Investigation of electrical and magnetic properties of ferro-nanofluid on transformers

This study investigated a simple model of transformers that have liquid magnetic cores with different concentrations of ferro-nanofluids. The simple model was built on a capillary by enamel-insulated wires and with ferro-nanofluid loaded in the capillary. The ferro-nanofluid was fabricated by a chemical co-precipitation method. The performances of the transformers with either air core or ferro-nanofluid at different concentrations of nanoparticles of 0.25, 0.5, 0.75, and 1 M were measured and simulated at frequencies ranging from 100 kHz to 100 MHz. The experimental results indicated that the inductance and coupling coefficient of coils grew with the increment of the ferro-nanofluid concentration. The presence of ferro-nanofluid increased resistance, yielding to the decrement of the quality factor, owing to the phase lag between the external magnetic field and the magnetization of the material.


Introduction
In coming decades, new generations of electronic products such as mobile phones, notebooks, and e-paper will be developed with the primary goals of mobilization and miniaturization. New CMOS fabrication technology will be applied to fabricate the miniaturized IC of electronic products on silicon substrates, including on-chip micro-transformers. Several issues of on-chip microtransformers have been investigated for many years . Some researches focused on the material of the magnetic core [1][2][3][4][5][6][7][8][9][10] and the geometry of the transformer [11][12][13][14]. Some papers discussed the parasitic effect of the conductive substrates. Transformer losses become dramatic at high frequencies and limit the performance of the transformers. Previous studies have discussed in detail the causes of transformer losses such as parasitic capacitance, ohmic loss, and substrate loss [15][16][17][18]. Core loss from the solid magnetic core significantly affected the performance of the transformers. The solutions for the solid magnetic core loss were proposed [19][20][21].
Consequently, only a few studies addressed transformers with liquid magnetic cores. The liquid magnetic core, ferro-nanofluid, with its distinguishing features of low electric conductivity and super-paramagnetism is regarded as a solution to the core losses of eddy current and hysteresis. In this study, a ferro-nanofluid was applied as a liquid magnetic core in a transformer. The performance of the transformer with the ferronanofluids was measured, simulated, and compared with that of a transformer with an air core.

Experiment
The ingredients of ferro-nanofluid used in this study were Fe 3 O 4 nanoparticles, oleic acid, and diesel oil. The oilbased Fe 3 O 4 nanofluid was synthesized by co-precipitation, surface modification, nanoparticles dispersing, and basefluid phase changing [10].
The shape and size of the Fe 3 O 4 nanoparticles was examined by a transmission electron microscope (TEM). Figure 1 shows the TEM photo of the Fe 3 O 4 nanoparticles. The average diameter of the nanoparticles was approximately 10 nm. The crystalline phases of Fe 3 O 4 nanoparticles were determined by X-ray diffraction, as shown in Figure 2. The magnetic properties of Fe 3 O 4 nanofluid were measured by a vibrating sample magnetometer (VSM). The magnetized curve of the Fe 3 O 4 nanofluid measured by a VSM is shown in Figure 3. The measured results illustrate that the synthesized ferro-nanofluids have the characteristic of super-paramagnetism. The saturated magnetizations of 0.25, 0.5, 0.75, and 1 M Fe 3 O 4 nanofluids were 3.75, 8.85, 12.7, and 16.7 emu/g, respectively.
A liquid magnetic core of a transformer was used in this study; the capillary served as a container in which the Fe 3 O 4 nanofluid was loaded. The coils of the transformer were made by winding enamel-insulated wires on a capillary. Figure 4 shows the transformer on a capillary, which loads the oil-based Fe 3 O 4 nanofluid. The diameter of the enamel-insulated wire used was 0.45 mm, and the thickness of the enamel layer was approximately 0.05 mm. The primary and secondary windings had 20 turns. The outer and inner diameters of the capillary were 3.2 and 2.3 mm, respectively, and the capacity of the capillary was 100 μL.

Results and discussion
Different magnetic cores, air, and Fe 3 O 4 nanofluids of 0.25, 0.5, 0.75, and 1 M were applied as the magnetic core of transformers. The inductance (L), coupling coefficient (K), resistance (R), and quality factor (Q) were measured by an Agilent 4294A Precision Impedance Analyzer. In this study, the simulation of the transformer was also established with HFSS 3D Full-wave Electromagnetic Field Simulation. By applying measured permeability, permittivity, and magnetic tangent loss and setting exciting sources, the impedances will be calculated by the finite element method. Both the frequencies of measurement and simulation range from 100 kHz to 100 MHz. Figure 5 shows the inductances of the coils of the transformers with different magnetic cores. Figure 5 illustrates that the inductance grows linearly with the increase of Fe 3 O 4 concentration. At frequencies ranging from 100 kHz to 15 MHz, the inductances decrease rapidly due to the skin effect of coils. At frequencies ranging from 15 to 100 MHz, the inductances increase gradually and approach the maximum inductance at the    resonance frequency. Figure 6 shows the measured and simulated results of the coupling coefficients of the transformers with different magnetic cores. The coupling coefficients also increase with the increase of Fe 3 O 4 concentration. It increases rapidly below frequencies of 5 MHz and increases gradually with frequencies over 5 MHz. These results show that the magnetic cores of nanofluids can improve the inductance and coupling coefficients. Figure 7 shows that the resistance increases with the increase of Fe 3 O 4 concentration, and it increases as a function of frequency. At 100 MHz, the resistances with the magnetic core of 0.25 and 1 M Fe 3 O 4 nanofluids were two and five times the resistance as the air core. It is speculated that this is because of the phase lag on the material magnetization behind the external magnetic field at high frequencies. When the relaxation times cannot keep up the alternate time of the magnetic field, the resistance of the coils will grow rapidly [10,22]. At high frequencies, the permeability should be regarded as a complex number. Rearranging complex permeability and the inductance of a solenoid-type inductor, the impedance equation is obtained as follows: where ω is the angular frequency, N is the turns of coil, A is the cross-sectional area of solenoid, and l is the length of solenoid, μ" is the real part of complex permeability, and μ" is the imaginary part of complex permeability. It can be observed that the imaginary part of complex permeability μ" reflects on the real part of impedance, which is the cause of increasing resistance. Then, the quality factor Q, which is defined as the ratio of inductance to resistance, becomes [10]: (2) Figure 8 shows the quality factor of coils of transformers with different magnetic cores. Owing to the fact that the increase of resistance is larger and faster than that of inductance with the presence of Fe 3 O 4 nanofluids, the quality factor decreases when the Fe 3 O 4 concentration rises. The simulated results show the same trend.

Conclusions
In this study, different concentrations of ferro-nanofluids were applied to the magnetic cores of transformers. The performance of transformers with magnetic cores of air  Due to phase lag on the material magnetization behind the external magnetic field at high frequencies, the resistance increased larger and faster than inductance, thus yielding a lower quality factor. For a micro-transformer, if a solid magnetic core is needed for higher inductance, it could be achieved by adding ferro-nanofluid and removing the base fluid repeatedly. This method has a lower thermal budget than the processes that sputtered or electroplated materials on chips. It is compatible with the MEMS process.