Pool boiling of water-Al2O3 and water-Cu nanofluids on horizontal smooth tubes
© Cieslinski and Kaczmarczyk; licensee Springer. 2011
Received: 31 October 2010
Accepted: 15 March 2011
Published: 15 March 2011
Experimental investigation of heat transfer during pool boiling of two nanofluids, i.e., water-Al2O3 and water-Cu has been carried out. Nanoparticles were tested at the concentration of 0.01%, 0.1%, and 1% by weight. The horizontal smooth copper and stainless steel tubes having 10 mm OD and 0.6 mm wall thickness formed test heater. The experiments have been performed to establish the influence of nanofluids concentration as well as tube surface material on heat transfer characteristics at atmospheric pressure. The results indicate that independent of concentration nanoparticle material (Al2O3 and Cu) has almost no influence on heat transfer coefficient while boiling of water-Al2O3 or water-Cu nanofluids on smooth copper tube. It seems that heater material did not affect the boiling heat transfer in 0.1 wt.% water-Cu nanofluid, nevertheless independent of concentration, distinctly higher heat transfer coefficient was recorded for stainless steel tube than for copper tube for the same heat flux density.
Recent advances in nanotechnology have allowed development of a new category of liquids termed nanofluids, which was first used by a group in Argonne National Laboratory USA  to describe liquid suspensions containing nanoparticles with thermal conductivities, orders of magnitudes higher than the base liquids, and with sizes significantly smaller than 100 nm. The augment of thermal conductivity could provide a basis for an enormous innovation for heat transfer intensification, which is pertinent to a number of industrial sectors including transportation, power generation, micro-manufacturing, chemical and metallurgical industries, as well as heating, cooling, ventilation, and air-conditioning industry. Literature findings regarding pool boiling of nanofluids can be summarized as follows.
Li et al.  studied boiling of water-CuO nanofluids of different concentrations (0.05% and 0.2% by weight) on copper plate. They observed deterioration of heat transfer as compared to the base fluid and attributed this fact to the sedimentation of nanoparticles which leads to the changing of radius of cavity, contact angle, and superheat layer thickness.
You et al.  reported that independent of the concentration of the nanoparticles (0.001 to 0.05 g/l) nucleate boiling heat transfer coefficients for water-Al2O3 nanofluid while boiling on plate appeared to be the same as for base fluid. They also found that the size of bubbles increased with addition of nanoparticles to water.
Das et al.  conducted an investigation on the pool boiling of water-Al2O3 nanofluids on a horizontal tubular heater having a diameter of 20 mm with different surface roughness at atmospheric pressure. It was found that the boiling heat transfer of nanoparticle-suspensions was deteriorated compared to that of pure water. Compared with pure water, surface roughness of the heating surface could also greatly affect the nucleation superheat. The subsidence of nanoparticles was considered as the main reason for the increase of the superheat.
Vassallo et al.  carried out an experiment of water-SiO2 nanofluids boiling on a horizontal NiCr wire at atmospheric pressure. No appreciable differences in the boiling heat transfer were found for the heat flux less than the CHF.
Bang and Chang  conducted an experimental investigation on the pool boiling of water-Al2O3 nanofluids on a plain plate at atmospheric pressure. The concentration of nanoparticles was 0.5%, 1%, 2%, and 4% by volume. It was found that the boiling curves were shifted right - towards higher wall superheats. The deterioration became worse as nanoparticle concentration increased and was related to the change of the heating surface characteristics by the deposition of nanoparticles on the heating surface.
Wen and Ding  studied boiling of water-Al2O3 nanofluids on a stainless steel disc with 150 mm in diameter at atmospheric pressure. Contrary to the Bang and Chang's work , heat transfer enhancement has been recorded. Possible explanation of this controversy is lower concentration of nanoparticles used (0.32%).
Shi et al.  carried out experiments with boiling of water-Al2O3 nanofluid and Fe-water nanofluid on horizontal, copper plate with 60 mm in diameter. The concentration of nanoparticles was 0.1%, 1%, and 2% by volume. Generally, the augmentation and deterioration of heat transfer was observed for water-Fe and water-Al2O3 nanofluids, respectively.
