1995) Assembly of multicomponent protein films by means of electrostatic layer-by-layer adsorption. J Am Chem Soc 117(22):6117–6123
Peng CQ, Thio YS, Gerhardt RA (2008) Conductive paper fabricated by layer-by-layer assembly of polyelectrolytes and ITO nanoparticles. Nanotechnology 19(50):505603
Tan WK, Hakiri N, Yokoi A, Kawamura G, Matsuda A, Muto H (2019) Controlled microstructure and mechanical properties of Al2O3-based nanocarbon composites fabricated by electrostatic assembly method. Nanoscale Res Lett 14:245
Tan WK, Shigeta Y, Yokoi A, Kawamura G, Matsuda A, Muto H (2019) Investigation of the anchor layer formation on different substrates and its feasibility for optical properties control by aerosol deposition. Appl Surf Sci 483:212–218
Xing Wei AY, Muto H (2018) Nano/microcomposite particles: preparation processes and applications. In: Makio Naito TY, Hosokawa K, Nogi K (eds) Nanoparticle Technology Handbook. Joe Hayton, Amsterdam, pp 781–785
Kuwana T, Tan WK, Yokoi A, Kawamura G, Matsuda A, Muto H (2019) Design of cellulose nanofiber-Al2O3 composite particle for selective laser sintering. J Jpn Soc Powder Powder Metall 66(4):168–173
Lvov Y, Decher G, Moehwald H (1993) Assembly, structural characterization, and thermal behavior of layer-by-layer deposited ultrathin films of poly(vinyl sulfate) and poly(allylamine). Langmuir 9(2):481–486
Guzmán E, Ritacco HA, Ortega F, Rubio RG (2012) Growth of polyelectrolyte layers formed by poly(4-styrenesulfonate sodium salt) and two different polycations: new insights from study of adsorption kinetics. J Phys Chem C 116(29):15474–15483
Xu L, Ankner JF, Sukhishvili SA (2011) Steric effects in ionic pairing and polyelectrolyte interdiffusion within multilayered films: a neutron reflectometry study. Macromolecules 44(16):6518–6524
Acknowledgements
Prof. Hiroyuki Muto and Dr. Wai Kian Tan would like to acknowledge Cross Ministerial Strategic Innovation Promotion Program (SIP) for funding of this research work.
Funding
Cross Ministerial Strategic Innovation Promotion Program (SIP), Japan Society for the Promotion of Science (JSPS) Grant-in-Aid for Scientific Research JP18H01706, JSPS KAKENHI Early-Career Scientist JP18K14013 and Toyohashi University of Technology Research Support Fund.
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HM and WKT designed the study and contributed to the manuscript writing. YA conducted the experimental work. AY, GK, and AM provided technical and scientific insight and contributed to the editing of the manuscript. All authors read and approved the final manuscript.
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Figure S1. The zeta potential increased with number of alternating PDDA and PSS coatings. (DOCX 36 kb)
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Tan, W.K., Araki, Y., Yokoi, A. et al. Micro- and Nano-assembly of Composite Particles by Electrostatic Adsorption. Nanoscale Res Lett 14, 297 (2019). https://doi.org/10.1186/s11671-019-3129-1
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DOI: https://doi.org/10.1186/s11671-019-3129-1