Fabrication of a Highly Sensitive Chemical Sensor Based on ZnO Nanorod Arrays

We report a novel method for fabricating a highly sensitive chemical sensor based on a ZnO nanorod array that is epitaxially grown on a Pt-coated Si substrate, with a top–top electrode configuration. To practically test the device, its O2 and NO2 sensing properties were investigated. The gas sensing properties of this type of device suggest that the approach is promising for the fabrication of sensitive and reliable nanorod chemical sensors.

the results, ZnO nanorods show an n-type semiconducting behavior and their electrical transport is strongly dependent on the adsorption and/or desorption nature of chemical species [9][10][11][12][13]. Despite significant achievements in the realization of chemical sensors based on single ZnO nanorods [14][15][16][17], there still remain many aspects that should be overcome before their actual application. Firstly, the fabrication of sensors based on individual nanorods involves a careful lithography process in which each fabrication step is expensive and tedious. Secondly, a precise system that can measure currents in the region of 10 -9 A is necessary to detect the small current changes that occur in a single nanorod during the adsorption/desorption of chemical species. Finally, the slightly different sizes of each nanorod and the different natures of the electrical contacts in each sensor cause poor reproducibility.
In order to overcome the disadvantages of single nanorod chemical sensors, recently the use of vertically aligned nanorod arrays (NRAs) in chemical sensors has been attempted [18][19][20]. In these works, metal electrodes were simply deposited on top of nanorod arrays using sputtering [18,20] or aerosol spray pyrolysis [19]. However, this approach is likely to result in not distinctive but gradient interfaces between nanorods and metal electrodes, possibly deteriorating sensor efficiency. Therefore, an approach for fabricating chemical sensors based on ZnO nanorod arrays (NRAs) using more reliable electrode configurations needs to be developed.
In this work, we report a novel approach to fabricating chemical sensors based on ZnO NRAs with a top-top electrode configuration. The approach used a coating and etching process with a photoresist (PR). The results show that the proposed ZnO NRA-based chemical sensor exhibits a comparable sensitivity, a higher reproducibility and can be made in a simpler way, suggesting that the proposed approach is promising for fabricating chemical sensors based on ZnO NRAs.
ZnO NRAs were synthesized on Pt-coated Si (001) substrates using a horizontal-type metal organic chemical vapor deposition (MOCVD) system without using any metal catalyst. Pt films of *120 nm in thickness were deposited on Si (001) substrates by a sputtering method. Before the Pt deposition, a Ti interlayer of *5 nm in thickness was deposited on the bare Si substrates using the same sputtering method. This was done in order to enhance the adhesion of the Pt films to the Si substrates. According to the high-resolution X-ray diffraction (XRD) results (which are not presented here), the resultant 120-nm-thick Pt films possessed a (111) preferred orientation normal to the substrate plane, while showing a random alignment in the in-plane direction. ZnO NRAs were grown at 500°C for 30 min using O 2 and diethylzinc as precursors with argon as a carrier gas. The pressure in the reactor was kept at 5 torr. The flow rates of the oxygen and diethylzinc were fixed to result in an O/Zn precursor ratio of 68. The microstructures and crystalline quality of the synthesized ZnO NRAs were investigated using field-emission scanning electron microscopy (SEM) and high-resolution transmission electron microscopy (TEM). The growth behavior, alignment nature, substrate dependency, size and shape control, fabrication of the field-effect transistors, and the temperature-dependent electrical transport of the single ZnO nanorods used in this study have been reported in detail in our previous works [21][22][23][24]. Figure 1 displays the schematic (left) and real (right) images in sequence on fabrication of chemical sensors in this study using the synthesized ZnO NRAs. The images of an as-synthesized ZnO NRA on a Pt-coated Si (001) substrate are shown in Fig. 1a. For the device fabrication, the NRA was synthesized partly on the substrate using a mask. Positive photoresist (PR) was spread on the surface of the ZnO NRA by a spin coater. As seen in Fig. 1b, a uniform and smooth PR layer was formed. The space between individual ZnO nanorods was completely filled with PR. Next, a small portion of the PR layer was removed by etching with inductively coupled plasma in oxygen atmosphere. This consequently resulted in exposure of the tipends of ZnO nanorods (see Fig. 1c). Then, using a mask of 2 mm 9 3 mm in area, Ni (*500 nm in thickness) and Au (*50 nm) were sequentially deposited on the exposed tipends by thermal evaporation, as shown in Fig. 1d. Finally, the PR filled into the space between nanorods as well as remained on the substrate was removed by dipping into acetone. Then the sample was dried into a vacuum oven at 100°C. Note that the well-defined interface between the nanorods and the electrode layer was formed, as shown in the right part of Fig. 1d. The inset figure shows a bird-view of the electrode part. It shows a continuous, well-defined electrode layer.