Nguyen et al.  investigated boiling of water-Al2O3 nanofluid on chrome-plated, very smooth face of copper block of a 100 mm diameter. The concentration of nanoparticles was 0.5%, 1%, and 2% by volume. In general, it was observed that for a given wall superheat, the heat flux considerably decreased with the increase of the particle concentration. Furthermore, for sufficiently high wall superheat, the heat flux tended to become nearly constant.
Coursey and Kim J.  showed that even if the Al2O3 nanoparticle concentration was increased by over two orders of magnitude, no enhancement or degradation of heat transfer was observed during boiling of ethanol-based nanofluids on glass or gold surface. It was attributed to the highly wetting nature of ethanol. For ethanol-Al2O3 nanofluids and copper surfaces, the nucleate boiling was improved with increasing nanoparticle concentration.
Liu and Liao  examined nanofluids, i.e., mixture of base fluid (water and alcohol), the nanoparticles (CuO and SiO2) and the surfactant (SDBS), and nanoparticles-suspensions consisted of the base liquid and nanoparticles during pool boiling on the face of copper bar having 20 mm diameter. The boiling characteristics of the nanofluids and nanoparticles- suspensions are poorer compared with that of the base fluids.
Narayan et al.  studied influence of tube orientation on pool boiling heat transfer of water-Al2O3 nanofluids from a smooth tube of diameter 33 mm inclined at 0°, 45°, and 90°. They found that horizontal orientation gave maximum heat transfer and the boiling performance deteriorated with increase in nanoparticle concentration (0.25%, 1%, and 2% by weight).
Lotfi and Shafii  performed transient quenching experiments with silver sphere 10 mm diameter immersed in water-Ag and water-TiO2 nanofluids. It was established that the quenching process was more rapid in pure water than in nanofluids and the cooling time was inversely proportional to the nanoparticle mass concentration (0.5%, 1%, 2%, and 4% - Al2O3 and 0.125%, 0.255, 0.5%, and 1% - TiO2).
Trisaksri and Wongwises  tested R141b-TiO2 nanofluids while boiling on horizontal copper cylinder 28.5 mm diameter. They discovered that adding a small amount of nanoparticles did not affect the boiling heat transfer, but addition of TiO2 nanoparticles at 0.03% and 0.05% by volume deteriorated the boiling heat transfer. Moreover, the boiling heat transfer coefficient decreased with increasing particle volume concentrations, especially at higher heat flux.
Kathiravan et al.  investigated boiling of water-Cu and water-Cu-SDS (9 wt.%) nanofluids on a 300 mm square stainless steel plate. They revealed that copper nanoparticles caused a decrease in boiling heat transfer coefficient for water as base liquid. The heat transfer coefficient decreased with increase of the concentration of nanoparticles (0.25%, 0.5%, and 1% by weight) for both water-Cu and water-Cu-SDS nanofluids.
Suriyawong and Wongwises  studied boiling of water-TiO2 nanofluids on horizontal circular plates made from copper and aluminium with different roughness (0.2 and 4 μm). The concentration of nanoparticles was very low: 0.00005%, 0.0001%, 0.0005%, 0.005%, and 0.01% by volume. For copper plate with nanofluid's concentrations more than 0.0001%, the heat transfer coefficient was found to be less than that of the base fluid at both levels of surface roughness. On the other hand, for aluminium surfaces the heat transfer coefficient was found to be less than that of base fluid at every level of nanofluids concentration and surface roughness.
Ahmed and Hamed  performed experiments with boiling of water-Al2O3 on a face of copper block of 25.4 mm diameter. Nanofluids at 0.01%, 0.1%, and 0.5% by volume concentrations were prepared at a neutral pH of 6.5 and an acidic pH of 5. Ultrasonic vibration and electrostatic stabilization were used to prepare nanofluids. It was found that concentration increase either reduced or had no effect on heat transfer coefficient. Enhancement of heat transfer coefficient was achieved only at low nanofluid concentration (0.01%) and the nanofluid at a pH of 6.5.
Recently, Kwark et al.  pointed out the transient characteristics of water-Al2O3 nanofluid boiling on horizontal copper plate. The longer a heater is subjected to nanofluid boiling process, the thicker the nanoparticle coating generated on its surface. The thickness of this nanoparticle coating can then dictate boiling heat transfer coefficient.