As a practical test for ZnO NRA chemical sensor, the sensing properties for O 2 and NO 2 were investigated. The fabricated NRA chemical sensor was introduced into a vacuum chamber equipped with a system that can measure current and voltage by changing O 2 and NO 2 environments using N 2 as a carrier gas. HP 4140B pA Meter/DC voltage source was used as the measurement tool, which was interfaced with a personal computer through a general purpose interface bus (GPIB) card. The chamber pressure was controlled using a gate valve and verified using an ion gauge. The sensor assembly was heated to the desired temperature by using a halogen lamp, and temperature was monitored through a thermocouple. In this study, the sensing measurement was performed at 573 K. The base pressure of the vacuum chamber, which was connected to a turbomolecular pump, was typically *5 9 10 -6 torr. Using mass flow controllers, O 2 and NO 2 environments were monitored.
As shown in a field-emission SEM image displayed in Fig. 1, vertically well-aligned ZnO nanorods grew over the Pt/Ti/Si (001) substrate. The nanorods are uniform in diameter and length. It is clear that a continuous ZnO interfacial layer exists. Our previous work on the early growth stages of ZnO nanoneedles on sapphire (0001) revealed that a continuous ZnO layer coherently strained to the substrate grows first [25]. On top of the existing continuous layer, aligned nanoneedles start to form as the growth proceeds further. A similar growth behavior appears to occur during the growth of the ZnO NRAs on Pt-coated Si substrates. The Ni/Au double layer that is deposited on the tip-ends of the ZnO nanorods shows a well-defined interface and the formation of a continuous layer. To further investigate the microstructure of the ZnO NRAs, TEM studies were carried out. Figure 2a is a bright-field TEM image taken at the interfacial area between the ZnO NRAs and the substrate. The presence of the ZnO layer is more evident in this image. Figure 2b is a selected area electron diffraction pattern of the ZnO nanorods. This shows their alignment with the (0001) planes parallel to the substrate surface. Highresolution TEM lattice images of the interfacial layer and ZnO nanorods are shown in Fig. 2c, d, respectively. These images show perfect lattice arrays without any considerable dislocations or stacking faults, meaning that the interfacial ZnO layer is of an epitaxial quality and that the individual ZnO nanorods are actually defect-free single crystals.
To practically test the NRA chemical sensor with the top-top electrode configuration, its sensing properties under O 2 and NO 2 environments were investigated.
where r is the electrical conductance, E A is the activation energy for atomic diffusion around the grain boundary, A is the pre-exponential factor, K is the gas constant, and T is the temperature in Kelvin. The inset of Fig. 3a shows the plot of log r versus log P O 2 . The slope was -1/2.85, indicating that m = -0.35. In case of p-type conduction, m is positive. On the other hand, it is negative for n-type conduction. Therefore, n-type conduction is operating in the ZnO NRA at the various O 2 pressures. The value of m relies on the dominating defects related to the sensing mechanism.
The dynamic testing of a sensing device provides useful information about the sensitivity, the response and recovery times, and the reproducibility. Note that as described before, the dynamic testing was performed in the vacuum chamber. Pumping away oxygen or NO 2 has been performed when ''gas off'' is indicated in Figs. 3, 4, and 5. Figure 3b shows typical response curves of a ZnO NRA chemical sensor to oxygen gas. When the sensor is exposed to oxygen gas, the resistance sharply increases. When the oxygen supply is stopped, the resistance quickly drops to a low value. In order to mention the response and recovery times more clearly, we have to wait for sufficient time and the steady state resistance in oxygen and without oxygen, i.e., saturated state. The resistance curves in Fig. 3b show no saturation. However, the amounts of the resistance change until the initiation of ''gas off'' were over 90% compared with the saturated values. Thus, although the data show no saturation, it is possible to mention the response and recovery times because they are usually defined as the time required to reach 90% of the final equilibrium value of the sensor signals. Based on this, the response and recovery times were 120-180 and 100-120 s, respectively, depending on the O 2 concentration. It should be noted that the sensor responses were very stable and reproducible for the repeated test cycles. The superior stability and reproducibility come from the fact that the sensing response is the average value from an enormous number of individual nanorods, unlike the sensing response for a single nanorod chemical sensor. For the NRA chemical sensor fabricated with the top-top electrode configuration, considering the total area of the two top electrodes is 12 mm 2 , the diameters of the nanorods are *100 nm, and the gaps between them are *100 nm, then *4 9 10 8 nanorods participate in the sensing process. Figure 4a shows the change in resistance as a function of time with different O 2 concentrations ranging from 1.4 to 500 ppm. Six cycles were successively recorded. As shown, the device recovery was reproducible for all O 2 concentrations. The gas sensitivity (S) was estimated using the relationship, S = ((R -R 0 )/R 0 ), where R 0 is the initial resistance in the absence of O 2 gas and R is the resistance measured in the presence of O 2 gas. Figure 4b shows the sensitivities extracted from Fig. 4a as a function of O 2 concentration. The sensitivity at an O 2 concentration of 1.4 ppm is 0.15, which is similar to the values previously reported for oxygen sensors based on single ZnO nanorods [27]. A linear relationship is obtained between sensitivity and O 2 concentration in the O 2 concentration range, as shown in Fig. 4b. The sensitivity of a semiconducting oxide is usually depicted as S = A[C] N ? B, where A and B are constants and [C] is the concentration of the target gas or vapor [28]. In the present study, the data fitting results in S = 0.0059 [C] ? 0.323 for the NRA chemical sensor. R 2 in the figure represents the quality of the curve fit. Figure 4c shows the dependence of resistance by Fig. 4  In addition to the O 2 sensing properties of the NRA sensor, its NO 2 sensing properties were investigated. Figure 5a shows the sensing cycles of the NRA sensor measured at 1-5 ppm NO 2 . As shown, the sensor well responds to the introduction and removal of NO 2 as low as 1 ppm. The sensitivity of the sensor to NO 2 is summarized in Fig. 5b. The linear slope gives the equation of S = 0.018 [C] ? 0.047. The inset of Fig. 5b displays the response and recovery times of the NRA sensor to NO 2 gas of various concentrations. The response time is about 50 s and shows no considerable difference depending on NO 2 concentration. In contrast, the recovery time prolongs from about 55 to 200 s with increasing NO 2 concentration from 1 to 5 ppm. The prolonged recovery time with higher gas concentrations is often observed [29][30][31].
In case of n-type semiconductors like ZnO, oxidizing gas such as O 2 or NO 2 mainly act as an electron accepter in the surface reactions, and the width of electron depletion layers is widened, leading to an increased resistance of the sensors. O 2 or NO 2 molecules adsorbed on the surface of ZnO layers take electrons from them, eventually leading to surface depletion in ZnO. Conversely, the release of electrons occurs in desorption of O 2 or NO 2 . This charge transfer accounts for the resistance change observed in the NRA sensor. The sensing results in this study demonstrate that the approach proposed in this study is promising for the fabrication of highly sensitive chemical sensors.
In summary, we have described a novel approach to chemical sensors based on aligned ZnO NRAs grown on Pt-coated Si substrates with a top-top electrode configuration. The O 2 and NO 2 sensing properties of the fabricated sensor showed both a high sensitivity and an excellent reproducibility during the repeated test cycles. The results show that the device proposed in this study is promising for use as a highly sensitive, reliable chemical sensor.