The currently available experimental data on boiling heat transfer of nanofluids are still limited. Additionally, conflicting results as far as effect of nanoparticles on the pool boiling heat transfer performance have been reported [19, 20]. As suggested in , further detailed investigations are necessary to understand the phenomena of boiling of nanofluids. In particular experiments are lacking on the effects of nanoparticles material and heating surface material on boiling heat transfer from horizontal smooth tubes. As a consequence, the main aim of the present study was to obtain boiling characteristics, i.e., boiling curves and heat transfer coefficients for water-Al2O3 and water-Cu nanofluids of different concentrations for copper and stainless steel tubes.
where U and I are cartridge heater voltage drop and current, respectively, D o /D i is the outside to inside diameter ratio, L is an active length of a tube, λ is a thermal conductivity of a tube material (copper or stainless steel) and t i was calculated as the arithmetic mean of 12 measured inside wall temperatures. The liquid level was maintained at ca. 15 mm above the centerline of the test tube at saturated state.
Preparation and characterization of the tested nanofluids
Dispersants were not used to stabilize the suspension. Ultrasonic vibration was used for 4-5 h in order to stabilize the dispersion of the nanoparticles. Nanoparticles were tested at the concentration of 0.01%, 0.1%, and 1% by weight.
In a typical experiment, before the test begins, a vacuum pump was used to evacuate the accumulated air from the vessel. Nanofluid at a preset concentration was charged and then preheated to the saturated temperature by auxiliary heater. Next, the cartridge heater was switched on. Measurement was first performed at the lowest power input. Data were collected by increasing the heat flux by small increments. Experiments were performed at atmospheric pressure. Each data point was taken at steady state, the condition of steady state being defined as a variation in the thermocouple outputs of less than 0.001 mV during the 3 min. It generally took about 15 min to achieve steady conditions after the power level was changed.
In order to ensure consistent surface state after each test, the boiling surface was prepared in the same manner, i.e., the stainless steel tube was finished with emery paper 400 and copper tube was polished with abrasive compound, next the test tube was placed in an ultrasonic cleaner for 1 h. Finally, the boiling surface was cleaned by water jet.
Where the absolute measurement errors of the electrical power ΔPmax, outside tube diameter ΔDo and active length of a tube ΔL are 10 W, 0.02 mm, and 0.2 mm, respectively. So, the maximum overall experimental limits of error for heat flux density extended from ± 1.3% for maximum heat flux density up to ± 1.2% for minimum heat flux density.
where the absolute measurement error of the wall superheat, δT, estimated from the systematic error analysis equals ± 0.2 K. The maximum error for average heat transfer coefficient was estimated to ± 2.3%.
Investigation of nucleate saturated pool boiling heat transfer on the outside of smooth horizontal tubes submerged in water-Al2O3 and water-Cu nanofluids has been carried out. The measurements were performed at atmospheric pressure and nanoparticles concentration of 0.01%, 0.1%, and 1% by weight.
Comparison of present results with literature data
Effect of nanoparticle material
Effect of nanofluid concentration
Effect of tube material
Independent of the concentrations tested (0.01%, 0.1%, and 1% by weight) nanoparticle material (Al2O3 and Cu) has almost no influence while boiling of water-Al2O3 or water-Cu nanofluids on smooth copper tube.
Contrary to stainless steel tube experiments, the adding of copper as well as Al2O3 nanoparticles deteriorates pool boiling heat transfer on copper smooth tubes. The higher concentration of nanoparticles was the lower heat transfer coefficient got for the same wall superheat.
Independent of concentration distinctly higher heat transfer coefficient was recorded for stainless steel tube than for copper tube for the same heat flux density. It seems that surface material does not affect the boiling heat transfer in 0.1% water-Cu nanofluid.
A thin solid coating (detected by eye) was observed on copper tubes after tests with water-Al2O3 and water-Cu nanofluids. The higher concentration of the nanoparticles was the thicker coating was recorded at the end of testing.
This work was sponsored by the Ministry of Research and Higher Education, Grant No. N N512 374435.
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